Read Highly functionalized cyclic β-amino acid moieties as promising scaffolds in peptide research and drug design, Amino Acids on DeepDyve, the largest online rental service for scholarly research with thousands of academic publications available at your fingertips.
Background and Aims: Root hairs increase the contact area of roots with soil and thereby enhance the capacity for solute uptake. The strict hair/non-hair pattern of Arabidopsis thaliana can change with nutrient deficiency or exposure to toxic elements, which modify root hair density. The effects of root hair density on cadmium (Cd) accumulation in shoots of arabidopsis genotypes with altered root hair development and patterning were studied. Methods: Arabidopsis mutants that are unable to develop root hairs (rhd6-1 and cpc/try) or produce hairy roots (wer/myb23) were compared with the ecotype Columbia (Col-0 ...
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Acetic acid;heptane-1,2,3,4,5,6,7-heptol | C9H20O9 | CID 312987 - structure, chemical names, physical and chemical properties, classification, patents, literature, biological activities, safety/hazards/toxicity information, supplier lists, and more.
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SIMILARITY:Belongs to the class-I pyridoxal-phosphate-dependent aminotransferase family.,,CAUTION:Similar to plant 1-aminocyclopropane-1-carboxylate synthases but lacks a number of residues which are necessary for activity. ...
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Title: The Enantioselective Synthesis of Conformationally Constrained Cyclic β- Amino Acids. VOLUME: 2 ISSUE: 1. Author(s):Jason A. Miller and SonBinh T. Nguyen. Affiliation:Northwestern University,Department of Chemistry, 2145 Sheridan Rd., Evanston, Illinois 60208-3113, USA.. Keywords:amino acids, cyclic amino acids, enantioselective synthesis, conformationally constrained, peptides, asymmetric synthesis. Abstract: Enantiomerically pure and conformationally constrained cyclic β-amino acids have been the subject of a vast amount of research across the chemical, biological, and medicinal disciplines. These valuable molecules are synthetic precursors for a wide variety of useful compounds that include natural products and modified peptides. Many methods have been developed to prepare chiral cyclic β-amino acids in high optical purity. This mini-review will discuss some of the most recent and successful approaches. ...
Comprehensive supplier list for rel-(1R,4R)-5-aminobicyclo[2.2.1]heptane-2-carboxylic acid,rel-(1R,4R,5S)-tert-Butyl 5-amino-2-azabicyclo[2.2.1]heptane-2-carboxylate
TY - JOUR. T1 - Identification and characterization of a full-length cDNA encoding for an auxin-induced 1-aminocyclopropane-1-carboxylate synthase from etiolated mung bean hypocotyl segments and expression of its mRNA in response to indole-3-acetic acid. AU - Botella, Jose R.. AU - Arteca, Jeannette M.. AU - Schlagnhaufer, Carl D.. AU - Arteca, Richard N.. AU - Phillips, Allen T.. PY - 1992/11/1. Y1 - 1992/11/1. N2 - 1-Aminocyclopropane-1-carboxylate (ACC) synthase (EC 4.4.1.14) is the key regulatory enzyme in the ethylene biosynthetic pathway. The identification and characterization of a full-length cDNA (pAIM-1) 1941 bp in length for indole-3-acetic acid (IAA)-induced ACC synthase is described in this paper. The pAIM-1 clone has an 87 bp leader and a 402 bp trailing sequence. The open reading frame is 1452 bp long encoding for a 54.6 kDa polypeptide (484 amino acids) which has a calculated isoelectric point of 6.0. In vitro transcription and translation experiments support the calculated ...
Competition assays allow for a massively parallel assessment of the relative fitness of variants in a functional context (1). Variant pools can be generated synthetically or harvested from the environment. Recently, deep mutational scanning was developed as a method to elucidate the sequence-function relationships and optimal catalytic sequences of proteins (2, 3). Using a doped DNA oligomer library as a starting point for selection assays, followed by next-generation sequencing, Fowler et al. (2, 3) mapped the mutational preferences of hundreds of thousands of protein variants for an important human protein domain and thereby assessed the fitness effects of nearly all the possible point mutations in the protein domain. This method is able to assay truly novel mutations and combinations of mutations affecting enzyme function, thereby helping to generate optimized engineered proteins for biomedical or other use.. The use of artificially produced proteins may be constrained for ethical and social ...
Turnover of LeACS2, a wound-inducible 1-aminocyclopropane-1-carboxylic acid synthase in tomato, is regulated by phosphorylation/dephosphorylation.: 1-aminocyclo
The key enzyme regulating ethylene biosynthesis in higher plants is 1-aminocyclopropane-1-carboxylate (ACC) synthase. In mung bean (MB), the existence of three genes encoding this enzyme has previously been reported [Botella et al., Plant Mol. Biol. 18 (1992) 793-797], one of which corresponds to a …
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4-Nitrophenyl bicyclo[4.1.0]heptane-7-carboxylate | C14H15NO4 | CID 579216 - structure, chemical names, physical and chemical properties, classification, patents, literature, biological activities, safety/hazards/toxicity information, supplier lists, and more.
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Catalogue #: AMX12-05. 6-APA Amoxicillin Amide ; (2S,5R,6R)-6-[[(2S,5R,6R)-6-[[(2R)-2-Amino-2-(4-hydroxyphenyl)acetyl] amino]-3,3-dimethyl-7-oxo-4-thia-1-azabicyclo[3.2.0]heptane-2-carbonyl] amino]-3,3-dimethyl-7-oxo-4-thia-1-azabicyclo[3.2.0]heptane-2-carboxylic acid ;. MORE INFO >> ...
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Invited paper) Characterization of 1-aminocyclopropane-1-carboxylate (ACC) oxidase in broccoli florets and from Escherichia coli cells transformed with cDNA of broccoli ACC ...
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Most endophytic bacteria in consortia, which provide robust and broad metabolic capacity, are attractive for applications in plant metabolic engineering. The aim of this study was to investigate the effects of engineered endophytic bacterial strains on rice sprout ethylene level and growth under saline stress. A protocol was developed to synthesize engineered strains by expressing bacterial 1-aminocyclopropane-1-carboxylate (ACC) deaminase gene on cells of endophytic Enterobacter sp. E5 and Kosakonia sp. S1 (denoted as E5P and S1P, respectively). Results showed that ACC deaminase activities of the engineered strains E5P and S1P were significantly higher than those of the wild strains E5 and S1. About 32-41% deaminase was expressed on the surface of the engineered strains. Compared with the controls without inoculation, inoculation with the wild and engineered strains increased the deaminase activities of sprouts. Inoculation with the engineered strains increased 15-21% more deaminase activities of
The exact role of ethylene in xylogenesis remains unclear, but the Zinnia elegans cell culture system provides an excellent model with which to study its role during the differentiation of tracheary elements (TEs) in vitro. • Here, we analysed ethylene homeostasis and function during Z. elegans TE differentiation using biochemical, molecular and pharmacological methods. • Ethylene evolution was confined to specific stages of TE differentiation. It was found to peak at the time of TE maturation and to correlate with the activity of the ethylene biosynthetic 1-aminocyclopropane-1-carboxylic acid (ACC) oxidase. The ethylene precursor ACC was exported and accumulated to high concentrations in the extracellular medium, which also displayed a high capacity to convert ACC into ethylene. The effects of adding inhibitors of the ethylene biosynthetic ACC synthase and ACC oxidase enzymes to the TE cultures demonstrated for the first time strict dependence of TE differentiation on ethylene biosynthesis ...
For genus and species identification, a colony PCR was performed with live cells cultured on solid Bacto Pseudomonas F or M79 medium as described previously (17). Species assignment was confirmed by submitting the 16S rRNA sequences to the Ribosomal Database Project II (http://rdp.cme.msu.edu) and comparing them with their nearest phylogenetic relatives.. Degenerate primers DegACC5′ (5′-GGBGGVAAYAARMYVMGSAAGCTYGA) and DegACC3′ (5′-TTDCCHKYRTANACBGGRTC) were designed based upon stretches of conserved base pairs towards the N terminus of the protein and around the putative pyridoxal phosphate cofactor binding domain of the protein (20), whereas for 3′ primer design, a conserved region close to the carboxyl terminus of the protein was utilized. This allows for the amplification of a fragment of approximately 750 bp. Thus, by using this PCR method, bacterial colonies can be quickly screened for the presence of the ACC deaminase gene.. Nucleotide sequences were aligned using MUSCLE v3.52 ...
1-aminocyclopropane-1-carboxylate synthase (ACS) enzymes catalyze the conversion of S-adenosyl-L-methionine (SAM) into 1-aminocyclopropane-1-carboxylate (ACC), a direct precursor of ethylene.
Biology and Biotechnology of the Plant Hormone Ethylene II by Klee, H. and Eu-Tmr-Euroconference Symposium on Biolo and Kanellis, A. K. available in Hardcover on Powells.com, also read synopsis and rThese papers assess existing knowledge and develop ideas on the mechanisms of ethylene synthesis,...
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When plants are exposed to ozone (O3), foliage frequently responds by emitting ethylene. A number of researchers have suggested that O3-induced ethylene is responsible for many subsequent effects of this pollutant. This hypothesis has been tested by using inhibitors of ethylene biosynthesis and demonstrating that other O3 responses were repressed as well. The inhibitors used in all of these studies were pyridoxal phosphate inhibitors, which are largely nonspecific. As such, while the results of the inhibitor studies were consistent with the notion of ethylene as a potential regulator of the O3 response, they could not provide a reliable test of the hypothesis. The enzyme 1-aminocyclopropane-1-carboxylic acid (ACC) synthase regulates ethylene biosynthesis. In this laboratory, a gene has been isolated for O3-induced foliar ACC synthase (ST-ACS4) in potato foliage. The objectives of this research project are to produce transformed potato plants which carry antisense for ST-ACS4, and then to test ...
Cas Index,Name Index,α-Amino Acids,β-Amino Acids,Cyclic β-amino Acids,α-hydroxy Acids,β-Hydroxy Acids,Chiral Amines,Chiral Alcohols,Chiral Amino Alcohols,Chiral Pyrrolidines,Succinates,Chiral Compounds,Chiral Ligands,Chiral Catalyst,Others,,Chiralblock
This page contains information on the chemical 4-Thia-1-azabicyclo(3.2.0)heptane-2-carboxylic acid, 3,3-dimethyl-7-oxo-6-(sulfoamino)-, sodium salt, hydrate (1:2:3), (2S-(2-alpha,5-alpha,6-beta))- including: 2 synonyms/identifiers.
0046] Suitable ether carboxylic acids or ether carboxylates include, but are not limited to, the following representatives referred to by their INCI names (INCI: nomenclature for raw materials according to the International Cosmetic Ingredient Dictionary, 7th Edition, published by the Cosmetic, Toiletry and Fragrance Association Inc. (CTFA), Washington D.C., USA): Butoxynol-5 Carboxylic Acid, Butoxynol-19 Carboxylic Acid, Capryleth-4 Carboxylic Acid, Capryleth-6 Carboxylic Acid, Capryleth-9 Carboxylic Acid, Ceteareth-25 Carboxylic Acid, Coceth-7 Carboxylic Acid, C9-C11 Pareth-6 Carboxylic Acid, C11-C15 Pareth-7 Carboxylic Acid, C12-C13 Pareth-5 Carboxylic Acid, C12-C13 Pareth-8 Carboxylic Acid, C12-C13 Pareth-12 Carboxylic Acid, C12-C15 Pareth-7 Carboxylic Acid, C12-C15 Pareth-8 Carboxylic Acid, C14-C15 Pareth-8 Carboxylic Acid, Deceth-7 Carboxylic Acid, Laureth-3 Carboxylic Acid, Laureth-4 Carboxylic Acid, Laureth-5 Carboxylic Acid, Laureth-6 Carboxylic Acid, Laureth-8 Carboxylic Acid ...
1A14_ARATH 1-aminocyclopropane-1-carboxylate synthase 4 / ACC synthase 4 (ACS4) / identical to gi:940370 [GB:U23481]; go_function: 1-aminocyclopropane-1-carboxylate synthase activity [goid 0016847]; go_process: ethylene biosynthesis [goid 0009693]; go_process: response to auxin stimulus [goid 0009733 ...
1J0C: Reaction intermediate structures of 1-aminocyclopropane-1-carboxylate deaminase: insight into PLP-dependent cyclopropane ring-opening reaction
Additionally, in myb12, the elevated PAP1 and TTG1 transcript levels after IAA and ACC are lost (Fig. 7B; Supplemental Fig. S3), suggesting an essential and upstream role for this MYB transcription factor in these auxin- and ethylene-driven transcriptional changes. As the myb12-1f allele that we used is predicted to encode a truncated MYB12 protein, an alternative possibility is that synthesis of this defective protein may interfere with the expression of PAP1 and TTG1. This possibility is represented in Figure 9 by a dashed arrow between MYB12 and PAP1/TTG1. One interesting surprise from these results is that, although PAP1 and TTG1 transcript accumulation increases after IAA and ACC treatment, transcript of a potential target of these transcriptional regulators, DFR, does not increase. This contrasts with the fact that anthocyanins accumulate in roots in the original activation-tagged pap1 line (Borevitz et al., 2000); however, this may also reflect substantially higher levels of PAP1 in this ...
To make this vision a reality, we attempted to transfer the plant ethylene biosynthesis pathway into E. coli. Plants produce ethylene through the Yang Cycle, which uses methionine as a base molecule to produce several different products. We studied the enzymes involved and designed a genetic circuit composed of SAM synthase, ACC synthase and ACC oxidase. E coli already possesses a gene for SAM synthase, so we added a second copy to our construct to ramp up production. ACC synthase and ACC oxidase are only found in plants, so we explored enzyme characterisation databases to find the most efficient and specific catalysts from the plant world. Our analysis pointed to apple for ACC synthase and tomato for ACC oxidase. With this in silico work done, our plan was to have all three genes synthesised by Mr. Gene after codon optimising them for E. coli. We would then add ribosome binding sites and link these three genes together in one construct for efficient ethylene production from E. coli. Naturally, ...
To make this vision a reality, we attempted to transfer the plant ethylene biosynthesis pathway into E. coli. Plants produce ethylene through the Yang Cycle, which uses methionine as a base molecule to produce several different products. We studied the enzymes involved and designed a genetic circuit composed of SAM synthase, ACC synthase and ACC oxidase. E coli already possesses a gene for SAM synthase, so we added a second copy to our construct to ramp up production. ACC synthase and ACC oxidase are only found in plants, so we explored enzyme characterisation databases to find the most efficient and specific catalysts from the plant world. Our analysis pointed to apple for ACC synthase and tomato for ACC oxidase. With this in silico work done, our plan was to have all three genes synthesised by Mr. Gene after codon optimising them for E. coli. We would then add ribosome binding sites and link these three genes together in one construct for efficient ethylene production from E. coli. Naturally, ...
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CCD:CCD00225634. CAS:39828-47-2. MDL:MFCD01547735. MF / MW:C4 H4 N2 O3 / 128.087. 同义词:2-OXO-2,3-DIHYDRO-1H-IMIDAZOLE-4-CARBOXYLIC ACID;2,3-DIHYDRO-2-OXO-1H-IMIDAZOLE-4-CARBOXYLIC ACID;1H-IMIDAZOLE-4-CARBOXYLIC ACID, 2,3-DIHYDRO-2-OXO-;2,3-DIHYDRO-2-OXO-1H-IMIDAZOLE-4-CARBOXYLICACID;BESTIPHARMA 543-714;ABLOCK AB-10-1646. ...
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The ACCs Adult Congenital and Pediatric Cardiology Section welcomes the perspective and participation from international colleagues.. The ACPC Section hosted a webinar with Childrens HeartLink on the release of the first brief, The Case for the Invisible Child as part of CHLs Invisible Child series. The webinar is available here.. Please email [email protected] with any international activities you would like to share with the ACPC Section.. ...
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The ACC gene encodes a truncated copy of the tomato 1-amino-cyclopropane-1-carboxylic acid (ACC) synthase encoding gene in order to suppress expression of the endogenous unmodified gene (which is required for normal ethylene biosynthesis) through gene silencing ...
Carboxylic acid is an organic molecule and an acid containing a carboxyl group, formula -COOH. They are a functional group present in both amino acids and fatty acids. Carboxylic acids are weak acids, and therefore dissociate incompletely in water, forming an equilibrium between the RCOOH molecule and the RCOO- and H+ ions. ...
CHE 242 Unit VIII The Structure, Properties, Reactions and Mechanisms of Carboxylic Acids and Their Derivatives CHAPTER TWENTY-ONE. Terrence P. Sherlock Burlington County College 2004. =>. Acid Derivatives. All can be converted to the carboxylic acid by acidic or basic hydrolysis....
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t-butoxycarbonyl-4-amino-1,2-dithiolane-4-carboxylic acid-4-amino-1,2-dithiolane-4-carboxylic acid methyl amide: structure in first source
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Chinas share of coal-based ethylene production gradually increased from a mere 3 per cent in 2010 to around 16 per cent in 2018, but change is in the air for the sector. ...
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