In the industrially important Wacker process, ethylene is converted to acetaldehyde via nucleophilic attack of hydroxide on a Pd(II)-ethylene intermediate followed by formation of a vinyl alcohol complex. (wikipedia.org)
The nucleophilic addition between indoles with vinylene carbonate proceeded smoothly in the presence of K2CO3 as the catalyst to produce novel indolyl-containing skeletons and 4-indolyl-1,3-dioxolanones in satisfactory to excellent yields (up to >97% yield). (bvsalud.org)
Complexes2
Allyl compounds with suitable leaving groups react with palladium(II) salts to pi-allyl complexes having hapticity 3. (wikipedia.org)
Various organic groups can bound to palladium and form stable sigma-bonded complexes. (wikipedia.org)
Reaction1
Uses of 2-Deoxy-D-ribose: it can be used to produce lithium 2-deoxy-D-erythro-pentonate at temperature of 40 °C. This reaction will need reagent 3 M KOH, 30 percent H 2 O 2 , MgO, 0.1 M LiOH with reaction time of 18 hours. (lookchem.com)
Acid1
A cooperative catalytic process through Palladium and Brønsted acid activation has been developed for the conjugate addition of cyclic ß -keto esters 2 to azoalkenes 1 directly followed by hemiaminal formation upon cyclization. (uni-leipzig.de)
Process2
This process involves the formation of a palladium-carbon covalent bond. (wikipedia.org)
1956 - In the Wacker process ethylene and oxygen react to acetaldehyde with catalyst PdCl2/CuCl2 1957 - Tetrakis(triphenylphosphine)palladium(0) is reported by Malatesta and Angoletta. (wikipedia.org)
Good1
Palladium(II) acetate and related compounds are common reagents because the carboxylates are good leaving groups with basic properties. (wikipedia.org)
Class2
This chemistry forms the basis of a large class of organic reactions called coupling reactions (see palladium-catalyzed coupling reactions). (wikipedia.org)
1,3-Oxathiolan-5-ones are a hitherto very poorly studied class of sulfur heterocycles some of which have been shown to be important precursors for HIV drugs or bioactive, anticarcinogenic compounds. (uni-leipzig.de)
Organopalladium chemistry is a branch of organometallic chemistry that deals with organic palladium compounds and their reactions. (wikipedia.org)
Palladium(II) acetate and related compounds are common reagents because the carboxylates are good leaving groups with basic properties. (wikipedia.org)
Allyl compounds with suitable leaving groups react with palladium(II) salts to pi-allyl complexes having hapticity 3. (wikipedia.org)
Zerovalent Pd(0) compounds include tris(dibenzylideneacetone)dipalladium(0) and tetrakis(triphenylphosphine)palladium(0). (wikipedia.org)
Palladium compounds owe their reactivity to the ease of interconversion between Pd(0) and palladium(II) intermediates. (wikipedia.org)
The compounds associated with a positive aroma were trimethyl orthoacetate, styrene, tridecan-7-amine and acetaldehyde, while compounds related to B. cinerea were hepten-2-one and butanoic acid. (bvsalud.org)
Stable2
Various organic groups can bound to palladium and form stable sigma-bonded complexes. (wikipedia.org)
In the reaction of 1,3-dienylboronic esters with nitrosoarenes, a one-pot hetero-Diels-Alder/ring contraction cascade affords N -arylpyrroles with low to good yields depending on the electronic properties of the substituents on the borodiene, whereas an sp 3 boron substituent led to the formation of stable boro-oxazines with high regioselectivity. (organic-chemistry.org)
Formation2
This process involves the formation of a palladium-carbon covalent bond. (wikipedia.org)
In the industrially important Wacker process, ethylene is converted to acetaldehyde via nucleophilic attack of hydroxide on a Pd(II)-ethylene intermediate followed by formation of a vinyl alcohol complex. (wikipedia.org)