Naphthalene produces species and cell selective injury to respiratory tract epithelial cells of rodents. In these studies we determined the apparent K{sub m}, V{sub max}, and catalytic efficiency (V{sub max}/K{sub m}) for naphthalene metabolism in microsomal preparations from subcompartments of the respiratory tract of rodents and non-human primates. In tissues with high substrate turnover, major metabolites were derived directly from naphthalene oxide with smaller amounts from conjugates of diol epoxide, diepoxide, and 1,2- and 1,4-naphthoquinones. In some tissues, different enzymes with dissimilar K{sub m} and V{sub max} appeared to metabolize naphthalene. The rank order of V{sub max} (rat olfactory epithelium , mouse olfactory epithelium , murine airways ≫ rat airways) correlated well with tissue susceptibility to naphthalene. The V{sub max} in monkey alveolar subcompartment was 2% that in rat nasal olfactory epithelium. Rates of metabolism in nasal compartments of the monkey were low. The ...
Parenteral administration of naphthalene produces a dose-dependent and tissue-, species-, and cell-selective lesion of murine Clara cells. The rate and stereoselectivity of naphthalene metabolism by microsomal preparations correlate with tissue and species differences in cytotoxicity. Because earlier studies used microsomes obtained from whole tissue, differences in susceptibility of proximal and distal airways could not be related to differences in the metabolic activation or detoxication of naphthalene. Specific subcompartments of the respiratory system, obtained by microdissection, have been used to study the cytochrome P450-dependent metabolism of naphthalene and the epoxide hydrolase/glutathione transferase-dependent metabolism of naphthalene oxide. The rates of naphthalene metabolism were substantially higher in mouse airways than in comparable airways of hamsters or rats. Rates of metabolism were higher in distal airways than in the trachea of all species studied. Metabolism in mouse ...
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Naphthalene is a type of polycyclic aromatic hydrocarbon (PAH) and possible carcinogen. It is found abundantly in outdoor air with traffic being the largest source. Elevated levels of naphthalene are also found in indoor air when mothballs or kitchen stoves burning biomass fuels are used.. Naphthalene is derived from petroleum and biofuel products and is found entirely in a gaseous phase rather than as a particulate. Human exposure to naphthalene is primarily through inhalation, although it can be ingested and absorbed through the skin. Due to the volatile nature of naphthalene, a box of mothballs can elevate indoor naphthalene levels to levels compatible with mid to upper level occupational exposure, with higher concentrations in smaller apartments or enclosed areas.. A cause of concern is that some Caribbean immigrant families in New York City frequently use mothballs as air fresheners. Therefore understanding potential downstream effects of naphthalene exposure has become increasingly ...
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TY - JOUR. T1 - Vapor-Liquid Equilibria in the System of Toluene/Aniline, Aniline/Naphthalene, and Naphthalene/Quinoline. AU - Lee, Chang-Ha. AU - Chen, Quen. AU - Mohamed, Rahoma S.. AU - Holder, Gerald D.. PY - 1992/4/1. Y1 - 1992/4/1. N2 - Vapor-liquid equilibria for the aniline/naphthalene, toluene/aniline, and naphthalene/quinoline systems have been determined at 0-1500 kPa and 490-623 K by using a static equilibrium cell. The data can be accurately correlated with the modified Peng-Roblnson equation of state by using density-dependent mixing rules. The binary interaction parameters and correction factors for the equation of state are reported at each isotherm. The presence of coal-derived solids in these binary systems did not influence any of the binary bubble pressures.. AB - Vapor-liquid equilibria for the aniline/naphthalene, toluene/aniline, and naphthalene/quinoline systems have been determined at 0-1500 kPa and 490-623 K by using a static equilibrium cell. The data can be accurately ...
Exposure to naphthalene, 1-methylnaphthalene, or 2-methylnaphthalene happens mostly from breathing air contaminated from the burning of wood, tobacco, or fossil fuels, industrial discharges, or moth repellents. Exposure to large amounts of naphthalene may damage or destroy some of your red blood cells. Naphthalene has caused cancer in animals. Naphthalene, 1-methylnaphthalene, and 2-methylnaphthalene have been found in at least 647, 37, and 410, respectively, of the 1,636 National Priority List sites identified by the Environmental Protection Agency (EPA).
Naphthalene is a commonly-occurring, volatile, polycyclic aromatic hydrocarbon, entering the environment from combustion processes, industrial uses, and consumer products (mothballs, cigarette smoke, etc.). Non-cancer air guidance Health-Based Values (HBV) were derived for naphthalene by MDH in 2004 for the acute (200 µg/m3) and chronic (9 µg/m3) durations. However, a cancer HBV has not been established. Possible carcinogenic concerns from inhalation of naphthalene have been an ongoing debate within the scientific community for nearly two decades (U. S. Environmental Protection Agency (EPA), 1998). The applicability of rodent respiratory (nasal/lung) tumors for deriving quantitative human health risk values is the critical outstanding issue.. The EPAs Integrated Risk Information System (IRIS) program evaluated naphthalene in 1998, 2004 (never completed), and is currently in the "Draft Development" stage for another update initiated in 2014. No estimate of naphthalene cancer potency, ...
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article{2003590, abstract = {During lung development, parabronchial SMC (PSMC) progenitors in the distal mesenchyme secrete fibroblast growth factor 10 (Fgf10), which acts on distal epithelial progenitors to promote their proliferation. beta-catenin signaling within PSMC progenitors is essential for their maintenance, proliferation, and expression of Fgf10. Here, we report that this Wnt/Fgf10 embryonic signaling cascade is reactivated in mature PSMCs after naphthalene-induced injury to airway epithelium. Furthermore, we found that this paracrine Fgf10 action was essential for activating surviving variant Clara cells (the cells in the airway epithelium from which replacement epithelial cells originate) located at the bronchoalveolar duct junctions and adjacent to neuroendocrine bodies. After naphthalene injury, PSMCs secreted Fgf10 to activate Notch signaling and induce Snail expression in surviving variant Clara cells, which subsequently underwent a transient epithelial to mesenchymal transition ...
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Mothballs in households arent as widespread since they used to be, but when you have these small orbs of pesticides, try to be aware of the risks they current. The key ingredient in mothballs is naphthalene, which triggers a breakdown of pink blood cells in children that has hop over to these guys a genetic affliction referred to as G6PD deficiency, and pediatricians in Australian identified as for just a ban on naphthalene following it absolutely was associated with one particular babys death and brain hurt in two Other folks ...
Having examined the absorption spectra of naphthalene and its methyl derivatives, I have continued the investigation in order to see how the spectrum of naphthalene is affected by the introduction of different groups in the alpha and beta positions. The technique employed for the solution and vapour spectra has been fully described elsewhere. Pure hexane§ was used as a solvent unless otherwise stated, ϵ is the molecular absorption coefficient. The substances were purified by crystallisation from hexane. Liquids were fractionally distilled in vacuo. ...
ZrO2 nH2O (hydrogel) impregnated with transition metals (Cu, Co, and Ni) was studied in this work as a precursor for the synthesis of CuO/ZrO2 (CuZ), CoOx/ZrO2 (CoZ), and NiO/ZrO2 (NiZ) catalysts, employed in the naphthalene oxidation reaction. Fresh and catalytically used materials were characterized by different physicochemical techniques, to compare the bulk and surface behavior, with particular attention to the effect of the supported metal species properties on the catalytic activity. Techniques such as X-ray diffraction (XRD), temperature programmed reduction (TPR), differential scanning calorimetry (DSC), Brunauer-Emmett-Teller (BET) surface area analyzer, diffuse reflectance spectroscopy (DRS UV-vis), and Raman spectroscopy, allow for establishing structural and textural aspects of the support, as well as the surface coordination and the accessibility of supported species. Results were in agreement with the CuZ > CoZ > NiZ sequence for the activity in naphthalene oxidation reaction.
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Naphthalene, 1,1-diethoxy-1,2,3,4-tetrahydro- | C14H20O2 | CID 71387374 - structure, chemical names, physical and chemical properties, classification, patents, literature, biological activities, safety/hazards/toxicity information, supplier lists, and more.
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Naphthyl (?), n. [Naphthalene + -yl.] Chemistry|Chem. A hydrocarbon radical regarded as the essential residue of naphthalene. &...
Similarly, in the chromatograms shown on the right hand side of figure 3, 2, 4 and 6 ml of a solution each containing 9.0 mg of naphthalene was injected onto the column and. The maximum sample volume that just permits the separation of naphthalene and anthracene, identified experimentally was 6 ml (theoretical value calculated from equation 2 was 6.1 ml). Destefano and Beachel (4) has also investigated the effect of volume and mass overload on resolution. They concluded that, given the choice, it is advantageous to overload a column with a large volume of a dilute solution of sample, as an alternative to using a small volume containing a high concentration of sample. They reported, however, that the validity of this conclusion, appeared to depend somewhat on the capacity ratios of the eluting solutes. In figure 4 the retention distance (measured in cm along the chart) is plotted against the sample volume. ...
In a similar manner and under identical conditions Scott and Kucera examined the effect of naphthalene over load (from 1.1 to 19.1 mg) on the retention of benzene, naphthalene and anthracene. The results are shown in figure 9.. ...
The National Institute of Standards and Technology (NIST) uses its best efforts to deliver a high quality copy of the Database and to verify that the data contained therein have been selected on the basis of sound scientific judgment. However, NIST makes no warranties to that effect, and NIST shall not be liable for any damage that may result from errors or omissions in the Database ...
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Naphthalene is a white solid that evaporates easily. Fuels such as petroleum and coal contain naphthalene. It is also called white tar, and tar camphor, and has been used in mothballs and moth flakes. Burning tobacco or wood produces naphthalene. It has a strong, but not unpleasant smell. The major commercial use of naphthalene is in the manufacture of polyvinyl chloride (PVC) plastics. Its major consumer use is in moth repellents and toilet deodorant blocks. 1-Methylnaphthalene and 2-methylnaphthalene are naphthalene-related compounds. 1-Methylnaphthalene is a clear liquid and 2-methylnaphthalene is a solid; both can be smelled in air and in water at very low concentrations. 1-Methylnaphthalene and 2-methylnaphthalene are used to make other chemicals such as dyes and resins. 2-Methylnaphthalene is also used to make vitamin K.
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