... is used to destroy toxic and potentially explosive sodium azide. For most purposes, nitrous acid is usually formed ... Free nitrous acid is unstable and decomposes rapidly. Nitrous acid can also be produced by dissolving dinitrogen trioxide in ... 2 HNO2 Nitrous acid is the main chemphore in the Liebermann reagent, used to spot-test for alkaloids. Gaseous nitrous acid, ... it can be deduced that nitrous is a faster, rather than a more powerful, oxidizing agent than dilute nitric acid. Nitrous acid ...
"Nitrous acid calcium". Archived from the original on 31 January 2012. Retrieved 6 October 2012. (Articles needing additional ... At the acid plant, ammonia is burned to produce the NOX gas for acid as well as calcium nitrite. Also, it can be prepared as ... It is a poisonous inorganic oxidiser, which can not be mixed with organic ammonium salt, acid or cyanide. It has to be kept in ... One is by reacting hydrated lime with NOX gas, which typically comes from a nitric acid plant. ...
Nitrous acid becomes protonated on its hydroxy group to form nitrosooxonium. This compound then splits off to form nitrosonium ... The nitrosonium group forms from nitrous acid (HNO2) under acidic conditions present in the tobacco curing process. It can also ... "oxyacid - Nitrous acid and nitrite salts , chemical compound". Encyclopedia Britannica. Retrieved 2017-05-06. Vogel, Arthur ... be formed in the stomach when stomach acid reacts with nitrite ions that are typically used as a salt to preserve red meats and ...
"Nitric Acid, Nitrous Acid, and Nitrogen Oxides". Ullmann's Encyclopedia of Industrial Chemistry. Weinheim: Wiley-VCH. doi: ... Nitrous oxide ("laughing gas") is a potent greenhouse gas produced by soil bacteria. Although most metal oxides are crystalline ... The chemical produced on the largest scale industrially is sulfuric acid. It is produced by the oxidation of sulfur to sulfur ... Müller, Hermann (2000). "Sulfuric Acid and Sulfur Trioxide". Ullmann's Encyclopedia of Industrial Chemistry. Weinheim: Wiley- ...
ISBN 0-12-352651-5. Thiemann, Michael; Scheibler, Erich; Wiegand, Karl Wilhelm (2005). "Nitric Acid, Nitrous Acid, and Nitrogen ... NO2 reacts with water to give nitric acid and nitrous acid: 2 NO2 + H2O → HNO2 + HNO3 This reaction is one of the steps in the ... It is also used as an oxidizer in rocket fuel, for example in red fuming nitric acid; it was used in the Titan rockets, to ... April 2002 ATSDR Nitrous Oxides. "The Impact of Unvented Gas Heating Appliances on Indoor Nitrogen Dioxide Levels in 'TIGHT' ...
ISBN 0-8493-0487-3. Thiemann, Michael; Scheibler, Erich; Wiegand, Karl Wilhelm (2005). "Nitric Acid, Nitrous Acid, and Nitrogen ... Although inefficient, this method does not require the use of any strong acid. It is also occasionally used as a desiccant. ... The principal use is as a dehydrating agent in the preparation of concentrated nitric acid. Its fertilizer grade has 10.5% ... The absorption of these nitrogen oxides in water is one possible route to synthesize nitric acid. ...
... reaction with nitrous acid gives (5). The rearrangement to a Sydnone then occurs to give CID:88166659 (6). Feprosidnine is sans ...
... is one of the most common types of acid used in acid attacks. He goes on to point out that "nitrous air" is the ... "Nitric Acid, Nitrous Acid, and Nitrogen Oxides". Ullmann's Encyclopedia of Industrial Chemistry. Weinheim: Wiley-VCH. doi: ... Nitric acid is also commonly used as a strong oxidizing agent. The discovery of mineral acids such as nitric acid is generally ... White fuming nitric acid, pure nitric acid or WFNA, is very close to anhydrous nitric acid. It is available as 99.9% nitric ...
Formally they are alkyl esters of nitrous acid. They are distinct from nitro compounds (R−NO2). The first few members of the ... Alkyl nitrites are also used in the formation of oximes with the stronger carbon acids and acid or base catalysis for example ... Organic nitrites are prepared from alcohols and sodium nitrite in sulfuric acid solution. They decompose slowly on standing, ... in the reaction of 2-butanone, ethyl nitrite and hydrochloric acid forming the oxime, the similar reaction with phenacyl ...
Typical reagents are nitrous acid or sodium nitrite. The reaction is a manifestation of nucleophilic aromatic substitution and ...
... nitrous acid and nitric acid, determination of the heat capacity and the atomic weight of beryllium, and the invention of gas ... 27) On free nitrous acid (ib., 1896, vol. 28) On the process of soda formation in nature (ib., 1896, vol. 28) Decomposition ... 25) Reaction of the formation of nitrous acid (ib., 1893, vol. 25) On the Arrhenius theory (ib., 1894, vol. 26) The ... In 1880, he showed that fumaric and maleic acids, upon oxidation, yield two isomeric hydroxycarboxylic acids, later shown to be ...
It reacts with nitrous acid to form diazonium salt, which can undergo coupling reaction to form an azo compound. As azo- ... Amines reacts with nitrous acid to give diazonium salts. The alkyl diazonium salts are of little importance because they are ... Acid-base extraction Amine value Amine gas treating Ammine Biogenic amine Ligand isomerism Official naming rules for amines as ... Acyl chlorides and acid anhydrides react with primary and secondary amines to form amides (the "Schotten-Baumann reaction"). ...
It is an ester of hexanol and nitrous acid. It has the structural formula of: CH3(CH2)5ONO The CAS Registry Number is 638-51-7 ... It is also known as nitrous acid, hexyl ester. It is the aliphatic analogue of cyclohexyl nitrite. Hexyl nitrite is one of the ...
The Demjanov rearrangement is the chemical reaction of primary amines with nitrous acid to give rearranged alcohols.[1][2][3] ... The reaction process begins with diazotization of the amine by nitrous acid. The diazonium group is a good leaving group, ... It showed that when an exo methylamine underwent Demjanov nitrous acid deamination, ring enlargement was not produced. However ... Products of the action of nitrous acid on tetramethylenylmethylamine]". Zhurnal Russkago Fiziko-Khimicheskago Obshchestva [J. ...
Stedman, G.; Whincup, P. A. E. (1969). "Oxidation of metal thiocyanates by nitric and nitrous acids. Part I. Products". Journal ... A suspension of anhydrous Pb(SCN)2 is treated with bromine in glacial acetic acid to afford a 0.1M solution of thiocyanogen ...
These fumes include ammonia, hydrocyanic acid, and nitrous fumes. The nitrous fumes have a characteristic yellow-brown colour. ...
Treatment with nitrous acid gives benzotriazole, a corrosion inhibitor. Condensation of substituted o-phenylenediamine with ... Its reactions with carboxylic acids and their derivatives produce benzimidazoles. The herbicides benomyl and fuberidazole are ...
... by the reduction of nitrous acid and nitrites with hydrogen; and also by the decomposition of ammonium salts by alkaline ... The Vemork hydroelectric plant in Norway used its surplus electricity output to generate renewable nitric acid from 1911 to ... Ammonia is also used for the production of plastics, fibres, explosives, nitric acid (via the Ostwald process), and ... 1971, requiring 15 mWh/ton of nitric acid. The same reaction is carried out by lightning, providing a natural source of soluble ...
Nitrous acid can be used to chemically depolymerize heparin/HS. Nitrous acid can be used at pH 1.5 or at a higher pH of 4. ... Its polyanionic structure can mimic nucleic acids like DNA and RNA, making it useful for purification of nucleic acid-binding ... Low-pH nitrous acid treatment is an excellent method to distinguish N-sulfated polysaccharides such as heparin and HS from non ... Under both conditions, nitrous acid effects deaminative cleavage of the chain. At both 'high' (4) and 'low' (1.5) pH, ...
The ban includes nitrous oxide (N2O) from adipic acid production. The reasons given were the perverse incentives, the lack of ... Schneider, L.; Lazarus, M.; Kollmuss, A (October 2010). "Industrial N2O Projects Under the CDM: Adipic Acid - A Case of Carbon ... Some CDM projects limit or eliminate the industrial emission of greenhouse gases, such as fluoroform (CHF3) and nitrous oxide ( ...
The ban includes nitrous oxide (N2O) from adipic acid production. The reasons given were the perverse incentives, the lack of ... such as nitrous oxide and perfluorocarbons. In 2012, the EU ETS was also extended to the airline industry, though this only ...
... , [NH4]NO2, is the ammonium salt of nitrous acid. It is not used in pure isolated form since it is highly ... 2 H2O It decomposes when heated or in the presence of acid into water and nitrogen. Ammonium nitrite solution is stable at ...
2002). "Nitrous acid, nitrogen dioxide, and ozone concentrations in residential environments". Environ Health Perspect. 110 (2 ... it diffuses into the lung and slowly hydrolyzes to nitrous and nitric acid which causes pulmonary edema and pneumonitis leading ... aerospace staffs and miners as well as those people whose occupations are connected with the nitric acid. Silo-filler's disease ...
In 1872, diphenylamine was suggested as a means to detect nitrous acid in sulfuric acid due to its blue coloration in the ... Withers, W. A. (1911). "A MODIFICATION OF THE DIPHENYLAMINE TEST FOR NITROUS AND NITRIC ACIDS". Journal of the American ... With strong acids, it forms salts. For example, treatment with sulfuric acid gives the bisulfate [(C6H5)2NH2]+[HSO4]− as a ... The diphenylaminesulfonic acid is a simple prototype redox indicator, owing to its improved aqueous solubility compared with ...
... is readily hydrolysed by hot caustic alkalis to benzoic acid and glycine. Nitrous acid converts it into benzoyl ... para-Aminohippuric acid ortho-Iodohippuric acid Methylhippuric acid (three different isomers) Wishart, David S.; Guo, An Chi; ... hippuric acid is produced from benzoic acid by direct glycine acylation. It is one of the two conjugates of benzoic acid ... they are converted to hippuric acid by reaction with the amino acid, glycine. A modern synthesis of hippuric acid involves the ...
Hydrazine is used to convert the ester to an acylhydrazine, which is reacted with nitrous acid to give the acyl azide. Heating ... Acyl azides are also obtained from treating acylhydrazines with nitrous acid. Alternatively, the acyl azide can be formed by ... Acid hydrolysis yields the amine from the carbamate and the carboxylic acid from the nitrile simultaneously, giving the product ... Preparation of α-amino acids from alkyl cyanoacetic acids), Journal für Praktische Chemie, 146 : 250-267. Gagnon, P. E.; Bovin ...
Moore, Gordon Earle (1954). I. Infrared Studies of Nitrous Acid, The Chloramines and Nitrogen Dioxide II. Observations ...
The thiol reacts with nitrous acid to give S-nitrosotriphenylmethanethiol (C6H5)3CSNO. Garnsey, Michelle R.; Wengryniuk, Sarah ...
At neutral pH, nitrite exists predominantly as the anion, not nitrous acid. Metal nitrosyl complexes undergo base hydrolysis, ... which now is a soft Lewis acid. The nitrite isomerizes to the N-bonded isomer, Fe(porph)NO2(L). The isomerization of [(NH3)5Co− ... H2O Some anionic nitrito complexes undergo acid-induced deoxygenation to give the nitrosyl complex. [LnMNO2]− + H+ → [LnMNO ...
... is the lithium salt of nitrous acid, with formula LiNO2. This compound is hygroscopic and very soluble in water ...