... alkane monooxygenase, 1-hydroxylase, AlkB, and alkane hydroxylase. It contains a diiron non-heme active site. Recently two ... In enzymology, an alkane 1-monooxygenase (EC 1.14.15.3) is an enzyme that catalyzes the chemical reactions an alkane + reduced ... Alkanes of 6 to 22 carbons have been observed as substrates. This enzyme belongs to the family of oxidoreductases, specifically ... The systematic name of this enzyme class is alkane, reduced-rubredoxin:oxygen 1-oxidoreductase. Other names in common use ...
... camphor 5-monooxygenase MeSH D08.811.682.690.708.170.500 - alkane 1-monooxygenase MeSH D08.811.682.690.708.170.915 - steroid ... 4-hydroxybenzoate 3-monooxygenase MeSH D08.811.682.690.708.557 - kynurenine 3-monooxygenase MeSH D08.811.682.690.708.601 - ... trans-cinnamate 4-monooxygenase MeSH D08.622.509.700 - pepsinogen a MeSH D08.622.509.725 - pepsinogen c MeSH D08.622.610.500 - ... monophenol monooxygenase MeSH D08.811.682.690.708.170 - cytochrome p-450 enzyme system MeSH D08.811.682.690.708.170.040 - aryl ...
... alkane, reduced-rubredoxin:oxygen 1-oxidoreductase) octane + reduced rubredoxin + O2 = 1-octanol + oxidized rubredoxin + H2O EC ... 2-monooxygenase [(+)-camphor, reduced-rubredoxin:oxygen oxidoreductase (1,2-lactonizing)] (+)-bornane-2,5-dione + reduced ... 1] The lower Fe2+ cation change of the reduced state leaves a higher negative charge on the Cys 9 Sγ-donor which attracts water ... Calderon, RH; de Vitry, C; Wollman, FA; Niyogi, KK (February 2023). "Rubredoxin 1 promotes the proper folding of D1 and is not ...
The n-alkanes are oxidized by monooxygenase to secondary alcohols, then to ketones and finally to fatty acids. R 1 − ( CH 2 ... linear alkanes branched alkanes > small aromatics > cyclic alkanes. Some compounds, such as the high molecular weight ... From the oxidation of the methyl group of n-alkanes by the alkane hydroxylase, n-alkanols are released which are further ... where toluene is converted into o-cresol by toluene 2-monooxygenase and subsequently another monooxygenase converts it to 3- ...
... olei to utilize petroleum hydrocarbons in farmland soil can be explained by its lack of alkane monooxygenase and aromatic ring- ... 1-13. ISBN 978-1-118-96060-8. Yabuuchi, E.; T. Kaneko; I. Yano; C.W. Moss; N. Miyoshi. (1 July 1983). "Sphingobacterium gen. ... Liu, Bin; Yang, Xiaojun; Sheng, Mengyao; Yang, Zhou; Qiu, Jiguo; Wang, Chenghong; He, Jian (1 March 2020). "Sphingobacterium ... 1 June 2017). "Sphingobacterium alkalisoli sp. nov., isolated from a saline-alkaline soil". International Journal of Systematic ...
Rasche ME, Hicks RE, Hyman MR, Arp DJ (September 1990). "Oxidation of monohalogenated ethanes and n-chlorinated alkanes by ... "Evidence that particulate methane monooxygenase and ammonia monooxygenase may be evolutionarily related". FEMS Microbiology ... Ammonia+monooxygenase at the U.S. National Library of Medicine Medical Subject Headings (MeSH) Portal: Biology (EC 1.14.99). ... Ammonia monooxygenase (EC 1.14.99.39, AMO) is an enzyme, which catalyses the following chemical reaction ammonia + AH2 + O2 ...
2-monooxygenase. EC 1.14.15.3: alkane 1-monooxygenase EC 1.14.15.4: steroid 11β-monooxygenase EC 1.14.15.5: corticosterone 18- ... valine N-monooxygenase EC 1.14.14.39: isoleucine N-monooxygenase EC 1.14.14.40: phenylalanine N-monooxygenase EC 1.14.14.41: (E ... steroid 17α-monooxygenase EC 1.14.99.10: Now EC 1.14.14.16, steroid 21-monooxygenase EC 1.14.99.11: estradiol 6β-monooxygenase ... arginine 2-monooxygenase EC 1.13.12.2: lysine 2-monooxygenase EC 1.13.12.3: tryptophan 2-monooxygenase EC 1.13.12.4: lactate 2- ...
Musaev, Djamaladdin G.; Basch, Harold; Morokuma, Keiji (2002). "Theoretical Study of the Mechanism of Alkane Hydroxylation and ... "Computational studies of reaction mechanisms of methane monooxygenase and ribonucleotide reductase". Journal of Computational ... 23 (1): 59-76. doi:10.1002/jcc.1157. ISSN 0192-8651. PMID 11913390. S2CID 24420102. Basch, Harold; Ratner, Mark A. (2003). " ...
Alkanes are the least reactive class of hydrocarbons due to their apolar sigma bonds. In the absence of high temperatures, high ... but serves as a reactant in the hydroxylation of both aliphatic and aromatic hydrocarbons via monooxygenase and dioxygenase ... It has also been shown that AK-01 uses not only alkanes but also 1-alkenes, 1-alkanols, fatty acids and other organic acids as ... AK-01 is a delta-proteobacterium capable of using C13-C18 alkanes as growth substrates (So et al., 1999). Analysis of labeled ...
... (MMO) is an enzyme capable of oxidizing the C-H bond in methane as well as other alkanes. Methane ... The particulate methane monooxygenase and related ammonia monooxygenase are integral membrane proteins, occurring in ... "Evidence that particulate methane monooxygenase and ammonia monooxygenase may be evolutionarily related". FEMS Microbiology ... This is a classic monooxygenase reaction in which two reducing equivalents from NAD(P)H are utilized to split the O-O bond of ...
The transformation can also performed biologically by methane monooxygenase. Overall Transformation RH + H2O + [PtCl6]2− → ROH ... "Reactions of alkanes in solutions of platinum chloride complexes" Zh. Fiz. Khim. 1972, 46, 1353-13544 Gol'dshleger, N. F.; ... and the nucleophilic oxidation of the alkane substrate. An equivalent transformation is performed industrially by steam ... 1] and [2] ). Such premature oxidation shuts down the catalysis. Finally the PtIV-CH2R undergoes nucleophilic attack by OH− or ...
These monooxygenases are especially important, as they account for long-chain n-alkane hydroxylation. A. Pacificus is closely ... Found were genes encoding for four integral-membrane alkane monooxygenases, three cytochrome P450 enzymes, and four genes ... Part of this difference results from a 549 nucleotide fragment of the alkane hydroxylase gene alkB, which was amplified from ... Lai Q, Shao Z (December 2012). "Genome sequence of an alkane-degrading bacterium, Alcanivorax pacificus type strain W11-5, ...
Another example is Mycobacterium vaccae, which uses an alkane monooxygenase enzyme to oxidize propane. Accidentally, this ... OX1 can degrade PCE under aerobic conditions by using toluene-o-xylene monooxygenase (ToMO), an enzyme they produce to derive ... Several aerobic microorganisms have been demonstrated to be capable of doing this, including n-alkane, aromatic compound (e.g. ... These bacteria degrade their growth-substrate methane with the enzyme methane monooxygenase (MMO). MMO was discovered to be ...
The methanol reacts in the presence of a zeolite catalyst to form alkanes. In terms of mechanism, methanol is partially ... The relevant enzymes are methane monooxygenases, which are found both in soluble and particulate (i.e. membrane-bound) ... alkanes), aromatics, naphthenes (cycloalkanes) and small amounts of olefins (alkenes), mostly from C6 (number of carbon atoms ... Most of the non-condensed gas from the product separator becomes recycled gas and is sent back to the feed stream to Reactor 1 ...
The aerobic metabolism of alkanes is carried out through the terminal alkane oxidation pathway, where monooxygenases initiate ... borkumensis can consume a wider variety of alkanes than other known species. A. borkumensis primarily uses alkanes as its ... The A. borkumensis genome has many sequences that each code for a different type of alkane, allowing it to be highly adaptable ... Whereas most organisms use sugars or amino acids for their source of carbon/energy, A. borkumensis uses alkanes, a type of ...
Alkane hydroxylase is thought to play a similar role in pseudomonas species capable of polyethylene degradation. Once enzymes ... Following the monooxygenase step, the polystyrene molecule is transformed into phenylacetic acid during the upper pathway of ... Bacteria that are capable of degrading this molecule are documented to release monooxygenases to initiate the oxidization of ... 4 (1): 15. doi:10.1186/s40643-017-0145-9. ISSN 2197-4365. S2CID 3698066. Luu, Rita A.; Schneider, Benjamin J.; Ho, Christie C ...
Thermophilic Thermus and Bacillus species have demonstrated higher gene expression for the alkane mono-oxygenase alkB at ... 5 (1): 109-16. doi:10.1111/j.1758-2229.2012.00348.x. PMID 23757139. Krupovic M, Gonnet M, Hania WB, Forterre P, Erauso G (2013 ... 26 (1): 44-71. doi:10.1039/b800164m. PMID 19374122. Rossi M, Ciaramella M, Cannio R, Pisani FM, Moracci M, Bartolucci S (July ... 4 (1): 110-21. Fakayode, S.O. (2005). "Impact assessment of industrial effluent on water quality of the receiving Alaro River ...
... or methane monooxygenase (MMO), which degrade various environmental pollutants (i.e.: alkanes, alkenes, and mono- and poly- ... encoding a subunit of particulate methane monooxygenase), and fae (encoding formaldehyde activating enzyme) genes." The data ... 1. p. 233-238. Baev M V, Chistoserdova L V, Polanuer B M, et al. "Effect of formaldehyde on growth of obligate methylotroph ... p. 1-10. Marchenko GN, Marchenko ND, Tsygankov YD, Chistoserdov AY. "Organization of threonine biosynthesis genes from the ...
Averaging across all studied species, 98.1%, 48.6%, and 76.4% of the initial Bunker C C10 alkane, C14 alkane, and phenanthrene ... certain fungi possess intracellular networks which constitute the xenome, consisting of cytochrome (CYP) P450 monooxygenases ... The subphylum Saccharomycotina mostly consists of yeasts and includes degraders of n-alkanes, n-alkylbenzenes, crude oil, the ... 198 (Pt 2): 1-11. doi:10.1016/j.jenvman.2017.05.010. PMID 28499155. The levels of adsorption of the phenolic and PAHs were ...
The enzyme methane monooxygenase produces methanol from methane, but cannot be used for industrial-scale reactions. Some ... Etymologically, the word methane is coined from the chemical suffix "-ane", which denotes substances belonging to the alkane ... Hydrogen Cycle Industrial gas Lake Kivu (more general: limnic eruption) List of straight-chain alkanes Methanation Methane ... 57-58 McBride, James Michael (1999) "Development of systematic names for the simple alkanes". Chemistry Department, Yale ...