Abstract : The objective of the present study was to evaluate the impact of biofield energy treatment on the thermal,spectroscopic, and chemical properties of anisole by various analytical methods such as gas chromatography-massspectrometry (GC-MS), high performance liquid chromatography (HPLC), differential scanning calorimetry (DSC),Fourier transform infrared (FT-IR) spectroscopy, and ultraviolet-visible (UV-Vis) spectroscopy. The anisole sample wasdivided into two parts, control and treated. The control part was remained same while the other part was treated withMr. Trivedis unique biofield energy treatment. Mass spectra showed the molecular ion peak with five fragmented peaksin control and all treated samples. The isotopic abundance ratio of 2H/1H, and 13C/12C [(PM+1)/PM] in treated samplewas increased by 154.47% (T1) as compared to the control [where, PM- primary molecule, (PM+1)-isotopic moleculeeither for 13C or 2H]. The HPLC chromatogram showed retention time of treated anisole was ...
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I dont think polarization is the issue. Adding $\ce{FeBr3}$ is just to reduce the $\ce{Br-Br}$ bond strength, speeding up the reaction (attack of the aromatic ring on the bromine is part of the rate determining step, which is slow in the bromination of benzene). It functions as a catalyst being recycled when the $\ce{Br-}$ grabs a $\ce{H+}$ to restore aromaticity in the ring. Im pretty sure - at least I see no reason to doubt - that the catalyst requirements for the bromination of anisole and the bromination of phenol do not differ much, if at all. That is, no catalyst is required for the bromination of anisole.. ...
Solution How Do You Convert the Following : Phenol to Anisole Concept: Preparation of Ethers from Dehydration of Alcohols and Williamson Systhesis.
Creative-Proteomics offer cas 87-40-1 2,4,6-TRICHLOROANISOLE UNLABELED 1 MG/ML IN METHANOL. We are specialized in manufacturing Stabel Isotope Labeled Analytical Standard products.
Estragole is suspected to be carcinogenic and genotoxic, as is indicated by a report of the European Union, Committee on Herbal Medicinal Products.[3] Several studies have clearly established that the profiles of metabolism, metabolic activation, and covalent binding are dose dependent and that the relative importance diminishes markedly at low levels of exposure (i.e. these events are not linear with respect to dose). In particular, rodent studies show that these events are minimal probably in the dose range of 1-10 mg/kg body weight, which is approximately 100-1000 times the anticipated human exposure to this substance. For these reasons it is concluded that the present exposure to estragole resulting from consumption of herbal medicinal products (short time use in adults at recommended posology) does not pose a significant cancer risk. In the meantime exposure of estragole to sensitive groups such as young children, pregnant and breastfeeding women should be minimized. The Scientific ...
First order-like plots, due to the large excess of methoxide, are obtained in each case, except with methyl benzoate (Plot 3) where metallic copper appeared after 1 hour (decomposition of catalyst). Slope ratio between the blank experiment (Plot 1) and the ethyl acetate one (Plot 6) is superior to 20, demonstrating the effectiveness of this co-catalyst (completion is reached within 45 min., with a quasi-quantitative yield).. Use of ethyl rather than methyl esters leads sometimes to traces of 2-ethoxy phenol (0.5 to 1%), due to releasing of ethoxide ion through transesterification of the co-catalyst by methoxide; methyl esters may therefore be preferred if highest purity of final product is required.. Anisole is also quasi-quantitatively obtained from bromobenzene in presence of ethyl acetate (10 mmole PhBr, 4 mmol EtOAc, 1,4 mmol CuBr in 6 ml 5M MeONa/MeOH, 98% conversion after 1h reflux, 100% after 2h, yield of isolated anisole >95% without detected phenetole).. Another example, of industrial ...
TY - JOUR. T1 - A porphyrin-based gelator assembly which is reinforced by peripheral urea groups and chirally twisted by chiral urea additives. AU - Tamaru, Shun Ichi. AU - Uchino, Shin Ya. AU - Takeuchi, Masayuki. AU - Ikeda, Masato. AU - Hatano, Tsukasa. AU - Shinkai, Seiji. PY - 2002/5/13. Y1 - 2002/5/13. N2 - A novel porphyrin (1b) bearing four urea groups at its periphery was synthesized. This compound tends to aggregate into one-dimensional direction, resulting in an organogel phase in anisole and diphenyl ether solvents. The gel can be formed even at 0.125 wt/vol% in anisole and the sol-gel phase transition temperatures (Tgel) are as high as 120-140°C, indicating that 1b acts as an excellent gelator for these specific solvents. The spectroscopic studies and electron-micrographic observations support the view that the π-π stacking interaction among porphyrin moieties and the hydrogen-bonding interaction among urea moieties operate synergistically to give rise to a stable one-dimensional ...
Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Extinguishing media: Use extinguishing media most appropriate for the surrounding fire. In case of fire use water spray, dry chemical, carbon dioxide, or appropriate foam ...
Sulfanilide / Thienothiazine / Methoxyaniline / Phenoxy compound / Anisole / Phenol ether / Methoxybenzene / 2,3,5-trisubstituted thiophene / Alkyl aryl ether / AralkylamineOrtho-thiazine / Organosulfonic acid amide / Organic sulfonic acid or derivatives / Organosulfonic acid or derivatives / Heteroaromatic compound / Sulfonyl / Thiophene / Aminosulfonyl compound / Secondary amine / Ether / Azacycle / Secondary aliphatic amine / Organoheterocyclic compound / Organic oxygen compound / Organic nitrogen compound / Hydrocarbon derivative / Organic oxide / Organosulfur compound / Organooxygen compound / Organonitrogen compound / Amine / Organopnictogen compound / Aromatic heteropolycyclic compound ...
5-phenylimidazole - 4-phenylimidazole - 1,2,4,5-tetrasubstituted imidazole - Phenoxy compound - Aryl thioether - Anisole - Phenol ether - Methoxybenzene - Alkyl aryl ether - Alkylarylthioether - Monocyclic benzene moiety - N-substituted imidazole - Benzenoid - Heteroaromatic compound - Azacycle - Ether - Thioether - Sulfenyl compound - Organosulfur compound - Organooxygen compound - Organonitrogen compound - Organic oxygen compound - Organic nitrogen compound - Hydrocarbon derivative - Aromatic heteromonocyclic compound ...
How do the senses of wine enthusiasts detect cork taint (the presence of the chemical TCA)? Is it a certain smell, like the musty pages of an old hymnal, or is it indicated by a general dampening of aroma and flavor? Find out how much of the phenomenon is subjective-and when to open another bottle.
We have studied the pyrolysis of aromatic combustion intermediates using an array of detection techniques. The molecules investigated include cyclic aromatic molecules with hydrocarbon substituents (ethylbenzene, n-propylbenzene, isopropylbenzene, and styrene), oxygen-containing substituents (anisole and phenol), triply substituted systems (vanillin), resonance stabilized radicals (benzyl radical and tropyl radical) and phenyl radical. At the exit of a resistively heated micro-reactor (1 mm inner diameter, 3 cm long), the pyrolysis fragments are detected using photoionization mass spectrometry (PIMS), matrix isolation vibrational spectroscopy, microwave spectroscopy, tunable VUV synchrotron-based PIMS, and table-top VUV PIMS with photoelectron photoion coincidence spectroscopy (PEPICO). This array of detection methods allows for the identification of all possible fragments including metastables, radicals, and atoms. The findings allow for detailed mechanistic information regarding which pathways ...
Lawessons reagent (full name 2,4-bis(4-methoxyphenyl)-1,3,2,4-dithiadiphosphetane 2,4-disulfide (or -disulphide) is a chemical compound with the formula C14H14O2P2S4, used in organic synthesis as a thiation (also called thionation or sulfuration) agent. This light yellow to beige powder has a strong and unpleasant odour.. Lawessons reagent was first produced in 1956 during a systematic study of the reactions of arenes with the comparable reagent P4S10. However it was Swedish chemist Sven-Olov Lawesson who popularized Lawessons reagent within the chemical community.. Being commercially available, Lawessons reagent can also be conveniently made in the laboratory by heating a mixture of anisole with phosphorus pentasulfide until the mixture is clear and no more hydrogen sulfide is formed, and then recrystallized from toluene or xylene.. The main application of Lawessons reagent is the thionation of carbonyl compounds - the carbonyl group is converted into thiocarbonyl group, carbon-oxygen ...
4-allylanisole, and three analogs, anisole, allylbenzene, and 4-isopropylanisole are demonstrated to be effective repellents for scolytid infestation. Conifers, a particular target for the scolytids, are protected by application of the compounds, either directly or suspended in a carrier.
A method and composition for the remediation of environmental contaminants in soil, sediment, aquifer material or water wherein contaminants are first reduced with a reducing agent found in sediment and are then oxidized to environmentally safe products. The composition includes a reducing agent, solubilized from sediment by a solvent, for reduction of environmental contaminants such as nitroorganics, halogenated hydrocarbons, cyano compounds, anisoles and metals.
You may also wish to search for items by Kumar. 27 matching references were found. Vatsa, R.K.; Kumar, A.; Naik, P.D.; Upadhyaya, H.P., et al., UV spectrum and decay kinetics of transient methylsilene produced in the 193 nm photolysis of gaseous 1-methyl-1-silacyclobutane, Chem. Phys. Lett., 1996, 255, 1-3, 129, https://doi.org/10.1016/0009-2614(96)00342-9 . [all data] Kumar, V.; Kumar, A., The study of afterglow spectra of nitrogen at different temperatures and pressures, Physica B+C: (Amsterdam), 1985, 132, 273-294. [all data] Kumar, A.; Meath, W.J., Pseudo-spectral dipole oscillator strengths and dipole-dipole and triple-dipole dispersion energy coefficients for HF, HCl, HBr, He, Ne, Ar, Kr and Xe, Mol. Phys., 1985, 54, 823-833. [all data] Kumar, A., Surface tension, viscosity, vapor pressure, density, and sound velocity for a system miscible continuously from a pure fused electrolyte to a nonaqueous liquid with a low dielectric constant: anisole, J. Am. Chem. Soc., 1993, 115, 9243-8. [all ...
The cell wall protein peptidoglycan complex (CW-PPC) ofMycobacterium tuberculosis H37Ra was isolated through sequential extraction of lipids, carbohydrates and soluble proteins. CW-PPC emulsified in FIA was found to induce significant protection in mice against challenge with LD50 dose ofM. tuberculosis H37Rv. To identify the immunoprotective components of CW-PPC, the proteins in avid association with peptidogican were dissociated by chemical treatment with trifluoromethanesulthonic acid (CF3CO3H): anisole (2:1). Immunoreactivity of total (CW-Pr) as well as its component proteins i.e., 71, 60 and 45 kDa proteins of cell wall was studied in animals immunized with CW-Pr-FIA. The 71 kDa protein was found to be most immunoreactive giving higher T-cell sensitization and humoral responses. Further, immunization of mice with 71 kDa-FIA demonstrated enhanced T- and B- cell responses. Mice immunized with 71 kDa-FIA gave significantly higher protection (P ≤ 0.05) against intravenous challenge with LD50 ...
As the situation with COVID-19 continues to unfold in every community, MedChemExpress is responding to the uncertainty caused by this outbreak thoughtfully and cautiously. Your need for high quality reagent doesnt stop during difficult times, and neither do we. Were doing our best to keep everyone healthy and safe in the workplace while also avoiding the interruptions to our day-to-day operations. If you need to change the delivery plan for items ordered, please contact us via email [email protected]. Thank you for being a loyal MedChemExpress customer, we are here to assist you as needed. ...
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Name L-(+)-Arginine hydrochloride. Synonyms L-Arginine hydrochloride; L-Arginine monohydrochloride; 2-Amino-5-guanidinovaleric acid monohydrochloride. Molecular Formula: C6H14N4O2.HCl. Molecular Weight: 210.66. CAS Registry Number: 1119-34-2. EINECS: 214-275-1. ...
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For iCal, an .ics file will be downloaded to your computer or device. You may need to take additional steps to add the event to your personal calendar.. ...
A metabolite of beta-asarone is the reason Acurus calamus is known in some cultures as a psychedelic. However, not all Acorus calamus contains sufficient quantities of beta-asarone to be effective. Acorus calamus from Nepal typically contains a large amount of beta-asarone. Acorus calamus from India usually contains very little beta-asarone, and will cause extreme nausea before doses high enough to get some minor effects from beta-asarone are ingested.. Its important to note that beta-asarone itself is not active. One of its metabolites can produce psychedelic effects in man. Not everyones body metabolizes beta-asarone the same way, leading to different results for different individuals. Some people are not able to experience psychedelic effects from ingesting beta-asarone. This is because their bodies do not produce enough of the active metabolite to experience effects.. The active metabolite of beta-asarone is currently unidentified. There has been speculation of it being an amphetamine, ...
Therapeutic properties:. Below are a few therapeutic properties that research studies have shown regarding Trans-anethole ((E)-anethole). Please keep in mind these are for the specific chemical component and may not be representative of the entire essential oil it is found in depending on the percentages shown in gas chromatography and mass spectronomy analysis.. Analgesic: (E)-Anethole is moderately analgesic, in both in vitro and in vivo tests2. Antifungal: anethole has been shown to exhibit synergistic antifungal activity against a budding yeast3 and candida6. Anti-inflammatory: (E)-Anethole blocks cellular responses induced by Tumor Necrosis Factor indicating an anti-inflammatory action4 (TNF is a chemical messenger that induces cell death. TNF is directed at "abnormal" cells to assist in preventing the formation of tumors.). There was a study also that showed anethole to be a potential candidate in supporting the restoration of functional dyspepsia.5. Balanced use:. It is important to ...
We have shown previously that low doses of selective sigma (sigma)- receptor ligands potentiate the excitatory response of pyramidal neurons to NMDA in the CA3 region of the dorsal hippocampus in the rat. Because progesterone competitively displaces the binding of the ligand N-[3H]allyl-normetazocine (SKF-10,047), the present studies were undertaken to determine in vivo the effect of neuroactive steroids on NMDA-induced excitation of rat CA3 pyramidal neurons. Low doses of dehydroepiandrosterone (DHEA) potentiated the NMDA response selectively and dose-dependently. The effect of DHEA was reversed by the selective sigma antagonist N-dipropyl-2-(4-methoxy-3- (2-phenylethoxy)phenyl)- ethylamine monohydrochloride (NE-100) and by haloperidol, but not by spiperone. Progesterone had no effect by itself but reversed, at low doses, the potentiation of the NMDA response induced by DHEA as well as those induced by nonsteroidal sigma ligands. Neither pregnenolone nor pregnenolone sulfate had any effect on ...
Looking for online definition of o-anisidine in the Medical Dictionary? o-anisidine explanation free. What is o-anisidine? Meaning of o-anisidine medical term. What does o-anisidine mean?
1-Methoxy-4-(2-propenyl)benzene, also known as methylchavicol or estragol, belongs to the class of organic compounds known as anisoles. These are organic compounds containing a methoxybenzene or a derivative thereof. 1-Methoxy-4-(2-propenyl)benzene is an extremely weak basic (essentially neutral) compound (based on its pKa). 1-Methoxy-4-(2-propenyl)benzene is a sweet, alcohol, and anise tasting compound. Outside of the human body, 1-Methoxy-4-(2-propenyl)benzene is found, on average, in the highest concentration within a few different foods, such as anises, fennels, and sweet basils and in a lower concentration in cumins, tarragons, and parsley. 1-Methoxy-4-(2-propenyl)benzene has also been detected, but not quantified in, several different foods, such as citrus, chinese cinnamons, caraway, fats and oils, and cloves. This could make 1-methoxy-4-(2-propenyl)benzene a potential biomarker for the consumption of these foods. 1-Methoxy-4-(2-propenyl)benzene, with regard to humans, has been linked to ...
TY - JOUR. T1 - Rapid conversion of glycerol to lactic acid under alkaline hydrothermal conditions, by using a continuous flow reaction system. AU - Shimanouchi, Toshinori. AU - Ueno, Shouhei. AU - Shidahara, Kazuki. AU - Kimura, Yukitaka. PY - 2014. Y1 - 2014. N2 - A rapid conversion of glycerol to lactic acid (lactate) could be successfully achieved under alkaline hydrothermal conditions, by using a continuous flow reaction system. A rapid conversion by a continuous flow-type reaction system made it possible to achieve the reaction under high-temperature conditions without side reactions. The rapid conversion and high reaction yield (reaction: 2min; yield: 90%) resulted from the rapid temperature-shift advantageous for the inhibition of side reactions.. AB - A rapid conversion of glycerol to lactic acid (lactate) could be successfully achieved under alkaline hydrothermal conditions, by using a continuous flow reaction system. A rapid conversion by a continuous flow-type reaction system made it ...
1-tert-butyl-4-propan-2-yl-5-(trifluoromethyl)imidazole chemical properties, What are the chemical properties of 1-tert-butyl-4-propan-2-yl-5-(trifluoromethyl)imidazole 129247-52-5, What are the physical properties of 1-tert-butyl-4-propan-2-yl-5-(trifluoromethyl)imidazole ect.
Patients randomized to vernakalant received a 10-minute infusion of 3 mg/kg vernakalant in one infusion line, followed by a 15-minute observation period and an additional 10-minute infusion of 2 mg/kg vernakalant if still in AF. To maintain blinding, a 60-minute infusion of placebo (5% dextrose in water) was administered in a second infusion line, followed by a maintenance infusion of placebo for an additional 60 minutes. Patients randomized to amiodarone received a 60-minute infusion of 5 mg/kg amiodarone in one infusion line, followed by a maintenance infusion of 50 mg amiodarone over an additional 60 minutes (equivalent to approximately 15 mg/kg over 24 hours). To maintain blinding, these patients received a 10-minute infusion of placebo (normal saline) in a second infusion line, followed by a 15-minute observation period and a second 10-minute infusion of placebo if still in AF ...
The report generally describes 2-tert-butyl-4-(α-carbethoxytridecyloxy)-phenol, examines its uses, production methods, patents. 2-tert-Butyl-4-(α-carbethoxytridecyloxy)-phenol
Most of the ADCs currently in the market and in clinical development carry tubulin polymerization inhibitors such as T-DM1 and SGN-35 (Brentuximab vedotin; ref. 13). We synthesized a novel ADC with a topoisomerase I inhibitor, which has a different mechanism of action from tubulin polymerization inhibitors, and a novel self-immolative linker system using an aminomethylene (AM) moiety. Although other cleavable linker systems applied to SGN-35 (Brentuximab vedotin) and several ADCs release amino group-containing payloads, this AM self-immolative linker system is able to release DXd containing the hydroxyl group from DS-8201a. Moreover, this novel linker-payload system enables a reduction in the hydrophobicity of the ADC and helps increase its DAR. In the case of T-DM1, lysine conjugation and noncleavable systems are used, and it is quite a different system from DS-8201a. DS-8201a showed potent HER2-specific efficacy both in vitro and in vivo, and by drug conjugation maintained the functional ...
The authors of the AVRO study also assert that, while both treatments were found to be safe and well tolerated, vernakalant had "low proarrhythmic potential and provides a rapidly acting therapeutic alternative".. The research team, led by Professor John Camm from St. Georges University of London, conducted a randomized, double-blind, multicenter superiority trial in 254 adult patients with underlying cardiovascular disease, making certain antiarrhythmic drugs inappropriate for use. 116 patients in each group received at least one dose of the study drug. Approximately 30% of patients in both treatment arms had no AF episodes prior to the initial diagnosis, whereas one-third had at least three.. Those in the vernakalant study arm received a 10-minute infusion of 3 mg/kg followed by an additional 10-minute infusion of 2 mg/kg if needed after a 15-minute observation period. Amiodarone patients received a 60-minute infusion of 5 mg/kg followed by an additional 60-minute maintenance infusion of 50 ...
The first indication in determining the quality of wine is if there is presence of any faults. The more common ones include cork taint (TCA) and oxidation and can be detected when an aroma or flavor in the wine appears off or just wrong. Cork taint occurs when 2,4,6 - Tricloranisole or TCA, generated by naturally-occurring fungi that often exist in the crevices of wood or cork, comes into contact with chlorine compounds present in pesticides, cleaning agents, wood treatments, etc. When cork taint occurs, the wine will have a musty, moldy aroma. Controlling the source of TCA has proven extremely difficult and currently there are no solutions.. Another wine fault is the oxidation or reduction of the wine - which happens when wines are either exposed to too much or too little oxygen respectively. When oxidation occurs, this usually results in a breakdown of its attractive color. Whites go a dull brown/straw, rosés go brown/orange, reds become paler with an orange/brown rim. Chilling grapes and ...
The present study reports densities (ρ), viscosities (η) and ultrasonic speeds (U) of pure dioxane (DOX), anisole (ANS), toluene (TOL) and ethylbenzene (ETB) and their binary liquid mixtures over the entire composition range at 293, 298, 303, 308 and 313 K. From the experimental data excess molar volume (VmE), excess intermolecular free length (LfE), excess adiabatic compressibility (βE) and excess acoustic impedance (ZE) have been computed. The excess values were correlated using Redlitch-Kister polynomial equation to obtain their coefficients and standard deviations (σ). With increase in temperature, the binary mixture of DOX+ANS shows larger deviations in βE, LfE and smaller deviations in ZE, VmE. These results suggest that ANS has strong molecular interactions with DOX than ETB and TOL.
United States Patent C 3,766,288 PROCESS FOR PREPARATION OF ALKENYLBENZENE Takeo Shima, Takanori Urasaki, and Iwao Omae, Iwakuni, Japan, assignors to Teiiin Limited, Osaka, Ja an N3 Drawing. Filed Mar. 27, 1972, Ser. No. 238,584 Claims priority, application Japan, Mar. 29, 1971, 46/ 18,602 Int. Cl. C07c 3/52 U.S. Cl. 260-668 B 9 Claims ABSTRACT OF THE DISCLOSURE A process for preparing alkenylbenzenes, which comprises reacting alkylbenzenes with 1,3-butadiene at an elevated temperature in the presence of an alkali metal catalyst in the substantial absence of oxygen and mois ture, wherein such catalyst is composed of (1) 0.005 to 0.4% by weight, based on the alkylbenzene, of metallic potassium, and (2) metallic sodium in an amount expressed by the following equation (4.1x+2.0) ;Na;(0.073x+0.05) wherein x represents the amount in weight percent of the metallic potassium. This invention relates to an improved process for preparing alkenylbenzenes by reacting alkylbenzenes with 1,3- butadiene in the ...
Looking for anise? Find out information about anise. annual plant of the family Umbelliferae , native to the Mediterranean region but long cultivated elsewhere for its aromatic and medicinal qualities. Explanation of anise
Many would argue that the sense of smell is our far most important sense when it comes to evaluating wine. This is because the olfactory sense plays a fundamental role both in the perception of aroma and also flavour. Without it all wines,3 rather than just a few, would appear to be uninteresting alcoholic solutions of acid and sugar. The sense of smell is by far the most powerful of our senses. It can discriminate between tens of thousands of different aromas, and is capable of detecting some compounds found in wine at levels around a single part per trillion. An example of this is the compound 2,4,6 Trichloroanisole, the primary compound responsible for cork taint. Some people can detect it at around 1 part per trillion which is analogous to a single second in thirty two years. Not bad I suppose, but when you think that an Alsatian or Beagle probably sees a three dimensional colliedescope like scent world, our olfactory efforts seem pretty pathetic in comparison. The olfactory system ...
Hydroquinone cream can be found in Germany through the store called the Chemical point. Some of them include 2-(1-Phenylethyl) hydroquinone. Hydroquinone, pharma grade, Hydroquinone dimethyl ether (1, 4-Dimethoxybenzene) and many more. There are many online pharmacies and online stores that provide all kinds of medicines including Hydroquinone.. One tube will cost $12.99 and $35.99 for three tubes. Shopeastwest is another medicine center or online pharmacy that will provide you with all kinds of generic and cheap drugs. There are other stores like Melalong by Ajanta Pharma users who are worried and confused about without worrying about its quality or how to buy without becoming confused in complicated websites. Shopeastwest provides you with a quality or how to buy with being confused in complicated websites.. All the drugs from Shopeastwest are delivered by FDA certified pharmaceutical companies and are tested for quality. The user friendly nature of the website can provide you with the best ...
2-tert-butyl-6-(2-phenylpropan-2-yl)phenol | C19H24O | CID 577322 - structure, chemical names, physical and chemical properties, classification, patents, literature, biological activities, safety/hazards/toxicity information, supplier lists, and more.
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Pesticide properties for N-((8-tert-butyl-1,4-dioxaspiro(4.5)dec-2-yl)methyl)propan-1-amine, including approvals, environmental fate, eco-toxicity and human health issues
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