Alkylation with N-Ethylpropylamine [20193-20-8] (4) gives Etidocaine (5). Sisk AL (1992). "Long-acting local anesthetics in ...
Bintang, Liu; Jinquan, Yu; Aiqun, Eng; Ping, Zhou; Shude, Xiao (1995-06-25). "Study on selective alkylation of guaiacol with ...
van Aalten, Lloyd; Seely, G. R.; Oliver, Juhn; Ritter, D. M. (1 June 1961). Kinetics and Equilibria in the Alkylation of ...
Alkylation with N-Butylamine (4) completed the synthesis of Butanilicaine (5). Haussler A, Ther L. [Chemical detection of ...
Typically the reaction is used for the alkylation of aryl halides; however, with the use of ultrasound the reaction can also be ...
Blanc reaction Electrophilic aromatic substitution Friedel-Crafts Alkylation Wang, Zerong (2009). "517: Quelet Reaction". ...
This transformation include alkylations with other classes of activated alkyl halides of synthetic interest. In particular, the ... In this approach for the α-alkylation of aldehydes, [Ru(bipy)3]2+ reductively fragments an activated alkyl halide, such as ... This type of mechanism is excluded for the photocatalytic alkylation reaction because whereas enamine radical cation was ... also investigated the productive merger of photoredox and organocatalytic methods to achieve enantioselective alkylation of ...
Beak P. (1977). "Energies and Alkylation of Tautomeric Heterocyclic-Compounds - Old Problems New Answers". Acc. Chem. Res. 10 ( ...
It also catalyzes alkylation reactions and the extraction of certain ores. Industrially significant organic compounds prepared ...
van Aalten, Lloyd; Seely, G. R.; Oliver, Juhn; Ritter, D. M. (1 June 1961). Kinetics and Equilibria in the Alkylation of ...
Ketone 2 was constructed via Enders alkylation starting from the hydrazone. Ozonolysis, the last step of the Enders alkylation ...
Members of an alkylation series have the same Kendrick mass defect. The Kendrick mass defect has also been defined as Kendrick ... Ions of the same family, for example the members of an alkylation series, have the same Kendrick mass defect but different ... The members of an alkylation series have the same degree of unsaturation and number of heteroatoms (nitrogen, oxygen and sulfur ...
Alkylation−Reoxidation: A Functionalization Sequence for Single-Wall Carbon Nanotubes". Journal of the American Chemical ... "Preferred functionalization of metallic and small-diameter single walled carbon nanotubes via reductive alkylation". Journal of ...
Also common are the 2-substituted derivatives with the formula RCH(CO2R)2, which arise by C-alkylation of the conjugate base ( ... They are often prepared by alkylation of the enolate of malondialdehyde. 1,3-Diketones are also called β-diketones. An ...
Bersohn, Malcolm (1961). "C versus O Alkylation in the Case of a Stable Cation". J. Am. Chem. Soc. 83 (9): 2136-2138. doi: ...
Its conjugate base, dithiobenzoate, undergoes S-alkylation to give dithiocarboxylate esters. Similarly, dithiobenzoate reacts ...
Similarly, alkylation with Grignard reagents provides a route to tertiary alcohols. Alkylation and arylation can be achieved ...
Quaternary ammonium compounds are prepared by the alkylation of tertiary amine. Industrial production of commodity quat salts ...
... obtained by the alkylation of phosphorus trichloride: RCl + PCl3 + AlCl3 → [RPCl3]+AlCl− 4 The main industrial procedure for ... are produced by alkylation of organophosphines. For example, the reaction of triphenylphosphine with methyl bromide gives ...
Nucleophilic catalysis of alkylation is rare, because protodesilylation tends to occur. Lewis acid activation is more commonly ...
OLT1177 is synthesized by alkylation of sodium methanesulfinate with 3-bromopropionitrile. This reaction produces crude ...
The main metabolic pathway for acrolein is the alkylation of glutathione. The WHO suggests a "tolerable oral acrolein intake" ...
Examples include Diels-Alder reactions, 1,3-dipolar cycloadditions, Friedel-Crafts alkylations or Michael additions. MacMillan ... Crafts Alkylation". Journal of the American Chemical Society. American Chemical Society (ACS). 123 (18): 4370-4371. doi:10.1021 ... The Direct Asymmetric Alkylation of Aldehydes". Science. 322 (5898): 77-80. Bibcode:2008Sci...322...77N. doi:10.1126/science. ...
Le, Chip; Liang, Yufan; Evans, Ryan W.; Li, Ximing; MacMillan, David W. C. (2017). "Selective sp3 C-H alkylation via polarity- ...
Although they are considered more reactive than Grignard reagents in alkylation, their use is still limited due to competing ... Most organolithium reagents used in alkylations are more stabilized, less basic, and less aggregated, such as heteroatom ... From Pinacolone to Selective C-Alkylations of Peptides. Difficulties and Opportunities Afforded by Complex Structures" (PDF). ... enolates are widely used as nucleophiles in carbon-carbon bond formation reactions such as aldol condensation and alkylation. ...
Two sequential deprotonation-alkylation reactions and a subsequent sulfur-lithium exchange reaction allow the synthesis of tri- ... An Exceptional Building Block for Isocyanide Alkylations". Organic Letters. 20 (18): 5910-5913. doi:10.1021/acs.orglett.8b02574 ...
"Carbon-Carbon Alkylations with Amines and Ammonium Salts". Organic Reactions. 7 (3): 99-197. doi:10.1002/0471264180.or007.03. ...
doi:10.1002/anie.201205449 Efficient catalytic asymmetric alkylations. 1. Enantioselective synthesis of (+)-indacrinone via ...
A total synthesis of biotin based on the stereoselective alkylation of sulfoxides. J. Am. Chem. Soc., 1978, 100, 1558. 1961: ...
Several dyes are prepared by the alkylation of aniline derivatives with chloroethanol. It is also used for manufacture of ...