Coordination isomerism
... is a form of structural isomerism in which the composition of the coordination complex ion varies. In a ... Isomerism - This type of isomerism arises from the interchange of ligands between cationic and anionic entities of different ... v t e (Coordination chemistry, Isomerism, All stub articles, Stereochemistry stubs). ...
Linkage isomerism
In chemistry, linkage isomerism or ambidentate isomerism is a form of isomerism in which certain coordination compounds have ... Linkage isomerism was first noted for nitropentaamminecobalt(III) chloride, [Co(NH3)5(NO2)]2+. This cationic cobalt complex can ... The complex cis-dichlorotetrakis(dimethylsulfoxide)ruthenium(II) (RuCl2(dmso)4) exhibits linkage isomerism of dimethyl ...
Ligand isomerism
In coordination chemistry, ligand isomerism is a type of structural isomerism in coordination complexes which arises from the ...
Hydration isomerism
In coordination chemistry, hydration isomerism is a kind of isomerism that is observed in some solids. Hydration isomers have ...
Conformational isomerism
In chemistry, conformational isomerism is a form of stereoisomerism in which the isomers can be interconverted just by ... The dynamics of conformational (and other kinds of) isomerism can be monitored by NMR spectroscopy at varying temperatures. The ... Wikiquote has quotations related to Conformational isomerism. Anomeric effect Backbone-dependent rotamer library Cycloalkane ... More specific examples of conformational isomerism are detailed elsewhere: Ring conformation Cyclohexane conformations, ...
Endo-exo isomerism
In organic chemistry, endo-exo isomerism is a special type of stereoisomerism found in organic compounds with a substituent on ...
Cis-trans isomerism
... , also known as geometric isomerism or configurational isomerism, describes certain arrangement of atoms ... A related type of isomerism in octahedral MX3Y3 complexes is facial-meridional (or fac-mer) isomerism, in which different ... According to IUPAC, "geometric isomerism" is an obsolete synonym of "cis-trans isomerism". In general, cis-trans stereoisomers ... An example of a small hydrocarbon displaying cis-trans isomerism is but-2-ene. 1,2-Dichlorocyclohexane is another example. Cis ...
Stereoisomerism
Conformational isomerism is a form of isomerism that describes the phenomenon of molecules with the same structural formula but ... "Cis-trans isomerism , NAL Agricultural Thesaurus". Clark, Jim (November 2012). "E-Z notation for geometric isomerism". ... In stereochemistry, stereoisomerism, or spatial isomerism, is a form of isomerism in which molecules have the same molecular ... so anomers have carbon atoms that have geometric isomerism and optical isomerism (enantiomerism) on one or more of the carbons ...
Sulfoxylic acid
Fentress, J.; Selwood, P. W. (February 1948). "Thallous Sulfoxylate Isomerism". Journal of the American Chemical Society. 70 (2 ...
Molecular Borromean rings
Wolf, Christian (2008). "Topological Isomerism and Chirality". Dynamic Stereochemistry of Chiral Compounds: Principles and ...
Isoflurane
Calvey TN (August 1995). "Isomerism and anaesthetic drugs". Acta Anaesthesiologica Scandinavica. Supplementum. 106: 83-90. doi: ...
Marcel Delépine
Formules de constitution, isomérie, isomérie optique, 1937 - Organic chemistry; constitutional formulas, isomerism, optical ... isomerism. Un Grand chimiste analyste : Louis-Nicolas Vauquelin, 1941 - The great analytical chemist, Louis-Nicolas Vauquelin. ...
Isomeric shift
Weiner, Richard (1959). "Nuclear Isomerism and Atomic Spectra". JETP. 8 (1): 196. Melissinos, Adrian C.; Davis, Sumner P. (1959 ...
N-Hydroxyphthalimide
The isomerism of the oximes. Part XXXIII. The oximes of opianic acid and of phthalic anhydride". J. Chem. Soc.: 529-539. doi: ...
List of Italian inventions and discoveries
Segrè, E.; Seaborg, G. T. (1938). "Nuclear Isomerism in Element 43". Physical Review. 54 (9): 772. Bibcode:1938PhRv...54..772S ...
Imine
Bjørgo, Johannes; Boyd, Derek R.; Watson, Christopher G.; Jennings, W. Brian; Jerina, Donald M. (1974). "E-Z-isomerism in ...
Norman Sheppard
He had a successful year, resulting in his contributing to a paper on Raman spectra and rotational isomerism. Sheppard returned ... "Spectroscopic Studies of Rotational Isomerism. I. Liquid n‐Butane and the Assignment of the Normal Modes of Vibration". Journal ...
Lithium lactate
The compound demonstrates optical isomerism. Lithium lactate emits acrid smoke when heated to decomposition. Lithium lactate ...
Technetium-99m
Segrè E, Seaborg GT (1 November 1938). "Nuclear Isomerism in Element 43". Physical Review. 54 (9): 772. Bibcode:1938PhRv...54.. ...
Mechanically interlocked molecular architectures
Lukin, Oleg; Godt, Adelheid; Vögtle, Fritz (2004). "Residual Topological Isomerism of Intertwined Molecules". Chemistry: A ... isomerism, modification, catalysis and molecular machines for synthesis" (PDF). Chemical Communications. 50 (40): 5128-42. doi: ... The idea of residual topological isomerism introduces a handy scheme of modifying the molecular graphs and generalizes former ...
Richard M. Weiner
translated in R. M. Weiner (1959). "Nuclear Isomerism and Atomic Spectra" (PDF). Journal of Experimental and Theoretical ...
Transition metal sulfoxide complex
This dichotomy is called linkage isomerism. O-bonded sulfoxide ligands are far more common, especially for 1st row metals. S- ...
Structural isomer
Coordination isomerism Descriptor (chemistry) Stereoisomer Metamerism (disambiguation) "Constitutional isomerism". IUPAC Gold ... Structural isomerism is the most radical type of isomerism. It is opposed to stereoisomerism, in which the atoms and bonding ... ISBN 9781400853410 Jim Clark (2000). "Structural isomerism" in Chemguide, n.l. Poppe, Laszlo; Nagy, Jozsef; Hornyanszky, Gabor ... ISBN 9781349188178 Zdenek Slanina (1986): Contemporary Theory of Chemical Isomerism. 254 pages. ISBN 9789027717078 H. Stephen ...
Isomer
Another type of isomerism based on nuclear properties is spin isomerism, where molecules differ only in the relative spin ... This type of isomerism is called axial isomerism. Enantiomers behave identically in chemical reactions, except when reacted ... Two main forms of isomerism are structural or constitutional isomerism, in which bonds between the atoms differ; and ... More generally, cis-trans isomerism (formerly called "geometric isomerism") occurs in molecules where the relative orientation ...
List of experiments
Otto Hahn discovers nuclear isomerism (1921). Albert Szent-Györgyi and Hans Adolf Krebs discover the citric acid cycle of ...
Isolated congenital asplenia
OMIM entry 208530: Right atrial isomerism; RAI. Johns Hopkins University. [3] Reference, Genetics Home. "Isolated congenital ...
Polymorphism (materials science)
Polymorphism is a form of isomerism. Any crystalline material can exhibit the phenomenon. Allotropy refers to polymorphism for ...
Johannes Wislicenus
He called this difference "geometrical isomerism". He would later promote J. H. van't Hoff's theory of the tetrahedral carbon ...
Electromerism
Bally, T. (2010). "Isomerism: The same but different" (PDF). Nature Chemistry. 2 (3): 165-166. Bibcode:2010NatCh...2..165B. doi ... Electromerism is a type of isomerism between a pair of molecules (electromers, electro-isomers) differing in the way electrons ... One group of electromers are excited electronic states but isomerism is usually limited to ground state molecules. Another ... Jones, L. W. (1917). "Electromerism, A Case of Chemical Isomerism Resulting from a Difference in Distribution of Valence ...
Nadic anhydride
... exhibits endo-exo isomerism. In the exo isomer, the acid anhydride group points in the same direction towards ...