In organic chemistry, nitro compounds are organic compounds that contain one or more nitro functional groups (−NO2). The nitro ... Chloramphenicol is a rare example of a naturally occurring nitro compound. At least some naturally occurring nitro groups arose ... Explosive decomposition of organo nitro compounds are redox reactions, wherein both the oxidant (nitro group) and the fuel ( ... Many contact explosives contain the nitro group. Functional group Reduction of nitro compounds Nitration Nitrite (also an NO2 ...
Alkyl and aryl nitro compounds behave differently. Most useful is the reduction of aryl nitro compounds. The reduction of ... Treatment of aromatic nitro compounds with metal hydrides gives good yields of azo compounds. For example, one could use: ... The reduction of nitro compounds are chemical reactions of wide interest in organic chemistry. The conversion can be effected ... Aliphatic nitro compounds can be reduced to aliphatic amines by several reagents: Catalytic hydrogenation using platinum(IV) ...
Gerald Booth (2007). "Nitro Compounds, Aromatic". Ullmann's Encyclopedia of Industrial Chemistry. Weinheim: Wiley-VCH. doi: ... It is a yellow crystalline solid that is important as a precursor to other compounds due to the two reactive sites present on ... 3-Nitrochlorobenzene is not useful itself but is a precursor to other useful compounds. Its derivative 3-chloroaniline, a ... 3-Nitrochlorobenzene is an organic compound with the formula C6H4ClNO2. ...
Gerald Booth (2007). "Nitro Compounds, Aromatic". Ullmann's Encyclopedia of Industrial Chemistry. Weinheim: Wiley-VCH. doi: ... o-Nitroanisole is an organic compound with the formula CH3OC6H4NO2. Three isomers of nitroanisole exist, but the o-isomer is ...
Menke nitration Zincke nitration Reactive nitrogen species Gerald Booth (2007). "Nitro Compounds, Aromatic". Ullmann's ... is that the nitrogen atom in nitro compounds is directly bonded to a non-oxygen atom (typically carbon or another nitrogen atom ... The difference between the resulting molecular structures of nitro compounds and nitrates (NO−3) ... Selectivity can be a challenge in nitrations because as a rule more than one compound may result but only one is desired, so ...
... is an organic compound with the formula H2NC6H4NO2. It is a derivative of aniline, carrying a nitro functional ... Gerald Booth (2007). "Nitro Compounds, Aromatic". Ullmann's Encyclopedia of Industrial Chemistry. Weinheim: Wiley-VCH. doi: ... Nitration of acetanilide gives only traces of 2-nitro isomer is obtained due to the great steric effect of the amide. ... Owing to the influence of the nitro substituent, the amine exhibits a basicity nearly 100,000x lower than aniline itself. ...
"Nitro Compounds, Aromatic". Ullmann's Encyclopedia of Industrial Chemistry. Weinheim: Wiley-VCH. doi:10.1002/14356007.a17_411. ... It is made by nitrating toluene at above -10 °C. This reaction affords a 2:1 mixture of 2-nitro and 4-nitro isomers. ... CDC - NIOSH Pocket Guide to Chemical Hazards - o-Nitrotoluene v t e (Chemical articles with multiple compound IDs, Multiple ... 2-Nitrotoluene or ortho-nitrotoluene is an organic compound with the formula CH3C6H4NO2. It is pale yellow liquid that ...
0452". National Institute for Occupational Safety and Health (NIOSH). Gerald Booth (2007). "Nitro Compounds, Aromatic". ... 4-Nitrochlorobenzene is the organic compound with the formula ClC6H4NO2. It is a pale yellow solid. 4-Nitrochlorobenzene is a ... Reductive alkylation of the nitro group affords secondary aryl amines, which are useful antioxidants for rubber. The U.S. ... The electron-withdrawing nature of the appended nitro-group makes the benzene ring especially susceptible to nucleophilic ...
Booth, Gerald (2005). "Nitro Compounds, Aromatic". Ullmann's Encyclopedia of Industrial Chemistry. Weinheim: Wiley-VCH. doi: ... 1-Nitronaphthalene is an organic compound with the formula C10H7NO2. It is one of two isomers of nitronaphthalene. A pale ...
"Nitro Compounds, Aromatic". Ullmann's Encyclopedia of Industrial Chemistry. Weinheim: Wiley-VCH. doi:10.1002/14356007.a17_411. ... o-Anisidine (2-anisidine) is an organic compound with the formula CH3OC6H4NH2. A colorless liquid, commercial samples can ...
Gerald Booth (2007). "Nitro Compounds, Aromatic". Ullmann's Encyclopedia of Industrial Chemistry. Weinheim: Wiley-VCH. doi: ... 2,4-Dinitrotoluene (DNT) or dinitro is an organic compound with the formula C7H6N2O4. This pale yellow crystalline solid is ...
cite book}}: ,journal= ignored (help) Markofsky, Sheldon B. (2000). "Nitro Compounds, Aliphatic". p. 6. doi:10.1002/14356007. ... β-Nitrostyrene is an aromatic compound and a nitroalkene used in the synthesis of indigo dye and the slimicide bromo- ... Nitro compounds, Phenyl compounds, Fungicides). ...
"Nitro Compounds, Aromatic". Ullmann's Encyclopedia of Industrial Chemistry (6th ed.). Weinheim: Wiley-VCH. doi:10.1002/14356007 ... Nitro solvents, IARC Group 2B carcinogens, Nonlinear optical materials, Aromatic solvents, Phenyl compounds). ... Nitrobenzene is an organic compound with the chemical formula C6H5NO2. It is a water-insoluble pale yellow oil with an almond- ... Bhattacharya A, Purohit VC, Suarez V, Tichkule R, Parmer G, Rinaldi F (March 2006). "One-step reductive amidation of nitro ...
By virtue of the two nitro groups, the chloride is susceptible to nucleophilic substitution. In this way, the compound is a ... Gerald Booth (2007). "Nitro Compounds, Aromatic". Ullmann's Encyclopedia of Industrial Chemistry. Weinheim: Wiley-VCH. doi: ... 2,4-Dinitrochlorobenzene (DNCB) is an organic compound with the chemical formula (O2N)2C6H3Cl. It is a yellow solid that is ... It is an important intermediate for the industrial production of other compounds. DNCB is produced commercially by the ...
Gerald Booth (2007). "Nitro Compounds, Aromatic". Ullmann's Encyclopedia of Industrial Chemistry. Weinheim: Wiley-VCH. doi: ... 4-Chloroaniline is an organochlorine compound with the formula ClC6H4NH2. This pale yellow solid is one of the three isomers of ...
... is an organic compound with the chemical formula CH 3NO 2. It is the simplest organic nitro compound. It is a polar liquid ... In this context, nitromethane is commonly referred to as "nitro fuel" or simply "nitro", and is the principal ingredient for ... "Nitro Compounds, Aliphatic". Ullmann's Encyclopedia of Industrial Chemistry. Weinheim: Wiley-VCH. doi:10.1002/14356007.a17_401. ... In more specialized organic synthesis, nitromethane serves as a Michael donor, adding to α,β-unsaturated carbonyl compounds via ...
The resulting nitro compound is reduced to the aniline. Trimethylaniline is a building block to a variety of bulky ligands. ... Gerald Booth (2007). "Nitro Compounds, Aromatic". Ullmann's Encyclopedia of Industrial Chemistry. Weinheim: Wiley-VCH. doi: ... 2,4,6-Trimethylaniline is an organic compound with formula (CH3)3C6H2NH2. It is an aromatic amine that is of commercial ... N-heterocyclic carbenes, as found in 2nd generation Grubbs' catalyst, are also prepared from this compound. ...
Booth, G. (2000). Nitro Compounds, Aromatic. ISBN 9783527306732. {{cite book}}: ,work= ignored (help) Sung-Kyu Shin; et al. ( ... Residual amounts of the compound and its metabolites can be found in crops. The degradation products, PCA and PCTA have been ...
"Nitro Compounds, Aromatic". Ullmann's Encyclopedia of Industrial Chemistry. Weinheim: Wiley-VCH. doi:10.1002/14356007.a17_411. ... It is primarily used as a high explosive compound for commercial mining and military applications. It has also been used as a ... 1,3,5-Trinitrobenzene is an organic compound with the formula C6H3(NO2)3. It is one of three trinitrated benzene-derivatives. A ... and a mediating agent to mediate the synthesis of other explosive compounds. 1,2,3-Trinitrobenzene TNT equivalent RE factor ...
Booth, Gerald (2000). "Nitro Compounds, Aromatic". Ullmann's Encyclopedia of Industrial Chemistry. Weinheim: Wiley-VCH. doi: ... 2-Nitronaphthalene is an organic compound with the formula C10H7NO2. It is one of two isomers of nitronaphthalene, the other ...
ISBN 0-93570248-2. Gerald Booth (2007). "Nitro Compounds, Aromatic". Ullmann's Encyclopedia of Industrial Chemistry. Weinheim: ... The mesityl group (Mes) is a substituent with the formula C6H2Me3 and is found in various other compounds. Mesitylene is ... Mesitylene is also a major urban volatile organic compound (VOC) which results from combustion. It plays a significant role in ... Chambers, Richard D. (2004). "Functional Compounds Containing Oxygen, Sulphur or Nitrogen and their Derivatives". Fluorine in ...
Gerald Booth (2007). "Nitro Compounds, Aromatic". Ullmann's Encyclopedia of Industrial Chemistry. Weinheim: Wiley-VCH. doi: ... The conversions of the 4-nitro derivative are similar. The major use of chlorobenzene is as an intermediate in the production ... Chlorobenzene is an aromatic organic compound with the chemical formula C6H5Cl. This colorless, flammable liquid is a common ...
Gerald Booth (2007). "Nitro Compounds, Aromatic". Ullmann's Encyclopedia of Industrial Chemistry. Weinheim: Wiley-VCH. doi: ... This compound is prepared by disulfonation of o-cresol. The resulting disulfonate is then treated with nitric acid to give DNOC ... Dinitro-ortho-cresol (DNOC) is an organic compound with the structural formula CH3C6H2(NO2)2OH. It is a yellow solid that is ...
Gerald Booth (2007). "Nitro Compounds, Aromatic". Ullmann's Encyclopedia of Industrial Chemistry. Weinheim: Wiley-VCH. doi: ... Nitrophenols are compounds of the formula HOC6H5−x(NO2)x. The conjugate bases are called nitrophenolates. Nitrophenols are more ... Fact sheet at atsdr.cdc.gov (Chemical articles with multiple compound IDs, Chemicals using indexlabels, Chemical articles with ...
ISBN 0-8493-0485-7. Gerald Booth (2007). "Nitro Compounds, Aromatic". Ullmann's Encyclopedia of Industrial Chemistry. Weinheim ... This reaction mainly affords a 2:1 mixture of 2-nitro and 4-nitro isomers, but after removal of the 2-isomer, the 3- ... 3-Nitrotoluene or meta-nitrotoluene is an organic compound with the formula CH3C6H4NO2. It is one of three isomers of ...
Toluene Dinitrotoluene Nitrobenzene Trinitrotoluene Booth, Gerald (2000). "Nitro Compounds, Aromatic". Ullmann's Encyclopedia ... Mononitrotoluene or nitrotoluene (MNT or NT), is any of three organic compounds with the formula C6H4(CH3)(NO2). They can be ... Mononitrotoluene comes in three isomers, differing by the relative position of the methyl and nitro groups. All are pale yellow ... p-Nitrotoluene This set index article lists chemical compounds articles associated with the same name. If an internal link led ...
Markofsky, Sheldon, B. (15 October 2011). "Nitro Compounds, Aliphatic". Ullmann's Encyclopedia of Industrial Chemistry. Vol. 24 ... Tris, or tris(hydroxymethyl)aminomethane, or known during medical use as tromethamine or THAM, is an organic compound with the ... MOPS HEPES MES Common buffer compounds used in biology "Tromethamine". pubchem.ncbi.nlm.nih.gov. Gomori, G., Preparation of ... "A patchwork pathway of apparently recent origin enables degradation of the synthetic buffer compound TRIS in bacteria". bioRxiv ...
Gerald Booth (2007). "Nitro Compounds, Aromatic". Ullmann's Encyclopedia of Industrial Chemistry. Weinheim: Wiley-VCH. doi: ... "Nitro Compounds, Aromatic". Ullmann's Encyclopedia of Industrial Chemistry. Weinheim: Wiley-VCH. doi:10.1002/14356007.a17_411. ... 4-Nitrotoluene or para-nitrotoluene is an organic compound with the formula CH3C6H4NO2. It is a pale yellow solid. It is one of ...
"Nitro Compounds, Aromatic". In Wiley-VCH (ed.). Ullmann's Encyclopedia of Industrial Chemistry (1 ed.). Wiley. doi:10.1002/ ... The compound is toxic by way of inhalation, ingestion, and absorption, and should be handled with care. Its LD50 in rats is ... The key step in this reaction sequence is an electrophilic aromatic substitution to install the nitro group para to the amino ... 4-Nitroaniline, p-nitroaniline or 1-amino-4-nitrobenzene is an organic compound with the formula C6H6N2O2. A yellow solid, it ...
Aliphatic nitro-compounds. Part VI. Reaction of α-nitro-olefins with hydrochloric acid". J. Chem. Soc.: 1485-1486. doi:10.1039/ ... Nitroso compounds, Organochlorides, Lachrymatory agents, Pulmonary agents, All stub articles, Organohalide stubs). ...