TY - JOUR. T1 - Hyperinakin, a new anti-inflammatory phloroglucinol derivative from Hypericum nakamurai. AU - Cheng, Yuan Bin. AU - Fazary, Ahmed Eid. AU - Lin, Yu Chi. AU - Lo, I. Wen. AU - Ong, Seow Chin. AU - Chen, Shun Ying. AU - Chien, Ching Te. AU - Lin, Yen Jung. AU - Lin, Wan Wan. AU - Shen, Ya Ching. PY - 2013/4/1. Y1 - 2013/4/1. N2 - Phytochemical investigation of Hypericum nakamurai (Masamune) Robson has led to the isolation of three phloroglucinol derivatives 1-3. The structures of these compounds were determined by the analysis of their spectroscopic data (IR, mass and UV), and by the application of 1-D and 2-D-NMR techniques. Hyperinakin (1) is a new compound. The anti-inflammatory activities of compounds 1-3 were also tested and evaluated. A biogenetic pathway for compounds 1-3 was also proposed.. AB - Phytochemical investigation of Hypericum nakamurai (Masamune) Robson has led to the isolation of three phloroglucinol derivatives 1-3. The structures of these compounds were ...

Phloroglucinol is an important chemical which has been successfully produced by engineered Escherichia coli. However, the toxicity of phloroglucinol can enormously inhibit E. coli cell growth and viability, and the productivity is still too low and not economically feasible for industrial applications. Therefore, strain tolerance to toxic metabolites remains a key issue during the production of chemicals using biological processes. In the present work, we examined the impact of the native GroESL chaperone system with different overexpression levels on phloroglucinol tolerance and production in E. coli. The groESL gene was cloned into an expression vector, of which expression level was regulated by three different promoters (natural, tac and T7 promoter). Strain tolerance was evaluated employing viable cell counts and phloroglucinol production. In comparison with the control strain, all GroESL overexpressing strains showed good characteristics in cell viability and phloroglucinol synthesis. Strain which

Five new phloroglucinol glycosides, cucalmainosides A-E (1-5), were isolated from the fresh fruits of Eucalyptus maideni, along with 15 flavonoids (6-20), seven (+)-oleuropeic acid derivatives (15, 16, and 22-26), three hydrolyzable tannins (32-34), and six simple phenolic compounds (21, 27-31). Their structures were determined on the basis of spectroscopic analysis, including HSQC, HMBC, and acidic hydrolysis. The in vitro anit-herpes simplex virus 1 (HSV-1) assay indicated that the flavonols, myricetin (6) and quercetin (7), and the ellagitannin isocoriariin F (33) showed weak anti-HSV-1 activity with TIC values of 0.31, 0.33, and 0.12 mM, respectively ...

tHGA is a geranyl acetophenone originally found in the young leaves of Melicope ptelefolia. It is also a phloroglucinol compound that contains phloroglucinols as its common monomer unit [31]. Previous studies have reported that tHGA, at 5 and 20 μM, exerts anti-allergic properties by preserving the morphology of MCs and attenuating the release of pro-inflammatory mediators in both cellular and animal model of IgE-mediated MC activation whereby inhibition of β-hexosaminidase and TNF-α were reported [18]. However, our results in the present study revealed that this phloroglucinol compound was unable to attenuate the release of both β-hexosamidase and TNF-α inflammatory by the DENV3-induced RBL-2H3 cells. It is possible that tHGA may not target the signaling molecules involved in the mechanism of action (MOA) of direct DENV infection in MCs. As tHGA has been previously reported to target the linker for activation of T cell, which is located along the classical signaling pathway of MC ...

Cell extracts, in the presence of dimethylsulfoxide (DMSO), catalyzed the conversion of pyrogallol to phloroglucinol with dimethylsulfide as a product. The isomerization reaction would also proceed if 1,2,3,5-benzenetetrol was present rather than DMSO. To quantitate this activity, an assay was developed that followed the disappearance of 1,2,4-benzenetriol colorimetrically after incubation with sodium molybdate at neutral pH. The products of this reaction are resorcinol and 1,6-dihydroxyquinone. The enzyme(s) catalyzing this reaction was purified 5-fold from cells grown on gallate. The purification procedure involved fractionation with 40% acetone, precipitation with ammonium sulfate, DEAE-cellulose chromatography, concentration by ultrafiltration (molecular weight retention above 100,000), and hydroxylapatite chromatography. This preparation had a specific activity of 14.7 umol/min/mg protein and a pH optimum about 7.5. Activity was strongly inhibited by p-chloromercuribenzoate. The mechanism ...

Microbial production of various useful chemicals becomes more and more important to our daily life [28]. However, the potential product toxicity to cells is one of the main issues when producing many valuable chemicals by engineered strains from renewable resources [29, 30], because the toxicity can inhibit the product synthesis and cell viability. Product toxicity usually interferes with important metabolic processes and damages cell membrane and cellular macromolecules, thus leading to poor cell viability. Furthermore, stresses on engineered strains can influence metabolic imbalances due to enzyme overexpression against the stress response, which will redistribute the metabolic fluxes and change the intracellular redox state [31]. These impacts will slow down product synthesis and diminish cell viability, and therefore improving product tolerance is an essential aspect for engineered strains. To address these challenges, many metabolic engineering strategies had been used to improve microbial ...

An alternative for the conservation of orchid species threatened with extinction is the seeds preservation for long periods by cryopreservation. This work aimed to evaluate the influence of cryogenic solutions on the orchids Epidendrum radicans and Arundina bambusifolia seeds cryopreservation in liquid nitrogen. Seven treatments were performed: 0.4 M sucrose; 2 M glycerol; PVS1; PVS2; PVS3; PVS2 + 1% phloroglucinol and the control. After liquid nitrogen removal, half of the seeds were subjected to tetrazolium test, and another half was in vitro cultured. After 30 days seed germination was evaluated. There was no significant difference between A. bambusifolia and E. radicans in tetrazolium test and seeds germination. On the other hand, it was observed that in A. bambusifolia tetrazolium and seed germination tests the solutions of PVS1, PVS2, PVS2 + 1% phloroglucinol showed the best results. E. radicans seeds with 4% water content cryopreservation does not require the use of cryoprotectant. On the ...

Bowl-like tris-[(N-methyl-2-imidazoyl)]methoxy]cyclotriguaiacyclene (TMIM-CTG) (1) was synthesized and cocrystallized with ethanol, resorcinol, and phloroglucinol to afford three molecular complexes (TMIM-CTG)-(ethanol)(3) (2), (TMIM-CTG)-(resorcinol)-(CH3CN)(2) (3), and (TMIM-CTG)-(phloroglucinol)center dot(CH3CN)(2) (4), whose Structures have been determined by X-ray single crystal analysis. Except for the hydrogen bonds between imidazole of 1 and the hydroxyl group of alcohol/phenols (O-H center dot center dot center dot N), all crystals contain self-inclusion motifs with cooperative C-H center dot center dot center dot pi, interactions which can be considered as the secondary way to extend the primary hydrogen-bonded networks to (lie frameworks with higher levels. In complex 2. two adjacent TMIM-CTGs form a self-clasping dimer by an edge-to-face C-H center dot center dot center dot pi interaction between the imidazole ring and the benzene ring of CTG, which is further extended to a ...

Role of hyperforin in diabetes and its associated hyperlipidemia in rats - hyperforin;diabetes;insulin;antihyperglycemic;antihyperlipidemic;antioxidant;

In addition to this being the first report of roles for DAPG or HCN in Fusarium suppression of tomato disease, our results have wider implications for the interpretation of studies designed to elucidate biocontrol mechanisms of action. While our study is the first example where a particular mechanism of action is biocontrol strain specific, it may not be the only case. Often, results obtained with one combination of a pathogen and biocontrol agent are generalized to conclude a role or lack thereof for a particular compound in biocontrol of a particular disease. Our results demonstrate the need to examine several strains that may have different regulatory responses to the same compounds. In situations where DAPG has been found to have no role in biocontrol (49) or in ecological fitness (9), other DAPG-producing strains may perform differently, and likewise, in the many cases where a role has been demonstrated, it cannot be assumed to be true for all DAPG-producing strains.. Our results offer a ...

Summary. Humanwell Healthcare (Group) Co Ltd (Humanwell), formerly Wuhan Humanwell Hi-Tech Industry Co Ltd is a pharmaceutical company that offers generic products. The company offers pharmaceutical, medical instrument and reproductive health care products and technologies. It provides anesthetics, biological products, herbal medicines, CNS medicines, womens health, anti-infection drugs, medical devices, OTC medicines and other products. Humanwell also manufactures buflomedil hydrochloride injectable, pantoprazole sodium injectable, omeprazole sodium injectable, phloroglucinol injectable, and simvastatin capsules. The company produces products in the forms of injection, tablets, syrup, granules, capsules, and suspension. Humanwell is headquartered in Wuhan, China.. Humanwell Healthcare (Group) Co Ltd (600079)-Pharmaceuticals & Healthcare-Deals and Alliances Profile provides you comprehensive data and trend analysis of the companys Mergers and Acquisitions (M&As), partnerships and financings. ...

1M13: Crystal Structure of the Human Pregane X Receptor Ligand Binding Domain in Complex with Hyperforin, a Constituent of St. Johns Wort

In the present study we have shown that intestinal P-gp plays a principal role in the fecal elimination pathways of docetaxel without modifying the pharmacokinetic behavior of the drug in the systemic circulation. Previous investigations have shown a major role of the cytochrome P450 3A4 isozymes in docetaxel metabolism. In humans, the principal biotransformation routes involve hydroxylation of the tert-butoxy function in the C13 side chain, followed by a spontaneous cyclization reaction (15) . The four principal metabolites resulting from this pathway have substantially less cytotoxic activity on tumor and nonmalignant hematopoietic cells as compared with the parent drug (12) . Fecal excretion of docetaxel and its metabolites has been previously reported in two other cases (14 , 15) , and in both, M4 was the main metabolite, very similar to our present findings, and accounted for a larger fraction of the recovered dose than docetaxel itself. Interestingly, this metabolite can only be detected ...

Tax regulation authors habitually infuse regulations with explanatory examples. These examples are viewed favorably by both the government that encourages their

Icons made by Dave Gandy from www.flaticon.com is licensed by CC 3.0 BY. Icons made by Madebyoliver from www.flaticon.com is licensed by CC 3.0 BY. ...

The primary aim of this study was to investigate the effects of seed inoculation with the biocontrol agent Pseudomonas fluorescens strain F113 (producing the antibiotic DAPG) and its modified derivative strain F113G22 (with DAPG production disrupted) on the uptake of nitrogen by pea and wheat plants. Uptake of N by the two plant species was investigated in soil microcosms amended with 15N-labelled fertilisers (urea or ammonium nitrate) or 15N-labelled plant residues. Uptake of fertiliser-N was unaffected by inoculation. However, uptake of N derived from organic residues was enhanced in pea inoculated with either strain. In contrast, uptake of N by wheat was reduced in the presence of either strain F113 or F113G22, suggesting that the effects of these microbial inocula on N-mineralisation in the rhizosphere were dependent on plant species. It was subsequently found that microfaunal populations, especially soil nematodes in the rhizosphere of inoculated pea were significantly larger than those ...

The genomic sequence of Pseudomonas fluorescens F113 has shown the presence of a 41 kb cluster of genes that encode the production of a second flagellar apparatus. Among 2535 pseudomonads strains with sequenced genomes, these genes are only present in the genomes of F113 and other six strains, all but one belonging to the P. fluorescens cluster of species, in the form of a genetic island. The genes are homologous to the flagellar genes of the soil bacterium Azotobacter vinelandii. Regulation of these genes is mediated by the flhDC master operon, instead of the typical regulation in pseudomonads, which is through fleQ. Under laboratory conditions, F113 does not produce this flagellum and the flhDC operon is not expressed. However, ectopic expression of the flhDC operon is enough for its production, resulting in a hypermotile strain. This flagellum is also produced under laboratory conditions by the kinB and algU mutants. Genetic analysis has shown that kinB strongly represses the expression of the flhDC

The transcriptional regulator AmrZ is a global regulatory protein conserved within the pseudomonads. AmrZ can act both as a positive and a negative regulator of gene expression, controlling many genes implicated in environmental adaption. Regulated traits include motility, iron homeostasis, exopolysaccharides production and the ability to form biofilms. In Pseudomonas fluorescens F113, an amrZ mutant presents a pleiotropic phenotype, showing increased swimming motility, decreased biofilm formation and very limited ability for competitive colonization of rhizosphere, its natural habitat. It also shows different colony morphology and binding of the dye Congo Red. The amrZ mutant presents severely reduced levels of the messenger molecule cyclic-di-GMP (c-di-GMP), which is consistent with the motility and biofilm formation phenotypes. Most of the genes encoding proteins with diguanylate cyclase (DGCs) or phosphodiesterase (PDEs) domains, implicated in c-di-GMP turnover in this bacterium, appear to ...

An investigation of the polar glycosidic fraction from the leaves of myrtle afforded four galloylated nonprenylated phloroglucinol glucosides (3a−d) related to the endoperoxide hormone G3 (4) in terms of structure and biogenesis. Despite their close similarity, significant antibacterial activity was shown only by one of these compounds (3b, gallomyrtucommulone B), while the G3 hormone (4) was inactive.. ...

Plants of which the roots are colonized by selected strains of non-pathogenic, fluorescent Pseudomonas spp. develop an enhanced defensive capacity against a broad spectrum of foliar pathogens. In Arabidopsis thaliana, this rhizobacteria-induced systemic resistance (ISR) functions independently of salicylic acid but requires responsiveness to jasmonic acid and ethylene. In contrast ... read more to pathogen-induced systemic acquired resistance (SAR), ISR is not associated with systemic changes in the expression of genes encoding pathogenesis-related (PR) proteins. To identify genes that are specifically expressed in response to colonization of the roots by ISR-inducing Pseudomonas fluorescens WCS417r bacteria, we screened a collection of Arabidopsis enhancer trap and gene trap lines containing a transposable element of the Ac/Ds system and the GUS reporter gene. We identified an enhancer trap line (WET121) that specifically showed GUS activity in the root vascular bundle upon colonization of the ...

St Johns wort is being studied for effectiveness in the treatment of certain somatoform disorders. Results from the initial studies are mixed and still inconclusive; some research has found no effectiveness, other research has found a slight lightening of symptoms. Further study is needed and is being performed.. A major constituent chemical, hyperforin, may be useful for treatment of alcoholism, although dosage, safety and efficacy have not been studied.[110][111] Hyperforin has also displayed antibacterial properties against Gram-positive bacteria, although dosage, safety and efficacy has not been studied.[112] Herbal medicine has also employed lipophilic extracts from St Johns wort as a topical remedy for wounds, abrasions, burns, and muscle pain.[111] The positive effects that have been observed are generally attributed to hyperforin due to its possible antibacterial and anti-inflammatory effects.[111] For this reason hyperforin may be useful in the treatment of infected wounds and ...

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St. Johns wort (Hypericum perforatum) is a flowering shrub native to Europe. It gets its name from the fact that it often blooms on the birthday of the biblical John the Baptist.. The flowers and leaves of St. Johns wort contain active ingredients such as hyperforin. St. Johns wort is available as a supplement in teas, tablets, liquids and topical preparations.. St. Johns wort is often used to treat depression and menopausal symptoms.. Research on St. Johns wort use for specific conditions shows:. ...

Interactions of St. Johns Wort preparations with several drugs such as cyclosporin, oral contraceptives or anticoagulants have been thoroughly investigated since the 1990ies. … [Read more...] about No clinically relevant interactions of a St. Johns Wort extract with low hyperforin content ...

Hyperforin is a plant-derived compound that has been found useful in the treatment of depression. In fact, this phytochemical was shown to be superior to popular antidepressants such as Prozac. What is this natural compound extracted from St. Johns wort? How does it improve the symptoms of depression and what are the main studies to back its claim? How should it be used? Read on to find the answers to these questions.

Ecklonia cava is a type of brown algae found in the oceans of Japan and Korea. It contains tannins that have both antibacterial and antimicrobial properties. Ecklonia cava is also rich in iodine, salt, iron, potassium, phosphorous, calcium, vitamin A and niacin.

Oxidation of quercetin by air oxygen takes place in water and aqueous ethanol solutions under mild conditions, namely in moderately-basic media (pH ∼ 8-10) at ambient temperature and in the absence of any radical initiators, without enzymatic catalysis or irradiation of the reaction media by light. The principal reaction products are typical of other oxidative degradation processes of quercetin, namely 3,4-dihydroxy-benzoic (proto-catechuic) and 2,4,6-trihydroxybenzoic (phloroglucinic) acids, as well as the decarboxylation product of the latter - 1,3,5-trihydroxybenzene (phloroglucinol). In accordance with the literature data, this process involves the cleavage of the γ-pyrone fragment (ring C) of the quercetin molecule by oxygen, with primary formation of 4,6-dihydroxy-2-(3,4-dihydroxybenzoyloxy)benzoic acid (depside). However under such mild conditions the accepted mechanism of this reaction (oxidative decarbonylation with formation of carbon monoxide, CO) should be reconsidered as preferably an

Bergapten is a natural compound coming from plants like the common fig, but it can also be synthesized. Most syntheses of linear furanocoumarins involve starting with a central aromatic unit and adding two heterocyclic rings. Alternate routes of synthesis are desirable to avoid regiochemical problems and moderate yields. The synthesis described here involves Iodine as a removable group to insure regiochemical integrity and convergence.[13] As shown in the diagram, phloroglucinol (compound 1) was the starting material. Mono-methylation was conducted followed by a reaction with ethyl propiolate in the presence of ZnCl2 to yield 7-hydroxy-5-methoxycoumarin (product 3, not shown) with 68% yield. The 8-position of 7-hydroxy-5-methoxycoumarin was then protected by iodine to avoid the formation of an angular furanocoumarin. Product 4 in the diagram is the result of that iodine protection. Product 5 was the result of the allylation of product 4. Osmium tetraoxide and sodium metraperiodate were used to ...

Pyranone ; Maltol ; Chelidonic acid ; Pronucleophiles ; Phenols ; Substituted phenols ; Microwave irradiation ; ¹³C-labelling ; Regioselective ¹³C-labelling ; Gallic acid ; Phloroglucinol ; Resorcinol ; C-H activation borylation and oxidation ; Anthocyanins ; Cyanidin glucoside ; Delphinidin glucoside ; QD341.P5M2 ; Phenols--Synthesis ; Polyphenols--Research

p>The checksum is a form of redundancy check that is calculated from the sequence. It is useful for tracking sequence updates.,/p> ,p>It should be noted that while, in theory, two different sequences could have the same checksum value, the likelihood that this would happen is extremely low.,/p> ,p>However UniProtKB may contain entries with identical sequences in case of multiple genes (paralogs).,/p> ,p>The checksum is computed as the sequence 64-bit Cyclic Redundancy Check value (CRC64) using the generator polynomial: x,sup>64,/sup> + x,sup>4,/sup> + x,sup>3,/sup> + x + 1. The algorithm is described in the ISO 3309 standard. ,/p> ,p class=publication>Press W.H., Flannery B.P., Teukolsky S.A. and Vetterling W.T.,br /> ,strong>Cyclic redundancy and other checksums,/strong>,br /> ,a href=http://www.nrbook.com/b/bookcpdf.php>Numerical recipes in C 2nd ed., pp896-902, Cambridge University Press (1993),/a>),/p> Checksum:i ...

Homologous recombination (HR) is essential for the accurate repair of DNA double-strand breaks (DSBs), potentially lethal lesions. HR takes place in the late S-G2 phase of the cell cycle and involves the generation of a single-stranded region of DNA, followed by strand invasion, formation of a Holliday junction, DNA synthesis using the intact strand as a template, branch migration and resolution. It is investigated that RecA/Rad51 family proteins play a central role. The breast cancer susceptibility protein Brca2 and the RecQ helicase BLM (Bloom syndrome mutated) are tumor suppressors that maintain genome integrity, at least in part, through HR ...

FIG. 2. Persistence of P. fluorescens CHA0-Rif, the algU mutant CHA212-Rif, and the gacA mutant CHA96-Rif at 60 days after inoculation in Eschikon soil (A), Tänikon soil (B), and Mellstorf soil (C). The numbers of total cells (immunofluorescence microscopy), viable cells (Kogures test), and CFU of the inoculants were determined. The error bars show the standard deviations. Data were analyzed separately for each soil. For each strain, statistically significant differences between cell counts (i.e., total counts, viable counts, and CFU) are indicated by the lowercase letters a, b, and c. For each type of cell count, statistically significant differences between the three strains are indicated by the Greek letters α, β, and γ. ...

Meridian Botanicals St. Johns wort complex teapills - Certified organic whole cut of St. Johns wort powder, reinforced with a full spectrum hydro-alcoholic extract that has been concentrated to a 3% hyperforin and 0.3% hypercin content. 400-450 mg herbs per capsule, 50 vegetarian capsules sealed in a brown amber glass jar. Also known as Hypericum perforatum Introduction Originally native to

Natural products, such as plants extract, either as pure compounds or as standardized extracts, provide unlimited opportunities for new and selective drug discoveries because of the unmatched availability of chemical diversity [16]. According to the World Health Organization (WHO), more than 80% of the worlds population relies on traditional medicine for their primary healthcare needs. The use of herbal medicines in Asia represents a long history of human interactions with the environment. Plants used for traditional medicine contain a wide range of substances that can be used to treat various diseases such as infectious diseases [5]. In the present investigation, we evaluated antileishmanial activity of methanolic extract and essential oil of M. communis and their cytotoxic activities against J774-A1 cells on an in vitro model.. Our findings demonstrated that M. communis, particularly its essential oil, significantly (P,0.05) inhibited the growth rate of promastigote and amastigote forms of L. ...

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1,3,5-三甲氧基苯 1,3,5-Trimethoxybenzene 是中国玫瑰品种中的主要芳香化合物。1,3,5-Trimethoxybenzene 在三个连续的甲基化步骤中由间苯三酚 (初始前体) 合成。1,3,5-Trimethoxybenzene 是一种有效的镇静剂 ...

Após a sua estréia, Chemistry teve uma recepção positiva da crítica, com as publicações The Guardin, New Music Express e Top Of The Pops o incluindo na lista dos melhores álbuns de 2005. De toda forma, o álbum foi o único lançamento do grupo que não alcançou o Top 10 no UK Albums Chart, a parada de álbuns do Reino Unido, mesmo vendendo muito bem nas primeiras semanas e recebendo a certificação de platina.. O álbum também foi lançado na Austrália e Nova Zelândia, em 20 de fevereiro de 2006, mas não conseguiu gerar muito interesse. Há ainda uma versão especial do álbum, lançada no Natal, com uma capa diferente, e um CD bônus, além do CD normal, com oito faixas com temas natalinos.. O grande trunfo do álbum é a sonoridade mais madura e as letras irônicas que são visíveis nas músicas Models, Watch Me Go e Swinging London Town. Biology, o single-chefe do álbum, foi considerado o single pop da década pelo The Observer.. ...

p>The checksum is a form of redundancy check that is calculated from the sequence. It is useful for tracking sequence updates.,/p> ,p>It should be noted that while, in theory, two different sequences could have the same checksum value, the likelihood that this would happen is extremely low.,/p> ,p>However UniProtKB may contain entries with identical sequences in case of multiple genes (paralogs).,/p> ,p>The checksum is computed as the sequence 64-bit Cyclic Redundancy Check value (CRC64) using the generator polynomial: x,sup>64,/sup> + x,sup>4,/sup> + x,sup>3,/sup> + x + 1. The algorithm is described in the ISO 3309 standard. ,/p> ,p class=publication>Press W.H., Flannery B.P., Teukolsky S.A. and Vetterling W.T.,br /> ,strong>Cyclic redundancy and other checksums,/strong>,br /> ,a href=http://www.nrbook.com/b/bookcpdf.php>Numerical recipes in C 2nd ed., pp896-902, Cambridge University Press (1993),/a>),/p> Checksum:i ...

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The National Institute of Standards and Technology (NIST) uses its best efforts to deliver a high quality copy of the Database and to verify that the data contained therein have been selected on the basis of sound scientific judgment. However, NIST makes no warranties to that effect, and NIST shall not be liable for any damage that may result from errors or omissions in the Database ...

Ségolène Depayras, Tatiana Kondakova, Nadine Merlet-Machour, Hermann Heipieper, Magalie Barreau, et al.. Impact of gaseous NO2 on P. fluorescens strain in the membrane adaptation and virulence. Congress of European Microbiologists (FEMS, 7, 2017), Jul 2017, Valence, Spain. ⟨hal-02398682⟩ ...

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SWISS-MODEL Repository entry for C3K5G7 (PDXB_PSEFS), Erythronate-4-phosphate dehydrogenase. Pseudomonas fluorescens (strain SBW25)

The enzyme contains heme. The bifunctional enzyme from Gaeumannomyces graminis catalyses the oxidation of linoleic acid to (8R,9Z,12Z)-8-hydroperoxyoctadeca-9,12-dienoate (cf. EC 1.13.11.60, linoleate 8R-lipoxygenase), which is then isomerized to (7S,8S,9Z,12Z)-5,8-dihydroxyoctadeca-9,12-dienoate [3 ...

Neil Young confirmou que seu mais novo disco será lançado no dia 5 de junho. O material novo naturalmente já mereceria destaque por se tratar de um álbum de um ícone do rock, mas ganha ainda mais em importância por trazer junto com Young nada menos que o seu clássico grupo Crazy Horse. Americana é o…

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by John Mekrut , Nov 25, 2017 , Just for fun, Uncategorized. Here is a brain teaser whose aim is to stim-u-late the con-nec-tions or asso-ci-a-tions between words in your tem-po-ral lobe. In the left col-umn you have a pair of words. Your goal is to find a third word that is con-nected or asso-ci-ated with both of these two ...

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The Honest Johns Dealership trope as used in popular culture. Youre in a sticky situation; you need to get something and there doesnt seem to be a cheap …