Allyl alcohols in general can be prepared by allylic oxidation of allyl compounds, as in the Riley oxidation or Kharasch- ... Allyl alcohol (IUPAC name: prop-2-en-1-ol) is an organic compound with the structural formula CH2=CHCH2OH. Like many alcohols, ... Allyl alcohol is the smallest representative of the allylic alcohols. Allyl alcohol can be obtained by many methods. It was ... Today allyl alcohol is produced commercially by the Olin and Shell corporations through the hydrolysis of allyl chloride: CH 2 ...

... is an organic compound with formula C3H5OC(O)CH3. This colourless liquid is a precursor to especially allyl ... Allyl acetate can be hydrolyzed to allyl alcohol: CH2=CHCH2OCOCH3 + H2O → CH2=CHCH2OH + CH3COOH Allyl alcohol is a precursor ... Allyl alcohol is also produced primarily from allyl chloride, but production via the hydrolysis of allyl acetate route avoids ... 2000). "Allyl Compounds". Ullmann's Encyclopedia of Industrial Chemistry. doi:10.1002/14356007.a01_425. ISBN 9783527303854. ( ...

... is an organic compound with the formula CH2CHCH2CN. Like other small alkyl nitriles, allyl cyanide is colorless ... Allyl cyanide is obtained by the reaction of allyl acetate with hydrogen cyanide. A laboratory route to allyl cyanide involves ... Allyl cyanide was discovered in 1863 by H. Will and W. Koerner in 1863, they found the compound to be present in mustard oil. ... Allyl Isothiocyanate and Allyl Cyanide Production in Cell-Free Cabbage Leaf Extracts, Shredded Cabbage, and Cole Slaw / J. ...

"Allyl Compounds". Ullmann's Encyclopedia of Industrial Chemistry. Weinheim: Wiley-VCH. doi:10.1002/14356007.a01_425. Berthelot ... The compound was isolated during studies on reactions between glycerol and gaseous hydrogen chloride. Reminiscent of ... This is the same intermediate formed in the allyl chloride/hypochlorous acid process, and is likewise then treated with base to ... Jun Li; Gongda Zhao; Shuang Gao; Ying Lv; Jian Li; Zuwei Xi (2006). "Epoxidation of Allyl Chloride to Epichlorohydrin by a ...

Ludger Krähling; Jürgen Krey; Gerald Jakobson; Johann Grolig; Leopold Miksche (2002). "Allyl Compounds". Ullmann's Encyclopedia ... Or by the reaction of allyl chloride with Hexamine. Pure samples can be prepared by hydrolysis of allyl isothiocyanate. It ... Allylamine, like other allyl derivatives is a lachrymator and skin irritant. Its oral LD50 is 106 mg/kg for rats. Nomenclature ... Allylamine is an organic compound with the formula C3H5NH2. This colorless liquid is the simplest stable unsaturated amine. All ...

Coffey, Samuel; Ward, Charles Frederick (1921). "CXLVIII.-The preparation of some allyl compounds". J. Chem. Soc., Trans. 119: ... Dioxalin readily loses two molecules of carbon dioxide at this high temperature to form allyl alcohol and therefore offers a ... Chattaway, Frederick Daniel (1915). "XLVII.-The preparation of allyl alcohol". J. Chem. Soc., Trans. 107: 407-410. doi:10.1039/ ... method for conversion of glycerol to allyl alcohol. ...

... other allyl compounds, such as allyl amines and allyl halides, and use of with rhodium catalysts, such as ... The Doyle-Kirmse reaction is an organic reaction in which a metal carbene reacts with an allyl compound with transposition of ... The reaction is not strictly limited to allyl compounds. Propargyl-sulfide substrates give allene products and conversely ... As originally developed, an allyl sulfide reacts with trimethylsilyldiazomethane to form the homoallyl sulfide compound. The ...

Many substituents can be attached to the allyl group to give stable compounds. Commercially important allyl compounds include: ... Allylation is the attachment of an allyl group to a substrate, usually another organic compound. Classically, allylation ... Transition-metal allyl complexes, such as allylpalladium chloride dimer Wikiquote has quotations related to Allyl group. ... In 1844, Theodor Wertheim isolated an allyl derivative from garlic oil and named it "Schwefelallyl". The term allyl applies to ...

Comonomers include acrylic acid, acrylamide, allyl compounds, and sulfonated styrene. Anionic polymerization also can be used ...

Organosilicon compounds, Allyl compounds, All stub articles, Organic compound stubs). ... The compound is bifunctional, containing reactive trichlorsilyl and allyl groups. The SiCl3 group undergoes the usual ... Allyltrichlorosilane is an organosilicon compound with the formula Cl3SiCH2CH=CH2. It is a colorless or white low-melting solid ... Hurd, Dallas T. "Preparation of vinyl and allyl chlorosilanes" Journal of the American Chemical Society 1945, volume 67, 1813- ...

... the irritating compound in hot chili peppers); and allyl isothiocyanate, the pungent compound in mustard and wasabi. The ...

... is an organic compound with the formula C5H11CO2CH2CH=CH2. It is a colorless liquid, although commercial ... Allyl hexanoate at The Good Scents Company Allyl caproate at Sigma-Aldrich Johannes Panten and Horst Surburg "Flavors and ... Allyl hexanoate is employed principally in the formulation of pineapple flavors but it can also be used for peach and apricot ... Chemical articles with multiple compound IDs, Multiple chemicals in an infobox that need indexing, Articles without EBI source ...

Organocobalt compounds are known with alkene, allyl, diene, and Cp ligands. A famous sandwich compound is cobaltocene, a rare ... The half-sandwich compounds of the type CpCoL2 have been well investigated (L = CO, alkene). The complexes CpCo(C2H4)2 and CpCo ... Organocobalt compounds are involved in several organic reactions and the important biomolecule vitamin B12 has a cobalt-carbon ... Other sandwich compounds are CoCp(C6Me6) and Co(C6Me6)2, with 20 electrons and 21 electrons, respectively. Reduction of ...

Allyl halides react with Ni(CO)4 to form pi-allyl complexes, (allyl)2Ni2Cl2. These compounds in turn are sources of allyl ... One 12 VE compound is di(mesityl)nickel prepared from (allyl)2Ni2Br2 and the corresponding Grignard reagent. (allyl)2Ni2Br2 + 4 ... Nickel compounds cause the coupling reaction between allyl and aryl halides. Other coupling reactions involving nickel in ... In (allyl)2Ni2Br2 and (allyl)Ni(C5H5), nickel is assigned to oxidation number +2, and the electron counts are 16 and 18, ...

Allyl compounds, Propyl compounds, All stub articles, Organic compound stubs). ... Allyl propyl disulfide is an organosulfur compound with the chemical formula C3H5S2C3H7. It is a volatile pale-yellow liquid ...

... is an organic compound with the formula C6H5OCH2CH=CH2. It is a colorless solid. Allyl phenyl ether is ... Allyl phenyl ether converts to 2-allylphenol in the presence of acid catalysts. This conversion is an example of the Claisen ... A Novel and Efficient Solid Superacid Catalyst for Claisen Rearrangement of Substituted Allyl Phenyl Ethers. Synthetic ... prepared by the reaction of sodium phenoxide with allyl bromide: C6H5ONa + BrCH2CH=CH2 → C6H5OCH2CH=CH2 + NaBr The yield is ...

Cyclopentadienyl allyl palladium is an organopalladium compound with formula (C5H5)Pd(C3H5). This reddish solid is volatile ... allyl) + 2 PR3 → Pd(PR3)2 + C5H5C3H5 The compound has been used to deposit thin film chemical vapor deposition of metallic ... The molecule consists of a Pd centre sandwiched between a Cp and allyl ligands. This complex is produced by the reaction of ... C3H5PdC3H5 → Pd(0) + C5H5C3H5 The compound readily reacts with alkyl isocyanides to produce clusters with the approximate ...

Allyl isothiocyanate is an unstable compound, degrading over the course of days at 37 °C (99 °F). Because of this instability, ... The distinctive pungent taste of horseradish is from the compound allyl isothiocyanate. Upon crushing the flesh of horseradish ... The allyl isothiocyanate serves the plant as a natural defense against herbivores. Since allyl isothiocyanate is harmful to the ... When cut or grated, enzymes from within the plant cells digest sinigrin (a glucosinolate) to produce allyl isothiocyanate ( ...

Allyl sulfide compounds produce the characteristic odour of the onion subfamily (Allioideae). The family, which was originally ... The Allioideae produce allyl sulfide compounds which give them their characteristic smell. Type species of Amaryllidaceae ...

... is an organosulfur compound with the chemical formula CH2=CHCH2SCH3. The molecule features two functional ... It is prepared by the reaction of allyl chloride with sodium hydroxide and methanethiol. CH2=CHCH2Cl + NaOH (aq) + CH3SH → CH2= ... groups, an allyl (CH2=CHCH2) and a sulfide. It is a colourless liquid with a strong odor characteristic of alkyl sulfides. It ...

... , or alpha-allyl-phenethylamine, is a chemical compound of the phenethylamine family. It was briefly investigated as ... Allyl compounds, Norepinephrine-dopamine releasing agents, Alkene derivatives). ... It has now been largely superseded by the newer compounds in this class, and only rarely found in scientific literature. The " ...

... is an organonickel compound with the formula Ni(η3-C3H5)2. The molecule consists of two allyl ligands bound to ... It can be prepared by the reaction of allyl magnesium bromide with anhydrous nickel chloride. It was first prepared similarly ... O'Brien, S.; Fishwick, M.; McDermott, B.; Wallbridge, M. G. H.; Wright, G. A. (1972). "Isoleptic Allyl Derivatives of Various ... A Theoretical Investigation and an Experimental Determination using Neutron Diffraction of the Structure of Bis(η3-allyl)nickel ...

These groups are found in many compounds. Propenyl compounds are isomeric with allyl compounds, which have the formula CH2-CH= ...

It decomposes in the human body into other compounds such as allyl methyl sulfide. In 1844, Theodor Wertheim separated by steam ... Allyl propyl disulfide allyl disulfide Diallyl disulfide at Sigma Aldrich Block, Eric (2010). Garlic and Other Alliums: The ... diallyl disulfide is produced from sodium disulfide and allyl bromide or allyl chloride at temperatures of 40-60 °C in an inert ... Fukao, T; Hosono, T; Misawa, S; Seki, T; Ariga, T (2004). "The effects of allyl sulfides on the induction of phase II ...

The sulfur compound allicin, produced by crushing or chewing fresh garlic, produces other sulfur compounds: ajoene, allyl ... This is because garlic's strong-smelling sulfur compounds are metabolized, forming allyl methyl sulfide. Allyl methyl sulfide ( ... A large number of sulfur compounds contribute to the smell and taste of garlic. Allicin has been found to be the compound most ... The resultant compounds are responsible for the sharp or hot taste and strong smell of garlic. Some of the compounds are ...

Industrially significant organic compounds prepared from hydrobromic acid include allyl bromide, tetrabromobis(phenol), and ... Dagani, M. J.; Barda, H. J.; Benya, T. J.; Sanders, D. C. (2012). "Bromine Compounds". Ullmann's Encyclopedia of Industrial ... It is a useful reagent for generating organobromine compounds. Certain ethers are cleaved with HBr. It also catalyzes ...

Silylated allylic acetates, carbonates and other substituted allyl compounds may form TMM synthons under palladium catalysis. ... Carbonyl compounds may be used as the 2π component under the appropriate conditions. For instance, in the presence of an indium ... Three classes of compounds have been used to generate synthetically useful TMM intermediates: diazenes, silyl-substituted ... Rapid racemization of chiral pi-allyl palladium complexes occurs, and only moderate diastereoselectivity is observed in ...

This is likely in cases when the allyl compound is unhindered, and a strong nucleophile is used. The products will be similar ... An allylic rearrangement or allylic shift is an organic reaction in which the double bond in an allyl chemical compound shifts ... Allyl shifts can also take place with electrophiles. In the example below the carbonyl group in benzaldehyde is activated by ... This is usual in allylic compounds which have a bulky leaving group in SN2 conditions or bulky non-leaving substituent which ...

Allyl compounds with suitable leaving groups react with palladium(II) salts to pi-allyl complexes having hapticity 3. These ... Palladium compounds owe their reactivity to the ease of interconversion between Pd(0) and palladium(II) intermediates. There is ... Fullerene ligands also bind with palladium(II). Palladium(II) acetate and related compounds are common reagents because the ... Zerovalent Pd(0) compounds include tris(dibenzylideneacetone)dipalladium(0) and tetrakis(triphenylphosphine)palladium(0). These ...

For example, allylglucosinolate and allyl glucosinolate refer to the same compound: both versions are found in the literature. ... The "ate" ending in the naming of these compounds implies that they are anions at physiological pH and an early name for this ... Care must be taken when discussing these compounds since some older publications do not make it clear whether they refer to the ... Glucosinolates constitute a natural class of organic compounds that contain sulfur and nitrogen and are derived from glucose ...

... is an organic compound used in adhesives and sealants and as a monomer for polymerization reactions. It is ... As a bifunctional compound, the alkene group or the epoxide group can be reacted selectively to yield a product where the other ... Allyl glycidyl ether is used in adhesives and sealants and as a monomer for various types of polymer preparations. ... By this reaction, allyl glycidyl ether finds use as an intermediate in the production of silane coatings for electrical ...

The compound consists of a phenyl group attached to an allyl group. Allylbenzene isomerizes to trans-propenylbenzene. In plant ... Allylbenzene or 3-phenylpropene is an organic compound with the formula C6H5CH2CH=CH2. It is a colorless liquid. ...