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Most of the engineering materials are alloys (solid solutions) and inevitably contain some impurities or defects such as vacancies. However, theoretical predictions of the hardness of this kind of materials have rarely been addressed in literature. In this paper, a hardness formula for multicomponent covalent solid solution is proposed based on the work of Simunek and Vackar [Phys. Rev. Lett. 96, 085501 (2006)]. With this formula, the composition dependence of the hardness is investigated for titanium nitrogencarbide (TiN1-xCx), off-stoichiometric transition-metal nitrides (TiN1-x and VN1-x), and B-doped semiconductors. The predicted hardness is in good agreement with experiments. To investigate the most frequently quoted correlation between hardness and elastic modulus, the elastic moduli of the systems involved in this paper have also been calculated. The results show that the elastic moduli cannot be used for rigorous predictions of the hardness of the solid solutions.. ...
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When a solid solution becomes unstable-due to a lower temperature, for example-exsolution occurs and the two phases separate into distinct microscopic to megascopic lamellae. This is mainly caused by difference in cation size. Cations which have a large difference in radii are not likely to readily substitute.[7]. Take the alkali feldspar minerals for example, whose end members are albite, NaAlSi3O8 and microcline, KAlSi3O8. At high temperatures Na+ and K+ readily substitute for each other and so the minerals will form a solid solution, yet at low temperatures albite can only substitute a small amount of K+ and the same applies for Na+ in the microcline. This leads to exsolution where they will separate into two separate phases. In the case of the alkali feldspar minerals, thin white albite layers will alternate between typically pink microcline,[7] resulting in a perthite texture. ...
We use molecular-dynamics simulation to examine the order-disorder behavior in pure ferroelectric KNbO{sub 3} and in KNbO{sub 3}-KTaO{sub 3} ferroelectric-paraelectric solid solutions and superlattices. We find that the order-disorder behavior is remarkably robust and plays an important role in both the polarization rotation associated with switching of the perfect crystal and in the dynamical behavior of the solid solutions and superlattices.
Autoxidation of lipids and antioxidation by α-tocopherol and ubiquinol in homogeneous solution and in aqueous dispersions of lipids: unrecognized consequences of lipid particle size as exemplified by oxidation of human low density lipoprotein
1ERG: THREE-DIMENSIONAL SOLUTION STRUCTURE OF THE EXTRACELLULAR REGION OF THE COMPLEMENT REGULATORY PROTEIN, CD59, A NEW CELL SURFACE PROTEIN DOMAIN RELATED TO NEUROTOXINS
View Notes - lect14_reel4_3pg from CHM 123 at Ohio State. Solid State Synthesis, Phase Diagrams and Solid Solutions Chemistry 123 Spring 2008 Dr. Woodward Solid State Reactions Example: MgO(s) +
STAFFORD, STEPHEN WILLIAM. THE THERMODYNAMICS OF INTERSTITIAL HYDROGEN SOLID SOLUTIONS AND METAL HYDRIDES. (1975) Diss., Rice University. https://hdl.handle.net/1911/15183 ...
Nancy E. Brown, Alexandra Navrotsky; Hematite-ilmenite (Fe 2 O 3 -FeTiO 3 ) solid solutions; the effects of cation ordering on the thermodynamics of mixing. American Mineralogist ; 79 (5-6): 485-496. doi: Download citation file:. ...
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Temperature indicating compositions are provided for use in disposable thermometers comprising a heat-conductive carrier sheet having at least one but preferably a plurality of regions (cavities) thereon, each region containing a thermally responsive substance which undergoes a change in state at a precise and predetermined temperature different from any other region. The thermally responsive materials used herein as temperature indicating compositions are solid solutions comprised of two components which, inter alia, have linear temperature-composition liquidous curves. The change of state of the solid solution in each region is readily detectable visually by an indicator system which is intimately associated with the solid solution in said regions in order to permit rapid and accurate visual determination of the temperature of the test subject.
NMR solution structure of the isolated N-terminal fragment of protein-G B1 domain. Evidence of trifluoroethanol induced native-like beta-hairpin
The join between the compositions K2Mg2(SO4)3 and K2Ca2(SO4)3 was studied by means of high-temperature equilibrium quenching techniques and by means of a heating stage mounted on an X-ray diffractometer. Complete solid solution exists in the system, but at 25??C members of the solid solution series are isometric only in the composition range 0-73??5 wt. per cent K2Ca2(SO4)3. At compositions richer in K2Ca2(SO4)3 than 73??5 wt. per cent, members of the series are optically biaxial. At higher temperatures members of the solid solution series are isometric at successively more calcium-rich compositions and pure K2Ca2(SO4)3 is isometric above about 200 ?? 2??C. The system is not binary, as mixtures richer in K2Ca2(SO4)3 than 42 wt. per cent decompose with the formation of liquid and CaSO4. ?? 1964....
By Jason Doub. A solution is defined as a homogeneous mixture or a mixture where the components are uniformly mingled. Normally we thing of a solution is the liquid state, but this is a common misconception; a solution can be in any state. For example, air is a solution of oxygen, nitrogen, and a variety of other gases all in the gas state. Steel is also solution of carbon and iron, but this solution exists in the solid state. However, the most important solutions in chemistry involve water, so this section will focus of aqueous solution.. Before we begin discussing the properties of solutions, we must define ways to describe the concentrations of various mixtures:. Molarity (M): the number of moles per liter (moles/Liter). Mole fraction (c ): the ratio of the number of moles of a compound to the number of moles of solution (c A = moles A / (Moles A + Moles B)). Molality (m): the number of moles solute1 per kilogram solvent (m = moles solute/ kilograms solvent). Mass percent or weight percent: ...
WAFER-LEVEL ACA FLIP CHIP PACKAGE USING DOUBLE-LAYERED ACA/NCA - A method of manufacturing a wafer-level flip chip package is capable of being used to produce a flip chip package by directly coating a flip chip package using anisotropic conductive adhesives (ACA) and non conductive adhesives (NCA) in a solution state as a double layer on a wafer. The method can be used to manufacture a non-conductive mixed solution and a conductive mixed solution and directly coat them on a substrate, such that it is possible to: increase productivity; simplify a manufacturing process; suppress a shadow effect; easily perform thickness control that is difficult with the anisotropic conductive adhesive paste or the non-conductive adhesive paste; and obtain the non-conductive layer and the anisotropic conductive layer in an initial state of a B-stage with a level not losing latent of hardening through a simple drying process to volatilize an organic solvent. Above all, the non-conductive layer and the anisotropic ...
Combine solutions A and B in a 1:1 ratio. Equal volumes of each solution are required to end up with a multivalent physiological ion solution of aCSF.. Recomended Storage Conditions: The aCSF solution may be stored at 4 degrees Celsius for up to 4 weeks. If the solution becomes cloudy, or there is indication of precipitation, discard and make a fresh batch. To preserve the pH and quality of the aCSF solution, we recommend making a fresh batch of the mixed solution (A and B) as needed. Solution A is a mixture of salts, and solution B is a mixture of buffers. When separate, solutions A and B may be stored at 4 degrees Celsius for longer periods. When mixed together, the solution is more prone to microbiological growth, thus it is recommended to store solutions A and B separately, and mix as needed.. ...
It is possible for solids to form a solution. Solid solution means that the solute component enters and becomes a part of the crystalline solvent, without altering its basic structure. Solid solutions with complete solid solubility, i.e., solid solubility over the entire range of the composition, are possible to form. For a metallic binary solution to exhibit a complete solid solubility, for instance, both metals must have the same type of crystal structure, nearly identical atomic radii and electronegativities, and similar valences because it must be possible to replace all the atoms of the initial solvent with solute atoms without causing a change in crystal structure. The copper-nickel system displays this behavior. The copper-nickel system is termed isomorphous because of this complete liquid and solid solubility of the two components. The phase diagram shapes are as shown below ...
The invention relates to new fluorescent dyes of formula (I) ##STR1##which can be used in high throughput screening both, on the solid phase as well as in homogeneous solution.
To ensure that you understand the material in this chapter, you should review the meanings of the bold terms in the following summary and ask yourself how they relate to the topics in the chapter.. A solution is a homogeneous mixture. The major component is the solvent, while the minor component is the solute. Solutions can have any phase; for example, an alloy is a solid solution. Solutes are soluble or insoluble, meaning they dissolve or do not dissolve in a particular solvent. The terms miscible and immiscible, instead of soluble and insoluble, are used for liquid solutes and solvents. The statement like dissolves like is a useful guide to predicting whether a solute will dissolve in a given solvent.. The amount of solute in a solution is represented by the concentration of the solution. The maximum amount of solute that will dissolve in a given amount of solvent is called the solubility of the solute. Such solutions are saturated. Solutions that have less than the maximum amount are ...
Use this formula to calculate ionic strength: I=1/2 ∑ Ci Zi^2. Let I equal ionic strength of the solution. The formula in Step 1 states that ionic strength is a squared sum of concentrations and valences of all ions in the solution.. Allow the molar concentration of ions to be represented by C. In mixed solutions, there will be several concentrations to sum. The unit is moles per liter for all ions.. Represent the ion with i. This could be sodium, chloride, etc. For example, there will be two Ci for the concentration of sodium in sodium chloride and the concentration of chloride in sodium chloride.. Symbolize the valence or the oxidation number of the ions with Z. This is also known as the electrical charge of the ion. Again, the i indicates the ion.. Square the valences on ions.. Sum the concentrations and valences.. ...
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A control solution packet for calibrating a bodily fluid sampling device includes a container, a control solution pressurized within the container, and a membrane for covering and sealing the container. The control solution can be pressurized before or during calibration so as to ensure the appropriate amount of control solution is delivered to the bodily fluid sampling device. The control solution is manufactured to have a viscosity that controls delivery of the control solution to the device. The membrane is permeable by a piercing device of the bodily fluid sampling device and seals around the piercing device during calibration. In another aspect, the container is in the form of a capsule or dosing attachment that contains the control solution along with a sponge-like material.
You can configure a solution to check for updates at specified intervals, and install updates automatically. The default setting for automatic updates is every seven days. After this interval is set and the solution is installed, the interval cannot be changed without installing an update. If your users want to force an update outside of the regular update intervals, the Office solution can be updated manually.. You can deploy updates by using the Publish Wizard. The Publish Wizard generates a new application manifest and copies the solution files to the same publish location as the earlier version. Updates are optional and users can cancel any solution update during the download stage and still run the add-in.. The publish action also updates the deployment manifest to point to the location of the new version of the solution. When the end users installed solution checks for updates at the specified interval, it will download and install the most recently deployed version. You can update ...
The electronic properties of Te doped-ZnSb systems are investigated by first-principles calculations. We focus on the Zn64Sb64−xTex systems (x = 0, 2, 3, 4), which respond to the 0, 1.56at%, 2.34at% and 3.12at% of Te doping concentration. We confirm that the amount of Te doping will change the conductivity type of ZnSb. In the cases of x = 2 and 3, we find that the Te element in ZnSb introduces some bands originating from Te s and p orbits and a donor energy level in the bottom of the conduction band, which induce the n-type conductivity of ZnSb. From these findings for the electronic structure and the conductivity mechanism, we predict that Te doping amounts such as 1.56at% and 2.34at% can be considered as suitable candidates for use as donor dopant.
The electronic properties of Te doped-ZnSb systems are investigated by first-principles calculations. We focus on the Zn64Sb64−xTex systems (x = 0, 2, 3, 4), which respond to the 0, 1.56at%, 2.34at% and 3.12at% of Te doping concentration. We confirm that the amount of Te doping will change the conductivity type of ZnSb. In the cases of x = 2 and 3, we find that the Te element in ZnSb introduces some bands originating from Te s and p orbits and a donor energy level in the bottom of the conduction band, which induce the n-type conductivity of ZnSb. From these findings for the electronic structure and the conductivity mechanism, we predict that Te doping amounts such as 1.56at% and 2.34at% can be considered as suitable candidates for use as donor dopant.
An automated sample-on-solid-support processing system includes a treatment solution supply subsystem which feeds solvent to a dispenser to dispense a measured amount of treatment solution to each well of a multi-well plate. The dispenser measures the solution within a fill container having a plurality of reservoir wells corresponding to the number of wells in the multi-well plate. The fill container is contained within a reservoir chamber that is filled with an excess of solution. Each reservoir well is surrounded by a plurality of bores which drains excess solution from the top of the fill container so that a precise amount of solution is left in the reservoir wells when solution is drained out of the reservoir chamber. Gas pressure is introduced into the reservoir chamber to force the solution out of the reservoir well through a bundle of tubes, with one tube per well, and into the wells of the multi-well plate.
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The range of pore size characterization by mercury intrusion porosimetry has been extended from 120 micrometers to approx. 850 micrometers by investment in an
Text analytics is applicable wherever big/fast text is found. True, not every analytical application directly involves text. But in a world powered by big data, every task may be enriched by the inclusion of text-sourced information.. This report looks at why and how text analytics has found success in industries such as consumer-facing businesses, public administration and government, life sciences and scientific research. It also shares the findings of a comprehensive market study focused on user experiences with the technology.. Finally, youll see how SAS can help organizations evaluate text like the human mind would (minus the inconsistencies) and achieve better discovery and analysis. ...
I knew that Pyro does not last long in sulfite and carbonate solutions, and I became upset with myself, for leaving the mixtures around in my lab. So in cleaning up my lab..., I remembered that Rodinal, does not do well with Borax, if left in a mixed solution longer than 4 to 6 hours, the chemical solution will start to break down, and with the same being true with Pyro. Unless the solutions are highly diluted with water, which then will lengthen the time to about 8 plus hours. before the solutions are totally worthless ...
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Molar solution is a standard solution The solution whose strength is known accurately is called standard solution. Again, molar solution is that solution w
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Solution Define Conductivity and Molar Conductivity for the Solution of an Electrolyte. Discuss Their Variation with Concentration. Concept: Conductance of Electrolytic Solutions - Measurement of the Conductivity of Ionic Solutions.
Preheat phase A to 90°C in a glass beaker and propeller mix until solution is dissolved and homogeneous. Mix phase B in a separate beaker at 95°C and stir until completely melted. Slowly add phase B to A and mix under propeller agitation until fully incorporated and uniform. Add phase C to A & B and slowly combine using a homogenizer. Premix phase D in a separate beaker at 70°C until uniform then add to phase A, B, C. Continue mixing until a smooth, creamy and homogeneous solution is present. Lower temperature of the batch to 70°C and pour into desired pans ...
Some aqueous solutions are conductive while other are insulative. These two kind of solution can be distinguished with a conductivity test. A conductive solution always contains electrical particles called ions
In this study, it was investigated that the solution behavior of two carbon monoxide releasing molecules; Mn(CO)3(bpy)(Nimidazole)]. PF6 (1), [Mn(CO)3(bpy)(N-methylimidazole)]PF6 (2) which showed anticancer activity via zetasizer properties such. as measuring particle size, electrophoretic mobility and zeta potential as a function of pH and determined the global reactivity. descriptors and molecular docking poses via computational chemistry. The activities of molecules in the different pHs were. checked by UV/Vis spectrophotometer.. ...
Solution structures by NMR. Structural Biology. • Structure • Mobility. }. • Protein-protein • Protein-ligand. interactions. NMR is a powerful method to address these problems. year. NMR structures per year. • 1984 1 (first structure!) • 1990 25 Slideshow 3344329 by lilike
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at multiple locations within a query. The NamedSubquery syntax is thus really a short hard which tells the query plan generator that some SubSelect is being used at multiple locations within the query. The NamedSubquery directs the query plan generator to explicitly lift out the SubSelect and run it before the main WHERE clause in the query. It is important to realize that much of the work of the database is join processing. Once you build up a complex solution set, you can reuse it over and over again. For example, when slicing the solutions in order to provide a paged view in a Web UI. What we have done is extend the SPARQL UPDATE syntax in a few simple ways to provide operations on solutions as well as graphs. This is a simple but powerful concept. Now you can use SPARQL UPDATE to save not only graphs but solution sets as well. You can make those solution sets durable or transient (cache). For example, lets assume that you have pre-computed a solution set using a SPARQL UPDATE. Once you have ...
1HRZ: Molecular basis of human 46X,Y sex reversal revealed from the three-dimensional solution structure of the human SRY-DNA complex.
Solution structure of tandem ACP.(A) The three-dimensional bead model constructed by dammif reveals a molecular volume of 96,600 Å3. (B) Simulation of th
Solution structure of the hTra2-β RRM in the RNA-free form. (A) Superposition of the 20 conformers of the hTra2-β RRM (Arg111-Thr201) for the best fit of th