• CYP2E1
  • In the conversion sequence of acetyl-CoA to glucose, CYP2E1 transforms acetone via hydroxyacetone (acetol) into propylene glycol and methylglyoxal, the precursors of pyruvate, acetate and lactate. (wikipedia.org)
  • unreactive
  • This reaction gives ethanol and sodium acetate, which is unreactive toward ethanol: CH3CO2C2H5 + NaOH → C2H5OH + CH3CO2Na The rate constant is 0.111 L/mol·s at 25 °C.[citation needed] The LD50 for rats is 5620 mg/kg, indicating low toxicity. (wikipedia.org)
  • catalyst
  • Byproducts of the dehydrogenation include diethyl ether, which is thought to arise primarily due to aluminum sites in the catalyst, acetaldehyde and its aldol products, higher esters, and ketones. (wikipedia.org)
  • catalytic activity
  • Pd + 4 HNO3 → Pd(NO3)2 + 2 NO2 + 2 H2O Pd(NO3)2 + 2 CH3COOH → Pd(O2CCH3)2 + 2 HNO3 Relative to the trimeric acetate, the mixed nitrate-acetate variant has different solubility and catalytic activity. (wikipedia.org)
  • Scientists
  • Scientists discovered that acetaldehyde can break and damage DNA within blood stem cells, causing rearranged chromosomes as well as permanently altering the DNA sequences within these cells. (rt.com)
  • metallic
  • The sensory threshold for acetaldehyde is 100-125 mg/L. Beyond this level it imparts a sherry type character to the wine which can also be described as green apple, sour and metallic. (wikipedia.org)
  • symptoms
  • therefore, it's believed that in order to reduce hangover symptoms, drinkers need to reduce the time acetaldehyde is present in the body. (cbslocal.com)
  • In these people, acetaldehyde accumulates after drinking alcohol, leading to symptoms of acetaldehyde poisoning, including the characteristic flushing of the skin and increased heart and respiration rates. (wikipedia.org)
  • chemical
  • Palladium(II) acetate is a chemical compound of palladium described by the formula [Pd(O2CCH3), abbreviated [Pd(OAc). (wikipedia.org)
  • This enzyme catalyses the following chemical reaction cobalt-precorrin-5A + H2O ⇌ {\displaystyle \rightleftharpoons } cobalt-precorrin-5B + acetaldehyde + 2 H+ This enzyme hydrolyses the ring A acetate delta-lactone of cobalt-precorrin-5A. (wikipedia.org)
  • reaction
  • For example, phenylpalladium acetate, used to isomerize allyl alcohols to aldehydes, is prepared by the following reaction: Hg(C6H5)(OAc) + Pd(OAc)2 → Pd(C6H5)(OAc) + Hg(OAc)2 Palladium(II) acetate reacts with acetylacetone (the "acac" ligand) to produce Pd(acac)2. (wikipedia.org)
  • important
  • Preventing, or controlling for the amount of, this impurity can be an important aspect for reliable use of palladium(II) acetate. (wikipedia.org)
  • forms
  • With a 1:2 stoichiometric ratio of palladium atoms and acetate ligands, the compound exists as molecular and polymeric forms. (wikipedia.org)
  • groups
  • It has a trimeric structure, consisting of an equilateral triangle of Pd atoms each pair of which is bridged with two acetate groups in a butterfly conformation. (wikipedia.org)
  • reduce
  • Light or heat reduce palladium acetate to give thin layers of palladium and can produce nanowires and colloids. (wikipedia.org)
  • production
  • Other uses of polyvinyl alcohol include: Injection moulding of soluble containers for active release of detergents and agrichemicals Paper adhesive with boric acid in spiral tube winding and solid board production Thickener, modifier, in polyvinyl acetate glues Textile sizing agent Paper coatings, release liner As a water-soluble film useful for packaging. (wikipedia.org)