Nemadectin is a macrocyclic lactone antibiotic with a broad-spectrum endectocidal and nematocidal activity [1]. In dogs, oral administration of 0.2-0.4 mg/kg nemadectin (a liquid formulation administered in gelatin capsules) was effective in eliminating
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Strigolactones, first discovered as germination stimulants for parasitic weeds [1], are carotenoid-derived phytohormones that play major roles in inhibiting lateral bud outgrowth and promoting plant-mycorrhizal symbiosis [2-4]. Furthermore, strigolactones are involved in the regulation of lateral and adventitious root development, root cell division [5, 6], secondary growth [7], and leaf senescence [8]. Recently, we discovered the strigolactone transporter Petunia axillaris PLEIOTROPIC DRUG RESISTANCE 1 (PaPDR1), which is required for efficient mycorrhizal colonization and inhibition of lateral bud outgrowth [9]. However, how strigolactones are transported through the plant remained unknown. Here we show that PaPDR1 exhibits a cell-type-specific asymmetric localization in different root tissues. In root tips, PaPDR1 is co-expressed with the strigolactone biosynthetic gene DAD1 (CCD8), and it is localized at the apical membrane of root hypodermal cells, presumably mediating the shootward ...
Lactones are cyclic esters of hydroxycarboxylic acids, containing a 1-oxacycloalkan-2-one structure, or analogues having unsaturation or heteroatoms replacing one or more carbon atoms of the ring. Lactones are formed by intramolecular esterification of the corresponding hydroxycarboxylic acids, which takes place spontaneously when the ring that is formed is five- or six-membered. Lactones with three- or four-membered rings (α-lactones and β-lactones) are very reactive, making their isolation difficult. Special methods are normally required for the laboratory synthesis of small-ring lactones as well as those that contain rings larger than six-membered. Lactones are usually named according to the precursor acid molecule (aceto = 2 carbon atoms, propio = 3, butyro = 4, valero = 5, capro = 6, etc.), with a -lactone suffix and a Greek letter prefix that specifies the number of carbon atoms in the heterocycle - that is, the distance between the relevant -OH and the -COOH groups along said backbone. ...
The effects of several lactones were studied in a microsomal fraction of dog myocardium thought to be sarcoplasmic reticulum. The lactones increased the steady-state accumulation and turnover of calcium only in the presence of ATP, and augmented the calcium-stimulated ATPase activity. When the effective concentrations of the lactones were exceeded, there were no further alterations in calcium accumulation or turnover. A correlation between the capacity of these lactones to increase calcium accumulation and turnover and their relative cardiotonic activity, as reported in the literature, was noted. The potency of the lactones in relation to calcium metabolism in the microsomes is influenced by ring saturation, position of the double bond, and presence of a steroid ring system to the lactone moiety.. ...
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We found a significant increase in mean serum creatinine concentration (p , 0.0001) already in the first month after initiation of treatment with rofecoxib. This increase was sustained during treatment and ranged around 0.15 mg/dl, corresponding to a decrease of eGFR of around 10 ml/min, reaching up to 14 ml/min in month 4. However, mean serum creatinine concentration remained within the normal range during and after end of the trial and no dialysis treatment was needed. Rofecoxib is known to cause acute renal failure at a rate of 1.2 to 1.5% in trials studying several thousands of patients [7, 8], but even a single dose of rofecoxib can cause severe acute renal failure [9]. Furthermore, the half life of COX-II inhibitors rofecoxib and celecoxib is prolonged in liver failure [10]. Though patients with severe hepatic failure were excluded from the present study, 52% of the patients presented with liver metastasis and thus might have been subjected to a higher exposure of rofecoxib due to ...
Technical Summary of BIMECTIN PLUS Injection for CATTLE - BIMEDA - ivermectin 1% + clorsulon 10%, macrocyclic lactone, benzenesulphonamide for the control of gastrointestinal roundworms, lungworms, eyeworms, liver flukes, lice, mites and grubs on cattle, cows, heifers, calves, bulls, bovine, Indications, spectrum of activity, recommended dose, safety, toxicity, LD50, withholding period, ingredientes, composición, administration, characteristics, features.
Technical Summary of MASTERMECTIN 10 mg/ml Solution for Injection for CATTLE, SHEEP & PIGS - C-CORP - ivermectin, macrocyclic lactone, for the control of gastrointestinal roundworms, lungworms, eyeworms, lice, mites and grubs on cattle, cows, heifers, calves, sheep, lambs, ewes, goats, swine, pigs, piglets. Indications, spectrum of activity, recommended dose, safety, toxicity, LD50, withholding period, ingredientes, composición, administration, characteristics, features.
Adams T.B., Greer D.B., Doull J., Munro I.C., Newberne P.M., Portoghese P.S., Smith R.L., Wagner B.M., Weil C.S., Woods L.A. and Ford R.A. 1998. The FEMA GRAS assessment of lactones used as flavor ingredients. Food and Chemical Toxicology. 36, 249.. ...
2,3-O-Isopropylidene-L-lyxono-1,4-lactone 152006-17-2 route of synthesis, 2,3-O-Isopropylidene-L-lyxono-1,4-lactone chemical synthesis methods, 2,3-O-Isopropylidene-L-lyxono-1,4-lactone synthetic routes ect.
Z-D-Homoserine Lactone chemical properties, What are the chemical properties of Z-D-Homoserine Lactone 41088-89-5, What are the physical properties of Z-D-Homoserine Lactone ect.
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The thermal and acid-catalyzed intramolecular rearrangement of the (Z)- and (E)-cyclodecene-1,4-dione compounds deriving from steroids, 2a,b and 3a,b, respectively, proceeds stereoselectively to give the corresponding configurationally different spiro-γ-lactone derivatives, the (5R,9R)-isomers 4a,b (from the (Z)-cyclodecenediones 2a,b) and the (5R,9S)-isomers 5a,b (from the (E)-cyclodecenediones 3a,b). The semiempirical MNDOAM1 and PM3 molecular orbital methods were applied to elucidate the possible mechanistic pathway of the observed intramolecular process leading to the spiro-γ-lactone structures.
Industry expert Tony OLenick asks Mark Garrison of Avon to explain the difference between esters and lactones, such as lactones being esters in a ring formation.
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Specialisation within the DWARF14 protein family confers distinct responses to karrikins and strigolactones in |i|Arabidopsis|/i|
Macrocyclic lactones are usually secreted into milk during lactation, causing very long suppression times in dairy cattle. To solve this problem, several macrocyclic lactones have been developed, like the eprinomectin, as this molecules presence in the milk is nearly zero, causing no suppression time. Furthermore, ABC transporters participate in many cellular functions, as they actively export substances outside the cell. These transporters are important as they have a role in the cellular resistance functions against several drugs, affecting the absorption, distribution, metabolism, and excretion of these molecules.. The innovation presented here provides a synergistic drug combination consisting on eprinomectin and either meloxicam or danofloxacin that, when applied together, increase and optimize the therapeutic action of the drugs. This combination has several advantages such as; it potentially generates a longer time of action of the analgesic action of the anti- inflammatory, it is the ...
Clark, J. , Hayes, S., Blake, A. and Gobbi, L. (2007) Synthesis of a lactone natural product found in Greek tobacco. Tetrahedron Letters, 48, pp. 2501-2503 ...
see article for more reactions. Abstract. The regioselective opening of Bn2N-α-methylserine-β-lactone with organocuprates gave enantiopure α-methyl amino acids in excellent yields.. ...
28 Nov 2016 The results showed that all investigated factors, explicitly GDL concentration, acidifiion temperature and . During the last 20 years, milk acidifiion with glucono-δ-lactone has been .. hydrolysis, J. Dairy Sci. .. to increase process control and flexibilitywhile reducing the use of energy and fresh water.. Chat Online ...
2-Fluoro-2,3-dideoxy-L-glycero-tetronic acid 1,4-lactone | C4H5FO2 | CID 13826493 - structure, chemical names, physical and chemical properties, classification, patents, literature, biological activities, safety/hazards/toxicity information, supplier lists, and more.
A new, cis-selective, approach for the synthesis of bicyclic δ-lactones bearing a fused cyclohex-2-en-1-one moiety is described. The strategy utilizes a cascade reactivity of cyclic 1,3-diketones and 3-arylidenefuran-2(3H)-ones with the butenolide-ring-opening reaction enabling the construction of the δ-lact
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2A4O: Dual Modes of Modification of Hepatitis A Virus 3C Protease by a Serine-derived beta-Lactone: Selective Crystallization and Formation of a Functional Catalytic Triad in the Active Site
View Notes - 2005 exam 1 from BIOCHEM 153L at UCLA. Chemistry 14C Fall 2005 Exam 1 Page 1 The questions on page 1 4 of this exam refer to rhizoxin whose structure can be found on the last page of
The National Institute of Standards and Technology (NIST) uses its best efforts to deliver a high quality copy of the Database and to verify that the data contained therein have been selected on the basis of sound scientific judgment. However, NIST makes no warranties to that effect, and NIST shall not be liable for any damage that may result from errors or omissions in the Database ...
ITO Shinsaku , KITAHATA Nobutaka , UMEHARA Mikihisa , HANADA Atsushi , KATO Atsutaka , UENO Kotomi , MASHIGUCHI Kiyoshi , KYOZUKA Junko , YONEYAMA Koichi , YAMAGUCHI Shinjiro , ASAMI Tadao Plant and Cell Physiology 51(7), 1143-1150, 2010-07-01 References (37) Cited by (6) ...
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TY - JOUR. T1 - A common mutation in paraoxonase-2 results in impaired lactonase activity. AU - Stoltz, David A.. AU - Ozer, Egon A.. AU - Recker, Thomas J.. AU - Estin, Miriam. AU - Yang, Xia. AU - Shih, Diana M.. AU - Lusis, Aldons J.. AU - Zabner, Joseph. PY - 2009/12/18. Y1 - 2009/12/18. N2 - Paraoxonases (PONs) are a family of lactonases with promiscuous enzyme activity that has been implicated in multiple diseases. PON2 is intracellularly located, is the most ubiquitously expressed PON, and has the highest lactonase activity of the PON family members. Whereas some single-nucleotide polymorphisms (SNPs) in PON1 have resulted in altered enzymatic activity in serum, to date the functional consequences of SNPs on PON2 function remain unknown. We hypothesized that a common PON2 SNP would result in impaired lactonase activity. Substitution of cysteine for serine at codon 311 in recombinant PON2 resulted in normal protein production and localization but altered glycosylation and decreased ...
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Strigolactones are a novel class of plant hormones controlling shoot branching in seed plants. They also signal host root proximity during symbiotic and parasitic interactions. To gain a better understanding of the origin of strigolactone functions, we characterised a moss mutant strongly affected in strigolactone biosynthesis following deletion of the CAROTENOID CLEAVAGE DIOXYGENASE 8 (CCD8) gene. Here, we show that wild-type Physcomitrella patens produces and releases strigolactones into the medium where they control branching of protonemal filaments and colony extension. We further show that Ppccd8 mutant colonies fail to sense the proximity of neighbouring colonies, which in wild-type plants causes the arrest of colony extension. The mutant phenotype is rescued when grown in the proximity of wild-type colonies, by exogenous supply of synthetic strigolactones or by ectopic expression of seed plant CCD8. Thus, our data demonstrate for the first time that Bryophytes (P. patens) produce ...
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Contribution to the elucidation of the anti-inflammatory activity of sesquiterpene lactones [Elektronische Ressource] / vorgelegt von Alfonso J. García Piñeres : Contribution to the Elucidation of the Anti-inflammatory Activity of Sesquiterpene Lactones Inaugural-Dissertation zur Erlangung der Doktorwürde der Fakultät für Chemie, Pharmazie und Geowissenschaften der Albert-Ludwigs-Universität Freiburg im Breisgau vorgelegt von Alfonso J. García Piñeres aus San José, Costa Rica April 2003 Gedruckt mit Unterstützung
Abstract: Sesquiterpene lactones have long been used in traditional Chinese medicines to treat inflammatory diseases. Recently, sesquiterpene lactone family compounds have been recognized as potential anticancer agents. Thus, it is necessary to explore new sesquiterpene lactones and their antitumor mechanism for cancer treatments. In the present study, we have explored the potential anti-cancer activity of a novel sesquiterpene lactone compound santamarine (STM) in HepG2 cells. It inhibited proliferation and induced apoptosis dose-dependently with IC50 ~ 70 μM. Induction of apoptosis was found to be linked with increased reactive oxygen species (ROS) generation, decreased activity of thioredoxin reductase (TrxR), glutathione (GSH) depletion, mitochondrial membrane potential (ΔΨm) dissipation, Bcl-2 family proteins modulation, cytochrome c release, caspases-9, -8 and -3 activation and PARP cleavage. Further mechanistic study demonstrated that STM inhibited the constitutive and TNF-α-induced ...
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TY - JOUR. T1 - Effects of tetrahydrolipstatin -a lipase inhibitor- on absorption of fat from the intestine of the rat. AU - Fernández, E.. AU - Borgström, B.. PY - 1989/1/1. Y1 - 1989/1/1. M3 - Article. VL - 0. SP - 249. EP - 255. IS - 1001. ER - ...
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