Bulky amide ligands have a lesser tendency to bridge. Amide ligands may participate in metal-ligand π-bonding giving a complex ... The alkali metal amides, MNH2 (M = Li, Na, K) are commercially available. Sodium amide (also known as sodamide) is synthesized ... Metal amides (systematic name metal azanides) are a class of coordination compounds composed of a metal center with amide ... Lithium amides are the most important amides. They are prepared from n-butyllithium and the appropriate amine R2NH + BuLi → ...

... amide ligands and are part of a broader category of metal amides. Due to the bulky hydrocarbon backbone metal bis( ... amide. In line with the general method, bis(trimethylsilyl)amides of transition metals are prepared by a reaction between the ... Cage Complexes of N-Heterocyclic Amide and Bis(trimethylsilyl)amide Ligands: Synthesis, Structure, and Magnetic Properties". ... Metal bis(trimethylsilyl)amides are strong bases. They are corrosive, and are incompatible with many chlorinated solvents. ...

Cyclic amides are called lactams; they are necessarily secondary or tertiary amides. Amides are pervasive in nature and ... In primary and secondary amides, the presence of N-H dipoles allows amides to function as H-bond donors as well. Thus amides ... "amide". The American Heritage Dictionary of the English Language (5th ed.). HarperCollins. "amide - Definition of amide in ... of amides is called the amide group (specifically, carboxamide group). In the usual nomenclature, one adds the term "amide" to ...

The dansyl amide moiety is also called a dansyl group, and it can be introduced into amino acids or other amines in a reaction ... Dansyl amide is a fluorescent dye that forms in a reaction between dansyl chloride and ammonia. It is the simplest ...

... is an inorganic compound with the chemical formula KNH2. Like other alkali metal amides, it is a white solid ... Potassium amide is produced by the reaction of ammonia with potassium. The reaction typically requires a catalyst. ... O. Glemser, H. Sauer (1963). "Silver Amide". In G. Brauer (ed.). Handbook of Preparative Inorganic Chemistry, 2nd Ed. Vol. 1. ... Takaki, Katherine S. (2001). "Potassium Amide". Encyclopedia of Reagents for Organic Synthesis. doi:10.1002/047084289X.rp193. ...

H2 The conjugate bases of amines are known as amides. Thus, a lithium amide may also refer to any compound in the class of the ... Lithium amide or lithium azanide is an inorganic compound with the chemical formula LiNH2. It is a white solid with a ... Sodium amide Butyllithium David, William I. F.; Jones, Martin O.; Gregory, Duncan H.; Jewell, Catherine M.; Johnson, Simon R.; ... The cyclic oligomers form when the nitrogen of the amide forms a sigma bond to a lithium, while the nitrogen lone pair binds to ...

As such, sodium amide is to be stored in a tightly closed container, under an atmosphere of an inert gas. Sodium amide samples ... Sodium amide can be prepared by the reaction of sodium with ammonia gas, but it is usually prepared by the reaction in liquid ... Sodium amide is mainly used as a strong base in organic chemistry, often in liquid ammonia solution. It is the reagent of ... Sodium amide induces the loss of two equivalents of hydrogen bromide from a vicinal dibromoalkane to give a carbon-carbon ...

... in such structures a 9-atom amide ring occurs between the amide side chain of the pentapeptide's asparagine and the main chain ... Amide Rings are small motifs in proteins and polypeptides. They consist of 9-atom or 11-atom rings formed by two CO...HN ... An amide ring is employed in the specificity of the adaptor protein GRB2 for a particular asparagine within proteins it binds. ... An 11-atom amide ring, involving a glutamine residue, occurs at the interior of the light chain variable domains of some ...

N,N-disubstituted amides can be reduced to aldehydes by using an excess of the amide:[citation needed] R(CO)NRR' + LiAlH4 → ... Amide reduction is a reaction in organic synthesis where an amide is reduced to either an amine or an aldehyde functional group ... Some amides can be reduced to aldehydes in the Sonn-Müller method. A well known method for amide reduction is hydrosilylation ... Zhou, S.; Junge, K.; Addis, D.; Das, S.; Beller, M. (2009). "A Convenient and General Iron-Catalyzed Reduction of Amides to ...

Fatty acid amides (FAAs) are amides formed from a fatty acid and an amine. In nature, many FAAs have ethanolamine as the amine ... Other fatty acid amides are fatty acid primary amides (FAPAs). They contain the functionality RC(O)NH2). Oleamide is an example ... The signalling is controlled in part by fatty acid amide hydrolases, which convert the amide to the parent fatty acid. One ... Aliphatic amides can be found in Zanthoxylum species found in Nigeria. Fatty acid ester McKinney, Michele K.; Cravatt, Benjamin ...

... (EC 1.8.1.16, GAR) is an enzyme with systematic name glutathione amide:NAD+ oxidoreductase. This ... glutathione amide disulfide + NADH + H+ Glutathione amide reductase is a dimeric flavoprotein (FAD). Vergauwen B, Pauwels F, ... Glutathione+amide+reductase at the U.S. National Library of Medicine Medical Subject Headings (MeSH) Portal: Biology (EC 1.8.1) ... Identification of a novel thiol peroxidase (Prx/Grx) fueled by glutathione amide redox cycling". The Journal of Biological ...

cyclic amide or lactam, a cyclic compound with the amide group -C(=O)N- in the ring. metal amide, an ionic compound ("salt") ... "amide". The American Heritage Dictionary of the English Language (5th ed.). HarperCollins. "amide - Definition of amide in ... the "Gold Book") (1997). Online corrected version: (2006-) "amides". doi:10.1351/goldbook.A00266 (Amides). ... 2NR2 The term amide may also refer to amide group, a functional group -C(=O)N= consisting of a carbonyl adjacent to a nitrogen ...

... or PEBA is a thermoplastic elastomer (TPE). It is known under the tradename of PEBAX® (Arkema) and ... Eustache, R.-P. (2005). "Poly(Ether -b-Amide) TPE: Structure, Properties and Applications". In Fakirov, Stoyko (ed.). Handbook ...

... (EC 1.11.1.17) is an enzyme with systematic name glutathione amide:hydrogen-peroxide ... Glutathione+amide-dependent+peroxidase at the U.S. National Library of Medicine Medical Subject Headings (MeSH) Portal: Biology ... Identification of a novel thiol peroxidase (Prx/Grx) fueled by glutathione amide redox cycling". The Journal of Biological ... This enzyme catalyses the following chemical reaction 2 glutathione amide + H2O2 ⇌ {\displaystyle \rightleftharpoons } ...

L-proline+amide+hydrolase at the U.S. National Library of Medicine Medical Subject Headings (MeSH) Portal: Biology (EC 3.5.1). ... L-proline amide hydrolase (EC 3.5.1.101, S-stereoselective piperazine-2-tert-butylcarboxamide hydrolase, LaaA, L-amino acid ...

... , Sigma-Aldrich Tesh, Kris F.; Hanusa, Timothy P.; Huffman, John C. (1990). "Ion pairing in [ ... Potassium bis(trimethylsilyl)amide (commonly abbreviated as KHMDS, Potassium(K) HexaMethylDiSilazide) or potassium ... Metal bis(trimethylsilyl)amides "Potassium Hexamethyldisilazane". sigmaaldrich.com. Retrieved 1 April 2023. ...

The von Braun amide degradation is the chemical reaction of a monosubstituted amide with phosphorus pentachloride or thionyl ... The secondary amide 1 reacts via its enolized form with phosphorus pentachloride to form the oxonium ion 2. This produces a ... Phillips, B.A.; Fodor, G.; Gal, J.; Letourneau, F.; Ryan, J.J. (1973). "Mechanism of the von Braun amide degradations with ...

... amides Watson, B. T.; Lebel, H. "Sodium bis(trimethylsilyl)amide" in Encyclopedia of Reagents for Organic Synthesis (Ed: L. ... Sodium bis(trimethylsilyl)amide is the organosilicon compound with the formula NaN(Si(CH3)3)2. This species, usually called ... amide". Organometallics. 16 (23): 5108-5112. doi:10.1021/om970444c. Sergey A. Kozmin, Shuwen He, and Viresh H. Rawal. " ...

... amides. MXn + n Li(HMDS) → M(HMDS)n + n LiX where X = Cl, Br, I and sometimes F Metal bis(trimethylsilyl)amide complexes are ... Lithium bis(trimethylsilyl)amide is a lithiated organosilicon compound with the formula LiN(Si(CH3)3)2. It is commonly ... S(N(Si(CH3)3)2)2 is prepared by the reaction of lithium bis(trimethylsilyl)amide and sulfur dichloride (SCl2). 2 LiN(Si(CH3)3)2 ... Lithium amide Lithium diisopropylamide Lithium tetramethylpiperidide Amonoo-Neizer, E. H.; Shaw, R. A.; Skovlin, D. O.; Smith, ...

... (NAAA) EC 3.5.1.- is a member of the choloylglycine hydrolase family, a subset of the N ... NAAA cleaves C-N non-peptide bonds in linear amides, particularly ethanolamides. Its mechanism is quite similar to that of AC, ... While NAAA operates much like fatty acid amide hydrolase (HUGO gene symbol: FAAH), the two enzymes are not homologous. On the ... and functional similarity to fatty acid amide hydrolase (FAAH) allow it to be studied extensively. The overall enzyme mechanism ...

... (3-Pentyllysergamide, LSP) is an analogue of LSD originally researched by David E. Nichols and ... Lysergic acid 2-butyl amide Methylisopropyllysergamide Nichols DE (2001). "LSD and Its Lysergamide Cousins". The Heffter Review ... "Stereoselective LSD-like activity in a series of d-lysergic acid amides of (R)- and (S)-2-aminoalkanes". Journal of Medicinal ...

Patricelli MP, Cravatt BF (October 1999). "Fatty acid amide hydrolase competitively degrades bioactive amides and esters ... Fatty-acid amide hydrolase 1 or FAAH-1(EC 3.5.1.99, oleamide hydrolase, anandamide amidohydrolase) is a member of the serine ... fatty-acid+amide+hydrolase at the U.S. National Library of Medicine Medical Subject Headings (MeSH) Proteopedia FAAH entry - ... In vivo, FAAH is the principal catabolic enzyme for a class of bioactive lipids called the fatty acid amides (FAAs). Members of ...

It is a structural isomer of LSD, with the two ethyl groups on the amide nitrogen having been replaced by a single sec-butyl ... Lysergic acid 2-butyl amide (2-Butyllysergamide, LSB) is an analogue of LSD originally developed by Richard Pioch at Eli Lilly ... US patent 2997470, Richard P. Pioch, "LYSERGIC ACID AMIDES", published 1956-03-05, issued 1961-08-22 Oberlender R, Pfaff RC, ... and while lysergic acid 2-butyl amide is more potent than LSD as a 5-HT1A agonist, it is slightly less potent as a 5-HT2A ...

A qualitative order of electrophilicity is RCHO (aldehydes) > R2CO (ketones) > RCO2R' (esters) > RCONH2 (amides). A variety of ...

... a nitroso group bonded to the nitrogen of an amide or similar functional group. Specific classes include the N-nitrosamides, N- ...

Primary amides (RC(O)NH2) are more amenable to this reaction. In contrast to the reluctance of amides as substrates, urea is ... Transamidation is a chemical reaction in which an amide reacts with an amine to generate a new amide: RC(O)NR'2 + HNR"2 → RC(O) ... "A two-step approach to achieve secondary amide transamidation enabled by nickel catalysis". Nature Communications. 7: 11554. ...

Akiyama, Masayasu; Katoh, Akira; Ogawa, Takuya (1989). "N-hydroxy amides. Part 8. Synthesis and iron(III)-holding properties of ...

Amides give thioamides. With 1,4-diketones the reagent forms thiophenes. It is also used to deoxygenate sulfoxides. The use of ...

Linda P, Stener A, Cipiciani A, Savelli G (January-February 1983). "Hydrolysis of amides. Kinetics and mechanism of the basic ...

It is an amide of nicotinic acid. Foods that contain niacinamide include yeast, meat, milk, and green vegetables. Niacinamide ... The structure of nicotinamide consists of a pyridine ring to which a primary amide group is attached in the meta position. It ... The enzyme allows for a more selective synthesis as further hydrolysis of the amide to nicotinic acid is avoided. Nicotinamide ... Schmidberger JW, Hepworth LJ, Green AP, Flitsch SL (2015). "Enzymatic Synthesis of Amides". In Faber K, Fessner WD, Turner NJ ( ...