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  • CYP2E1
  • In the conversion sequence of acetyl-CoA to glucose, CYP2E1 transforms acetone via hydroxyacetone (acetol) into propylene glycol and methylglyoxal, the precursors of pyruvate, acetate and lactate. (wikipedia.org)
  • unreactive
  • This reaction gives ethanol and sodium acetate, which is unreactive toward ethanol: CH3CO2C2H5 + NaOH → C2H5OH + CH3CO2Na The rate constant is 0.111 L/mol·s at 25 °C.[citation needed] The LD50 for rats is 5620 mg/kg, indicating low toxicity. (wikipedia.org)
  • catalyst
  • Byproducts of the dehydrogenation include diethyl ether, which is thought to arise primarily due to aluminum sites in the catalyst, acetaldehyde and its aldol products, higher esters, and ketones. (wikipedia.org)
  • catalytic activity
  • Pd + 4 HNO3 → Pd(NO3)2 + 2 NO2 + 2 H2O Pd(NO3)2 + 2 CH3COOH → Pd(O2CCH3)2 + 2 HNO3 Relative to the trimeric acetate, the mixed nitrate-acetate variant has different solubility and catalytic activity. (wikipedia.org)
  • Scientists
  • Scientists discovered that acetaldehyde can break and damage DNA within blood stem cells, causing rearranged chromosomes as well as permanently altering the DNA sequences within these cells. (rt.com)
  • metallic
  • The sensory threshold for acetaldehyde is 100-125 mg/L. Beyond this level it imparts a sherry type character to the wine which can also be described as green apple, sour and metallic. (wikipedia.org)
  • chemical
  • Palladium(II) acetate is a chemical compound of palladium described by the formula [Pd(O2CCH3), abbreviated [Pd(OAc). (wikipedia.org)
  • This enzyme catalyses the following chemical reaction cobalt-precorrin-5A + H2O ⇌ {\displaystyle \rightleftharpoons } cobalt-precorrin-5B + acetaldehyde + 2 H+ This enzyme hydrolyses the ring A acetate delta-lactone of cobalt-precorrin-5A. (wikipedia.org)
  • reaction
  • For example, phenylpalladium acetate, used to isomerize allyl alcohols to aldehydes, is prepared by the following reaction: Hg(C6H5)(OAc) + Pd(OAc)2 → Pd(C6H5)(OAc) + Hg(OAc)2 Palladium(II) acetate reacts with acetylacetone (the "acac" ligand) to produce Pd(acac)2. (wikipedia.org)
  • effects
  • The increased ethanol metabolism, in turn, leads to alteration of the redox balance of the cells and impairment of RXR/PPAR functions by direct and indirect effects of acetaldehyde, resulting in deranged lipid metabolism, oxidative stress, and release of proinflammatory cytokines. (hindawi.com)
  • important
  • Preventing, or controlling for the amount of, this impurity can be an important aspect for reliable use of palladium(II) acetate. (wikipedia.org)
  • forms
  • With a 1:2 stoichiometric ratio of palladium atoms and acetate ligands, the compound exists as molecular and polymeric forms. (wikipedia.org)
  • reduce
  • Light or heat reduce palladium acetate to give thin layers of palladium and can produce nanowires and colloids. (wikipedia.org)
  • groups
  • It has a trimeric structure, consisting of an equilateral triangle of Pd atoms each pair of which is bridged with two acetate groups in a butterfly conformation. (wikipedia.org)