of the Gesellschaft Deutscher Chemiker 1994 International Edition in English 33/21 Pages 2121 -2228 COVER PICTURE The cover picture shows probably the most densely oxygenated complex fragment of ! The central triol-triacid "core" a natural product yet synthesized-C,,H,,O, (space-filling model at the top) of the fungal metabolite zaragozic acid A/squalestatin S1 (structural formula and space-filling model at the bottom) is depicted. Showing unprecedented promise as a medicinally useful inhibitor of squalene synthase (the enzyme controlling the first committed step in the biosynthesis of cholesterol), zaragozic acid A has attracted much attention in biological and chemical circles. The synthesis of the central core and the first total synthesis of zaragozic acid A/ squalestatin S1- -another race is over are described by K. C. Nicolaou et al. on p. 2184ff, 1187ff.. and 2190ff. (Red: oxygen. black: carbon, white: hydrogen; photograph: L. Gomez-Paloma, The Scripps Research Institute.) REVIEWS ...
2672-58-4 - RGCHNYAILFZUPL-UHFFFAOYSA-N - Trimethyl benzene-1,3,5-tricarboxylate - Similar structures search, synonyms, formulas, resource links, and other chemical information.
Ross, B C, Chan, C, Cox, B, Evans, G L, Giblin, G M P, Lester, M G, McCarthy, A D, Procopiou, P A, Sareen, M, Sharratt, P J and Watson, N S (1993) The squalestatins: potent inhibitors of squalene synthase. In: 206th American Chemical Society National Meeting, August 22-27, 1993, Chicago, Illinois, USA. Full text not available from this repository ...
Montalbo, R G. and Kabara, J J., "Tricarboxylic acid cycle intermediates in muscular dystrophic mice (strain 129)." (1974). Subject Strain Bibliography 1974. 1366 ...
TA and TB toxins are host-specific phytotoxins produced by the fungus Altemaria altemata f. sp. Iycopersici, the causative agent of stem canker disease in tomato. The two toxins are similar in structure: TB lacks the C(5) hydroxy group present in TA toxin. Both compounds are isolated as an equilibrium mixture of the two esters formed by either the C(13) or C(14) hydroxy groups of the (2S,4R,5R,11R,13S,14R,15R)-1-amino-11,15¬dimethylhepta-decane-2,4,5, 13, 14-pentol backbone with the Re prochiral carboxy group of tricarballylic acid. The synthesis for these toxins is necessary in order to study their structure-activity relationships. The aim of the synthetic study outlined in this dissertation is the development and implementation of methodology for the synthesis of the C(1)-C(9) unit of the C17 aminopentol backbone of TA toxin with the appropriate stereochemistry. Retrosynthetic analysis of the C17 aminopentol backbone of TA toxin identifies (2R,4S,-5R,6R)-2,6-dimethyloctane-1.4,5-triol, ...
K00164 2-oxoglutarate dehydrogenase E1 component [EC:1.2.4.2] , (GenBank) sucA; E1(0) component of 2-oxoglutarate dehydrogenase, subunit of 2-oxoglutarate decarboxylase, thiamin-requiring and 2-oxoglutarate dehydrogenase ...
Hepatic organelle interaction. II. Effect of tricarboxylic acid cycle intermediates on N-demethylation and hydroxylation reactions in rat liver.:
cis-Aconitate is used to designate the isomer (Z)-prop-1-ene-1,2,3-tricarboxylate. This isomerization could take place either in a direct cis-trans interconversion or by an allylic rearrangement; the enzyme has been shown to catalyse the latter change ...
3-[(E)-1-[4-[2-(dimethylamino)ethoxy]phenyl]-2-phenylbut-1-enyl]phenol,2-hydroxypropane-1,2,3-tricarboxylic acid 97752-20-0 safety info, 3-[(E)-1-[4-[2-(dimethylamino)ethoxy]phenyl]-2-phenylbut-1-enyl]phenol,2-hydroxypropane-1,2,3-tricarboxylic acid chemical safety search, Chemical 3-[(E)-1-[4-[2-(dimethylamino)ethoxy]phenyl]-2-phenylbut-1-enyl]phenol,2-hydroxypropane-1,2,3-tricarboxylic acid safety technical specifications ect.
2.A.47 The Divalent Anion:Na+ Symporter (DASS) Family. Functionally characterized proteins of the DASS family (also called the SLC13 family) transport (1) organic di- and tricarboxylates of the Krebs Cycle as well as dicarboxylate amino acid, (2) inorganic sulfate and (3) phosphate. These proteins are found in Gram-negative bacteria, cyanobacteria, archaea, plant chloroplasts, yeast and animals. They vary in size from 432 amino acyl residues (M. jannaschii) to 923 residues (Saccharomyces cerevisiae). The three S. cerevisiae proteins are large (881-923 residues); the animal proteins are substantially smaller (539-616 residues), and the bacterial proteins are still smaller (461-612 residues). They exhibit 11-14 putative transmembrane α-helical spanners (TMSs). An 11 TMS model for the animal NaDC-1 and hNaSi-1 carriers has been proposed (Li and Pajor, 2003; Pajor, 1999). Two serine residues in the human sulfate transporter, hNaSi-1 (Q9BZW2), one in TMS 5 and one in TMS 6, are required for sulfate ...
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Figure: Reaction of the isomerisation of citrate to isocitrate. In the second reaction of the Krebs cycle, the isomerisation of citrate to isocitrate takes place. As an intermediate, cis-aconitate is formed. Therefore, it is a two-step reaction sequence. In the first step, H2O is removed from the cireate molecule (see Figure). Thie dehydration ledas to the intermediate, cis-aconitate which is bound to the enzyme. In the second step, cis-aconitate is hydrated again. Therefore, the proton (from C2 to C3) and the OH group (from C3 to C2) swap places. A tretiary aclohol is transformed into a secondary alcohol.. This conversion is of utmost importance for the subsequent decarboxylation, because a tertiary alcohol (the citrate) can not be directly oxidized to a keto carboxylic acid.. ...
If a substance is on this list, it means that a Member State has evaluated or will evaluate it over the coming years. The list is called the Community rolling action plan (CoRAP).. For each substance, the table shows the evaluating Member State, the (planned) year of evaluation and a short description of the concern which led to it being placed on the list.. Documents to do with substance evaluation are also available here. They include: documents justifying selection of the substances, decisions to request more information. Member States conclusions and Member States final evaluation reports are included for substances for which evaluation has been finalised.. ...
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice ...
mouse Sfxn3 protein: CTPL - citrate transporter protein-like protein; Sfxn family member expressed in pancreatic islet; RefSeq mRNA Sequence NM_053197; Source Sequence BC012208; Product NP_444427 sideroflexin 3
Current therapies for Parkinsons disease are able to ameliorate the symptoms in the early stages, however as the disease progresses, they become less effective and patients often develop debilitating side effects. There is currently a significant unmet need for disease modifying or neuroprotective drugs to slow the rate of disease progression and provide long-term symptomatic relief. Novel therapeutics that can provide symptomatic relief whilst attenuating the ongoing neurodegeneration are therefore sought. The targeting of metabotropic glutamate (mGlu) receptors has become a therapeutic focus in recent years. The group III mGlu receptors are the focus of this thesis as they currently hold the most therapeutic promise, with evidence suggesting activation of these receptors not only modulates aberrant neurotransmission in the basal ganglia to provide symptom relief, but also provides neuroprotective effects in the nigrostriatal system through a variety of mechanisms. Recent advances in the ...
Acosta-Cabronero J, Betts MJ, Cardenas-Blanco A, Yang S, Nestor PJ (2015). In vivo MRI mapping of brain iron deposition across the adult lifespan. J.Neurosci. (in press). Betts MJ, ONeill M, Duty S (2012). Allosteric modulation of the group III mGlu receptor 4 provides functional neuroprotection in the rodent 6-OHDA model of Parkinsons disease. Br J Pharmacol. Aug;166(8):2317-30. Broadstock M, Austin P, Betts MJ, Duty S (2012). Antiparkinsonian potential of targeting group III metabotropic glutamate receptor subtypes in the rodent substantia nigra pars reticulata. Br J Pharmacol. Feb;165(4b):1034-45. Austin P, *Betts MJ, Broadstock M, ONeill M, Mitchell S, Duty S (2010). Symptomatic and neuroprotective effects following activation of nigral group III metabotropic glutamate receptors in rodent models of Parkinsons disease. Br J Pharmacol. Aug;160(7):1741-5. * Denotes co-first author. Book chapters. Düzel E, Guitart-Masip M, Maaß A, Haemmerer D, Betts M, Speck O, Weiskopf N, Kanowski M ...
Koerner and Cotman (1981) initially described that the diacidic amino acid analog l-2-amino-4-phosphonobutyric acid (l-AP4) selectively suppressed glutamate excitations by a presynaptic mechanism in the lateral perforant pathway of the hippocampus. This inhibitory activity of l-AP4 on glutamate excitations was also observed in other preparations, including the mossy fiber synapse, lateral olfactory tract, and spinal cord (seeThomsen, 1997). Until the 1990s, presynaptic inhibition induced by l-AP4 was ascribed to a relatively nebulous "l-AP4" receptor. However, with the cloning of the group III mGlu receptors, which Nakanishi (1992) defined by their sensitivity to l-AP4, it was recognized that certain group III mGlu subtypes might be responsible forl-AP4-induced suppression of glutamate release. Current data suggest a role for mGlu7, mGlu8, and possibly mGlu4 as candidates for these presynaptic effects of l-AP4 in the brain (seeThomsen, 1997).. In general, when compared with mGlu7 or mGlu2/3 ...
Thus, the two substrates of this enzyme are (1R,2S)-1-hydroxybutane-1,2,4-tricarboxylate and NAD+, whereas its 4 products are 2-oxoadipate, CO2, NADH, and H+. This enzyme belongs to the family of oxidoreductases, specifically those acting on the CH-OH group of donor with NAD+ or NADP+ as acceptor. The systematic name of this enzyme class is (1R,2S)-1-hydroxybutane-1,2,4-tricarboxylate:NAD+ oxidoreductase (decarboxylating). Other names in common use include 2-hydroxy-3-carboxyadipate dehydrogenase, 3-carboxy-2-hydroxyadipate dehydrogenase, homoisocitric dehydrogenase, (−)-1-hydroxy-1,2,4-butanetricarboxylate:NAD+ oxidoreductase, (decarboxylating), 3-carboxy-2-hydroxyadipate:NAD+ oxidoreductase (decarboxylating), and HICDH. This enzyme participates in lysine biosynthesis. ...
In this study we investigated the transcriptional role of the sterol regulatory element (SRE) present in the promoter of the mitochondrial citrate carrier (CIC). We show that wild-type (but not mutated) CIC SRE cloned in front of the luciferase promoter confers transcriptional activation of the gene reporter. We also demonstrate that insulin activates, and polyunsaturated fatty acids (PUFA) inhibit, the gene reporter activity driven by the CIC promoter containing wild-type (but not mutated) SRE. Finally, both insulin treatment and overexpression of SRE binding protein (SREBP-1) increase the CIC transcript and protein levels, whereas PUFA have an opposite effect. These results show that SRE/SREBP-1 play a role in the transcriptional regulation of CIC by insulin and PUF. ...
Chemicals - Water Treatment China, 2 Phosphonobutane 1 4 Tricarboxylic Acid Sodium Salt Pbtca Na4, 2-Phosphonobutane -1, 2, 4-Tricarboxylic Acid, Sodium salt (PBTCA•Na4) CAS No. 40372-66-5 Molecular Formula: C7H7O9P•Na4...
Pravastatin AET is a medicine available in a number of countries worldwide. A list of US medications equivalent to Pravastatin AET is available on the Drugs.com website.
HELOCUR ist ein breit wirksames Fungizid aus der Gruppe der Ergosterol-Biosynthesehemmer mit systemischen Eigenschaften gegen pilzliche Krankheitserreger in Getreide- und Rapskulturen. Es erreicht eine Wirkungsdauer von mehreren Wochen und wirkt sowohl vorbeugend (protektiv) als auch befallsstoppend (kurativ bzw. eradikativ).. Aufwandmengen:. Winterweizen: Frühjahrsanwendung Echter Mehltau (BBCH30-61) 1,0 l/ha. Braunrost (BBCH 30-69) 1,0 l/ha. Gelbrost (BBCH 30-69) 1,0 l/ha. Spätanwendung Fusarium-Arten (BBCH 61-69) 1,0 l/ha. Wintergerste und -triticale: Frühjahrsanwendung echter Mehltau (30-61) 1,25 l/ha. Wintertriticale: Spätanwendung Fusarium-Arten (BBCH 61-69) 1,25 l/ha. Winterraps: Herbstanwendung Phoma (BBCH16) und Frühjahrsanwendung Phoma (BBCH55-59) 1,5 l/ha. ...
TY - JOUR. T1 - Squalene synthetase. Solubilization from yeast microsomes of a phospholipid requiring enzyme. AU - Agnew, William. AU - Popjak, G.. PY - 1978. Y1 - 1978. UR - http://www.scopus.com/inward/record.url?scp=0017821357&partnerID=8YFLogxK. UR - http://www.scopus.com/inward/citedby.url?scp=0017821357&partnerID=8YFLogxK. M3 - Article. C2 - 350878. AN - SCOPUS:0017821357. VL - 253. SP - 4574. EP - 4583. JO - Journal of Biological Chemistry. JF - Journal of Biological Chemistry. SN - 0021-9258. IS - 13. ER - ...
New imidyl-benzene-dicarboxylic and -tricarboxylic acid derivatives, in particular 5-maleimidyl-trimellitic acid derivatives and 3,5-bis-(maleimidyl)-phthalic acid derivatives, and a process for their manufacture are described. These imidyl-benzene-dicarboxylic and -tricarboxylic acid derivatives are suitable for the manufacture of crosslinkable polymers, above all polycondensation and polymerization products, which are distinguished by good processability and good solubility in customary organic solvents. Imidyl compounds, according to the definition, which have anhydride groups can also be used as curing agents for optionally modified epoxide resins.
The report generally describes 3-bromopropane-1,1,1-tricarboxylic acid triethyl ester, examines its uses, production methods, patents. 3-Bromopropane-1,1,1-tricarboxylic
2CGO: Structural and Mechanistic Studies on the Inhibition of the Hypoxia-Inducible Transcription Factor Hydroxylases by Tricarboxylic Acid Cycle Intermediates.
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Reitman and colleagues had a hunch that the genetic mutation seen in cancer might trigger a similar functional change to a closely related enzyme found in yeast and bacteria (homoisocitrate dehydrogenase), which would create the elusive 2-hydroxyadipate dehydrogenase necessary for "green" adipic acid production.. They were right. The functional mutation observed in cancer could be constructively applied to other closely related enzymes, creating a beneficial outcome - in this case the missing link that could enable adipic acid production from cheap sugars. The next step will be to scale up the overall adipic acid production process, which remains a considerable undertaking.. "Its exciting that sequencing cancer genomes can help us to discover new enzyme activities," Reitman said. "Even genetic changes that occur in only a few patients could reveal useful new enzyme functions that were not obvious before.". Yan, a professor in the Department of Pathology and senior author of the study, said the ...
The PDB archive contains information about experimentally-determined structures of proteins, nucleic acids, and complex assemblies. As a member of the wwPDB, the RCSB PDB curates and annotates PDB data according to agreed upon standards. The RCSB PDB also provides a variety of tools and resources. Users can perform simple and advanced searches based on annotations relating to sequence, structure and function. These molecules are visualized, downloaded, and analyzed by users who range from students to specialized scientists.
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Round 2 [Aug 16] IK Sirius 1-1 Hammarby IF [aet, 4-3 pen] [Aug 18] Enskede IK 0-1 Landskrona BoIS IK Frej 2-1 Trelleborgs FF L rje/Angereds IF 1-1 sters IF [aet, 2-3 pen] IFK Uddevalla 0-7 Syrianska FC Kristianstads FF 1-2 Falkenbergs FF Nyk pings BIS 5-3 IF Brommapojkarna [aet] Ronneby BK 2-5 Halmstads BK IFK H ssleholm 0-2 Ume FC Karlstad BK 0-0 Gefle IF [aet, 3-4 pen] stersunds FK 0-3 Mj llby AIF Raml sa S dra FF 0-7 Assyriska FF Rynninge IK 0-2 IFK Norrk ping Aram./Syr. Botkyrka 1-3 GIF Sundsvall Valsta Syrianska IK 0-1 IK Brage [Aug 19] Sel nger FK 0-6 Ljungskile SK Mariehem SK 0-2 rebro SK Motala AIF 1-2 Varbergs BoIS Torns IF 1-2 ngelholms FF karps IF 0-3 BK H cken rgryte IS 3-0 Degerfors IF R sl tt SK 2-3 IFK V rnamo Sk vde AIK 0-3 tvidabergs FF Utsiktens BK 0-3 GAIS IK Sleipner 0-2 J nk pings S dra IF [aet] [Aug 20] Dalstorps IF 1-5 Djurg rdens IF FC Gute 0-4 Kalmar FF L ngholmen FC 0-9 IFK G teborg Sandvikens IF 3-6 Malm FF [aet] [Sep 12] Torslanda IK 0-1 AIK [Nov 11] FC H llviken 1-2 ...
Developed as part of Rafaels proprietary Altered Energy Metabolism Directed (AEMD) drug platform, CPI-613 was discovered at Stony Brook University. CPI-613 is designed to target the mitochondrial tricarboxylic acid (TCA) cycle, an indispensable process essential to tumor cell multiplication and survival, selectively in cancer cells.. CPI-613s attack on the TCA cycle also substantially increases the sensitivity of cancer cells to a diverse range of chemotherapeutic agents. This synergy allows for combinations of CPI-613 with lower doses of these generally toxic drugs to be highly effective with lower patient side effects. Combinations with CPI-613 represent a diverse range of potential opportunities to substantially improve patient benefit in many different cancers.. ...
At the end of the month, the dreaded sequester is set to take effect. Hands up if you know what exactly that means - and be honest. Dont worry, were here to set you straight. Read on for answers to some of the most-asked questions about the impending cuts.
5-Hydroxy-4-oxo-5-(2-oxopropyl)-4,5-dihydro-1h-pyrrolo[2,3-f]quinoline-2,7,9-tricarboxylic acid | C17H12N2O9 | CID 189780 - structure, chemical names, physical and chemical properties, classification, patents, literature, biological activities, safety/hazards/toxicity information, supplier lists, and more.
Despite the existence of several studies showing a lipid-lowering effect of squalene synthase inhibitors, so far, no data exist on the effect of any such compound on atherosclerosis in vivo. The experimental model of diet-induced atherosclerosis in rabbits has been extensively used to study the role of different pathways in atherogenesis as well as to evaluate the ability of pharmacological treatment to modulate atherosclerosis mainly because the atherosclerotic lesions in this model resemble those occurring in humans (Sugano et al., 1996; Yang et al., 1998). High cholesterol levels are easily achieved in rabbits fed an HC diet. However, the cholesterol-lowering effect of statins is a phenomenon restricted to higher animal species, including primates and man, because in lower animals, enzyme inhibition is followed by a dramatic rise of tissue enzyme levels blunting the plasma cholesterol-lowering response (Endo, 1992). Therefore, it is not unexpected that inconsistent results have been obtained ...
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... IUPAC name 2-hydroxypropane-1,2,3-tricarboxylic acid Other names 3-hydroxypentanedioic acid-3-carboxylic acid Hydrogen citrate
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Study TCA Cycle flashcards from Christina Provenza's class online, or in Brainscape's iPhone or Android app. ✓ Learn faster with spaced repetition.
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Order 4 5-Dihydro-4 5-dioxo-1H-pyrrolo 2 3-f quinoline-2 7 9-tricarboxylic Acid Methoxatin Pyrroloquinoline PQQ 01016339105 at Gentaur 4,5-Dihydro-4,5-dioxo-1H-pyrrolo[2,3-f]quinoline-2,7,9-tricarboxylic Acid (Methoxatin, Pyrroloquinoline, PQQ)
To provide an active energy ray curable aqueous ink composition exhibiting excellent curing performance by including a water-soluble polymerizable substance with high reactivity and a water-soluble polymerization initiator having high initiation efficiency; and an inkjet recording method, ink cartridge, recording unit, and inkjet recording apparatus all using the active energy ray curable aqueous ink composition. The active energy ray curable aqueous ink composition includes at least water; a polymerizable substance which undergoes radical polymerization by active energy rays; and a polymerization initiator which generates radicals by active energy rays, in which the polymerizable substance is a water-soluble compound having 2 to 6 (meth)acrylic groups; and the polymerization initiator is a water-soluble acylphosphine oxide compound.
This review provides a description of the biochemistry and enzymology of the α-aminoadipate pathway for lysine biosynthesis in fungi. The α-aminoadipate pathway is unique to fungi and is thus a potential target for the rational design of antifungal drugs. The present state of knowledge of the mechanisms of the seven enzymes in the pathway is presented, as well as detailed information with respect to structures and mechanisms of homocitrate synthase, saccharopine reductase, and saccharopine dehydrogenase. ...
TY - JOUR. T1 - Regulation of σ(B) levels and activity in Bacillus subtilis. AU - Benson, A. K.. AU - Haldenwang, W. G.. PY - 1993/1/1. Y1 - 1993/1/1. N2 - The sigB operon of Bacillus subtilis encodes σ(B) plus three additional proteins (RsbV, RsbW, and RsbX) that regulate σ(B) activity. Using an anti- σ(B) monoclonal antibody to monitor the levels of σ(B) protein, P(SPAC) to control the expression of the sigB operon, and a ctc-lacZ reporter system to monitor σ(B) activity, we observed that the rsbV and rsbW products control σ(B) activity at the ctc promoter independently of their effects on σ(B) levels. In contrast, RsbX was found to have no effect on expression of ctc when the sigB operon was controlled by P(SPAC). The data are consistent with RsbV and RsbW being regulators of σ(B) activity and RsbX acting primarily as a negative regulator of sigB operon expression. Evidence that stationary- phase induction of the σ(B)-dependent ctc promoter is accomplished by a reduction in ...
Laupitz, R., Hecht, S., Amslinger, S., Zepeck, F., Kaiser, J., Richter, G., Schramek, N., Steinbacher, S., Huber, R., Arigoni, D., Bacher, A., Eisenreich, W. und Rohdich, F. (2004) Biochemical characterization of Bacillus subtilis type II isopentenyl diphosphate isomerase, and phylogenetic distribution of isoprenoid biosynthesis pathways. Eur. J. Biochem. 271 (13), S. 2658-2669 ...
Sir Krebs outlined the steps of the cycle in 1937. For this reason, it may be called the Krebs cycle. Its also known as the citric acid cycle, for the molecule that is consumed and then regenerated. Another name for citric acid is tricarboxylic acid, so the set of reactions is sometimes called the tricarboxylic acid cycle or TCA cycle.. ...
Devices and methods for improving cardiac efficiency involve measuring, patient-internally, an oxygen saturation parameter indicative of oxygen usage of myocardial tissue of the heart. A cardiac electrical therapy is adjusted to cause a change of the measured oxygen saturation parameter, and the adjusted cardiac electrical therapy is selected for delivery based on a changed oxygen saturation parameter indicative of an increase in cardiac efficiency.
Sodium sitrat - Trisodium sitrat - Sodium sitrat dihidrat l Farmakope Inggris Sodium Citrate BP Sodium Citrate Ph Eur. Trisodium Citrate Ph Eur. C6H5Na3O7,2H2O - 294.1 - 6132-04-3 DEFINISI Trisodium 2-hydroxypropane-1,2,3-tricarboxylate dihydrate. Konten 99,0 persen hingga 101,0 persen (zat anhydrat). KARAKTER ...