It is the anhydride of phthalic acid. Phthalic anhydride is a principal commercial form of phthalic acid. It was the first ... Phthalic acid is however easily dehydrated to form phthalic anhydride. Above 180 °C, phthalic anhydride re-forms. Chiral ... Phthalic anhydride is a degradation product of CAP. Phthalic anhydride is a versatile intermediate in organic chemistry, in ... Studies show that exposure to phthalic anhydride can cause rhinitis, chronic bronchitis, and asthma. Phthalic anhydride's ...
The more commonly used polyacids are phthalic, isophthalic, terephthalic and adipic acid. Phthalic and trimellitic anhydrides ... Acids include isophthalic, terephthalic, adipic, benzoic, succinic acids and phthalic, maleic and trimellitic anhydride. ... To make them waterborne organic acids or anhydrides are added in a two-stage process but there are other methods too. ... With alkyds typical methods include maleinazation of unsaturated fatty acids with maleic anhydride. This involves making a ...
It is the imide derivative of phthalic anhydride. It is a sublimable white solid that is slightly soluble in water but more so ... Phthalimide can be prepared by heating phthalic anhydride with alcoholic ammonia giving 95-97% yield. Alternatively, it may be ... "Phthalic Acid and Derivatives". Ullmann's Encyclopedia of Industrial Chemistry. Weinheim: Wiley-VCH. doi:10.1002/14356007.a20_ ... prepared by treating the anhydride with ammonium carbonate or urea. It can also be produced by ammoxidation of o-xylene. ...
Wainwright, Mark S.; Foster, Neil R. (1 January 1979). "Catalysts, Kinetics and Reactor Design in Phthalic Anhydride Synthesis ...
o-Xylene is an important precursor to phthalic anhydride. The demand for isophthalic acid is relatively modest, so m-xylene is ...
Microwave irradiation of phthalic anhydride and hydroxylamine hydrochloride in pyridine produces N-hydroxyphthalimide in 81% ... Three possibilities were discussed and are shown in the Figure below: a mono-oxime of phthalic anhydride ("phthaloxime", I), an ... The oximes of opianic acid and of phthalic anhydride". J. Chem. Soc.: 529-539. doi:10.1039/JR9280000529. Hurd, Charles D.; ... Even in the absenceof a base, phthalic anhydride and hydroxylamine phosphate react to produce N-hydroxyphthalimide in 86% yield ...
... can be synthesized from thymol and phthalic anhydride. Phenolphthalein "Thymolphthalein". pubchem.ncbi.nlm.nih. ...
Unlike resorcinol it does not give a fluorescein with phthalic anhydride. Oxidation of the ammoniacal solution gives orcein, ...
Phthalates Dibutyl phthalate Phthalic anhydride Isobutanol Schettler, Ted (2006-02-07). "Human exposure to phthalates via ... It is formed by the esterification of isobutanol and phthalic anhydride. This and other phthalates are used as plasticizers due ... In 1836 French chemist Auguste Laurent oxidized naphthalene with chromic acid and created phthalic anhydride, of which ... Synthesis of phthalate esters via FeCl3-catalyzed nucleophilic addition of alcohols to phthalic anhydride". Results in ...
... upon reaction with phthalic anhydride, to quinizarin. The commercial dye quinizarin is produced by the reaction of phthalic ... anhydride and 4-chlorophenol followed by hydrolysis of the chloride. Haynes, p. 3.116 Haynes, p. 5.90 Haynes, p. 3.577 Haynes, ...
DBP is produced by the reaction of n-butanol with phthalic anhydride. DBP is an important plasticizer that enhances the utility ... Phthalic acid Phthalates Diisobutyl phthalate (DIBP) Nail polish NIOSH Pocket Guide to Chemical Hazards. "#0187". National ... Dibutyl phthalate (DBP) is one of the six phthalic acid esters found on the Priority Pollutant List, which consists of ... Hydrolysis of DBP leads to phthalic acid and 1-butanol. Monobutyl phthalate (MBP) is its major metabolite. Biodegradation by ...
It is an isomer of 3-chlorophthalic anhydride and a derivative of phthalic anhydride. It has a melting point of around 99 °C. ... Like most acid anhydrides, it can hydrolyze in the presence of water. It can be produced by chlorination of phthalic anhydride ... Chlorination of phthalic anhydride http://www.freepatentsonline.com/4297283.html (Articles without EBI source, Articles without ... 4-Chlorophthalic anhydride is a monochlorinated aromatic anhydride. ...
The useful dye quinizarin is produced by diacylation of hydroquinone with phthalic anhydride. Hydroquinone undergoes oxidation ...
... is manufactured commercially via the esterification of phthalic anhydride with methanol. The reaction can be ... US 5534652, Jones L, Daniels PH, Krauskopf LG, Rigopoulos KR, "Preparation of plasticizer esters from phthalic anhydride ... MMP may also be further hydrolysed to phthalic acid. However, low molecular weight phthalates such as MMP are primarily ... Huang, Ling; Zhu, Xunzhi; Zhou, Shixing; Cheng, Zhenrui; Shi, Kai; Zhang, Chi; Shao, Hua (July 2021). "Phthalic Acid Esters: ...
The Friedel-Crafts reaction of benzene and phthalic anhydride in presence of AlCl3. o-Benzoylbenzoic acid is an intermediate. ...
Naphthalene is a precursor in the production of phthalic anhydride. This application has been displaced by alternative ...
It is an isomer of 4-chlorophthalic anhydride and a derivative of phthalic anhydride. 3-Chlorophthalic anhydride has a melting ... 3-Chlorophthalic anhydride may be used to produce herbicides and pesticides, intermediates for active pharmaceutical ... 4-Chlorophthalic anhydride Preparation of 3-chlorophthalic anhydride http://www.freepatentsonline.com/5683553.html (Articles ... 3-Chlorophthalic anhydride is a monochlorinated aromatic anhydride. ...
Phthalic anhydride production shifts from catalytic oxidation of naphthalene to the o-xylol process. Catalytic upgrading of gas ...
... phthalic anhydride, and phthalimides. Alternatively, heating phthalic anhydride in the presence of urea yields H2Pc. Using such ... Phthalocyanine is formed through the cyclotetramerization of various phthalic acid derivatives including phthalonitrile, ... On the products of the reaction of acetic anhydride with phthalamide]. Berichte der Deutschen Chemischen Gesellschaft (in ...
... is produced by the catalytic oxidation of naphthalene or ortho-xylene directly to phthalic anhydride and a ... P1 degrades phthalic acid. Isophthalic acid Phthalate Phthalic anhydride Potassium hydrogen phthalate, a primary standard for ... Typically phthalate esters are prepared from the widely available phthalic anhydride. Reduction of phthalic acid with sodium ... Although phthalic acid is of modest commercial importance, the closely related derivative phthalic anhydride is a commodity ...
Upon treatment with phthalic anhydride derivatives, the diamine converts to phthaloperinones. The derivative from phthalic ... anhydride itself, Solvent Orange 60, is a useful orange pigment. It is a precursor to 1,8-bis(dimethylamino)naphthalene. This ...
... are produced industrially by the acid catalysed reaction of phthalic anhydride with excess alcohol. The synthesis of ... as well as alternative plasticizers not based on phthalic anhydride. The legacy use of phthalate plasticizers has prevented ... odorless liquids produced by reacting phthalic anhydride with an appropriate alcohol (usually 6- to 13-carbon). The mechanism ... Bi M, Liu W, Luan X, Li M, Liu M, Liu W, Cui Z (October 2021). "Production, Use, and Fate of Phthalic Acid Esters for Polyvinyl ...
The compound is produced by the reaction of phthalic anhydride and toluene. It can be chlorinated to give 1-chloro-2- ...
They are formed by the reaction of phthalic anhydride with various phenols. They are a subclass of triarylmethane dyes. Common ...
Phthalic anhydride is poorly reactive toward bromine, necessitating the use of acidic media. The Gatterman reaction can also be ... The main aryl bromides produced commercially are tetrabromophthalic anhydride, decabromodiphenyl ether, and tetrabromobisphenol ...
... can be synthesized by condensation of phthalic anhydride with two equivalents of phenol under acidic conditions ...
... the oxidation of o-xylene for the production of phthalic anhydride (Quinta Ferreira et al., 1999)." "Among the several ...
In 1871 he discovered the synthesis of phenolphthalein by condensation of phthalic anhydride with two equivalents of phenol ... as he had synthesised it from phthalic anhydride and resorcinol. The term fluorescein would not start to be used until 1878. In ...
Parallels exist with the production of phthalic anhydride: While older methods use naphthalene, modern methods use o-xylene as ... Maleic anhydride is also a skin and respiratory sensitizer. Maleic anhydride is a low hazard profile chemical. Maleic anhydride ... Maleic anhydride is an organic compound with the formula C2H2(CO)2O. It is the acid anhydride of maleic acid. It is a colorless ... Maleic anhydride is used in many applications. Around 50% of world maleic anhydride output is used in the manufacture of ...
Many xanthene dyes can be prepared by condensation of derivates of phthalic anhydride with derivates of resorcinol or 3- ...