... organometallic compounds; unsaturated hydrocarbons; polyaromatic hydrocarbons; additive remains; products of oil decomposition ...
Typical organotechnetium compounds thus feature the tricarbonyl motif. Typical methods of organometallic compounds synthesis ... These organotechnetium compounds are mostly seen as technetium tri-carbonyl compounds and technetium cyclopentadienyl compounds ... which are organometallic compounds containing carbon-to-technetium chemical bonds. The most common organotechnetium compounds ... There are a number of "classical" organometallic organotechnetium compounds, specifically containing carbon-technetium bonds ...
Organometallic compounds. Quantitative chemical analysis is a key part of environmental chemistry, since it provides the data ... Organic compounds, including PAHs, are commonly measured also using mass spectrometric methods, such as Gas chromatography-mass ... Sigel, A. (2010). Sigel, H.; Sigel, R.K.O. (eds.). Organometallics in Environment and Toxicology. Metal Ions in Life Sciences. ... More sophisticated approaches are used in the determination of trace metals and organic compounds. Metals are commonly measured ...
Ruppert, Ingo; Schlich, Klaus; Volbach, Wolfgang (1984). "Fluorinated organometallic compounds. 18. First trifluoromethyl- ... The compound is a reagent used in organic chemistry for the introduction of the trifluoromethyl group. The compound was first ... Trifluoromethyl compounds, Reagents for organic chemistry, Carbosilanes, Trimethylsilyl compounds). ... Trifluoromethyltrimethylsilane (known as Ruppert-Prakash reagent, TMSCF3) is an organosilicon compound with the formula CF3Si( ...
In organometallic chemistry, metal tetranorbornyls are compounds with the formula M(nor)4 (M = a metal in a +4 oxidation state ... "Dispersion Effects in Stabilizing Organometallic Compounds: Tetra-1-norbornyl Derivatives of the First-Row Transition Metals as ... Lastly, a recrystallization step from pentane to obtain the crystalline compound. Alternative methods for the preparation of ... Compounds Fe(1-norbornyl) 4 and Fe(cyclohexyl) 4". The Journal of Physical Chemistry A. 124 (34): 6867-6876. Bibcode:2020JPCA.. ...
"Polyfluoroaryl organometallic compounds. Part VIII. Synthesis of and nucleophilic substitution in octafluorodibenzofuran". J. ... and conversion of nitroso compounds to nitro compounds or nitramines. For example, a mixture of hydrogen peroxide and ... The hypervalent compound is accessible in two ways, and which is chosen usually depends on what materials are available: it can ... In the case of an allyl alcohol compound with a proximate carbonyl functional group, the epoxide can undergo a ring-expansion ...
Ang, W.; Casini, A.; Sava, G.; Dyson, P. J. (2011). "Organometallic ruthenium-based antitumor compounds with novel modes of ... It is envisaged that RAPTA derivatives have the "piano stool" structure like others organometallic half-sandwich compound. This ... Gasser, G.; Ott, I.; Metzler-Nolte, N. (2011). "Organometallic anticancer compounds". J. Med. Chem. 1 (1): 3-25. doi:10.1021/ ... Gasser, G.; Ott, I.; Metzler-Nolte, N. (2011). "Organometallic anticancer compounds". J. Med. Chem. 1 (1): 3-25. doi:10.1021/ ...
960-963 of: Schlenk, Wilhelm (1924). "Organometallverbindungen [Organometallic compounds]". In Weyl, Josef (ed.). Die Methoden ... An explosion may occur due to reaction of the liquid oxygen with any organic compounds also in the trap. Vacuum/gas manifold ... Perkin triangle - used for the distillation of air-sensitive compounds. The prototype of what became the "Schlenk line" appears ... Schlenk lines are useful for safely and successfully manipulating moisture- and air-sensitive compounds. The vacuum is also ...
D. Sutton (1993). "Organometallic diazo compounds". Chem. Rev. 93 (3): 995-1022. doi:10.1021/cr00019a008. Jun Ho Shin; Brian M ... The need for additional nomenclature for organometallic compounds became apparent in the mid-1950s when Dunitz, Orgel, and Rich ... "IR-9.2.4.1 Coordination Compounds: Describing the Constitution of Coordination Compounds: Specifying donor atoms: General" (PDF ... Reduction of the 18-VE compound [Ru(η6-C6Me6)2]2+ (where both aromatic rings are bonded in an η6-coordination), results in ...
In organometallic chemistry, a metallacycle is a derivative of a carbocyclic compound wherein a metal has replaced at least one ... Many compounds containing metals in rings are known, for example chelate rings. Usually, such compounds are not classified as ... attractive compounds for organometallic chemistry and catalysis". Chem. Soc. Rev. 36 (5): 719-728. doi:10.1039/b605734a. PMID ... One main effect that metallic atom substitution on a cyclic carbon compound is distorting the geometry due to the large size of ...
Yttrium compounds, Organometallic compounds). ... Organoytrium compounds are often prepared by alkylation of YCl ... Organoyttrium chemistry is the study of compounds containing carbon-yttrium bonds. These compounds are almost invariably formal ... Schumann, H.; Fedushkin, I. L. (2006). "Scandium, Yttrium & The Lanthanides: Organometallic Chemistry". Encyclopedia of ... Organoyttrium compounds are mainly of academic interest. ...
Synthesis of Organometallic Compounds: A Practical Guide Sanshiro Komiya Ed. S. Komiya, M. Hurano 1997. Pericles Stavropoulos, ... This compound has been used as a catalyst in some laboratory experiments. It can be prepared by many routes, a typical method ... A variety of half-sandwich compounds have been prepared from (C5H5)Re(CO)3 and (C5Me5)Re(CO)3. Notable derivatives include the ... Organorhenium chemistry describes the compounds with Re−C bonds. Because rhenium is a rare element, relatively few applications ...
Crompton, T. R. (6 December 2012). Gas Chromatography of Organometallic Compounds. Springer. pp. 80-83. ISBN 978-1-4684-4226-7 ... Adams, Roy M. (September 1959). "Organoboron Compounds" (PDF). Metal-Organic Compounds. Advances in Chemistry. Vol. 23. p. 92. ... The compound boils at −43 °C. Methyldiborane liquid has a density of 0.546 g/ml at −126° At −78.5 the vapour pressure is 55 ... doi:10.1016/s0040-4039(00)96380-9. Bell, R. P.; Emeléus, H. J. (1948). "The boron hydrides and related compounds". Quarterly ...
Organometallic chemistry, Cyclic compounds). ... in such compounds, the parent acyclic hydrocarbon ligand is ... Landorf, C. W.; Jacob, V.; Weakley, T. J. R.; Haley, M. M. (2004). "Rational Synthesis of Platinabenzenes†". Organometallics. ... Organometallics. 28 (17): 5183. doi:10.1021/om900439z. Poon, K. C.; Liu, L.; Guo, T.; Li, J.; Sung, H. H. Y.; Williams, I. D.; ... Organometallics. 26 (10): 2705. doi:10.1021/om070195k. Wu, L.; Feng, L.; Zhang, H.; Liu, Q.; He, X.; Yang, F.; Xia, H. (2008 ...
Many organometallic compounds exhibit fluxionality. Fluxionality is however pervasive. Temperature dependent changes in the NMR ... "Stereochemically Nonrigid Organometallic Compounds. I. π-Cyclopentadienyliron Dicarbonyl σ-Cyclopentadiene". J. Am. Chem. Soc. ... Such compounds do rearrange intramolecularly via the Ray-Dutt twist and the Bailar twist, but the barriers for these processes ... For some compounds, dynamics occur via dissociation of a ligand, giving a pentacoordinate intermediate, which is subject to the ...
Dictionary of organometallic compounds. - 2nd supplement. - Chapman and Hall Ltd, 1986. - p. 19 Duncan, Leonard C.; Cady, ... Organometallic and organometalloidal fluorine compounds. Part VIII. The electrochemical fluorination of dimethyl sulphide and ... E 10b/2, 4th Edition Supplement: Organo-Fluorine Compounds - Synthesis of Fluorinated Compounds II, Transformations of ... Advances in Organometallic Chemistry. Academic Press. 1964. p. 154. ISBN 9780080580029. Parsons, Theran D.; Baker, Everett D.; ...
1994-11-10). Dictionary of Organometallic Compounds. p. 468. ISBN 9780412430602. Baker, Charles J. (2001). The Fire Fighter's ... 1,1-Dimethyldiborane is the organoboron compound with the formula (CH3)2B(μ-H)2BH2. A pair of related 1,2-dimethyldiboranes are ... Bell, R. P.; Emeléus, H. J. (1948). "The boron hydrides and related compounds". Quarterly Reviews, Chemical Society. 2 (2): 132 ... Holliday, A.K.; N. Jessop, G. (November 1967). "The reaction of tetramethyllead with diborane". Journal of Organometallic ...
Eisch, John J.; Galle, James E. (July 1975). "Rearrangements of organometallic compounds. XIII. Boraaromatic systems. IV. ... However, if the phenyls are positioned in a [c,e] fashion (see below) then the resulting compound is less stable than dibenzo[b ... Like many other main group compounds, borepins have been in the field since the mid-late 1900s yet lay dormant until more ... Chemists like Ashe were able to utilize this knowledge in the 1990s to functionalize borepins as a compound, leading to the ...
Organometallic compounds, Nickel compounds). ... These high-valent nickel compounds are intermediates or models ... Camasso, N. M.; Sanford, M. S. (2015-02-05). "Design, synthesis, and carbon-heteroatom coupling reactions of organometallic ... Organonickel(IV) complex are organonickel compounds that feature nickel in the +4 oxidation state. ... Dimitrov, Vladimir; Linden, Anthony (2003-06-16). "A Pseudotetrahedral, High-Oxidation-State Organonickel Compound: Synthesis ...
cite book}}: ,journal= ignored (help); Missing or empty ,title= (help) Behr, Arno (2000). "Organometallic Compounds and ... Allyl iodide (3-iodopropene) is an organic halide used in synthesis of other organic compounds such as N-alkyl-2-pyrrolidones, ... Schorlemmer, C. (1874). A manual of the chemistry of the carbon compounds. London: Macmillan and Co. p. 262. Datta, Rasek Lal ( ... v t e (CS1 errors: periodical ignored, CS1 errors: missing title, Chemical articles with multiple compound IDs, Multiple ...
Roy, Jackson W; Thomson, RJ; MacKay, M.F. (1985). "The Stereochemistry of Organometallic Compounds. XXV. The Stereochemistry of ... Chlorodiphenylphosphine is an organophosphorus compound with the formula (C6H5)2PCl, abbreviated Ph2PCl. It is a colourless ... ISBN 0-471-31824-8 Svara, J.; Weferling, N.; Hofmann, T. "Phosphorus Compounds, Organic," In 'Ullmann's Encyclopedia of ... 2 PhPCl2 → Ph2PCl + PCl3 Alternatively such compounds are prepared by redistribution reactions starting with triphenylphosphine ...
Behr, Arno (2000). "Organometallic Compounds and Homogeneous Catalysis". Ullmann's Encyclopedia of Industrial Chemistry. p. 10 ... The compound exists as endo and exo isomers, but these are not typically separated. It is an intermediate in the production of ... Vinyl norbornene (VNB) is an organic compound that consists of a vinyl group attached to norbornene. It is a colorless liquid. ...
... is an organometallic compound. Its chemical formula is C 6H 15In. This compound can be obtained by reacting ... The compound reacts with halomethanes to form diethyl indium halides. Triethylindium is highly reactive with water: In(C2H5)3 ... doi:10.1016/S0022-328X(00)82987-3. Sakaki, H.; Woo, J.C.; Yokoyama, N.; Harayama, Y. (1999). Compound Semiconductors: ... Proceedings of the Twenty-Fifth International Symposium on Compound Semiconductors held in Nara, Japan, 12-16 October 1998. CRC ...
Behr, Arno (2000). "Organometallic Compounds and Homogeneous Catalysis". Ullmann's Encyclopedia of Industrial Chemistry. doi: ... to form various N-heterocyclic compounds through the aza-Diels-Alder reaction. Nitroso compounds (R-N=O) can react with dienes ... Ashby, E. C.; Chao, L.-C.; Neumann, H. M. (1973). "Organometallic reaction mechanisms. XII. Mechanism of methylmagnesium ...
Behr, Arno (2000). "Organometallic Compounds and Homogeneous Catalysis". Ullmann's Encyclopedia of Industrial Chemistry. p. 10 ... The compound consists of E- and Z-stereoisomers, but the mixtures are typically not separated. It is prepared by isomerization ... Ethylidene norbornene (ENB) is an organic compound that consists of an ethylidene (CH3C(H)=) group attached to norbornene. It ...
Relative Reactivities of Organometallic Compounds. XX.* Metalation Henry Gilman, Robert L. Bebb J. Am. Chem. Soc.; 1939; 61(1 ... Examples of DMG's are the methoxy group, a tertiary amine group and an amide group.The compound can be produced by directed ... New methodology for the preparation of ortho-substituted thiophenols and related compounds Garret D. Figuly, Cynthia K. Loop, J ... sodium salt of TMP and di-tert-butylzinc is a meta zincated complex as a stable crystalline compound. This complex reacts with ...
These naturally occurring organometallic compounds. This area is more focused on the utilization of metals by unicellular ... The organic compounds (proteins, lipids and carbohydrates) contain the majority of the carbon and nitrogen and most of the ... Bioorganometallic compounds are significant in environmental chemistry. A number of drugs contain metals. This theme relies on ... 2010). Organometallics in Environment and Toxicology. Metal Ions in Life Sciences. Vol. 7. Cambridge: RSC publishing. ISBN 978- ...
Gilman, Henry; Straley, James M. (2010). "Relative reactivities of organometallic compounds. XIII. Copper and silver". Recueil ... The Role of Copper in the Conjugate Addition of Organometallic Reagents". The Journal of Organic Chemistry. 31 (10): 3128-3141 ... Kochi, Jay K. (1978). Organometallic Mechanisms and Catalysis. New York: Academic Press. pp. 381-386. ISBN 978-0-12-418250-9. ... Lipshutz, Bruce H. (2002). Schlosser, Manfred (ed.). Organometallics in Synthesis: A Manual. Wiley. pp. 665-815. ISBN 978- ...
Evans, D. F.; Fazakerley, G. V.; Phillips, R. F. (1970). "Organometallic compounds of bivalent ytterbium". Journal of the ... Evans, D. F.; Fazakerley, G. V.; Phillips, R. F. (1971). "Organometallic compounds of bivalent europium, ytterbium, and ... He made a number of studies on organometallic and coordination complexes. An example of his ingenuity in this area is to show ... He also used the technique of double irradiation of organic compounds to establish the relative signs of coupling constants. ...
Functional groups compatible with the parent organometallic compound are generally also stable upon transmetallation to cerium ... These compounds comprise a subset of the organolanthanides. In general, organocerium compounds are not isolable, and are rather ... but whether this type of polymer exists once the organometallic reagent is formed is unknown. Organocerium compounds are ... These latter compounds have found less widespread use due to their oxidizing nature, and the majority of literature regarding ...