• 3 CF 3COOCOCF 3 + 4 Na 2CO 3·1+1⁄2H 2O 2 → 6 CF 3COOOH + 4 Na 2CO 3 + 3 H 2O Trifluoroperacetic acid can also be generated in situ, allowing it to react promptly with the target substrate rather than pre-synthesizing a batch of the reagent for later use. (wikipedia.org)
  • The reaction uses the urea·hydrogen peroxide addition complex as a peroxide source for the in situ generation of trifluoroperacetic acid. (brad.ac.uk)
  • Reacting trifluoroacetic anhydride with sodium percarbonate, 2Na 2CO 3·3H 2O 2, yields trifluoroperacetic acid and sodium carbonate, obviating the need for an additional buffer. (wikipedia.org)
  • Sodium Percarbonate is a chemical, an adduct of sodium carbonate and hydrogen peroxide (a per hydrate), with formula 2Na2CO3 • 3H2O2. (niir.org)
  • it provides a convenient and cheap approach to this reagent without the need to obtain highly concentrated hydrogen peroxide. (niir.org)
  • Emmons is remembered in part as the pioneer and developer of trifluoroperacetic acid as a laboratory reagent, which has since become useful as a reagent for many different types of synthetic reactions. (wikipedia.org)
  • The hypervalent compound is accessible in two ways, and which is chosen usually depends on what materials are available: it can be prepared from its acetate analogue by an exchange reaction, or by reacting iodobenzene with a combination of trifluoroperacetic acid and trifluoroacetic acid: Trifluoroperacetic acid is one of the strongest reagents used for Baeyer-Villiger oxidations, as a consequence of its high acidity relative to similar peracids and peroxides. (wikipedia.org)