... (also known as α-Cresol) is an aromatic alcohol with the formula C6H5CH2OH. The benzyl group is often ... Benzyl alcohol is toxic to neonates and is associated with the gasping syndrome. "Benzyl alcohol". Archived from the original ... Sensitization to benzyl alcohol occurs very rarely, mainly in patients with stasis dermatitis. Benzyl alcohol is not considered ... Benzyl esters also occur naturally. Benzyl alcohol is produced industrially from toluene via benzyl chloride, which is ...
... (EC 2.3.1.196, benzoyl-CoA:benzyl alcohol benzoyltransferase, benzoyl-CoA:benzyl alcohol/ ... benzyl alcohol O-benzoyltransferase. This enzyme catalyses the following chemical reaction benzoyl-CoA + benzyl alcohol ⇌ {\ ... Benzyl+alcohol+O-benzoyltransferase at the U.S. National Library of Medicine Medical Subject Headings (MeSH) Portal: Biology ( ... benzyl alcohol benzoyltransferase, benzoyl-coenzyme A:phenylethanol benzoyltransferase) is an enzyme with systematic name ...
It is prepared by treating benzyl chloride with base. Friedrich Brühne; Elaine Wright (2007). "Benzyl Alcohol". Ullmann's ... It is classified as an ether derived from benzyl alcohol. A colorless, nearly odorless oil, the compound's main use is as a ...
It is rapidly hydrolyzed to benzoic acid and benzyl alcohol. Benzyl alcohol is subsequently metabolized to benzoic acid. The ... generated from sodium and benzyl alcohol) as catalyst: Knowles CO (1991). "22.4.2 Benzyl Benzoate". In Hayes WJ, Laws ER (eds ... It is the ester of benzyl alcohol and benzoic acid. It forms either a viscous liquid or solid flakes and has a weak, sweet- ... Benzyl benzoate is produced industrially by the reaction of sodium benzoate with benzyl chloride in the presence of a base, or ...
Another example of a SKIE is the oxidation of benzyl alcohols by dimethyldioxirane where three transition states for different ... Angelis YS, Hatzakis NS, Smonou I, Orfanopoulos M (2006). "Oxidation of benzyl alcohols by dimethyldioxirane. The question of ... By NMR spectroscopy, it is therefore easy to detect whether the alcohol in wine was fermented from glucose, or from illicitly ... Another example of tunneling contribution to proton transfer in enzymatic reactions is the reaction carried out by alcohol ...
... preparation containing benzyl alcohol derivative, polysorbate 80 and propylene glycol should be used in ... "The Gasping Syndrome and Benzyl Alcohol Poisoning". New England Journal of Medicine. 307 (22): 1384-1388. doi:10.1056/ ...
... contain 15 mg benzyl alcohol per 1 mL as a preservative. Premature infants who have been given large amounts of benzyl alcohol ... Gershanik J, Boecler B, Ensley H, McCloskey S, George W (November 1982). "The gasping syndrome and benzyl alcohol poisoning". ...
Benzyl alcohol is used as well. Activators increase the penetration rate; for dichloromethane water is suitable, other choices ...
Alcohol 12 was protected by a benzyl group. The acetonide protecting group was removed from the ketone. Ketone 14 was converted ... The primary alcohol was protected as a silyl ether and the secondary alcohol was activated as a triflate (11). Heating this ... Subsequent reduction using sodium borohydride produced alcohol 51 . Reaction of this alcohol with the Ojima lactam 52 and a ... In the next step, the aldehyde was protected as a dimethyl acetal, and the ester was reduced to give primary alcohol 18. The ...
Benzyl trichloroacetimidate is easily accessible from benzyl alcohol and trichloroacetonitrile. Benzyl trichloroacetimidate is ... 1993). "A useful application of benzyl trichloroacetimidate for the benzylation of alcohols". Tetrahedron. 49 (8): 1619-1624. ... For example, alcohols give O-alkyltrichloroacetimidates under basic catalysis in a direct and reversible addition, which can be ... Schaefer, Fred C.; Peters, Grace A. (1961). "Base-Catalyzed Reaction of Nitriles with Alcohols. A Convenient Route to Imidates ...
Benzyl is most commonly abbreviated Bn. For example, benzyl alcohol can be represented as BnOH. Less common abbreviations are ... In IUPAC nomenclature, the prefix benzyl refers to a C6H5CH2 substituent, for example benzyl chloride or benzyl benzoate. ... Treatment of alcohol with a strong base such as powdered potassium hydroxide or sodium hydride and benzyl halide (BnCl or BnBr ... Benzyl is commonly used in organic synthesis as a robust protecting group for alcohols and carboxylic acids. ...
As a preservative, the injectable solution contains benzyl alcohol. Toxicity from propylene glycol has been reported in the ... They should also not drive, operate machinery, or use alcohol within this period. Drug and alcohol dependence - The risk of ... benzyl alcohol as preservative. Lorazepam injectable solution is administered either by deep intramuscular injection or by ... It is the classic way in which acute alcohol intoxication may affect a person. Benzodiazepines should not be administered to ...
... death and other symptoms resulting from benzyl alcohol poisoning. The symptoms caused by benzyl alcohol explosure include ... Benzyl alcohol Carl R. Baum (2008), "Examples of mass exposures involving the pediatric population", in Jerrold B. Leikin; ... 1982), "The gasping syndrome and benzyl alcohol poisoning", N Engl J Med, 307 (22): 1384-8, doi:10.1056/nejm198211253072206, ... "Neonatal Deaths Associated With Use Of Benzyl Alcohol -- United States". CDC. (Poisons). ...
In Australia, Cēpacol lozenges contain cetylpyridinium chloride and benzyl alcohol. Cepacaine lozenges contains lignocaine and ...
Benzyl alcohol and benzyl chloride and virtually all benzyl derivatives are readily oxidized to benzoic acid. Benzoic acid is ... 3, p. 337 Cosmetic Ingredient Review Expert Panel Bindu Nair (2001). "Final Report on the Safety Assessment of Benzyl Alcohol, ... Reduction to benzaldehyde and benzyl alcohol is possible using DIBAL-H, LiAlH4 or sodium borohydride. Decarboxylation to ... "Oxidation of Benzyl Alcohol using in Situ Generated Hydrogen Peroxide". Organic Process Research & Development. 18 (11): 1455- ...
Formulations of amiodarone that contain benzyl alcohol should not be given to neonates, because the benzyl alcohol may cause ... Centers for Disease Control (CDC) (June 1982). "Neonatal deaths associated with use of benzyl alcohol--United States". MMWR. ...
"New oxidase from Bjerkandera arthroconidial anamorph that oxidizes both phenolic and nonphenolic benzyl alcohols". Biochimica ... that form long-chain unbranched primary alkenes and alcohols, and in the low-pressure polymerization of ethene and propene. ...
"Structure-Reactivity Studies and Catalytic Effects in the Photosolvolysis of Methoxy-Substituted Benzyl Alcohols". J. Chem. Soc ... Additionally, the addition of an o-hydroxy group enables the release of alcohols, phenols and carboxylic acids due to the ... Barltrop and Schofield first demonstrated the use of a benzyl-based PPG, structural variations have focused on substitution to ... Zhao, H.; Sterner, E. S.; Coughlin, E. B.; Theato, P. (28 February 2012). "Nitrobenzyl Alcohol Derivatives: Opportunities in ...
Benzyl alcohol can be formed from benzaldehyde by means of hydrogenation. Reaction of benzaldehyde with anhydrous sodium ... Numerous other methods have been developed, such as the partial oxidation of benzyl alcohol, alkali hydrolysis of benzal ... one molecule of the aldehyde is reduced to the benzyl alcohol and another molecule is simultaneously oxidized to benzoic acid. ... "The benzaldehyde oxidation paradox explained by the interception of peroxy radical by benzyl alcohol" (PDF). Nature ...
It is formed by the condensation of benzyl alcohol and acetic acid. Similar to most other esters, it possesses a sweet and ... It is collected and used by the bees as an intra-specific pheromone; In apiculture benzyl acetate is used as a bait to collect ... "Benzyl acetate". The Good Scents Company. Schiestl, F.P. & Roubik, D.W. (2004). "Odor Compound Detection in Male Euglossine ... Natural sources of benzyl acetate include varieties of flowers like jasmine (Jasminum), and fruits like pear, apple, etc. " ...
The ketone is then reduced with sodium borohydride yielding a benzyl alcohol. Condensation with 4-hydroxycoumarin under HCl ... She had no history of liver disease or alcohol or illicit substance abuse. Initial physical examination was remarkable only for ...
It contains 2% benzyl alcohol, so it is less painful than ethanol. However it does cause hemolysis and kidney failure in large ... The alcohol does need some time to denature proteins of the endothelium and activate the coagulation system to cause a blood ... polyvinyl alcohol (PVA) - These are permanent agents. They are tiny balls 50-1200 um in size. The particles are not meant to ... Ethylene Vinyl Alcohol Copolymer, soluted in Dimethyl-Sulfoxide (DMSO) under the trade name Onyx. Depending on the desired ...
Peligot's salt can oxidize benzyl alcohol, a reaction which can be catalyzed by acid. A related salt, pyridinium chlorochromate ... Özgün, B.; Pek, A. (1991). "Kinetics and mechanism of the oxidation of benzyl alcohol by potassium chlorochromate". Reaction ...
There is a formulation with benzyl alcohol, which is toxic to babies; other formulations should be used. Sargramostim has not ...
Newer generic formulations contain sodium metabisulfite or benzyl alcohol as antimicrobial agents. Propofol emulsion is an ... The American Journal of Drug and Alcohol Abuse. 40 (6): 428-437. doi:10.3109/00952990.2014.933840. PMID 25083822. S2CID ...
... (veratryl alcohol) is an organic compound related to veratrole and also to benzyl alcohol. It can be obtained ... Veratrole alcohol is the raw material for the synthesis of cyclotriveratrylene which is used in host-guest chemistry. It is a ... Zapanta, L. S.; Tien, M. (1997). "The roles of veratryl alcohol and oxalate in fungal lignin degradation". Journal of ... Primary alcohols, All stub articles, Aromatic compound stubs). ...
Another isomer of cresol is called Benzyl alcohol, or alpha-cresol (α-cresol). Benzyl alcohol has a hydroxy group inside a ...
... solutions often contain preservatives such as benzalkonium chloride and benzyl alcohol. Preservative-free products ...
An early method for production of benzoyl chloride involved chlorination of benzyl alcohol. It reacts with water to produce ... It reacts with alcohols to give the corresponding esters. Similarly, it reacts with amines to give the amide. It undergoes the ...
For example, benzaldehyde decomposes into benzoic acid and benzyl alcohol, the Cannizzaro reaction. In the autumn of 1855, ... Cannizzaro, S. (1853). "Ueber den der Benzoësäure entsprechenden Alkohol" [On the alcohol corresponding to benzoic acid]. ... aldehydes are decomposed by an alcoholic solution of potassium hydroxide into a mixture of the corresponding acid and alcohol. ...