Separation of dicarboxylic acids by means of a host-guest interaction is challenging because the mixtures include isomers or molecules that are very geometrically similar. This is the case for two important dicarboxylic acids, fumaric acid and maleic acid. Fumaric acid is an intermediate product in the energy metabolism of all cells. It has many applications in the food and pharmaceutical industries. Maleic acid is used in polymer production, dying cotton, and decalcifying agents.. Fumaric acid is usually obtained through the isomerization of maleic acid, which is harmful to health, so all residues of maleic acid must be scrupulously removed from the fumaric acid product. As the host molecule for their separation, the research team selected a polyamine that consists of two oxygen-containing, six-membered, hydrocarbon rings bound together through a hydrocarbon chain that contains three amino groups. This compound is flexible and can crystallize in different conformations. This host molecule ...
Styrene/maleic acid copolymers (SMA) have recently attracted great interest for in vitro studies of membrane proteins, as they self-insert into and fragment biological membranes to form polymer-bounded nanodiscs that provide a native-like lipid-bilayer environment. SMA copolymers are available in di …
Global Styrene-Maleic Anhydride Copolymer Market is a professional and in-depth study on the current state of the industry. The report provides a basic overview of the Styrene-Maleic Anhydride Copolymer market including definitions, classifications, applications and industry chain structure. This report also states import/export consumption, supply and demand figures, cost, price, revenue and gross margins, and the global market size (volume and value).. Access complete report at: https://www.themarketreports.com/report/2017-global-styrene-maleic-anhydride-copolymer-industry-depth-research-report. Key companies profiled in this report are Polyscope Polymers, Total Cray Valley (Tcv), Ineos, Sinopec, Baoding Lucky Chemical, Yinxin Chemical, Kaixin Fine Chemical more in terms of basic information, product categories, Sales (Volume), Revenue (Million USD), Price (USD/Unit) and Gross Margin (%) (2012-2017).. Global Styrene-Maleic Anhydride Copolymer Market Report covers Alternate Styrene-Maleic ...
The use of styrene-maleic acid (SMA) copolymers to extract and purify transmembrane proteins, while retaining their native bilayer environment, overcomes many of the disadvantages associated with conventional detergent-based procedures. This approach has huge potential for the future of membrane protein structural and functional studies. In this investigation, we have systematically tested a range of commercially available SMA polymers, varying in both the ratio of styrene and maleic acid and in total size, for the ability to extract, purify and stabilise transmembrane proteins. Three different membrane proteins (BmrA, LeuT and ZipA), which vary in size and shape, were used. Our results show that several polymers, can be used to extract membrane proteins, comparably to conventional detergents. A styrene:maleic acid ratio of either 2:1 or 3:1, combined with a relatively small average molecular mass (7.5-10 kDa), is optimal for membrane extraction, and this appears to be independent of the protein ...
Background: The present study aimed to evaluate and compare the efficacy of 17% ethylenediaminetetraacetic acid (EDTA), 18% etidronic acid, 10% citric acid, and 7% maleic acid in the removal of smear layer at the apical third of the root canals. Materials and methods: Sixty single-rooted teeth were equally divided into four study groups (n = 15), according to the type of irrigant used (17% EDTA, 18% etidronic acid, 10% citric acid, and 7% maleic acid) to remove the smear layer effectively from apical third of root canal. In each group, respective irrigant was used with 5.25% of sodium hypochlorite during instrumentation. Each study sample was then sectioned longitudinally and removal of smear layer was observed using a scanning electron microscope (SEM) at 2000×. Results: A 7% maleic acid revealed better smear layer removal than all other three groups at apical third. A 10% citric acid was found to be more efficient than EDTA and etidronic acid. The intergroup comparison was performed using ...
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A selectivity to benzaldehyde was found to reach a maximum of 93 compared with a conventional stirred glass reactor while the conversion could be increased to 81 . Tadepalli et al. 146 used a laboratory semi-batch reactor (25 mL) and a packed-bed microreactor (775 mm ID) for the kinetic study of hydrogenation reactions. · In recent years the increase in demand for fumaric acid from industry has resulted in an increased need for a high-selectivity process for the conversion of maleic acid to fumaric acid. A highly selective conversion of fumaric acid was achieved without a catalyst by a simple one-step hydrothermal reaction. In addition the competitive conversion of maleic acid fumaric acid and malic acid Contact Online ...
between the reactants and products, specifically, between the protonated (HA) and deprotonated (A−) forms of the substance. Paulings second rule[1] states that the value of the first pK for acids of the formula XOm(OH) n is approximately independent of n and X and is approximately 8 for m=0, 2 for m=1, -3 for m=2 and ,-10 for m=3. This correlates with the oxidation state of the central atom, X: the higher the oxidation state the stronger the oxyacid. For example, pKa for HClO is 7.2, for HClO2 is 2.0, for HClO3 is -1 and HClO4 is a strong acid. With organic acids inductive effects and mesomeric effects affect the pKs. The effects are summarised in the Hammett equation and subsequent extensions. Structural effects can also be important. The difference between fumaric acid and maleic acid is a classic example. Fumaric acid is (E)-1,4-but-2-enedioic acid, a trans isomer, whereas maleic acid is the corresponding cis isomer, i.e. (Z)-1,4-but-2-enedioic acid (see cis-trans isomerism). Fumaric acid ...
EasySperse™ polymers are effective dispersants of hydrophobic actives.. EasySperse polymer is based on a copolymer of the monobutyl/ethyl ester of poly (methyl vinyl ether/maleic acid) partially neutralized with sodium hydroxide. The material is supplied as a 25 percent aqueous solution and is an excellent film-former.. EasySperse P-20 polymer is a spray-dried, optimized composite polyvinyl pyrrolidone (PVP) and methyl vinyl ether/maleic acid half ester. It offers superior stability of hydrophobic actives and excellent compatibility with formulation ingredients.. ...
A low color or colorless polymaleate as determined by a Gardner color number of 8 or less, said polymaleate is prepared by aqueous solution polymerization of 70 to 99.9 weight percent of maleic acid, 0.1 to 30 weight percent of an allylic sulfonate monomer, and 0.5 to 50 μm, based on the moles of monomer, of a polyvalent transition metal ion selected from group consisting of Group IVA, VA, VIA, VIIA, VIIIA, IB, IIB, and combinations thereof, wherein the weight percents are based on the total weight of monomer, provided that 10 to 60 mole percent of the carboxylic acid groups on the maleic acid are neutralized prior to polymerization. The low color or colorless polymaleates provide permanent press properties to textiles treated therewith and increases the resistance of such textiles to laundering abrasion. The polymaleates also may be used in cleaning compositions to disperse and suspend soils.
question 1:In flouroacetic acid and iodo acetic acid,who is stronger and why? question 2:In floroacetic acid and tri flouroacetic acid,who is stronger and why? question 3:In 2-chlororopionic acid and 3-chloroacetic acid,who is stronger and why? question 4:In formic acid and acetic acid,who is stronger and why? question 5:Removal of second hydrogen is much more difficult as compare to the removal of first hydrogen in maleic acid,why? question 6:Removal of second hydrogen from succinic acid is easier as compare to maleic acid why ...
The National Institute of Standards and Technology (NIST) uses its best efforts to deliver a high quality copy of the Database and to verify that the data contained therein have been selected on the basis of sound scientific judgment. However, NIST makes no warranties to that effect, and NIST shall not be liable for any damage that may result from errors or omissions in the Database ...
North America and Europe Acrylic Acid Copolymer Market by Manufacturers, Regions, Type and Application, Forecast to 2023. In the report, we mainly research Ethylene and Acrylic Acid Copolymer(EAA), Maleic Acid and Acrylic Acid Copolymer(MA/AA), Acrylamide and Acrylic Acid Copolymer. Scope of the Report: This report focuses on the Acrylic Acid Copolymer in North America and Europe market, especially in United States, United Kingdom, Canada, Germany, France, Italy and Spain. .... February 2018 , $4480 ,View Details>> ...
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0085] As the milling aids, for example, anionic milling aids and/or dispersants may be used, preferably selected from the group comprising homopolymers or copolymers of polycarboxylic acid salts based on, for example, acrylic acid, methacrylic acid, maleic acid, fumaric acid or itaconic acid and acrylamide or mixtures thereof. Homopolymers or copolymers of acrylic acid, polysalt S from the company BASF, Ludwigshafen, are especially preferred. The molecular weight Mw of such products is preferably in the range of 2000-35000, with a molecular weight Mw 3000-7000 being especially preferred. The molecular weight Mw of such products is also preferably in the range of 2000 to 150000 g/mol, and an Mw of 15000 to 50000 g/mol is especially preferred, e.g., 35000 to 45000 g/mol. The molecular weight of the milling aids and/or dispersants is selected so that they do not act as a binder but instead act as a parting compound. The polymers and/or copolymers may be neutralized with monovalent and/or polyvalent ...
Disclosed are compositions suitable for use in embolizing blood vessels which compositions comprise a polymer, a biocompatible solvent and a contrast agent. The polymer is selected from the group consisting of polyacrylonitrile, polyurethane, polyvinylacetate, cellulose acetate butyrate, nitrocellulose and copolymers of urethane/carbonate and copolymers of styrene/maleic acid.
Rust is removed from metal surfaces by applying a coating of an aqueous solution of copolymer of maleic acid and monomer. The rust becomes incorporated into the coating during drying and the coating d
A closed cell, light weight packaging material having biodegradable properties and being formed initially from a nonmodified starch material which has been modified by reaction within an extrusion barrel with (i) a mild acid selected from the group consisting of malic acid, tartaric acid, citric acid, maleic acid and succinic acid in the presence of water and (ii) a carbonate composition to generate CO2 gas. This modified starch material has decreased molecular weight and a dominant pattern of nonuniformity of hydrogen bonding within and between starch chains, and a dominant pattern of structural randomness of the starch chains. The resultant packaging material has a closed cellular structure with a density less than 0.032 grams per cubic centimeter and with resilient properties which enable substantial return of the compressed structure to its original, expanded shape with structural integrity. Also set forth is a process for preparing this material, as well as modification for enhancing hydrophobicity
Animals. Crabs, C. borealis, were obtained from commercial suppliers (Boston, MA) and the Marine Biological Laboratory (Woods Hole, MA). Animals were maintained in aerated artificial seawater at 10-12°C, and were cold-anesthetized by packing in ice for 20-40 min before dissection. The stomach, including the STNS, was removed from the animal, and the rest of the dissection was performed in chilled (∼4°C) physiological saline. Data were obtained from 190 male crabs.. Solutions. C. borealis physiological saline had the following composition (in mm): NaCl, 440; MgCl2, 26; CaCl2, 13; KCl, 11; Trizma base, 10; and maleic acid, 5, pH 7.4-7.6.. Immunocytochemistry. Whole-mount immunocytochemistry was performed using standard techniques for this system (Beltz and Kravitz, 1983; Blitz et al., 1995). Briefly, tissue was fixed for 2-24 hr with either 4% paraformaldehyde or 4% 1-ethyl 3-(3 dimethylaminopropyl)-carbodiimide (EDAC; Sigma, St Louis, MO) in 0.1m sodium phosphate, pH 7.3. Preparations were ...
Swelling studies of an acrylamide/maleic acid/methylene-bis-acrylamide-based hydrogel prepared by free radical polymerization (weight ratio of 90/10/3) are presented. Water penetration mechanism was studied by using two ...
cation of 2,3-BD with maleic acid, were found to be useful in mol?glucose1 (69% of theoretical yield) at a speci?c oxygen uptake rate. Get Price ...
Calclium citrate maleate contains a blend of select Vitamins and Elements. Calclium citrate maleate act as a supplement in maintaining a healthy lifestyle.
Nrf2 (Nfe2l2) Knockout mice. This strain is a useful model for the in vivo analysis of chemical carcinogenesis and resistance to anti-cancer drugs. A phenolic antioxidant significantly induced the expression of phase II enzymes such as glutathione S-transferase and NAD(P)H: quinone oxidoreductase in normal mice. However, in the homozygous Nrf2 deficient mice the induction of the phase II enzymes by a phenolic antioxidant was largely eliminated in the liver and intestine. Since Nrf2 is constantly degraded by proteasome under normal condition, it is hardly to detect Nrf2 protein in the absence of stimuli. Electrophilic chemicals, such as DEM (diethyl maleate) and tBHQ (tert-buthyl hydroquinone), are generally used to stabilize Nrf2. Or proteasomal inhibitors, such as MG132, are also effective increasing the protein amount of Nrf2. C57BL/6 background (RBRC01390), BALB/c background (RBRC02190), A/J background (RBRC02414), ICR mixed background (RBRC00984). Homozygous mutant mice are viable and ...
Bei manchen Anwendungen der im Patent 191 von Brockway et al. In some applications in patent 191 Brockway et al. beschriebenen Druckme vorrichtung kann das Geh use aufgrund physikalischer Einschr nkungen und praktischer berlegungen hinsichtlich des chirurgischen Prozesses nicht in unmittelbarer N he des Bereiches implantiert werden, in dem der Druck zu messen ist. The pressure measurement device described, the housing can due to physical limitations and practical considerations of the surgical process not be implanted in the immediate vicinity of the area in which the pressure is to be measured. Wenn sich das Geh use nicht in unmittelbarer N he des Bereiches befindet, in dem der Druck zu messen ist, kann die dann erforderlich werdende L nge des Katheters zu gro werden, so da Fehler, die sich aus dem dann schlechteren dynamischen Verhalten oder bei einer nderung der Haltung ergeben, f r die jeweilige Anwendung nicht mehr innerhalb akzeptabler Grenzen liegen. If not, the housing is located in ...
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PRIMARY OBJECTIVES:. I. To determine if the addition of cediranib (cediranib maleate) to chemoradiation treatment enhances treatment efficacy as measured by the 6-month progression-free survival rate.. SECONDARY OBJECTIVES:. I. To determine if the addition of cediranib to chemoradiation treatment enhances treatment efficacy as measured by overall survival.. II. To determine if the addition of cediranib to chemoradiation treatment enhances treatment efficacy as measured by progression-free survival.. III. To determine if there is an association between tumor O6-methylguanine-deoxyribonucleic acid (DNA) methyltransferase (MGMT) gene methylation status and treatment response and outcome.. IV. To compare and record the toxicities of the cediranib + chemoradiation arm versus the chemoradiation arm.. V. To evaluate whether 6-month progression-free survival is associated with overall survival.. OUTLINE: Patients are randomized to 1 of 2 treatment arms.. ARM I: Patients receive cediranib maleate orally ...
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Answer your questions about predicting bulk material behavior and show you how to use Rocky DEM in your heavy equipment design processes, giving you crucial insights.
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The term DEM, DTM and DSM has several meanings and are not always understood properly, correctly or misinterpreted. Difference between DEM/DTM and DSM
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Das Ausführungsbeispiel nach Fig. 7 unterscheidet sich von dem nach den Fig. 1 bis 4 nur dadurch, daß die Außensei- te des Aerosolabscheiders (6) zwei mit dem Innenraum des Gehäuses (4) über den Aerosolabscheider (6) in gedrosselter Durchlaßverbindung stehende Unterdruckkammern (25) auf- weist, in denen ein etwas geringerer Druck als in dem Ge- häuse (4) in der Nähe seiner Innenseite herrscht. Zu diesem Zweck können die Unterdruckkammern (25) über eine im Querschnitt erheblich dünnere Rohrleitung als die der Rohre (9) und (11) oder über ein eine Drossel aufweisendes Rohr mit dem Abluftventilator verbunden sein. Zusätzlich ist der Ae- rosolabscheider (6) luftdurchlässig, wobei der Gesamtdurch- trittsquerschnitt des Aerosolabscheiders (6) so eng bemes- sen ist, daß er gleichsam wie eine Drossel wirkt, so daß die in dem Aerosol enthaltenen Schwebeteilchen zwar mit ei- ner etwas größeren Kraft zum Aerosolabscheider (6) hin ab- gelenkt werden und sich an ihm abscheiden können, aber ...
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Mastektomia z powodu raka piersi ma na celu doszczętne wycięcie miąższu gruczołu. Konieczność resekcji klinicznie zdrowej tkanki w obrębie fałdu podpiersiowego (ang. inframammary fold - IMF) jest poddawana dyskusji. Usunięcie miąższu także w okolicy IMF może potencjalnie zmniejszyć ryzyko powstania wznowy raka piersi. Jednakże u pacjentek poddawanych operacji odtwórczej zachowanie fałdu podpiersiowego może przyczynić się do uzyskania naturalnie wyglądającej, nieznacznie opadającej, piersi. Odrębnym problemem jest obecność pierwotnego ogniska raka gruczołu piersiowego w okolicy fałdu podpiersiowego. Celem pracy było przedstawienie opisu przypadku pacjentki leczonej z powodu inwazyjnego raka piersi w obrębie IMF oraz analiza onkologicznego aspektu postępowania chirurgicznego z fałdem podpiersiowym podczas mastektomii w odniesieniu do znaczenia tej struktury anatomicznej w rekonstrukcji piersi. Zaprezentowano przypadek 52-letniej kobiety leczonej z powodu guza lewej piersi.
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