... can be prepared by heating benzyl chloride and excess sodium cinnamate in water to 100-115 °C or by heating ... Benzyl cinnamate is the chemical compound which is the ester derived from cinnamic acid and benzyl alcohol. Benzyl cinnamate ... "Benzyl cinnamate". Sigma-Aldrich. George A. Burdock (2010), "BENZYL CINNAMATE", Fenaroli's Handbook of Flavor Ingredients (6th ... Benzyl cinnamate is used in heavy oriental perfumes and as a fixative. It is used as a flavoring agent. It is used ...
... , at goodscents.com Methyl cinnamate, at Sigma-Aldrich "Methyl cinnamate". pubchem.ncbi.nlm.nih.gov. Viña, ... Methyl cinnamate is the methyl ester of cinnamic acid and is a white or transparent solid with a strong, aromatic odor. It is ... Methyl cinnamate is used in the flavor and perfume industries. The flavor is fruity and strawberry-like; and the odor is sweet ... Eucalyptus olida has the highest known concentrations of methyl cinnamate (98%) with a 2-6% fresh weight yield in the leaf and ...
... can dimerize to the truxillic acid derivative truxilline. It is notable that methylecgonine cinnamate ... Methylecgonine cinnamate is a natural tropane alkaloid found within the coca plant. Its more common name, cinnamoylcocaine, ... the discovery of differing impurity products yielding methylecgonine cinnamate in confiscated cocaine have led enforcing ...
... is the ester of cinnamic acid and ethanol. It is present in the essential oil of cinnamon.[citation needed] ... Pure ethyl cinnamate has a "fruity and balsamic odor, reminiscent of cinnamon with an amber note". The p-methoxy derivative is ...
... may refer to: Trans-cinnamate 2-monooxygenase Trans-cinnamate 4-monooxygenase This disambiguation page ...
Other names in common use include uridine diphosphoglucose-cinnamate glucosyltransferase, and UDPG:t-cinnamate ... In enzymology, a cinnamate beta-D-glucosyltransferase (EC 2.4.1.177) is an enzyme that catalyzes the chemical reaction UDP- ... The systematic name of this enzyme class is UDP-glucose:trans-cinnamate beta-D-glucosyltransferase. ... the two substrates of this enzyme are UDP-glucose and trans-cinnamate, whereas its two products are UDP and trans-cinnamoyl ...
... cytochrome P450 cinnamate 4-hydroxylase, cinnamate 4-hydroxylase, cinnamate 4-monooxygenase, cinnamate hydroxylase, cinnamic 4- ... In enzymology, a trans-cinnamate 4-monooxygenase (EC 1.14.14.91) is an enzyme that catalyzes the chemical reaction trans- ... The systematic name of this enzyme class is trans-cinnamate,NADPH:oxygen oxidoreductase (4-hydroxylating). Other names in ... trans-cinnamate 4-hydroxylase, and trans-cinnamic acid 4-hydroxylase. Potts JR, Weklych R, Conn EE, Rowell J (1974). "The 4- ...
... cinnamate 2-monooxygenase, cinnamic 2-hydroxylase, cinnamate 2-hydroxylase, and trans-cinnamic acid 2-hydroxylase. This enzyme ... In enzymology, a trans-cinnamate 2-monooxygenase (EC 1.14.13.14) is an enzyme that catalyzes the chemical reaction trans- ... The systematic name of this enzyme class is trans-cinnamate,NADPH:oxygen oxidoreductase (2-hydroxylating). Other names in ... H2O The 4 substrates of this enzyme are trans-cinnamate, NADPH, H+, and O2, whereas its 3 products are 2-hydroxycinnamate, ...
"Chlorogenic acids and other cinnamates. Nature, occurrence and dietary burden". Journal of the Science of Food and Agriculture ...
Ngan, Vanessa (2012). "Allergy to cinnamate". DermNet NZ. Retrieved 18 October 2021. Aysan, Erhan; Bektas, Hasan; Kaygusuz, ...
Synthesis of cinnamates by reacting aromatic aldehydes with esters. The reaction is known as the Claisen reaction and was ...
Ethyl cinnamate is a common example. Reduction of the carboxylic acid functional groups in the cinnamic acids provides the ... Hydroxylation of cinnamic acid in the 4-position by trans-cinnamate 4-monooxygenase leads to p-coumaric acid, which can be ...
"Enantioselective Catalytic Epoxidation of Cinnamate Esters". Tetrahedron. 50 (15): 4323-4334. doi:10.1016/S0040-4020(01)89369-8 ...
Clifford M (1999). "Chlorogenic acids and other cinnamates - nature, occurrence and dietary burden". J. Sci. Food Agric. 79 (3 ...
Rasool, Nazli; Khan, Abdul Qasim; Malik, Abdul (1990). "Plicatin a and B, two phenolic cinnamates from Psoralea plicata". ...
The analysis and characterization of chlorogenic acids and other cinnamates". In Santos-Buelga, C.; Williamson, G. (eds.). ... Clifford, M. N. (1999). "Chlorogenic acids and other cinnamates - nature, occurrence and dietary burden". Journal of the ...
Plicatin A and B, two phenolic cinnamates from Psoralea plicata. Nazli Rasool, Abdul Qasim Khan and Abdul Malik, Phytochemistry ...
This is evidenced by cinnamates, salicylates, benzylidine camphor, and dibenzoylmethane derivatives. Octyl methoxycinnamate ( ... "The role of direct photolysis and indirect photochemistry in the environmental fate of ethylhexyl methoxy cinnamate (EHMC) in ... Cinnamates Ethylhexyl methoxycinnamate (OMC) Isoamyl p-methoxycinnamate (IMC, amiloxate) Camphor derivatives Terephtalydene ...
For methyl cinnamate, the two substituents (Ph v.s. COOMe) compete at withdrawing electrons from the alkene. The carboxyl is ... For example, consider the cycloaddition of diazomethane to three dipolarophiles: methyl acrylate, styrene or methyl cinnamate. ...
"Anti-inflammatory and chemopreventive effects of triterpene cinnamates and acetates from shea fat". Journal of Oleo Science. 59 ...
Another population is rich in methyl cinnamate with two chemotypes. Melaleuca viridiflora is a useful and adaptable small tree ...
Lanthanide-mediated epoxidation has been successfully applied to cinnamates and β-heteroaryl unsaturated esters. Amides are ...
It is a derivative of hydroxycodeinone, being the 14-cinnamate ester. In another paper, Buckett assigns the potency as 177 with ...
It contains methyl cinnamate, giving it a flavor reminiscent of cinnamon. Cinnamon basil has somewhat narrow, slightly serrated ...
The enzyme cinnamate decarboxylase converts p-coumaric acid to 4-vinylphenol. 4-Vinylphenol is further reduced to 4-ethylphenol ...
Decarboxylation gives 4-vinylphenol as catalyzed by the enzyme cinnamate decarboxylase. 4-Vinylphenol is further reduced to 4- ...
The same study of methyl cinnamate did not show this effect. It has also been shown that this oil can reduce the chance of ... The taste of Ecuadorian cinnamon is thought to come from the presence of methyl cinnamate and trans-cinnamaldehyde which are ...
Mandelate also arises from trans-cinnamate via phenylacetic acid, which is hydroxylated. Phenylpyruvic acid is another ...
The yeast converts this to 4-vinylphenol via the enzyme cinnamate decarboxylase. 4-Hydroxycinnamate decarboxylase can also be ...
The second mechanism involves two cinnamate units coupled together by malonyl-CoA. Both use cinnamic acid as their starting ...