... sometimes prepared in situ by reacting sodium cyanide with bromine). Alternate synthesis routes generally involve more steps, ... such as replacing cyanogen bromide with sodium or potassium cyanate to form an intermediate and then reacting it with ...
... silafluofen silica gel sodium arsenite sodium cyanide sodium fluoride sodium silicofluoride sodium tetrathiocarbonate sodium ... buprofezin butacarb butathiofos butethrin butocarboxim butonate butoxycarboxim cadusafos calcium arsenate calcium cyanide ... halofenozide HCH HEOD heptachlor heptafluthrin heptenophos heterophos hexaflumuron HHDN hydramethylnon hydrogen cyanide ...
... which included sodium cyanide (500 grams), diisopropyl fluorophosphate, and a range of corrosive acids. Subsequent analysis of ... When Helman was first questioned about the incident on March 7, he told police that he had only coated the card with sodium ... and police seized from him what appeared to be sodium hydroxide and a notebook with a ricin recipe. Helman was charged on March ...
... is produced from the reaction of the sodium salt of chloroacetic acid with sodium cyanide, which produces the ... The use of a conventional base may give base hydrolysis products - for example, sodium hydroxide would simply produce sodium ... Diethyl malonate can be nitrosated with excess sodium nitrite in acetic acid to afford diethyl oximinomalonate, catalytic ... sodium chloroacetate undergoes carboxyesterification by treatment with carbon monoxide and ethanol: ClCH2CO2Na + CO + 2 C2H5OH ...
... forming mandelonitrile with sodium cyanide, which is hydrolyzed: Alternatively, it can be prepared by base hydrolysis of ... Mandelonitrile can also be prepared by reacting benzaldehyde with sodium bisulfite to give the corresponding adduct, ...
Alkylation with iodomethane gave an intermediate quaternary ammonium salt which reacted with sodium cyanide in a nucleophilic ... Detosylation of 11 (sodium naphthalenide) and amidation with acid chloride 3-bromoacryloyl chloride gave amide 12 and another ... double bond isomerization (sodium / iPrOH), Boc group deprotection (triflic acid) and amine alkylation with (Z)-BrCH2CICH= ... Finally the newly formed double bond was reduced by sodium borohydride to indoline 9 with the C8 hydrogen atom approaching from ...
... with potassium cyanide or sodium thiosulfate) All of this was done in a matter of minutes, and some of the steps in (red) ...
Cyanide fishing is a method of collecting live fish mainly for use in aquariums, which involves spraying a sodium cyanide ... Recent studies have shown that the combination of cyanide use and stress of post capture handling results in mortality of up to ...
Racemic alanine can be prepared by the condensation of acetaldehyde with ammonium chloride in the presence of sodium cyanide by ... Alanine was first synthesized in 1850 when Adolph Strecker combined acetaldehyde and ammonia with hydrogen cyanide. The amino ...
... including the manufacture of sodium peroxide, a bleaching agent, and sodium cyanide which was used in the gold mining industry ... Sodium was relatively expensive at that time and Castner devised a process of producing it by the reduction of caustic soda ... Castner's only asset then was his cheap sodium and he worked to develop uses for this, ... this business around 1884 and worked to devise a process for manufacturing aluminium by reducing aluminium chloride with sodium ...
... cyanide, sodium sulphate and chloride. An Interim Action conducted under Agreed Order No. DE-5698 between the Port of Tacoma ... Aluminium, cyanide and fluoride salts were identified as the major toxic agents in SPL. The genotoxic potential of SPL and its ... Cyanide compounds form in the pot lining when nitrogen from air reacts with other substances. For example, nitrogen reacting ... Dissolved fluorides and cyanides from SPL that are placed in landfills, along with other leachates may have environmental ...
X-ray Fluorescence of Potassium Sodium Platinum Cyanide and Potassium Lithium Platinum Cyanide (1896) (Greek) Apparatus of the ...
The warehouse stored large quantities of toxic chemicals, including 700 tons of Sodium Cyanide, and the death toll from the ...
... calcium and sodium metals, formaldehyde, cyanide and other metals (i.e. antimony, mercury, arsenic, zinc, manganese, and iron ... cyanides and fluorides, and medium- and low-level radioactive wastes. Operation CHASE Marine debris MARPOL 73/78 (1973 & 1978 ...
10 February - Police arrests an archpriest of the Georgian Orthodox Church, accusing him of carrying sodium cyanide in his ...
... which with sodium cyanide, converts to 3-hexenedinitrile, which in turn can be hydrogenated to adiponitrile: ClCH2CH=CHCH2Cl + ...
... sodium, vanadium, and cyanide in Ikeya-Seki's coma. The properties of the ionized iron and nickel lines suggested Ikeya-Seki ... sodium, and other metals. Spectrograms were also obtained by a rocket launched from the White Sands Missile Range to observe ...
LLP has been established in October 2013 with the aim of organizing the production of 25 thousand tons of sodium cyanide per ... sodium cyanide, potassium sulfate, polypropylene and propylene oxide, glyphosate, calcium chloride, polyethylene, polyvinyl ...
Reaction of α,α′-dibromoadipic acid with sodium cyanide in ethanol yields the cyano cyclobutane: In the so-called Franchimont ... Though both nitriles and cyanides can be derived from cyanide salts, most nitriles are not nearly as toxic. The N−C−C geometry ... A commercial source for the cyanide group is diethylaluminum cyanide Et2AlCN which can be prepared from triethylaluminium and ... The first compound of the homolog row of nitriles, the nitrile of formic acid, hydrogen cyanide was first synthesized by C. W. ...
Sodium arsenate Sodium azide Sodium cacodylate Sodium cyanide Sodium fluoroacetate Sodium pentachlorophenate Sodium selenate ... Picrotoxin Piperidine Pirimifos-ethyl Plutonium Polonium-210 Potassium arsenite Potassium cyanide Potassium silver cyanide ... amine Valinomycin Vinyl acetate monomer Warfarin Warfarin sodium Xylylene dichloride Zinc phosphide List of highly toxic gases ... Benzotrichloride Benzyl chloride Benzyl cyanide Bicyclo(2.2.1)heptane-2-carbonitrile Bis(chloromethyl) ketone Bitoscanate Boron ...
Cyanide fishing is a method of collecting live fish mainly for use in aquariums, which involves spraying a sodium cyanide ...
... sodium cyanide, zinc sulfate or sulfuric acid. The spills began to clog the bay, and to generate a serious landscape and ...
... followed by exchange of the bromine atom for a cyano group by means of sodium cyanide." Milnacipran Dhir A, Kulkarni SK (June ...
A large quantity of sample (between 2 and 5 kg) is digested or leached with cold sodium cyanide (NaCN) solution (generally 0.1 ... The gold is dissolved through its formation of a cyanide complex, which is concentrated through the solvent exchange process ...
... sodium azide, sodium cyanide, mercury oxycyanide, cantharides, colchicine, powerful anticoagulants such as brodifacoum, ...
166 Leuchter also claimed that consultation relating to sodium cyanide and hydrogen cyanide with DuPont was "an on-going thing ... This would have severely affected his results, because unlike Prussian blue and other iron based cyanides, cyanide salts are ... However, residual iron-based cyanide compounds are not a categorical consequence of cyanide exposure. By not discriminating ... where no cyanides at all were detected. In addition, tests conducted at Auschwitz in 1945 revealed the presence of cyanides on ...
... such as sodium sulfide, cyanides, amines, etc. This: Removes the hair and other keratinous matter Removes some of the ... Once bating is complete, the hides and skins are treated by first soaking them in a bath containing common salt (sodium ... After application of the chromium agent, the bath is treated with sodium bicarbonate in the basification process to increase ...
... bond Triple bond Inorganic acid Organic ester Metal ester Organic carbonate Nitrile group Cyanide ion Perchlorate ion Sodium ... To understand how a chemical state differs from an oxidation state, anion, or cation, compare sodium fluoride (NaF) to ...
... which usually uses the chemical compound sodium cyanide Cyanide (2006 film), a 2006 Indian Kannada language film Cyanide (1930 ... Cyanide is a class of chemical compounds. Cyanide may also refer to: Cyanide poisoning, a form of poisoning that occurs when a ... "Cyanide", a song by Daniel Caesar from his album Case Study 01 (2019) Cyanide (company), a game development studio Cyanide ... "Cyanide", a song by Bad Religion from their album The Dissent of Man (2010) "Cyanide", a song by Deathstars from their album ...
Sodium azide is as toxic as sodium cyanide (with an oral LD50 of 27 mg/kg in rats) and can be absorbed through the skin. Heavy ... Sodium azide is made industrially by the reaction of nitrous oxide, N2O with sodium amide NaNH2 in liquid ammonia as solvent: ... the main product being sodium azide. Sodium azide NaN3 is the propellant in automobile airbags. It decomposes on heating to ... Heavy-metal azides are formed when solutions of sodium azide or HN3 vapors come into contact with heavy metals or their salts. ...
Classically acyl cyanides are produced by the salt metathesis reaction of acyl chlorides with sodium cyanide: R − C ( O ) Cl + ... attached to cyanide (−C≡N). Examples include acetyl cyanide, formyl cyanide, and oxalyl dicyanide. Acyl cyanides are reagents ... With aqueous base, acyl cyanides break down to cyanide and the carboxylate: R − C ( O ) CN + 2 NaOH ⟶ R − CO Na 2 + Na CN + H 2 ... In organic chemistry, an acyl cyanide is a functional group with the formula R−C(O)CN and structure R−C(=O)−C≡N. It consists of ...
Here it was reacted with an excess of sodium cyanide (5), dispersed in dry chlorobenzene, yielding the intermediate ... and hydrogen cyanide (9). After the reaction, the mixture (consisting of about 75% chlorobenzene and 25% tabun, along with ... was filtered to remove the insoluble salts and vacuum-distilled to remove hydrogen cyanide and excess chlorobenzene, so ... dimethylamidophosphoric dicyanide (not depicted in the scheme) and sodium chloride (8); then, absolute ethanol (6) was added, ...
More than 3 million gallons of cyanide, benzene, toluene, sodium copper(I) cyanide, polychlorinated biphenyls (PCBs) and other ...
... which restricted the usage of poisons such as strychnine and sodium cyanide for predator control. The report's visionary goal ...
... "relies on a 125-year-old method that treats gold-containing ore with large quantities of poisonous sodium cyanide... this new ... In 2015, Barrick Gold Corporation spilled over 1 million liters of cyanide into a total of five rivers in Argentina near their ... The extraction of target minerals by this technique requires that they be soluble, e.g., potash, potassium chloride, sodium ... "Exclusive: Barrick faces sanctions for Argentina cyanide spills". Reuters. 2017-05-08. Leppänen, Jaakko Johannes; Weckström, ...
This new method used ammonia and coal as starting materials and was able to meet the rising demands on sodium cyanide for the ... Cyanide patent[dead link] Works by or about George Beilby at Internet Archive (CS1 maint: archived copy as title, CS1 maint: ... He became director of the profitable Cassel Cyanide Company and then became a director of the Castner-Kellner Company at ... Inventor of Processes for the manufacture of cyanides, ammonia, fuel gas and paraffin oils, which have had an important ...
An example is gold cyanidation, where pulverized ores are extracted with a solution of sodium cyanide, which, in the presence ...
Na2CuCl4 Sodium cyanate - NaCNO Sodium cyanide - NaCN Sodium dichromate - Na2Cr2O7·2H2O Sodium dioxide - NaO2 Sodium dithionite ... NaNO3 Sodium nitrite - NaNO2 Sodium nitroprusside - Na2[Fe(CN)5NO]·2H2O Sodium oxide - Na2O Sodium perborate - NaBO3·H2O Sodium ... NaBH4 Sodium bromate - NaBrO3 Sodium bromide - NaBr Sodium bromite - NaBrO2 Sodium carbide - Na2C2 Sodium carbonate - Na2CO3 ... Sodium fluoride - NaF Sodium fluorosilicate - Na2[SiF6] Sodium formate - HCOONa Sodium hydride - NaH Sodium hydrogen carbonate ...
Cream Sodium Cyanide (青酸クリームソーダ, Seisan Kurimu Soda) (Kodansha, Tokyo, 2009) Short story collection Nine Stories (ナイン・ストーリーズ, ...
In June 1988 the EPA sent in teams to clean it up, finding an unsecured cylinder of hydrogen cyanide, remaining sodium metal, a ... Rain began to leak in, causing the sodium to explode and requiring the town to shelter in their homes while the fire was put ... In one infamous example, the company had agreed to dispose of the sodium coolant from the closed Fermi 1 nuclear reactor, which ...
... which further reacts with aqueous sodium cyanide to give the racemic product: Sigma-Aldrich product page The Merck Index (12th ... Mandelonitrile can break down into cyanide and benzaldehyde, a reaction that can be catalyzed by the enzyme mandelonitrile ... In a one pot reaction, benzaldehyde is reacted with sodium bisulfite to give the corresponding adduct, ...
Cyanide fishing is a method of collecting live fish mainly for use in aquariums, which involves spraying a sodium cyanide ... Recent studies have shown that the combination of cyanide use and stress of post capture handling results in mortality of up to ...
2 CO Sodium cyanide is used in cyanide process in gold mining. It can also be used in the preparation of calcium cyanide and ... In fact, the initial target product sodium cyanide can also be obtained from calcium cyanamide by melting it with sodium ... CaCO3 It was used to produce sodium cyanide by fusing with sodium carbonate: CaCN2 + Na2CO3 + 2 C → 2 NaCN + CaO + ... In their search for a new process for producing cyanides for cyanide leaching of gold, Frank and Caro discovered the ability of ...
Chaos", was arrested by Chicago police for hoarding potassium cyanide and sodium cyanide in a Chicago Transit Authority ... Chaos' a true danger: Cyanide suspect waives hearing, stays in custody". Milwaukee Journal Sentinel. Archived from the original ...
The ore will then be crushed to a size of 3/4 inch and sent to a heap leach, where a sodium cyanide solution would be used to ... Cyanide, a toxin, would be used to separate the silver from the rock. Prior to regional protests against mining, construction ...
... and are forced to resort to the illegal use of sodium cyanide due to demand and high prices offered by the industry.[citation ... The process of cyanide fishing involves dissolving crushed cyanide tablets and squirting this solution from a bottle toward the ... The use of cyanide makes a stronger argument in that the more coral reef fish captured alive, the more lucrative the catch is ... The cyanide fishers profit by taking away from everyone else's trade and food. 'If people were using poison and my take dropped ...
"You had sodium cyanide around, and I'm sure it was in the bomb." However, while the bomb's true composition was not able to be ... "no forensic evidence indicating the presence of sodium cyanide at the bomb site." Furthermore, Yousef is said only to have ... There was a popular belief at the time that there was cyanide in the bomb, which was reinforced by Judge Duffy's statement at ... considered adding cyanide to the bomb, and to have regretted not doing so in Peter Lance's book 1000 Years for Revenge. Six ...
... generated by the reaction of an aqueous solution of sodium cyanide and DA (DC process, NaCN method), with cyanide being used in ... An idealized equation is shown: Ph2AsO2H + SO2 + HCl → Ph2AsCl + H2SO4 The process adopted by Edgewood Arsenal, the "sodium ... used the Sandmeyer reaction between phenyldiazonium chloride and sodium arsenite. The acidified product was reduced and then ... of DA for chemical warfare purposes employed a reaction between chlorobenzene and arsenic trichloride in the presence of sodium ...
In her Preface, the author thanks Robin Page "for his advice on sodium cyanide", Guy Cotteril "for his plan of the Temple", and ... Moreover, Alleyn finds an old book in Garnette's quarters that opens up to a page on how to make cyanide at home. The book ... which proves to contain cyanide. Bathgate, the 'Watson' of Alleyn's early cases, attaches himself to the police investigation ... leading Alleyn to believe one of the initiates dropped the cyanide into the goblet in that manner. ...
... sodium cyanide production facilities in Western Australia, PVC resin and specialty chemicals production facilities in Victoria ...
West Cape Three Points in Ghana and the spillage of sodium cyanide in a water body in Kenyase, Ghana, by Newmont Ghana Gold ... West Cape Three Points in Ghana and the spillage of Sodium Cyanide in a Water Body in Kenyase, Ghana, by Newmont Ghana Gold ...
... and aqueous sodium cyanide injection into the whole animal and in vitro slice preparation. These methods can be used to mimic ...
... including using explosives and sodium cyanide. After campus protests, some of South Africa's most prestigious universities ...
... in the Unified Soil Classification System Sodium cyanide Switched capacitor, an electronic circuit element implementing a ...
From 1983-86 the Northern Queensland Gold Company Ltd conducted agglomeration heap-leaching (spraying a sodium cyanide solution ... The cyanide works (of which remnants still remain south of Elphinstone Creek) was erected c. 1904. The cyanide works were not ... the on-ground cyanide agitator to the north retains its internal mechanism and the cyanide cone to the south is suspended on ... and a rectangular cyanide tank divided into five bays. Additional plant - an Oliver filter unit (north of the cyanide tanks); a ...
The executioner pulled the lever three minutes later and 16 pellets of sodium cyanide dropped into a vat of sulfuric acid as ...
... itself prepared by the analogous reaction of benzyl bromide with sodium cyanide. Manipulation of functional groups can lead to ... In this case, the cyanide anion is the synthetic equivalent for the −COOH synthon, while benzyl bromide is the synthetic ... 4, p. 760 Roger Adams; A. F. Thal (1941). "Benzyl Cyanide". Organic Syntheses.{{cite journal}}: CS1 maint: multiple names: ... phenylacetic acid has been synthesized from benzyl cyanide, ...
p. 65) set to the tune of that jig, which begins "Paradimethylaminobenzaldehyde, / Sodium citrate, ammonium cyanide, / ..." ...