2004) Organotin Chemistry, 2nd Edition Weinheim: Wiley-VCH. ISBN 978-3-527-31023-4 (Organotin compounds, Tin(IV) compounds). ... In aqueous or aquatic environments, most organotin compounds contain this group. Stannoxanes form upon hydrolysis of organotin ... Stannoxane is a functional group in organotin chemistry with the connectivity SnIV−O−SnIV (IV indicates the oxidation state of ... For example, hydrolysis of dibutyltin dichloride gives the tetratin compound (((CH3(CH2)3)2ClSn)2O)2. The hydrolysis appears to ...
Organotantalum reagents arise via transmetalation of organotin compounds with tantalum(V) chloride. These organotantalum ... Organotantalum compounds are invoked as intermediates in C-alkylation of secondary amines with 1-alkenes using Ta(NMe2)5. The ... Organotantalum compounds are of academic interest, but few or no commercial applications have been described. Schrock, Richard ... A wide variety of compound have been reported, initially with cyclopentadienyl and CO ligands. Oxidation states vary from Ta(V ...
This chemical belongs to a subclass of organotin compounds called diorganotin dihalides (R2SnX2, where R is organyl and X is a ... Dipropyltin dichloride is an organotin compound with the chemical formula (CH3CH2CH2)2SnCl2. It is a white solid. ... Organic compound stubs, Organotin compounds). ...
... tetracyclopentadienylstannate a novel type of organotin(II) compound". Journal of Organometallic Chemistry. 168 (2): 159-162. ... Phosphonic acids and phosphinic acids combine with pentamethylantimony to yield compounds like (CH3)4SbOP(O)Ph2, (CH3)4SbOP(O)( ... Some other antimony(V) organometallic compounds include pentapropynylantimony (Sb(CCCH3)5) and pentaphenyl antimony (Sb(C6H5)5 ... Wallenhauer, Stephan; Seppelt, Konrad (January 1995). "Antimony(V) and Bismuth(V) Methyl Compounds: A Structural Comparison". ...
... relationship to cellular sensitivity to organotin compounds". Neurochemistry International. 31 (6): 801-15. doi:10.1016/S0197- ...
This led to a worldwide ban on organotin compound applications on ships starting in 2003. In 2008, organotin compounds acting ... TBT, or tributyltin, tributylstannyl or tributyl stannic hydride compounds are organotin compounds. They have three butyl ... Exposure to organotin compounds causes the development of male accessory sex organs in female prosobranch gastropods. This ... Tributyltin (TBT) is an umbrella term for a class of organotin compounds which contain the (C4H9)3Sn group, with a prominent ...
"Toxicity of Organotin Compounds on Embryos of a Marine Invertebrate (Styela plicata;Tunicata)". Ecotoxicology and Environmental ...
Organotin compounds, Foul-smelling chemicals, Tin(IV) compounds, All stub articles, Organic compound stubs). ... It is an important example of an organotin compound, often abbreviated as TET. Tetraethyltin is a colourless flammable liquid, ... Tetraethyltin or tetraethyl tin is a chemical compound with the formula (CH3CH2)4Sn, that is, a tin atom attached to four ethyl ...
... on the other hand certain organotin compounds are almost as toxic as cyanide. Even though zinc is an essential requirement for ... Insoluble compounds as well as the metallic forms often exhibit negligible toxicity. The toxicity of any metal depends on its ... Many thallium(I) compounds are highly soluble in water and are readily absorbed through the skin.[citation needed] Exposure to ... Thallium and its compounds are often highly toxic. Contact with skin is dangerous, and adequate ventilation should be provided ...
Organotin compounds, Vinyl compounds, Tin(IV) compounds). ... Vinyl tributyltin is an organotin compound with the formula ... The compound is prepared by the reaction of vinylmagnesium bromide with tributyltin chloride. It can be synthesized in the ... As a source of vinyltin reagents, early work used vinyl trimethyltin, but trimethyltin compounds are avoided nowadays owing to ...
Organotin compounds, Four-membered rings, Eight-membered rings, Two-dimensional nanomaterials, Tin(IV) compounds, Butyl ... Dibutyltin oxide, or dibutyloxotin, is an organotin compound with the chemical formula (C4H9)2SnO. It is a colorless solid that ... Dibutyltin compounds, such as dibutyltin dilaurate are widely used curing catalysts for the production of silicones and ... Otera's catalyst Davies, Alwyn G. "Organotin Chemistry", 2nd Edition, 2004, Wiley-VCH: Weinheim. ISBN 978-3-527-31023-4. Harris ...
Articles with short description, Short description is different from Wikidata, Organotin compounds, Tin(II) compounds, ... Stannylenes (R2Sn:) are a class of organotin(II) compounds that are analogues of carbene. Unlike carbene, which usually has a ... The crystal structure of the synthesized compound showed the arrangement of one B-H bond toward the Sn atom with the B-H--Sn ... In some cases, stannylenes have been prepared by reduction of a tin(IV) compound by KC8 Amidostannylene can also be synthesized ...
Organotin compounds, Tin(IV) compounds, Vinyl compounds). ... is an organotin compound with a chemical formula of C8H12Sn. ... "The Disproportionation of Tetravinyltin with Tin Tetrachloride and the Cleavage of Some Vinyltin Compounds with Bromine". ...
Boronic acids are less toxic and safer for the environment than organotin and organozinc compounds. It is easy to remove the ... The organoboron compounds do not undergo transmetalation in the absence of base and it is therefore widely believed that the ... Scaled up reactions have been carried out in the synthesis of a number of important biological compounds such as CI-1034 which ... The nickel catalyzed Suzuki coupling reaction also allowed a number of compounds that did not work or worked worse for the ...
DCOIT has attracted attention as an antifouling compound. It is a replacement for organotin compounds that have been largely ... Dichlorooctylisothiazolinone, DCOIT or DCOI, is the organic compound with the formula SC(Cl)=C(Cl)C(O)NC7H15. It is a white ... It is an isothiazolinone, a class of heterocyclic compounds used as biocides. ...
... and facile method for ketone synthesis from acid chlorides and organotin compounds catalyzed by palladium". Journal of the ... Phenyl compounds, All stub articles, Aromatic compound stubs). ...
... synthetic catalytic scavengers are their synthetic counterparts Organotin compounds are used in polymer manufacture as ...
... is an organometallic compound with the formula (CH3)4Sn. This liquid, one of the simplest organotin compounds, ... Organotin compounds, Tin(IV) compounds, Methyl complexes). ... which are precursors to other organotin compounds. These ... Di- and trimercaptotin compounds are used to inhibit the dehydrochlorination, which is the pathway for photolytic and thermal ... 4 HgCl2 + 4 (CH3)4Sn → 4 Me3SnCl + 4 MeHgCl A variety of methyltin compounds are used as precursors for stabilizers in PVC. ...
... (abbreviated DBTDL) is an organotin compound with the formula (CH3(CH2)10CO2)2Sn((CH2)3CH3)2. It is a ... Davies, Alwyn George (2004). Organotin chemistry (2nd ed.). Weinheim: Wiley-VCH. Applications, Environmental Issues, and ... Organotin compounds, Tin(IV) compounds). ...
... and facile method for ketone synthesis from acid chlorides and organotin compounds catalyzed by palladium". J. Am. Chem. Soc. ...
Organotin compounds, Oxides, Tin(IV) compounds, Butyl compounds). ... Tributyltin oxide (TBTO) is an organotin compound chiefly used as a biocide (fungicide and molluscicide), especially a wood ... Organotin Chemistry, Second Edition. Alwyn G. Davies, 2004, Wiley-VCH Verlag GmbH & Co. KGaA. ISBN 3-527-31023-1 Davies, Alwyn ... 2004) Organotin Chemistry, 2nd Edition Weinheim: Wiley-VCH. ISBN 978-3-527-31023-4 National Pollutant Inventory Fact Sheet for ...
... are considered as nucleophiles and the reactivity of them is between that of organosilicon and organotin compounds. Some ... Such compounds are prepared by the reduction of bulky arylgermanium(II) halides. Compounds containing Ge=C (germenes) double ... Some organogermanium compounds participate in cross coupling reactions. Organogermanium compounds are used in relatively few ... Compounds with multiple bonds to Ge are usually highly reactive or require bulky organic substituents for their isolation. This ...
Gielen, M. (2002). "Review: Organotin compounds and their therapeutic potential: a report from the Organometallic Chemistry ... The three highest cited papers (> 250 citations each) are: Tiekink, E.R.T. (1991). "Structural chemistry of organotin ...
It can be used in place of palladium in the Stille reaction, which couples two carbon atoms using an organotin compound. http ... compounds, Bromides, Metal halides, All stub articles, Inorganic compound stubs). ... Manganese(II) bromide is the chemical compound composed of manganese and bromine with the formula MnBr2. ... Chemical articles with multiple compound IDs, Chemicals using indexlabels, Chemical articles with multiple CAS registry numbers ...
It can be used in place of palladium in the Stille reaction, which couples two carbon atoms using an organotin compound. It can ... Manganese can form compounds in the +2, +3 and +4 oxidation states. The manganese(II) compounds are often light pink solids. ... Typical alkylating agents are organolithium or organomagnesium compounds. The chemistry of organometallic compounds of Mn(II) ... The reactivity of organomanganese compounds can be compared to that of organomagnesium and organozinc compounds. The ...
The first isolated representatives were prepared from organotin halides or acids with orthometalated arylplatinum(II) compounds ... Many metallodendrimers have repeating units based on organoplatinum compounds. Organoplatinum compounds are implicated in the ... but organoplatinum compounds are more stable and therefore less useful as catalysts. Most organoplatinum(0) compounds contain ... The compound Me(PEt3)2PtOTf reacts reversibly with triflic acid between -60 and -80 °C, forming methane and (PEt3)2Pt(OTf)2 at ...
Organosilanes are readily available compounds that, upon activation (much like organotin or organoboron compounds) from ... Organozinc reagents are moisture sensitive, organotin compounds are toxic, and organoboron reagents are not readily available, ... organosilicon compounds are inactive. Other organometallic reagents using metals such as zinc, tin, and boron, reduce the ... "NaOH-Promoted cross-coupling reactions of organosilicon compounds with organic halides: Practical routes to biaryls, ...
This reaction will give substantial yields only if the 1-vinyltetrazole is made efficiently from an organotin compound, such as ... The compound is classified as aromatic due to the presence of a planar ring containing 6 π-electrons (a pair of electrons from ... The N3 of the imidazole compound binds to the heme iron atom of ferric cytochrome P450, whereas the N4 of the triazoles bind to ... Imidazole (ImH) is an organic compound with the formula C3N2H4. It is a white or colourless solid that is soluble in water, ...
The organotin compound undergoes As/Sn exchange with arsenic trichloride to give 1-chloroacyclohexadiene, which loses a HCl ... The study of arsabenzene and related compounds was an important step in the understanding of compounds that contain multiple ... It belongs to a group of compounds called heteroarenes that have the general formula C5H5E (E= N, P, As, Sb, Bi). This air ... ISBN 3-527-29390-6. Cadogan, J. I. G.; Buckingham, J.; Macdonald, F. (1997). Dictionary of Organic Compounds. Vol. 10 (6th ed ...
... possible evidence of environmental contamination derived from organotin compounds in Rio de Janeiro and Fortaleza, Brazil". ...