Sodium triethylborohydride
Borohydrides, Organoboranes, Reducing agents). ...
List of MeSH codes (D01)
... borohydrides MeSH D01.132.250.075 - borates MeSH D01.139.300.050 - bromides MeSH D01.139.300.050.100 - cyanogen bromide MeSH ...
Achmatowicz reaction
... and then ketone reduction with sodium borohydride produce an intermediate from which many monosaccharides can be synthesised. ...
Amine oxide
... sodium borohydride, catalytic reduction, zinc / acetic acid, and iron / acetic acid. Pyridine N-oxides can be deoxygenated by ...
Glibornuride
Gliburnide is an endo-endo derivative made from camphor-3-carboxamide by borohydride reduction (exo approach), followed by ...
Imine
Other reducing agents are lithium aluminium hydride and sodium borohydride. The asymmetric reduction of imines has been ...
Gas-pak
Sodium borohydride - NaBH4 Sodium bicarbonate - NaHCO3 Citric acid - C3H5O(COOH)3 Cobalt chloride - CoCl2 (catalyst) The ...
N,N-Dimethyltryptamine
Sodium borohydride can be used but requires a larger excess of reagents and lower temperatures due to it having a higher ... result in the creation of cyanated tryptamine and beta-carboline byproducts of unknown toxicity while using sodium borohydride ...
Atomic absorption spectroscopy
... aqueous solution of sodium borohydride, all of which is contained in a glass vessel. The volatile hydride generated by the ...
Borazine
12 H2 An alternative more efficient route begins with sodium borohydride and ammonium sulfate: 6 NaBH4 + 3 (NH4)2SO4 → 2 B3N3H6 ... 3 Reduction with sodium borohydride The addition reaction with bromine does not require a catalyst. Borazines undergo ...
Oxocarbenium
... sodium cyanoborohydride and sodium triacetoxyborohydride are poorer reducing agents than sodium borohydride, and their direct ...
Kuwajima Taxol total synthesis
Deprotection (TBAF) to diol 3.3, reprotection as the benzaldehyde acetal 3.4 and reduction (sodium borohydride) to alcohol 3.5 ...
Potassium octacyanomolybdate(IV)
... with potassium borohydride (KBH4) in a solution with potassium cyanide and acetic acid. Yields of 70% are typical and the ...
Chemoselectivity
Examples include the greater relative chemoselectivity of sodium borohydride versus lithium aluminium hydride for the organic ...
Thiazole
... organic reduction with sodium borohydride, and hydrolysis with Mercury(II) chloride in water. Thiazoles can react in ...
Beryllium hydride
... with beryllium borohydride, Be(BH4)2: Be(BH4)2 + 2 PPh3 → BeH2 + 2 Ph3PBH3 Isolated molecules of BeH 2 (sometimes called ...
Dendrimer-encapsulated nanoparticles
After a complex has formed, a reducing agent such as sodium borohydride is introduced in a high molar excess and the metal ions ...
Meyers synthesis
... is reduced with sodium borohydride and the resulting oxazine (a hemiaminal) hydrolyzed with water and oxalic acid to the ...
Paclobutrazol
The final reduction reaction uses sodium borohydride, which in cold methanol gives almost exclusively the diastereomer pair ...
Dodecaborate
It is more conveniently prepared in two steps from sodium borohydride. First the borohydride is converted into a triborate ...
Jocic reaction
... then undergoing a Jocic reaction with either sodium borohydride or sodium phenylseleno(triethoxy)borate as the nucleophile in ...
Sodium dithionite
2 The sodium borohydride method obeys the following stoichiometry: NaBH4 + 8 NaOH + 8 SO2 → 4 Na2S2O4 + NaBO2 + 6 H2O Each ...
Bakthan Singaram
... ketones to enantiomerically pure secondary alcohols in conjunction with the use of the mild reducing agent sodium borohydride. ...
Zirconium(IV) bromide
It can also be prepared by treatment of the borohydride complex with hydrogen bromide: Zr(BH4)4 + 4 HBr → ZrBr4 + 4 H2 + 2 B2H6 ...
Lactone
... tetroxide and lead tetraacetate with ring-opening and finally reduction of the aldehyde to the alcohol with sodium borohydride ...
Thorium
... and the borohydride (first prepared in the Manhattan Project) has coordination number 14. These thorium salts are known for ...
Trinickel boride
Recently it has been found that Ni 3B can be formed (together with other nickel borides) by heating sodium borohydride with ... "The nature of the nickel boride formed by the action of sodium borohydride on nickel salts". Inorganic Chemistry, volume 3, ... "catalyst to 250 °C. This catalyst is produced by reduction of nickel salts with sodium borohydride. Trinickel boride can be ...
Acetoacetate decarboxylase
Reaction of 5-NSA with acetoacetate decarboxylase and subsequent reduction of the resulting Schiff base with sodium borohydride ...
List of German Americans
... co-discovered sodium borohydride in 1940 Frank Schlesinger - astronomer Alfred Schütz - philosopher/sociologist Rusty ...
Sodium hydroselenide
... can be made by reducing selenium with sodium borohydride: Se + NaBH4 → NaSeH + BH3(g) Alternatively it can ...