• carbohydrate
  • Arriving in New Zealand in 1970 as Victoria University's first Chair of Organic Chemistry, Ferrier continued to lead work on the monosaccharides, specialising in their use as starting materials for the synthesis of non-carbohydrate compounds of pharmaceutical interest. (wikipedia.org)
  • anomeric
  • While most studies on the anomeric effects have been theoretical in nature, the n-σ* (hyperconjugation) hypothesis has also been extensively criticized on the basis that the electron density redistribution in acetals proposed by this hypothesis is not congruent with the known experimental chemistry of acetals and, in particular, the chemistry of monosaccharides. (wikipedia.org)
  • The number of monosaccharides, ring size, the different anomeric stereochemistry, and the existence of the branched-chain sugars all contribute to the amazing complexity of the oligosaccharide structures. (wikipedia.org)
  • cellulose
  • Monosaccharides attached to cellulose conjugates as ester-appended aldohexoses and ketohexoses were prepared on cotton gauze as monosccharide-citrate-cellulose-esters for HNE sequestration. (mdpi.com)
  • The monosaccharide-cellulose analogs demonstrated selective binding when the derivatized cotton dressings were measured for sequestration of HNE. (mdpi.com)
  • Each monosaccharide-cellulose conjugate was prepared as a cellulose citrate-linked monosaccharide ester on the cotton wound dressing, and assayed under wound exudate-mimicked conditions for elastase sequestration activity. (mdpi.com)
  • The monosaccharide cellulose conjugate families each gave distinctive profiles in elastase-lowering effects. (mdpi.com)
  • Possible mechanisms of elastase binding to the monosaccharide-cellulose conjugates are discussed. (mdpi.com)
  • Thus
  • Thus, monosaccharide-induced lipogenesis reduced hepatic HNF-4α levels, which in turn attenuated SHBG expression. (jci.org)
  • chemistry
  • His reviews were of particular benefit to the chemical community but perhaps of most value was the book "Monosaccharide Chemistry, written with Dr Peter Collins in 1972 and majorly updated as "Monosaccharides: Their chemistry and their roles in natural products in 1995. (wikipedia.org)
  • derivatives
  • Several derivatives of monosaccharides are important. (britannica.com)
  • Recently, digitoxin and several of its novel synthetic derivatives, such as -L-rhamnose monosaccharide derivative (D6-MA), have been synthesized and studied for their profound anticancer activity in various cancer cell lines. (cdc.gov)
  • concentration
  • The close parallelism between the effects of buffer salt type and concentration, monosaccharide structure and temperature activation on autoxidation and NADPH oxidation imply that autoxidation is a prerequisite for the NADPH oxidation, probably via the hydroperoxy radical. (biochemj.org)
  • Smaller nanoparticles were formed at high pH levels due to the concentration of the monosaccharides. (wikipedia.org)
  • aldose
  • Low apparent aldose reductase activity, as measured by NADPH oxidation, can be produced by the spontaneous autoxidation of monosaccharides. (biochemj.org)
  • Glutathione reductase-catalysed NADPH oxidation in the presence of autoxidizing monosaccharide showed many characteristics of the aldose reductase reaction. (biochemj.org)
  • These results indicate that low apparent aldose reductase activities may be due to artifacts of monosaccharide autoxidation, and could provide an explanation for the non-linear steady-state kinetics observed with DL-glyceraldehyde and aldose reductase. (biochemj.org)
  • If the carbonyl is at the very beginning of the chain (carbon 1), the monosaccharide is said to be an aldose, otherwise it is a ketose. (wikipedia.org)
  • Different
  • Monosaccharides are used in a number of different ways, including: (a) acting as a ligand for the metal, (b) providing the appropriate reduction potential for a chemical process and (c) acting as a reducing agent for the formation and stabilization of catalytically active metal nanoparticles. (hud.ac.uk)
  • human
  • Monosaccharide digitoxin derivative sensitize human non-small cell lung cancer cells to anoikis through Mcl-1 proteasomal degradation. (cdc.gov)