Top 50 Articles of 2016: Organic Chemistry Home
Rh(III)-catalyzed diastereoselective C-H bond addition/cyclization cascade of enone tethered aldehydes Jeffrey A. Boerth and ...
A three-component reaction of arynes, sodium sulfinates, and aldehydes toward 2-sulfonyl benzyl alcohol derivatives - Organic &...
... and aldehydes under mild reaction conditions is described. This transformation provides a direct synthetic approach to 2- ... A three-component reaction of arynes, sodium sulfinates, and aldehydes toward 2-sulfonyl benzyl alcohol derivatives† ... A three-component reaction of arynes, sodium sulfinates, and aldehydes toward 2-sulfonyl benzyl alcohol derivatives Y. Hu, Y. ... A novel three-component reaction of arynes, sodium sulfinates, and aldehydes under mild reaction conditions is described. This ...
Copper-catalyzed highly efficient oxidative amidation of aldehydes with 2-aminopyridines in an aqueous micellar system - Green...
... amides from aldehydes and 2-aminopyridines has been developed under mild reaction conditions. This approach requires Cu(OTf)2 ... Copper-catalyzed highly efficient oxidative amidation of aldehydes with 2-aminopyridines in an aqueous micellar system† ... An environmentally benign protocol for the synthesis of N-(pyridine-2-yl)amides from aldehydes and 2-aminopyridines has been ... Copper-catalyzed highly efficient oxidative amidation of aldehydes with 2-aminopyridines in an aqueous micellar system O. P. S ...
Editor's Choice: Main group reagents and catalysts in organic reactions Home
The air-stable Lewis acid [(terpy)PPh][B(C6F5)4]21 mediates the hydrosilylation of aldehydes, ketones, and olefins. The ... Silylene induced cooperative B-H bond activation and unprecedented aldehyde C-H bond splitting with amidinate ring expansion V ... A Lewis acidic cationic organoaluminum catalyst is demonstrated to perform aldehyde dimerization and ketone hydrosilylation via ... Silylene mediated B-H and aldehyde C-H bond splitting were realized under ambient conditions. ...
Combining experiment and theory to elucidate the role of supercritical water in sulfide decomposition - Physical Chemistry...
The aldehyde quickly decomposes into CO plus pentane by radical reactions. The time is ripe for quantitative modelling of ... The mercaptoalcohol decomposes into an aldehyde and H2S either directly or via a water-catalyzed 6-membered ring transition ...
HOx radical regeneration in isoprene oxidation via peroxy radical isomerisations. II: experimental evidence and global impact -...
aldehydes (PACALDs) is shown to generate ample additional OH. . Global modeling demonstrates the major importance of the new ...
Organocatalytic oxa-Diels-Alder reaction of α,β-unsaturated ketones under non-classical conditions - New Journal of Chemistry ...
Oxa-Diels-Alder reaction of acyclic α,β-unsaturated ketones with aldehydes is a challenging transformation that affords ... Oxa-Diels-Alder reaction of acyclic α,β-unsaturated ketones with aldehydes is a challenging transformation that affords ...
Directing transition metal-based oxygen-functionalization catalysis - Chemical Science (RSC Publishing) DOI:10.1039/D1SC01272J
... aldehyde, and acetal. Fig. 8a shows the proposed mechanism of the production of ester products. By passing an electric current ... such as aldehydes, acids, alcohols, epoxides, and ketones.14 Here, we categorize non-electrochemical oxygen functionalization ... aldehydes, and carboxylic acids. Notably, the anodic oxidation of these low-cost unsaturated hydrocarbons can proceed with or ... which strongly favored the selectivity of aldehydes. However, for the oxidation of secondary alcohols, the Au catalyst acted as ...
2020 Frontier and Perspective articles Home
Not just hilariously effective baits! Rare-earth-metal compounds selectively react with aldehydes, ketones and carbon dioxide ...
Investigating templating within Polymer-Scaffolded Dynamic Combinatorial Libraries - Polymer Chemistry (RSC Publishing)
... have been prepared in aqueous solution by the reversible conjugation of two different acylhydrazide residues onto aldehyde- ... aldehyde. -functionalized dimethylacrylamide-based polymer scaffolds. PS-DCLs have been shown by 1H NMR. spectroscopic analysis ... aldehyde. functionalized monomer and the extent of amplification of the preferred residue upon template addition has also been ... aldehyde. functionalities, affect the behaviour of resultant PS-DCLs is detailed. Increasing the molecular weight of the ...
Unlocking the catalytic potential of tris(3,4,5-trifluorophenyl)borane with microwave irradiation - Chemical Communications ...
Under conventional conditions, the borane was found to be active only in the hydroboration of aldehyde, ketone and imine ... Under conventional conditions, the borane was found to be active only in the hydroboration of aldehyde, ketone and imine ...
Synthetic studies toward the brasilinolides: controlled assembly of a protected C1-C38 polyol based on fragment union by...
Throughout this work, asymmetric boron-mediated aldol reactions of chiral ketones with aldehydes proved effective both for ...
Two-photon, red light uncaging of alkyl radicals from organorhodium(iii) phthalocyanine complexes - Chemical Communications ...
... phthalocyanine complexes was found to induce the activation of the axial metal-carbon bond to generate alkyl radicals/aldehydes ... phthalocyanine complexes was found to induce the activation of the axial metal-carbon bond to generate alkyl radicals/aldehydes ...