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*  Rotaxane
"Rotaxane by capping". youtube.com. Romero, Antonio. "Rotaxane by capping 3d". Rotaxane by capping 3d. 3D video. "The Nature of ... These rotaxane machines can be manipulated both by chemical and photochemical inputs. Rotaxane based systems have also been ... Therefore, the graphical representation of rotaxane displayed above would be a [2]rotaxane as it consists of a single dumbbell ... rotaxanes, [3]rotaxanes, and molecular shuttles, and some observations on the mechanism of the Cu(I)-catalyzed azide-alkyne 1,3 ...
*  Polyrotaxane
Through polymerizing stable rotaxane monomers, polyrotaxanes are obtained. This method requires that the monomeric rotaxane ... in which the rotaxane units locate on the main chain (axis), and side chain polyrotaxanes, in which the rotaxane units are ... Poly[2]rotaxane "daisy chains" (like a string of daisies with stems linked to form a chain)is an example of a molecule that can ... Poly[2]rotaxane can expand or shrink in response to external stimulus, which is similar to behaviors of muscle, a ideal model ...
*  Ribosomally synthesized and post-translationally modified peptides
Additionally, lasso peptides are formally rotaxanes. The N-terminal "ring" can be from 7 to 9 amino acids long and is formed by ...
*  Supramolecular chemistry
Examples of mechanically interlocked molecular architectures include catenanes, rotaxanes, molecular knots, molecular Borromean ... synthesis of rotaxanes), and may include some covalent chemistry that goes along with the supramolecular. In addition, the ... Rotaxanes". European Journal of Organic Chemistry. 1998 (11): 2565-2571. doi:10.1002/(SICI)1099-0690(199811)1998:11. 3.0.CO;2-8 ...
*  Viologen
Rotaxanes". Eur. J. Org. Chem. 1998 (11): 2565-2571. doi:10.1002/(SICI)1099-0690(199811)1998:11. 3.0.CO;2-8. Burgess, Mark; ...
*  Vincenzo Balzani
1. [2]Rotaxanes and a [2]catenane made to order. In: Journal of the American Chemical Society 114, Issue 1, (1992), 193-218, ...
*  Cyclodextrin
In particular they have been used to synthesize certain mechanically interlocked molecular architectures, such as rotaxanes and ... "Synthesis of fluorescent stilbene and tolan rotaxanes by Suzuki coupling". Chemical Communications (5): 493. doi:10.1039/ ...
*  Harry Anderson (chemist)
Stanier, C. A.; o'Connell, M. J.; Anderson, H. L.; Clegg, W. (2001). "Synthesis of fluorescent stilbene and tolan rotaxanes by ...
*  Cucurbituril
More recently, rotaxane with a CB[8] wheel was synthesized. This rotaxane can bind neutral guest molecules. Cucurbituril's host ... In another rotaxane system with a CB[7] wheel, the axle is a 4,4'-bipyridinium or viologen subunit with two carboxylic acid ... the first step to the formation of rotaxanes and polyrotaxenes of thepolyester type Hans-Jürgen Buschmann, Klaus Jansen, ... their high affinities to form inclusion complexes cucurbiturils have been employed as the macrocycles component of a rotaxane. ...
*  Steric effects
This is the effect responsible for the observed shape of rotaxanes. When a Lewis acid and Lewis base cannot combine due to ...
*  Mechanically interlocked molecular architectures
Therefore if the ring in a rotaxane is made smaller the strength of non-covalent interactions increases, the same effect is ... Because of this effect hydrogenation of an alkene on the thread of a rotaxane is significantly slower as compared to the ... Rotaxane Catenane Molecular knot Molecular Borromean rings Browne, Wesley R.; Feringa, Ben L. (2006). "Making molecular ... The introduction of a mechanical bond alters the chemistry of the sub components of rotaxanes and catenanes. Steric hindrance ...
*  Catenane
Safarowsky, O.; Windisch, B.; Mohry, A.; Vögtle, F. (June 2000). "Nomenclature for Catenanes, Rotaxanes, Molecular Knots, and ... such as rotaxanes, molecular knots or molecular Borromean rings. Recently the terminology "mechanical bond" has been coined ...
*  Kinetic isotope effect
Another example of the steric isotope effect is in the deslipping reaction of rotaxanes. The deuterium isotope, due to its ... Felder, T.; Schalley, C. A. (2003). "Secondary Isotope Effects on the Deslipping Reaction of Rotaxanes: High-Precision ... resulting in faster rates of deslipping for the deuterated rotaxanes. Reactions are known where the deuterated species reacts ...
*  Molecular machine
A common molecular shuttle consists of a rotaxane where the macrocycle can move between two sites or stations along the ... such as rotaxanes and catenanes. Carbon nanotube nanomotors have also been produced. Molecular motors are molecules that are ... theoretical modeling can be extremely useful to understand the self-assembly/disassembly processes of rotaxanes, important for ...
*  Copper
"Cadiot-Chodkiewicz Active Template Synthesis of Rotaxanes and Switchable Molecular Shuttles with Weak Intercomponent ...
*  Molecular knot
in Angewandte Chemie International Edition in 2000 by analogy with rotaxane and catenane. The term, however, has yet to be ...
*  Nicola Armaroli
3.0.CO;2-Z. Nicola Armaroli et al., Rotaxanes Incorporating Two Different Coordinating Units in Their Thread: Synthesis and ...
*  Cyclobis(paraquat-p-phenylene)
The modifications include mechanically entrapped compounds such as catenanes and rotaxanes, molecular switches and larger ...
*  Pillararene
... rotaxanes Using a Cooperative Capture Strategy. Chem. Commun. 2014, 50, 6196-6199. Li, H.; Chen, D.-X.; Sun, Y.-L.; Zheng, Y. B ... arene as a Co-Factor in Templating Rotaxane Formation. J. Am. Chem. Soc. 2013, 135, 17019-17030. Xue, M.; Yang, Y.; Chi, X.; ...
*  Interlock (disambiguation)
Catenane and Rotaxane molecules, and Molecular knot Interlock fabric, a double-knitted jersey fabric. Interlocking directorate ...
*  Thiol-yne reaction
"Synthesis of Sulfuric Macrocycles and a Rotaxane through Thiol-yne Click and Dithiol Coupling Reactions". Organic Letters. 12 ( ...
*  Synthetic ribosome
David Alan Leigh's lab built synthetic ribosome using a chemical structure based on a rotaxane. The Cédric Orelle research ...
*  Macrocycle
Rotaxane: macrocycle(s) stuck on a stick, generally freely Catenane: interlocked molecular rings (like a chain). Molecular knot ...
*  Molecular shuttle
Academic interest also exists for synthetic molecular shuttles, the first prototype reported in 1991 based on a rotaxane. This ...
*  Squaraine dye
This encumbrance can be attenuated by the formation of a rotaxane around the dye to protect it from nucleophiles. They are ...