Tert-Butyl hydroperoxide
"TERT-BUTYL HYDROPEROXIDE" at CAMEO Chemicals NOAA tert-BUTYL HYDROPEROXIDE at Chemicalland21 tert-Butyl hydroperoxide at http ... tert-butyl hydroperoxide is potentially dangerous, but explosions are rare. A solution of tert-butyl hydroperoxide and water ... tert-Butyl hydroperoxide (tBuOOH) is the organic compound with the formula (CH3)3COOH. It is one of the most widely used ... Industrially, tert-butyl hydroperoxide is used to prepare propylene oxide. In the Halcon process, molybdenum-based catalysts ...
Baeyer-Villiger oxidation
... tert-butyl hydroperoxide. The peroxides are much less reactive than the peroxyacids. The use of hydrogen peroxide even requires ...
Di-tert-butyl peroxide
tert-Butyl hydroperoxide RajanBabu, T. V.; Simpkins, Nigel S. (2005). "1,1-Di-tert-butyl Peroxide". 1,1-Di-tert-butyl Peroxide ... Di-tert-butyl peroxide or DTBP is an organic compound consisting of a peroxide group bonded to two tert-butyl groups. It is one ... The peroxide bond undergoes homolysis at temperatures above 100 °C. For this reason di-tert-butyl peroxide is commonly used as ... of the most stable organic peroxides, due to the tert-butyl groups being bulky. It is a colorless liquid. ...
Asymmetric catalytic oxidation
tert-Butyl hydroperoxide is the oxidant. This conversion, the Sharpless asymmetric dihydroxylation, was recognized by a Nobel ... doi:10.1016/S0957-4166(00)00352-9. Weix, DJ; Ellman, JA (2005). "(RS)-(+)-2-Methyl-2-Propanesulfinamide [tert-Butanesulfinamide ...
Sharpless epoxidation
The oxidizing agent is tert-butyl hydroperoxide. The method relies on a catalyst formed from titanium tetra(isopropoxide) and ...
Epoxide
Metal-catalyzed epoxidations were first explored using tert-butyl hydroperoxide (TBHP). Association of TBHP with the metal (M) ... Both t-butyl hydroperoxide and ethylbenzene hydroperoxide can be used as oxygen sources. More typically for laboratory ... Indictor N., Brill W. F. (1965). "Metal Acetylacetonate Catalyzed Epoxidation of Olefins with t-Butyl Hydroperoxide". J. Org. ...
Ethylbenzene hydroperoxide
Together with tert-butyl hydroperoxide and cumene hydroperoxide, ethylbenzene hydroperoxide is important commercially. The ...
Jin-Quan Yu
2/C-Mediated Selective Oxidation of Silyl Enol Ethers by tert-Butylhydroperoxide, a Useful Method for the Conversion of Ketones ... Mediated Oxidation of Olefins by tert-Butylhydroperoxide". Organic Letters. 4 (16): 2727-2730. doi:10.1021/ol0262340. ISSN 1523 ...
Protocatechuic acid
"In vivo protective effect of protocatechuic acid on tert-butyl hydroperoxide-induced rat hepatotoxicity". Food and Chemical ...
Tetrabutylammonium
"Tetrabutylammonium Iodide Catalyzed Synthesis of Allylic Ester with tert-Butyl Hydroperoxide as an Oxidant". Organic Letters. ...
Roselle (plant)
"Protective effect of Hibiscus anthocyanins against tert-butyl hydroperoxide-induced hepatic toxicity in rats". Food and ...
Holton Taxol total synthesis
The allylic alcohol was epoxidized to epoxyalcohol 3 using tert-butyl hydroperoxide and titanium(IV)tetraisopropoxide. In the ... Reaction of epoxide 1 with tert-butyllithium removed the acidic α-epoxide proton, leading to an elimination reaction and ... Further treatment of 44 with potassium tert-butoxide furnished α-hydroxyketone 45 through a Lobry-de Bruyn-van Ekenstein ... which was then protected as the tert-butyldimethylsilyl ether 7 in 94% yield over three steps. As shown in Scheme 2, the next ...
Hydroperoxide
Important compounds made in this way include tert-butyl hydroperoxide, cumene hydroperoxide and ethylbenzene hydroperoxide: R-H ... Hydroperoxides are typically more volatile than the corresponding alcohols: tert-BuOOH (b.p. 36 °C) vs tert-BuOH (b.p. 82-83 °C ... In the Halcon process tert-butyl hydroperoxide (TBHP) is employed for the production of propylene oxide. Of specialized ...
Organic peroxides
Examples of organic peroxides tert-Butyl hydroperoxide, a hydroperoxide (formula: ROOH) that is used to epoxide alkenes. ... tert-butylperoxybenzoate, a peroxy ester (formula: RCO3R') that used as a radical initiator. dibenzoyl peroxide, a diacyl ... Peresters, an example being tert-Butyl peroxybenzoate, are produced by treating acid anhydrides or acid chlorides with ...
Isatin
Wei, W.T. (2018). "Synthesis of Indoline-2,3-diones by Radical Coupling of Indolin-2-ones with tert-Butyl Hydroperoxide". ...
W. Clark Still
The first epoxide was introduced via nucleophilic epoxidation of the enone using potassium hydride and tert-butylhydroperoxide ...
Isobutane
... is oxidized to tert-butyl hydroperoxide, which is subsequently reacted with propylene to yield propylene oxide. The ... tert-butanol that results as a by-product is typically used to make gasoline additives such as methyl tert-butyl ether (MTBE). ...
Paeonia anomala
"Protective effect of Paeonia anomala extracts and constituents against tert-butylhydroperoxide-induced oxidative stress in ...
Methyl gallate
"Protective effect of Paeonia anomala extracts and constituents against tert-butylhydroperoxide-induced oxidative stress in ...
Tert-Butyl peroxybenzoate
... tert-butanol, benzoic acid and benzene. A standard procedure for the preparation of peresters is the acylation of tert-butyl ... In the reaction a large excess of tert-butyl hydroperoxide is used and the hydrogen chloride formed is removed in vacuo whereby ... tert-Butyl peroxybenzoate (TBPB) an organic compound with the formula C6H5CO3CMe3 (Me = CH3). It is the most widely produced ... The main decomposition products of tert-butyl peroxybenzoate are carbon dioxide, acetone, methane, ...
Methyl hydroperoxide
... unlike tertiary hydroperoxides such as tert-butylhydroperoxide. Its laboratory preparation was first reported in 1929. Logan, ...
Cucurbitane
"Cucurbitane Triterpenoids from Momordica charantia and Their Cytoprotective Activity in tert-Butyl Hydroperoxide-Induced ...
Cucurbitacin
December 2010). "Cucurbitane triterpenoids from Momordica charantia and their cytoprotective activity in tert-butyl ...
Anthrax
The spray formula is applied to an infested area and is followed by another spray containing tert-butyl hydroperoxide. Using ...
Vanadyl acetylacetonate
It is used in organic chemistry as a catalyst for the epoxidation of allylic alcohols by tert-butyl hydroperoxide (TBHP). The ...
Oligonucleotide synthesis
Oxidation may be carried out under anhydrous conditions using tert-Butyl hydroperoxide or, more efficiently, (1S)-(+)-(10- ...
Peroxide
One example is tert-butylhydroperoxide. Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). ...
Wacker process
Michel, Brian W.; Steffens, Laura D.; Sigman, Matthew S. (June 2011). "On the Mechanism of the Palladium-Catalyzed tert - ... Butylhydroperoxide-Mediated Wacker-Type Oxidation of Alkenes Using Quinoline-2-Oxazoline Ligands". Journal of the American ...
Copper(I) hydroxide
As a catalyst in these reactions, it is used with potassium tert-butoxide and argon with tert-butyl hydroperoxide and ...
Methyl tert-butyl ether
In the Halcon process, t-Butyl hydroperoxide derived from isobutane oxygenation is reacted with propylene to produce propylene ... Di-tert-butyl ether List of gasoline additives tert-Amyl methyl ether (TAME) Record of Methyl tert-butyl ether in the GESTIS ... Methyl tert-butyl ether (MTBE), also known as tert-butyl methyl ether, is an organic compound with a structural formula (CH3) ... MTBE is used in industry as a safer alternative to diethyl ether (which is commonly used in academic research) as the tert- ...
Halcon process
... the Halcon process refers to technology for the production of propylene oxide by oxidation of propylene with tert-butyl hydroperoxide ... The oxidation is thought to proceed by formation of Mo(η2-O2-tert-Bu) complexes. The peroxy O center is rendered highly ... CH2OCHCH3 The byproduct tert-butanol is recycled or converted to other useful compounds. The process once operated at the scale ...