• enzymology
  • In enzymology, an aldehyde ferredoxin oxidoreductase (EC 1.2.7.5) is an enzyme that catalyzes the chemical reaction an aldehyde + H2O + 2 oxidized ferredoxin ⇌ {\displaystyle \rightleftharpoons } an acid + 2 H+ + 2 reduced ferredoxin This enzyme belongs to the family of oxidoreductases, specifically those acting on the aldehyde or oxo group of donor with an iron-sulfur protein as acceptor. (wikipedia.org)
  • chiral
  • To date, all practical methods for the preparation of chiral a-sulfenylated aldehydes have been multistep procedures that involve chiral auxiliaries. (docme.ru)
  • Asymmetric Catalysis Enantioselective Organocatalyzed a Sulfenylation of Aldehydes** Mauro Marigo, Tobias C. Wabnitz, Doris Fielenbach, and Karl Anker Jørgensen* Optically active a-heterosubstituted aldehydes are versatile building blocks for the synthesis of chiral molecules that bear heteroatom functionalities. (docme.ru)
  • molecule
  • Aldehydes have properties that are diverse and that depend on the remainder of the molecule. (wikipedia.org)
  • The active site binds to one molecule of an aldehyde and an NAD(P)+ that functions as a cofactor. (wikipedia.org)
  • Cyclamen aldehyde is a fragrance molecule which has been used in soaps, detergents, lotions and perfumes since the 1920s. (wikipedia.org)
  • anion
  • The anionic species formally derived from deprotonation of an aldehyde proton, known as an acyl anion, is highly unstable and must be kept at low temperatures. (wikipedia.org)
  • The Vanderwal group has also reported the synthesis of 4-stannyldienals from Zincke aldehydes by addition of tributylstannyl anion and quenching with acetyl chloride. (wikipedia.org)
  • group
  • Related to (i), the aldehyde group is somewhat polar . (wikipedia.org)
  • If the presence of another functional group demands the use of a suffix, the aldehyde group is named with the prefix formyl- . (wikipedia.org)
  • In 2009, the Vanderwal group reported another interesting rearrangement of Zincke aldehydes. (wikipedia.org)
  • The nomenclature is derived from the nomenclature of the alkanes, the ending -al is added to indicate the aldehyde group. (wikipedia.org)
  • Polyunsaturated aldehydes (PUAs) are a group of allelopathic chemicals typically associated with diatom-copepod predator-prey interactions. (wikipedia.org)
  • The aldehyde tag is a short peptide tag which can be introduced into fusion proteins and by subsequent treatment with the formylglycine-generating enzyme (FGE) a reactive aldehyde group is generated for further coupling. (wikipedia.org)
  • A carbonyl group is introduced into proteins as a chemical reporter using different techniques, including modern methods like stop codon suppression and the herein discussed aldehyde tag. (wikipedia.org)
  • This enzyme belongs to the family of oxidoreductases, specifically those acting on the aldehyde or oxo group of donor with NAD+ or NADP+ as acceptor. (wikipedia.org)
  • To provide for facile product elaboration, S-benzyl-protected a-sulfenylated aldehydes were chosen as synthetic targets, as there are well-established methods for the cleavage of this protecting group. (docme.ru)
  • Synthetic
  • Nouvelle méthode générale synthétique de préparation des aldéhydes" [Novel general synthetic method for preparing aldehydes]. (wikipedia.org)
  • chains
  • Since there already is an array of aldehyde-specific reagents commercially available (such as aminooxy or hydrazide reagents), possible applications are diverse and include the conjugation of fluorophores, glycans, PEG (polyethylene glycol) chains or reactive groups for further synthesis (see applications). (wikipedia.org)
  • Discrimination between aldehydes with longer carbon chains was reduced. (biologists.org)
  • species
  • Aldehyde oxidase is a member of the molybd-flavo protein family and has a very complex evolutionary profile-as the genes of AO varies according to animal species. (wikipedia.org)
  • Thalassiosira rotula represents the most well-studied diatom species in terms of polyunsaturated aldehyde production. (wikipedia.org)
  • alcohol
  • The word aldehyde was coined by Justus von Liebig as a contraction of the Latin al cohol dehyd rogenatus (dehydrogenated alcohol). (wikipedia.org)
  • The term aldehyde was coined in 1835 by von Liebig from the term dehydrogenated alcohol (alcohol dehydrogenatus). (perfumerflavorist.com)
  • addition
  • Upon addition of a N,N-disubstituted formamide (such as DMF) a hemiaminal is formed, which can easily be hydrolyzed into the desired aldehyde. (wikipedia.org)
  • processes
  • These genes participate in a wide variety of biological processes including the detoxification of exogenously and endogenously generated aldehydes. (wikipedia.org)
  • Zuschriften aldehydes and the merits of organocatalytic processes, which circumvent the undesired association of sulfur reagents with metal catalysts. (docme.ru)