• anomeric
  • While most studies on the anomeric effects have been theoretical in nature, the n-σ* (hyperconjugation) hypothesis has also been extensively criticized on the basis that the electron density redistribution in acetals proposed by this hypothesis is not congruent with the known experimental chemistry of acetals and, in particular, the chemistry of monosaccharides. (wikipedia.org)
  • Thus
  • Thus, monosaccharide-induced lipogenesis reduced hepatic HNF-4α levels, which in turn attenuated SHBG expression. (jci.org)
  • chemistry
  • His reviews were of particular benefit to the chemical community but perhaps of most value was the book "Monosaccharide Chemistry, written with Dr Peter Collins in 1972 and majorly updated as "Monosaccharides: Their chemistry and their roles in natural products in 1995. (wikipedia.org)
  • derivatives
  • Several derivatives of monosaccharides are important. (britannica.com)
  • Recently, digitoxin and several of its novel synthetic derivatives, such as -L-rhamnose monosaccharide derivative (D6-MA), have been synthesized and studied for their profound anticancer activity in various cancer cell lines. (cdc.gov)
  • concentration
  • The close parallelism between the effects of buffer salt type and concentration, monosaccharide structure and temperature activation on autoxidation and NADPH oxidation imply that autoxidation is a prerequisite for the NADPH oxidation, probably via the hydroperoxy radical. (biochemj.org)
  • Smaller nanoparticles were formed at high pH levels due to the concentration of the monosaccharides. (wikipedia.org)
  • aldose
  • Low apparent aldose reductase activity, as measured by NADPH oxidation, can be produced by the spontaneous autoxidation of monosaccharides. (biochemj.org)
  • Glutathione reductase-catalysed NADPH oxidation in the presence of autoxidizing monosaccharide showed many characteristics of the aldose reductase reaction. (biochemj.org)
  • These results indicate that low apparent aldose reductase activities may be due to artifacts of monosaccharide autoxidation, and could provide an explanation for the non-linear steady-state kinetics observed with DL-glyceraldehyde and aldose reductase. (biochemj.org)
  • If the carbonyl is at the very beginning of the chain (carbon 1), the monosaccharide is said to be an aldose, otherwise it is a ketose. (wikipedia.org)
  • Different
  • Monosaccharides are used in a number of different ways, including: (a) acting as a ligand for the metal, (b) providing the appropriate reduction potential for a chemical process and (c) acting as a reducing agent for the formation and stabilization of catalytically active metal nanoparticles. (hud.ac.uk)
  • Cells
  • Moreover, inhibition of lipogenesis prevented monosaccharide-induced downregulation of HNF-4α and reduced SHBG expression in HepG2 cells. (jci.org)
  • Monosaccharide digitoxin derivative sensitize human non-small cell lung cancer cells to anoikis through Mcl-1 proteasomal degradation. (cdc.gov)