E1cB-elimination reaction Coleman, G. H.; Johnstone, H. F. (1925). "Cyclohexene". Organic Syntheses. 5: 33. doi:10.15227/orgsyn ...
Cyclohexenes often undergo retro Diels-Alder reactions. Similar to alkenes, alkynes often show strong molecular ion peak. ... This reaction occurs mainly in cyclohexene and its derivatives. Upon ionization, the pi electrons are excited and generate a ...
doi:10.1002/anie.197308411.. S. Hünig, E. Lücke, and W. Brenninger (1961). "1-Morpholino-1-Cyclohexene". Organic Syntheses: 65 ...
For instance, the cleavage of cyclohexene to give butadiene and ethylene has been observed, but only at temperatures exceeding ... Uchiyama, Masao; Tomioka, Tadao; Amano, Akira (2002-05-01). "Thermal Decomposition of Cyclohexene". The Journal of Physical ... is the microscopic reverse of the Diels-Alder reaction-the formation of a diene and dienophile from a cyclohexene. It can be ... providing diene and dienophile from starting cyclohexene derivatives. As early as 1929, this process was known and applied to ...
The molecule consists of a cyclohexene ring with a methylene bridge between carbons 1 and 4. The molecule carries a double bond ... "2-Cyclohexene-1,4-dione". Organic Syntheses.; Collective Volume, 9, p. 186 Thansandote, Praew; Chong, Eugene; Feldmann, Kai- ...
Oda, M.; Kawase, T.; Okada, T.; Enomoto, T. (1996). "2-Cyclohexene-1,4-dione". Organic Syntheses. 73: 253. doi:10.15227/orgsyn. ...
Q. Ashton Acton (2013). Cyclohexenes-Advances in Research and Application: 2013 Edition: ScholarlyBrief. ScholarlyEditions. ...
1-methyl-4-(1-methylvinyl)cyclohexene". ECHA. January 2019. Media related to Citrus sinensis at Wikimedia Commons Data related ...
1-Methyl-4-(1-methylethenyl)cyclohexene. 4-Isopropenyl-1-methylcyclohexene. p-Menth-1,8-diene. Racemic: DL-Limonene; Dipentene ...
It can also be oxidized to cyclohexene. Cyclohexanecarboxylic acid exhibits the reactions typical of carboxylic acids, ...
1,4-Cyclohexadiene Cyclohexene Schaefer, John P.; Endres, Leland (1967). "1,3-Cyclohexadiene". Organic Syntheses. 47: 31. doi: ...
Cyclohexene. Cycloalkene C5H12. n-pentane. Alkane C7H14. Cycloheptane. Cycloalkane ...
Claus, Ronald E.; Schreiber, Stuart L. (1986). "Ozonolytic Cleavage of Cyclohexene to Terminally Differentiated Products". 64: ...
Less stable epoxides are cleaved or react further; cyclohexene, styrene or α-methylstyrene yield no isolable epoxides. In the ...
"Studies on the Mechanism of the Oxymercuration of Substituted Cyclohexenes.". Journal of the American Chemical Society (1971), ... below is an example of regioselectivity and stereospecificity of the oxymercuration reaction with substituted cyclohexenes. A ...
... because the cyclohexene product bears substituents in positions that are analogous to the ortho and para positions of ... on those same carbons with respect to the cyclohexene ring. Likewise, cis,cis- and trans,trans-disubstitued dienes give cis ... to form a substituted cyclohexene derivative. It is the prototypical example of a pericyclic reaction with a concerted ...
Another synthesis path is the addition of HBr on cyclohexene. http://web.pdx.edu/~wamserc/C334F99/Fans.htm Wiederseiner, S., ...
With cyclohexene nucleic acid, research has shown that CeNAs with stereochemistry similar to the D form can create stable ... Gu P, Schepers G, Rozenski J, Van Aerschot A, Herdewijn P (2003). "Base pairing properties of D- and L-cyclohexene nucleic ... Types of synthetic XNA created so far include: 1,5-anhydrohexitol nucleic acid (HNA) Cyclohexene nucleic acid (CeNA) Threose ...
"A spectrophotometric and polarographic investigation of three new cyclohexene-substituted benzodiazepines". Talanta. 25 (4): ...
Heating in the presence of acid catalysts converts cyclohexanol to cyclohexene. Cyclohexanol has at least two solid phases. One ...
... direct oxidation of cyclohexenes with 30 percent hydrogen peroxide". Science. 281 (5383): 1646-47. Bibcode:1998Sci...281.1646S ... 4CO2H Another method is oxidative cleavage of cyclohexene using hydrogen peroxide. The waste product is water. Historically, ...
In a related reaction, KSCN converts cyclohexene oxide to the corresponding episulfide. C6H10O + KSCN → C6H10S + KOCN KSCN is ...
It can be produced by the retro-Diels-Alder reaction of cyclohexene. Sulfolene is a convenient solid storable source for 1,3- ...
Monocyclic cycloalkenes are cyclopropene, cyclobutene, cyclopentene, cyclohexene, cycloheptene, cyclooctene, and so on. ...
Two hydrocarbons that can serve as hydrogen donors are cyclohexene or cyclohexadiene. In this case, an alkane is formed, along ...
In other syntheses, pimelic acid is made from cyclohexene-4-carboxylic acid, and a fourth method also exists based on the 1,4 ... "The Synthesis of Pimelic Acid from Cyclohexene-4-carboxylic Acid and its Derivatives". Journal of the American Chemical Society ...
In some cases, purified cyclohexanol, obtained by hydration of cyclohexene, is the precursor. Alternatively, cyclohexanone can ...
... can be produced in two step starting with the hydroformylation of cyclohexene. This process also give ... "The Unmodified Homogeneous Rhodium-Catalyzed Hydroformylation of Cyclohexene and the Search for Monometallic Catalytic ...
... it is produced by the alkylation of benzene with cyclohexene. It is generated by the hydrodesulfurization of dibenzothiophene. ...
... is a bicyclic monoterpene consisting of fused cyclohexene and cyclopropane rings. It occurs as a constituent of ...