Global Oil Field Corrosion Inhibitor Market Professional Survey Report 2018 1 Industry Overview of Oil Field Corrosion Inhibitor 1.1 Definition and Specifications of Oil Field Corrosion Inhibitor 1.1.1 Definition of Oil Field Corrosion Inhibitor 1.1.2 Specifications of Oil Field Corrosion Inhibitor 1.2 Classification of Oil Field Corrosion Inhibitor 1.2.1 Imidazoline 1.2.2 Quaternary Ammonium salt 1.2.3 Inorganic Corrosion Inhibitor 1.2.4 Organic phosphorus 1.2.5 Others 1.3 Applications of Oil Field Corrosion Inhibitor 1.3.1 Acidification Operation 1.3.2 Sewage Treatment 1.3.3 Pipeline Corrosion Inhibition 1.3.4 Others 1.4 Market Segment by Regions 1.4.1 North America 1.4.2 China 1.4.3 Europe 1.4.4 Southeast Asia 1.4.5 Japan 1.4.6 India 2 Manufacturing Cost Structure Analysis of Oil Field Corrosion Inhibitor 2.1 Raw Material and Suppliers 2.2 Manufacturing Cost Structure Analysis of Oil Field Corrosion Inhibitor 2.3 Manufacturing Process Analysis of Oil Field Corrosion Inhibitor 2.4 Industry ...
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Bautista and S. Feliu, Cem. Concr. , 1996, 26, 501. 5. P. Novák, R. Malá and L. Joska, Cem. Concr. , 2001, 31, 589. 6. W. Breit, Mater. , 1998, 49, 539. 7. O. A. Kayyali and M. N. Haque, Mag. Concr. , 1995, 47, 235. 8. L. Zimmermann, B. Elsener and H. Böhni, Corrosion of Reinforcement in Concrete, Corrosion Mechanisms and Corrosion Protection, European Federation of Corrosion Publication No 31, IOM Communications Ltd, 2000, p. 25. 9. P. Novák and R. Malá, Corrosion of Reinforcement in Concrete, Corrosion Mechanisms and Corrosion Protection, EFC Publication No 31, IOM Communications Ltd, 2000, p. The values for the real and imaginary components at a given frequency were much higher for electrodes with high corrosion potentials than those with low. In contrast with exposure in alkaline solutions, a well-defined polarization resistance hardly exists for zinc in cement mortar. Very different values were obtained with different techniques. Therefore, the corrosion rate in mortar could not be ...
ABSTRACT. This research work investigated the corrosion characteristics of aluminium bronze alloy in four selected aggressive media which are H2SO4, HCl, NaOH, and NaCl. Aluminium bronze alloy was produced locally via sand casting method. Copper coils and aluminium materials which constitute waste to the environment were used in producing the alloy. Test specimens were produced from the as cast alloy and immersed in H2SO4, HCl, NaOH, and NaCl environment. The concentrations of the environment were varied as 0.1 M, 0.3 M and 0.5 M. The aluminium bronze produced from sand casting has mechanical properties that are closer to the standards proposed by CDA [1]. The corrosion rate was determined by weight loss method at an interval of 3 days. It was observed that the corrosion behaviour exhibited by aluminium bronze in acidic media followed similar trends in 0.1 M, 0.3 M and 0.5 M respectively. However, the corrosion rates increases with increase in the concentration of H2SO4 and NaCl media, but the ...
Copper corrosion rate and corrosion products originating from acetic acid vapors have been studied using gravimetric, scanning electron microscopy, X-ray photoelectron spectroscopy, and argon-ion sputtering techniques. Copper specimens were exposed to the action of 10, 100, and 300 ppm acetic acid vapors generated in laboratory experiments at 40 and 80% relative humidity (RH) for a period of 21 days and at 30°C. The copper corrosion rate was in the range from 0.08 to 0.17 mg/dm2/day (mdd) for 40% RH and from 0.11 to 6.53 mdd for 80% RH. The main compounds found were cuprite [Cu2O], copper hydroxide [Cu(OH)2], and copper acetate [Cu(CH3COO)2]. A corrosion process model is proposed in which copper acetate is formed from copper hydroxide present on the copper surface ...
While various corrosion inhibitors are known in various arts, the efficacy and usefulness of any particular corrosion inhibitor is dependent on the particular circumstances in which it is applied. Thus, efficacy or usefulness under one set of circumstances often does not imply the same for another set of circumstances. As a result, a large number of corrosion inhibitors have been developed and are in use for application to various systems depending on the medium treated, the type of surface that is susceptible to the corrosion, the type of corrosion encountered, and the conditions to which the medium is exposed. For example, U.S. Pat. No. 3,909,447 describes certain corrosion inhibitors as useful against corrosion in relatively low temperature oxygenated aqueous systems such as water floods, cooling towers, drilling muds, air drilling and auto radiator systems. That patent also notes that many corrosion inhibitors capable of performing in non-aqueous systems and/or non-oxygenated systems perform ...
Certain metal surfaces are often unable to be contacted effectively with fluids containing hydrofluoric acid due to significant corrosion issues. Steel surfaces represent but one example. Corrosion inhibitor compositions comprising an N-(phosphonoalkyl)iminodiacetic acid or any salt thereof can be used to suppress corrosion of steel surfaces, including those that contain multiple types or grades of steel. Methods for suppressing corrosion of a steel surface can comprise: contacting a steel surface with a corrosive environment, the corrosive environment comprising hydrofluoric acid; exposing the steel surface to a corrosion inhibitor composition, the corrosion inhibitor composition comprising an N-(phosphonoalkyl)iminodiacetic acid or any salt thereof; and suppressing corrosion of the steel surface being contacted with the corrosive environment through exposure to the corrosion inhibitor composition.
A two-dimensional numerical analysis of oxygen transport and corrosion behaviors in a coupled natural convection and lead bismuth eutectic (LBE) flow in a two dimensional container was carried out in detailed. In present study, it is assumed the corrosion product (iron) concentration is at its equilibrium level at the wall. The wall boundary condition for the mass transfer of corrosion production and oxygen concentration was taken based on the active oxygen control model. And also the oxygen transport in the LBE loop flow was simulated for testing and calibrating flow concentration level oxygen sensors. Both of the corrosion/precipitation rates at the wall, distribution of corrosion product and oxygen, and oxygen diffusion time are analyzed. Some useful information was obtained to understand the mechanism of corrosion behavior and oxygen transport.. Copyright © 2005 by ASME ...
TY - CONF. T1 - Corrosion behavior of flame-resistant Calcium-added Magnesium alloy in NaCl aqueous solution containing various anion species. AU - Tsunakawa, Mika. AU - Shiratori, Ryota. AU - Nakamura, Kae. AU - Ishizaki, Takahiro. PY - 2016/1/1. Y1 - 2016/1/1. N2 - Flame-resistant Ca-added Mg alloys are highly desirable as the materials for transport industry from viewpoints of the safety and lightweight. Recently, exposure tests of the Ca-added Mg alloys demonstrated that the anion species other than chloride ion, such as nitrate and sulfate ions, were present in the corrosion products formed on the Mg alloys. However, details of the corrosion behavior of the Ca-added Mg alloys have been not yet clarified. In this study, we aimed to investigate the corrosion behavior of the flame-resistant Ca-added Mg alloy in NaCl aqueous solution with and without sulfate ions by immersion testing. XRD and FT-IR measurements demonstrated that the corrosion products formed on the Ca-added Mg alloy AZX612 were ...
Biofilms cause various problems such as medical infections, fouling of water cooling system, product contamination, and microbiologically influenced corrosion (MIC). MIC accounts for as much as 20% of all forms of corrosion, amounting to billions of dollars in losses each year. Among bacteria related to MIC, sulfate reducing bacteria (SRB) are most often blamed. The ubiquity of these bacteria leads to a variety of impressive industrial, economic and ecological effects because of their proneness to generate large quantities of H2S. SRB are the main reason to cause the MIC by accelerating corrosion rate, inducing stress corrosion and pitting corrosion. The aim of this study was to evaluate the corrosion associated with the formation of SRB biofilms on carbon steel surfaces ...
A new approach to the assessment of the corrosion behaviour of zinc coatings under atmospheric conditions can be achieved using gel-type electrolytes as an alternative to standard aqueous test electrolytes. Gel-type electrolytes allow minimally invasive corrosion investigations on zinc coatings. They also provide the possibility to carry out corrosion investigations onsite. By using gel-type electrolytes corrosion-relevant characteristic values such as corrosion currents and polarization resistances can be determined. These allow to describe the formation and the stability of the formed corrosion product layers under various climatic conditions. With this knowledge, a prediction of the zinc coating life cycle is possible. In this contribution, the value of gel-type electrolytes for corrosion research on zinc coatings is presented.
Recently, SiC-based ceramics have been found to exhibit corrosion damage patterns, which can only be explained by electrochemical processes. Therefore, the current work focusses on the electrochemical test procedures to determine the corrosion behaviour of solid state sintered silicon carbide (SSiC) ceramics in acidic and alkaline media. The corrosion current densities have been determined from linear voltammetric scans. At anodic polarization potentials, electrochemically induced etching patterns were observed in alkaline solution. The formation of pores and crevices during electrochemical oxidation in acidic solution could be monitored by field emission scanning electron microscopy (FESEM) in addition to transmission electron microscopy (TEM). Impedance spectra measured after anodic polarization could be described by the assumption of a pore model equivalent circuit. ...
In light water reactors corrosion-induced material degradation is a critical issue not only for material integrity but also for plant radiation field build-up. In BWRs nickel-base alloys, such as Alloy 600, Alloy 82 and Alloy 182, are applied in various parts of reactor components including welds. However, their corrosion mechanisms are not very well understood. Although the complex compositions of different nickel-base alloys generally prohibit us to single out some specific alloy constituent having a major impact on alloy corrosion rate, a higher chromium content is often thought to be beneficial to forming a more protective oxide film against corrosion attack. In this paper we report a corrosion kinetics study on high chromium nickel-base alloy welding consumables, Alloy 52M and Alloy 152, under simulated BWR normal water chemistry conditions and high flow velocity for up to nine weeks exposure. The corrosion rates are derived from measurements of weight losses of test coupons, oxide ...
Preferential weld corrosion occurs in the hydrocarbon carrying pipelines due to CO2 presence. The weld segments consist of parent metal, HAZ and weld metal that causes corrosion due to potential difference. The corrosion could be mitigated with the formation of protective layer (FeCO3). However, the mitigation has not been effective as the FeCO3 layer formation is disrupted by environmental conditions like the pH and also the presence of weak acids like Acetic Acid (HAc) The purpose of this research is to investigate the presence of HAc and its effect on the corrosion rate of the weld segments. The influence of pH on the FeCO3 formation on the weld segments with and without HAc present is also analyzed. A coupled sample and an un-coupled sample is prepared from the API 5L X52 mild steel weld segment. Test parameters were set to varying pH 4 and 6.6 with and without 1000ppm HAc present. 4 glass cells are set up to measure the intrinsic corrosion rate of the un-coupled sample and 4 glass cells are ...
Monitoring of Concrete Permeability, Carbonation and Corrosion Rates in the Concrete of the Containers of El Cabril (Spain) Disposal (O393 ...
Many methods are presented herein including a method comprising: providing a metal surface; and contacting the metal surface with a treatment fluid comprising an aqueous base fluid, an acid, a corrosion inhibitor, and a corrosion inhibitor intensifier composition comprising a corrosion inhibitor compound that corresponds to a formula: PR1R2R3, wherein R1, R2, and R3 are chosen from the group consisting of C1-C20 alkyl, cycloalkyl, oxyalkyl, and aryl groups, and R1, R2, and R3 may or may not be equal. Corrosion inhibitor intensifier compositions also are provided.
The low density and high specific strength of magnesium alloys have created a great deal of interest in the use of these alloys in the automotive and aerospace industries and in portable electronics. All of these industries deal with applications in which weight is extremely important. However, an obstacle to overcome when using magnesium alloys in engineering applications are their unsatisfactory corrosion properties. This thesis is devoted to the atmospheric corrosion of the two magnesium alloys AZ91D and AM50, in particular the ways the microstructure and exposure parameters of these alloys influence their corrosion behaviour. The work includes both laboratory and field studies. The results obtained show that the microstructure is of vital importance for the corrosion behaviour under atmospheric conditions.. The microstructure of magnesium-aluminium alloys contains different intermetallic phases, e.g. Al8Mn5 and β-Mg17Al12. The local nobility of these intermetallic phases was measured on a ...
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The basic function of the electrically conductive surface of electrical contacts is electrical conduction. The electrical conductivity of contact materials can be largely reduced by corrosion and in order to avoid corrosion, protective coatings must be used. Another phenomenon that leads to increasing contact resistance is fretting corrosion. Fretting corrosion is the degradation mechanism of surface material, which causes increasing contact resistance. Fretting corrosion occurs when there is a relative movement between electrical contacts with surfaces of ignoble metal. Avoiding fretting corrosion is therefore extremely challenging in electronic devices with pluggable electrical connections. Gold is one of the most commonly used noble plating materials for high performance electrical contacts because of its high corrosion resistance and its good and stable electrical behavior. The authors have investigated different ways to minimize the consumption of gold for electrical contacts and to improve the
Corrosion and irritation tests of a dental aluminium bronze. B.I. ARDLIN*1,2, B. LINDHOLM-SETHSON1 and J.E. DAHL2, 1Umeå University, Sweden, 2NIOM - Nordic Institute of Dental Materials, Haslum, Norway. Objectives: The aims of this investigation were to study the corrosion of a copper-aluminium-nickel alloy for fixed prostheses, and to evaluate possible irritant effects of the corrosion products.. Methods: The alloy NPG+2 with the nominal composition Cu:77.3; Al:7.8; Ni:4.3; Fe:3.0; Zn:2.7; Au:2.0; Mn:1.7, was characterized. Static immersion in saline lactic acid solution was selected to quantify metallic elements released in a milieu simulating the condition of plaque build-up in interproximal areas. Corrosion and surface reactions in artificial saliva and saline solutions were studied by electrochemical techniques including registration of polarization curves and impedance spectra. Irritative effect of the corrosion products was assed by the Hens egg test-chorio-allantoic membrane, ...
Lead-tin alloy pipes in historic organs frequently suffer from damaging atmospheric corrosion. Organic acids emitted from the wood of organ cases had been established previously as the cause of deterioration in pure lead pipes. In the present study, lead-tin alloy samples containing 3.4 and 15 atom % tin were subjected to laboratory exposure experiments under atmospheres of 1100 ppb acetic acid, 350 ppm CO 2 , and 60 or 95% relative humidity (RH). Wet and dry corrosion mass gains were monitored, and corrosion product compositions and morphologies were characterized by grazing incidence angle X-ray diffraction and scanning electron microscopy. Cross sections were cut through corrosion sites using a focused ion beam milling method, and elemental information was obtained using wavelength dispersive and energy dispersive X-ray analyses. The corrosion products and morphologies observed in the alloys are the same as those reported for pure lead, but the corrosion susceptibilities of the alloys show a much
External corrosion is a growing threat to the integrity of ageing pressure equipment. Consequently, plant owner/operators usually have in place fabric maintenance programmes aimed at preventing external corrosion but where it is found already active the focus shifts to rectification. This relies on removal of corrosion product, cleaning and repainting or repair using composite wraps. Before the corrosion product can removed it is necessary to establish that there is sufficient remaining wall thickness to allow the work to be completed safely. Hence there is a need in the industry to reasonably accurately measure the remaining wall thickness under regions of external corrosion.. Sonomatic offers a number of inspection solutions for measurement of steel thickness under corrosion.. ...
External corrosion is a growing threat to the integrity of ageing pressure equipment. Consequently, plant owner/operators usually have in place fabric maintenance programmes aimed at preventing external corrosion but where it is found already active the focus shifts to rectification. This relies on removal of corrosion product, cleaning and repainting or repair using composite wraps. Before the corrosion product can removed it is necessary to establish that there is sufficient remaining wall thickness to allow the work to be completed safely. Hence there is a need in the industry to reasonably accurately measure the remaining wall thickness under regions of external corrosion.. Sonomatic offers a number of inspection solutions for measurement of steel thickness under corrosion.. ...
The corrosion process (anodic reaction) of the metal dissolving as ions generates some electrons that are consumed by a secondary process (cathodic reaction). These two processes have to balance their charges. The sites hosting these two processes can be located close to each other on the metals surface, or far apart depending on the circumstances. This simple observation has a major impact in many aspects of corrosion prevention and control, for designing new corrosion monitoring techniques to avoiding the most insidious or localized forms of corrosion.. One simple way to illustrate the two processes in a corrosion reaction is to use an external power source as illustrated in the corrosion current experiment. ...
Corrosion Protection Rubber Coating Market Research Report Now Available at Research Corridor. Research Corridor has published a new research study titled "Corrosion Protection Rubber Coating Market - Growth, Share, Opportunities, Competitive Analysis and Forecast, 2017 - 2025". The Corrosion Protection Rubber Coating market report studies current as well as future aspects of the Corrosion Protection Rubber Coating Market based upon factors such as market dynamics, key ongoing trends and segmentation analysis. Apart from the above elements, the Corrosion Protection Rubber Coating Market research report provides a 360-degree view of the Corrosion Protection Rubber Coating industry with geographic segmentation, statistical forecast and the competitive landscape.. Browse the complete report at http://www.researchcorridor.com/corrosion-protection-rubber-coating-market/. Geographically, the Corrosion Protection Rubber Coating Market report comprises dedicated sections centering on the regional market ...
Novel chitosan-zinc copper oxide (Zn1−xCuxO) composites were electrochemically synthesized through galvanostatic deposition. The prepared chitosan-based composite thin films were elaborately investigated to determine their structural, morphological, compositional, impedance, and corrosion properties. X-ray diffraction analysis was performed to reveal their structural orientation of composite thin films. Energy dispersive analysis by X-ray evidently confirmed the existence of Zn, Cu, and O in the composite thin films. Nyquist plots revealed that the chitosan-Zn1−xCuxO thin films had obvious semi-circular boundaries, and higher resistance was observed for chitosan-ZnO due to the grain boundary effect. Corrosion properties were evaluated using both an electrochemical method and the ASTM weight gain method, which revealed good corrosion rates of 34 and 35 × 10−3 mm/y, respectively, for chitosan-ZnO thin film.
Free Online Library: Corrosion products on brass condenser tube cooled by seawater.(Report) by Annals of DAAAM & Proceedings; Engineering and manufacturing Anticorrosion coatings Properties Condensers (Steam) Design and construction Marine corrosion Research Sea-water corrosion Steam condensers
Corrosion is a process that attacks buried metallic water distribution and transmission piping often resulting in unexplained water loss, service disruptions, and increased maintenance and operating costs. A recent study indicated the annual cost of corrosion of water systems in the United States alone exceeds $22 billion and is expected to grow.. The goal of this material is to identify the corrosion process and proven measures that can be employed to reduce corrosions negative impact on metallic piping and associated fittings. Eliminating or reducing corrosion will not only help conserve water, but also reduce leaks and extend the life of water piping systems. Topics to be reviewed and discussed will include stray electrical currents, aggressive soils, bimetallic coupling, coatings, cathodic protection, corrosion coupons and polyethylene encasement. Several municipal case histories will also be discussed.. ...
the meaning of corrosion, types of corrosion, the meaning of corrosion inhibitor and its types, corrosion testing, Corrosion-Resistant Materials
Magnesium alloys as biodegradable materials can be used in body as an implant materials but since they have poor corrosion resistance, it is required to decrease their corrosion rate by biocompatible coatings. In this study, hydroxyapatite (HA) coatings in the presence of an intermediate layer of ZrN as a biocompatible material, deposited on AZ91 magnesium alloy by ion beam sputtering method at 300 °C temperature and at different times 180, 240, 300, 360 and 420 min. Then changes in corrosion resistance of samples in Ringers solution as a solution similar to the human body was evaluated in two ways, potentiodynamic polarization and electrochemical impedance spectroscopy (EIS). To investigate the causes of the destruction of the samples, the surface of samples was studied by scanning electron microscopy (SEM). The results showed that because of porous coatings created, the corrosion potential of the samples was about +55mV higher than the uncoated substrate that by changing the deposition time, was
I have tested stainless steel sample coated by a layer that claims to improve the hardness of the material without reducing corrosion resistance. After 72 hours of salt corrosion tests, I have found that there was corrosion. The corrosion was on the outside it did not travel beyond the coating layer and SEM analysis confirmed this. So say only the coating material experiences some corrosion and it improves hardness with no corrosion to the base material (Stainless Steel Sample ...
C876 - 15 Standard Test Method for Corrosion Potentials of Uncoated Reinforcing Steel in Concrete , concrete-corrosion activity, concrete-corrosion of reinforcing steel, corrosion, corrosion activity, corrosion potentials,,
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0003]It is well known that steel surfaces will corrode in the presence of the acid environments described. While the rate at which corrosion will occur depends on a number of factors, such as the steel alloy itself, the strength and type of corrosive components in the environment, the temperature of the environment, the length of contact, etc., some sort of corrosion invariably occurs. Alloy technology has provided materials to withstand the incidental contact of steel with corrosive components such as CO2 and/or H2S, but the corrosion problem is particularly aggravated when there is no choice but to contact steel with these components, as in the case of hydrocarbon exploration, recovery and refining--such as the oil and gas industry and in chemical processing and the like, where these components are inevitably present. In instances where the liquid is not required to remain pure and where the contact is inevitable, attention has turned toward providing corrosion inhibitors in the liquid medium ...
Intrinsically Conducting Polymers (ICPs) and their composite coatings were successfully electrodeposited on aluminium alloy AA-2024 substrate from an aqueous solution containing oxalic acid and monomers. The monomers used were pyrrole (Py), aniline (ANi) and metanilic acid (MAA). Electropolymerization was done using constant potential, constant current and cyclic voltammetry methods. The applied potential, applied current, monomer concentration, co-monomer feed ratio and reaction time were varied and their effect on the yield and corrosion performance were assessed. The progress of electropolymerization was monitored by using coating thickness measurements, current - time (I-t) and potential-time (E-t) transients.The coatings were characterized by reflection-absorption infrared spectroscopy (RAIR) and scanning electron microscopy (SEM). The corrosion performance of the ICPs and their composites were determined by using DC Polarization (DCP) studies.The corrosion rate of the coatings was found to ...
Intumescent coating is a mineral based or organic resin based product functioning as fire retardant coating where it can be applied to metallic materials, polymers, textiles, wood as well as structural steel in buildings, storage tank in order to protect them from weakening when encounter elevated temperature in a fire. Most of the offshore and marine structure are heavily exposed to the marine environment mainly seawater which is one of the corrosion medium. Coating protect steels through barrier layer action of the coating, secondary barrier action of corrosion product layer. The presence of the mechanical damage allows the access of corrodents to the substrate, eventually resulting in destruction of the coating by the growth of corrosion products. Researcher will develop an intumescent coating formulation which consist of three agents mainly Acid Source (AAP, Polyphosphate), Carbon source (EG, Expandable Graphite) and blowing agent (MEL, Melamin) followed by epoxy, Boric Acid, Polyamide ...
Powertrain applications of alloy AJ62 arose from its comparative resistance to high temperature deformation among magnesium alloys. In this research, AJ62 permanent-mould cast in different section thicknesses was subjected to immersion corrosion in commercially-available engine coolant. The objective was to determine corrosion behaviour variation among casting thicknesses. Corrosion product accumulation suggests passive film formation, and unlike in other media, the film exhibits certain stability. Extreme thicknesses were used to generate polarization curves for their respective microstructures in engine coolant. Variation with casting section thickness was observed in the curves. These preliminary results indicate coarsened microstructures reduce corrosion resistance of the permanent mold cast AJ62 alloy ...
The effect of temperature and acid concentration on a newly formulated tannin as a corrosion inhibitor for carbon steel in oil and gas facilities was investigated. Corrosion rate of carbon steel in HC
Multi-functional corrosion inhibitor for closed cooling and chilled systems with a leak detection dye. Accepta 2807 is a nitrite-based chemical treatment used for the control of corrosion in closed cooling systems and chilled water systems. A highly efficient combination of ferrous and non-ferrous corrosion inhibitors, a non-carbonate buffer, scale inhibitors, dispersants with the added benefit of an in built leak detection dye...
In the present paper, the effect of Mg and Cu additions on melting, mechanical and corrosion behavior of Al-9Zn alloy was studied and analyzed. It was found that, addition of Cu and Mg led to form the Al-Cu, Al-Mg and Mg-Zn intermetallic compounds. These compounds tend to increase the hardness values due to the precipitation strengthening hardening mechanism of these compounds. Also corrosion behavior of the Cu and Mg content alloys measured by the weight loss method is better than those of the Al-9Zn alloy. Furthermore, corrosion resistance of the Cu content alloys is superior to that of the Mg content alloys.
... Date: Saturday, March 17, 2001 at 09:09:43 PM Amalgam Alloy - mixture of metals Amalgam - alloy including mercury Used for more than 150 years 100 million amalgam restorations per year in the USA for the last 20 years Billions sold with no adverse effects Components 1. Silver - Increases strength, expansion and reactivity. Decreases creep. Corrosion products are AgCl and AgS. 2. Tin - Increases reactivity and corrosion. Decreases strength and hardness. Corrosion products are SnO, SnCl, and SnS. 3. Copper - Increases strength, expansion and hardness. Decreases creep. Corrosion products are CuO and CuS. 4. Zinc - Increases plasticity, strength and the Hg:alloy ratio. Decreases creep. Causes secondary expansion. Corrosion products are ZnCl and ZnO. 5. Mercury - Wets the alloy particles. Decreases strength if in excess amounts. Implicated in toxic and allergic reactions. Types 1. Spherical - AgSnCu + Hg AgHg + CuSn + AgSnCu 2. Lathe cut - AgSn + Hg AgHg + SnHg + AgSn 3. ...
An electrochemical investigation of the corrosion on AISI 316 austenitic stainless steel and AISI 1010 carbon steel in sodium chloride solution (3.0 wt.%) was performed in the absence and presence of imidazole and benzimidazole corrosion inhibitors. The results showed that at any inhibitor concentration (25 ppm to 1000 ppm), there was an increase in the polarisation resistance of both steels. The highest efficiency of corrosion inhibition was obtained using imidazole at a concentration of 50 ppm for both steels, with values of 96% for the AISI 316 stainless steel and 73% for the AISI 1010 carbon steel.
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Confidence in ultrasonic inspection to detect and quantify corrosion in field applications has often required the disassembly of systems and testing in water baths. Results of various tests have shown that the detection of hidden corrosion on various aluminum alloys of varying thickness was useful above 10 percent metal loss, but the technique was not applicable for metal loss below 10 percent. To improve the ability to detect hidden corrosion, there have been continued efforts to apply the dripless bubbler ultrasonic scanner, which is an ultrasonic technique that does not require a water bath and disassembly.10 This technique was selected as a primary candidate by the Air Force Logistics Center in Oklahoma City (OCALC) for the detection and quantification of intergranular corrosion prior to the onset of exfoliation around wing skin fasteners. This is a major inspection problem for aging aircraft. Figure 4 shows the results of tests for corrosion detection around wing skin fasteners. In a ...
Biofilm formation on 304 stainless steel (S30400) does not necessarily result in an ennoblement of the corrosion potential. Instead, biofilms composed of aerobic and anaerobic bacteria from Gulf of Mexico water formed an anaerobic biofilm/metal interface and caused the corrosion potential to move in the negative direction. Biofilms from the same source containing photosynthetic diatoms in the presence of light produced aerobic biofilm/metal interfaces and a positive shift (ennoblement of the corrosion potential). Corrosion potentials of stainless steels exposed in natural seawater cannot be predicted without an understanding of the composition of the biofilm and its impact on interfacial chemistry. In this paper, measurements of corrosion potential, interfacial pH and dissolved oxygen have been correlated with SEM/EDAX surface analyses to evaluate the electrochemical behaviour of stainless steels exposed to Gulf of Mexico water. The interfacial chemistries that influence the corrosion potential ...
The effects of seven macrocyclic compounds comprising four phthalocyanines (Pcs) namely 1,4,8,11,15,18,22,25-octabutoxy-29H,31H-phthalocyanine (Pc1), 2,3,9,10,16,17,23,24-octakis(octyloxy)-29H,31H-phthalocyanine (Pc2), 2,9,16,23-tetratert- butyl-29H,31H-phthalocyanine (Pc3) and 29H,31H-phthalocyanine (Pc4), and three naphthalocyanines namely 5,9,14,18,23,27,32,36-octabutoxy-2,3-naphthalocyanine (nPc1), 2,11,20,29-tetra-tert-butyl-2,3-naphthalocyanine (nPc2) and 2,3-naphthalocyanine (nP3) were investigated on the corrosion of aluminium (Al) in 1 M HCl using a gravimetric method, potentiodynamic polarization technique, quantum chemical calculations and quantitative structure activity relationship (QSAR). Synergistic effects of KI on the corrosion inhibition OPEN ACCESS properties of the compounds were also investigated. All the studied compounds showed appreciable inhibition efficiencies, which decrease with increasing temperature from 30 °C to 70 °C. At each concentration of the inhibitor, ...
A prominent Fe-base bulk amorphous steel (BAS) alloy which presents high glass forming ability (GFA), good corrosion resistance, superior mechanical properties and relative lower cost. The Fe41Cr15Co 7Mo14C21-xBxY2 (x = 5-10) BAS rods with a diameter of 2-6 mm, can be fabricated by the suction casting method. The highest GFA value can be obtained by adjusting the ratio of boron/carbon, reaching to the value of γ = 0.4 and γm = 0.69 for the alloy composition of Fe41Ce15Co 7Mo14C12B9Y2. Meanwhile, this alloy also presents very large supercooled liquid region up to 81 K, favourable to be fabricated into micro-surgery tools by thermoplastic forming. In addition, the Fe-base BAS alloy exhibits extremely high hardness around 1200 Hv. The anodic polarization measurement of the Fe-based BAS exhibits a higher corrosion resistance than 304 SS and 316 SS in the Hanks balanced salt solution. The sharpness test results reveal that the Fe-based BAS blade exhibits much higher sharpness because of its lower ...
Corrosion tests of several US martensitic and austenitic steels were performed in a forced circulation lead-bismuth eutectic non-isothermal loop at the Institute of Physics and Power Engineering (IPPE), Russia. Tube and rod specimens of austenitic steels 316/316L, D-9, and martensitic steels HT-9, T-410 were inserted in the loop. Experiments were carried out simultaneously at 460 °C and 550 °C for 1000, 2000 and 3000 h. The flow velocity at the test sections was 1.9 m/s and the oxygen concentration in LBE was in the range of 0.03-0.05 wppm. The results showed that at 460 °C, all the test steels have satisfactory corrosion resistance: a thin protective oxide layer formed on the steel surfaces and no observable dissolution of steel components occurred. At 550 °C, rod specimens suffered rather severe local liquid metal corrosion and slot corrosion; while tube specimens were subject to oxidation and formed double-layer oxide films that can be roughly described as a porous Fe3O4 outer layer over a chrome
High-temperature corrosion is a mechanism of corrosion that takes place in gas turbines, diesel engines, furnaces or other machinery coming in contact with hot gas containing certain contaminants. Fuel sometimes contains vanadium compounds or sulfates which can form compounds during combustion having a low melting point. These liquid melted salts are strongly corrosive for stainless steel and other alloys normally inert against the corrosion and high temperatures. Other high-temperature corrosions include high-temperature oxidation, sulfidation and carbonization. Two types of sulfate-induced hot corrosion are generally distinguished: Type I takes place above the melting point of sodium sulfate and Type II occurs below the melting point of sodium sulfate but in the presence of small amounts of SO3. In Type I the protective oxide scale is dissolved by the molten salt. Sulfur is released from the salt and diffuses into the metal substrate forming discrete grey/blue colored aluminum or chromium ...
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