TY - JOUR. T1 - Diallyl disulfide potentiates anti-obesity effect of green tea in high-fat/high-sucrose diet-induced obesity. AU - Bae, Jaehoon. AU - Kumazoe, Motofumi. AU - Fujimura, Yoshinori. AU - Tachibana, Hirofumi. PY - 2019/2/1. Y1 - 2019/2/1. N2 - Obesity is a major problem in developed countries and a burden on social health care systems. Several epidemiological studies showed the protective effects of green tea against obesity-related diseases. Cyclic guanosine monophosphate (cGMP) acts as a mediator for the physiological effects of (−)-epigallocatechin-3-O-gallate, the major constituent of green tea. Here, we showed that the level of phosphodiesterase 5, a negative regulator of cGMP, was up-regulated in adipose tissues of high-fat/high-sucrose (HF/HS) diet-fed mice and that this up-regulation was ameliorated by diallyl disulfide (DADS), the major organosulfur in garlic. A green tea extract (GT) and DADS in combination attenuated HF/HS diet-induced adipose increase and triglyceride ...

Dimethyl trisulfide (DMTS) is an organic chemical compound and the simplest organic trisulfide. It is a flammable liquid with a foul odor, which is detectable at levels as low as 1 part per trillion. Dimethyl trisulfide has been found in volatiles emitted from cooked onion, leek and other Allium species, from broccoli and cabbage, as well as from Limburger cheese, and is involved in the unpalatable aroma of aged beer and stale Japanese sake. It is a decomposition product of bacterial decomposition, including the early stages of human decomposition, and is a major attractant for blowflies looking for hosts. Dimethyl trisulfide along with dimethyl sulfide and dimethyl disulfide have been confirmed as volatile compounds given off by the fly-attracting plant known as dead-horse arum (Helicodiceros muscivorus). These flies are attracted to the odor of fetid meat and help pollinate this plant. DMTS contributes to the foul odor given off by the fungus Phallus impudicus, also known as the common ...

A number of the new studies on garlic that have recently appeared deal with garlic and cancer. One from the Republic of Korea cites diallyl disulfide (DADS) as the most prevalent oil-soluble sulfur compound in garlic, inhibiting cell proliferation in many cell lines. Scientists there examined DADS ability to kill cells in a process involving free radical production. They found that the famous tumor suppressor gene, p53, arrested the cell cycle when DADS treatment was present. Cancer cells died following 24 hour DADS treatment that activated the p53 gene. They also found that DADS induced cell death was prevented by treatment with a compound known to prevent p53 dependent cell death by reducing free radical levels in the mitochrondria, the cellular furnaces. Their results showed that mitochrondrial free radicals may serve as second messengers in DADS-induced cell death, which requires activation of p53. This study can be found in the January Journal of Biochemical and Molecular Toxicology ...

Isethionic acid (2-Hydroxyethanesulfonic acid) is an organosulfur compound. Isethionic acid is widely distributed in animal species and in a few red algal species. Isethionic acid can be used as an anionic detergent and has anti-settlement activity against Balanus amphitrite. - Mechanism of Action & Protocol.

garlic, glioblastoma, MUSC, neuro-oncology, The Medical University of South Carolina, Dr. Arabinda Das, DATS, diallyl trisulfide, brain tumor

A novel method for producing a diallyl ester of an aromatic dicarboxylic acid, particularly a diallyl ester of an aromatic symmetrical dicarboxylic acid by ester-exchange of a dialkyl ester of the aromatic dicarboxylic acid with allyl alcohol in the co-presence of two kinds of catalysts is disclosed.The obtained diallyl ester of an aromatic dicarboxylic acid according to the present invention is excellent in transmissivity.

This thesis deals with secondary interactions in asymmetric catalysis and their impact on the outcome of catalytic reactions.. The first part revolves around the metal-catalyzed asymmetric allylic alkylation reaction and how interactions within the catalyst affect the stereochemistry. An OH-Pd hydrogen bond in Pd(0)-π-olefin complexes of hydroxy-containing oxazoline ligands was identified by density functional theory computations and helped to rationalize the contrasting results obtained employing hydroxy- and methoxy-containing ligands in the catalytic reaction. This type of hydrogen bond was further studied in phenanthroline metal complexes. As expected for a hydrogen bond, the strength of the bond was found to increase with increased electron density at the metal and with increased acidity of the hydroxy protons.. The second part deals with the use of hydroxy- and methoxy-containing phosphinooxazoline ligands in the rhodium- and iridium-catalyzed asymmetric hydrosilylation reaction. The ...

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Extracts of fresh garlic, or Allium sativum, that are aged over a prolonged period contain antioxidant phytochemicals that fight against oxidant damage. These antioxidant phytochemicals include unique water-soluble organosulfur compounds, lipid-soluble organosulfur components and flavonoids, notably allixin and selenium. Longterm extraction of garlic (up to 20 months) ages the extract, retaining garlic nutrients while creating antioxidant properties by modifying unstable molecules with antioxidant activity, such as allicin. This aging process also increases stable and highly bioavailable organosulfur compounds, such as Sallylcysteine and S allylmercaptocysteine more antioxidant phytochemicals. And the aging process results in a truly odorless supplement. As a result, in addition to offering heart, brain, colon and other health benefits, AGE works as a powerful antioxidant, age-defying supplement by scavenging those pesky ROS, enhancing certain cellular antioxidant enzymes and increasing ...

Antimony trisulfide (Sb2S3) is found in nature as the crystalline mineral stibnite and the amorphous red mineral metastibnite. It is manufactured for use in safety matches, military ammunition, explosives and fireworks. It also is used in the production of ruby-colored glass and in plastics as a flame retardant. Historically the stibnite form was used as a grey pigment in paintings produced in the 16th century. It is a semiconductor with a direct band gap of 1.8-2.5 eV.[citation needed] With suitable doping, p and n type materials can be produced. Sb2S3 can be prepared from the elements at temperature 500-900 °C: 2Sb + 3S → Sb2S3 Sb2S3 is precipitated when H2S is passed through an acidified solution of Sb(III). This reaction has been used as a gravimetric method for determining antimony, bubbling H2S through a solution of Sb(III) compound in hot HCl deposits an orange form of Sb2S3 which turns black under the reaction conditions. Sb2S3 is readily oxidised, reacting vigorously with oxidising ...

An antioxidant lubricant composition has at least 50 wt % of a lubricating base oil and an oil-soluble metal compound providing between 1 and 2,000 parts per million of metal to the lubricant composition, the metal compound being chosen from the group consisting of molybdenum, tungsten titanium and boron compounds, and an oil-soluble hindered amine providing between about 0.001 and about 2 wt % of oil-soluble hindered amine to the lubricant composition, and optionally, an oil-soluble diarylamine providing between 0.001 and about 2 wt % of oil-soluble diarylamine to the lubricant composition.

Close The Infona portal uses cookies, i.e. strings of text saved by a browser on the users device. The portal can access those files and use them to remember the users data, such as their chosen settings (screen view, interface language, etc.), or their login data. By using the Infona portal the user accepts automatic saving and using this information for portal operation purposes. More information on the subject can be found in the Privacy Policy and Terms of Service. By closing this window the user confirms that they have read the information on cookie usage, and they accept the privacy policy and the way cookies are used by the portal. You can change the cookie settings in your browser. ...

The green onion is an unassuming little vegetable. Its generally content to hang around in the background of many dishes, including much of what you find at our Seattle Korean restaurant, rarely ever drawing notice to itself. In case youve ever paid them any thought, though, its worth noting the many health benefits that the green onion offers.. A typical vegetable, the green onion is low in calories and features no fat or cholesterol. A single stalk of the plant offers ten percent of your recommended daily intake of vitamin A, nine percent of your vitamin C, and a touch of calcium and iron.. Green onions also contain organosulfur compounds. These compounds are good for preventing the decline of your cartilage as you age. A diet rich on organosulfur compounds can therefore help you avoid osteoarthritis, a painful condition associated with the atrophy of cartilage in the joints.. Quercetin, a valuable flavonoid found in green onions, is a valuable part of a healthy body. Not only does it ...

Allyl isothiocyanate (AITC) is the organosulfur compound with the formula CH2CHCH2NCS. This colorless oil is responsible for the pungent taste of mustard, radish, horseradish, and wasabi. This pungency and the lachrymatory effect of AITC are mediated through the TRPA1 and TRPV1 ion channels ...

Allyl isothiocyanate is phytochemical containing sulfur in the class of organosulfur compound, found abundantly in horseradish, mustard, wasabi, etc. Health Benefits 1. Brain Cancer In the investigation of that AITC significantly decreased proliferation and viability of human brain malignant glioma GBM 8401 cells in a dose-dependent manner with IC50 9.25+/-0.69 microM for 24 h-treatment, showed …. ...

Jun 16, 2010 . The volatile oils in garlic (which have the antiseptic action) . We rub the garlic oil around the ear, especially underneath the ear and jaw moving down into the throat. . Intestinal parasites; Lice, skin parasites . They ranged in size from your average pencil eraser size down to smaller than a pin head ...

To explore the underlying mechanisms for the protective effects of garlic oil (GO) against nitrosodiethylamine (NDEA)-induced hepatocarcinoma, 60 male Wistar rats were randomized into 4 groups (...

I was at the LFS and they had a teeny tiny bottle of garlic oil for 15.95. I make my own herbal oils and I was wondering if there would be anything wrong in making my own. The oil consists of pressed

Green World Garlic Oil Capsule contains amino acids, vitamin E, alliin, linoleic acid, iron, calcium, selenium and other nutrients beneficial to human health. It features anti-microbial, antioxidant, blood pressure, blood sugar and blood lipid lo...

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1. ABDA-Datenbank: Allium sativum monograph. WuV, Eschborn and Micromedex Inc, Englewood, CO; 1997. 2. Agarwal KC: Therapeutic actions of garlic constituents. Med Res Rev 1996; 16:111-124. 3. Apitz-Castro R, Escalante J, Vargas R et al: Ajoene, the antiplatelet principle of garlic, synergistically potentiates the antiaggregatory action of prostacyclin, forskolin, indomethacin, and dypiridamole on human platelets. Thromb Res 1986; 42:303-311. 4. Berthold HK, Sudhop T & von Bergmann K: Effect of a garlic oil preparation on serum lipoproteins and cholesterol metabolism. A randomized controlled trial. J Am Med Assoc 1998; 279:1900-1902. 5. Burnham BE: Garlic as a possible risk for postoperative bleeding (letter). Plast Reconstr Surg 1995; 95(1):213. 6. Canduela V, Mongil I, Carrascosa M et al: Garlic: always good for the health (letter)? Br J Dermatol 1995; 132(1):161-162. 7. Couturier P & Bousquet J: Occupational allergy secondary to inhalation of garlic dust (letter). J Allergy Clin Immunol 1983; ...

Garlic contains diallyl disulfide, which prevents enzymes from damaging cartilage. The allicin in garlic also reduces pain in people who have chronic and excessive inflammation. Opt for fresh garlic because may garlic powders contain preservatives that decrease the positive effects [12].. Although there is no cure for arthritis, certain foods have been shown to fight inflammation, strengthen bones and boost the immune system. Add these foods to your diet to help keep your arthritis pain at bay.. ...

Nominated Substances: Allyl bromide. Nomination Date: 07/05/1995 Nominator: NCI Rationale: Widespread use leading to human exposure associated with its manufacture and use; persistence as an environmental pollutant; a suspicion of carcinogenicity; alkylating agent; positive genotoxicity test results. NTP Principles: 2, 3, 6, 7. Status: Selected ...

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Amino acids in garlic reduce the bad cholesterol (LDL) and triglycerides, and increase the concentration of good cholesterol (HDL), even in the case of consumption of very fatty foods. It helps in the treatment of various diseases of the lungs, and is extremely effective in the treatment of influenza and chronic bronchitis.. It strengthens the immune system and makes the body resistant to viruses and infections of any type. It is effective in the case of headaches, painful cramping in the calves, common herpes on the body, Candida and other types of fungal infections.. It reduces blood pressure for amazing 5% to 10%.. The garlic oil is necessary for the treatment of diabetes due to its hypoglycemic properties. Scientists have proven that the regular consumption of garlic oil reduces the risk of cancer and slows the development of tumor cells in the body.. Garlic oil boosts the immune system and it is a strong fighter against respiratory infections, it facilitates breathing and coughing. In ...

Acetaminophen (APAP) when administered in excess can cause severe hepatic necrosis in vivo. To study the mechanism of APAP toxicity and the role of cytochrome P450, a previously established human hepatoma HepG2 subline, MVh2E1-9, that constitutively expresses human CYP2E1 was used as a model. At high concentrations (above 5 mM) and when intracellular reduced glutathione (GSH) was depleted, APAP caused severe cytotoxicity in MVh2E1-9, but not in MV-5 cells which lack CYP2E1. The APAP cytotoxicity was dependent on the concentration of APAP and time of exposure, and could be blocked by 4-methylpyrazole, ethanol, diallyl sulfide, N-acetylcysteine and N-t-butyl-alpha-phenylnitrone, but not by propylgallate, an inhibitor of lipid peroxidation. Significantly more 14C-labeled APAP protein adduct was detected in MVh2E1-9 cells than MV-5 cells, especially after depletion of GSH. The formation of the APAP adducts could be inhibited by the same agents which prevent APAP cytotoxicity. At a lower ...

Supplementary MaterialsAdditional file 1: Figure S1. expression of the TetR family protein when induced with different inducer concentrations. Lane1: marker, lane2: cells with uninduced TetR family protein, lane3-6: cells with induced TetR family protein (0.2?mM, 0.5?mM, 1?mM and 2?mM IPTG concentration). 13568_2019_801_MOESM1_ESM.pdf (426K) GUID:?E4D189AF-6495-44A5-9CF1-3575D2773CCA Data Availability StatementAll data analyzed throughout this Mouse monoclonal to EhpB1 study is shown in the article. Abstract Biodesulfurization helps in removal of sulfur from organosulfur present in petroleum fractions. All microorganisms isolated to date harbor a desulfurization operon consisting of three genes and -which encode for monooxygenases (DszA & C) and desulfinase (DszB). Most of the studies have been carried out using dibenzothiophene as the model organosulfur compound, which is converted into 2 hydroxybiphenyl by a 4S pathway which maintains the calorific value of fuel. There are few studies reported ...

Gear oils and gear oil additive concentrates of enhanced positraction performance are described. They comprise: (i) at least one oil-soluble sulfur-containing extreme pressure or antiwear agent; (ii) at least one oil-soluble amine salt of a partial ester of an acid of phosphorus; and (iii) at least one oil-soluble succinimide of the formula ##STR1## where R.sub.1 is an alkyl or alkenyl group having an average of 8 to 50 carbon atoms, and each of R.sub.2, R.sub.3 and R.sub.4 is a hydrogen atom or an alkyl or alkenyl group having an average of up to about 4 carbon atoms. These compositions preferably contain one, more preferably two, and most preferably all three of the following additional components: (iv) at least one amine salt of a carboxylic acid; (v) at least one nitrogen-containing ashless dispersant; and (vi) at least one trihydrocarbyl ester of a pentavalent acid of phosphorus.

Propylene Dichloride (PDC) is a byproduct of several Dow processes. The thermal cracking of PDC produces l - cis-chloropropene , I - trans-chloropropene, 2- chloropropene , and allyl chloride . By oxidizing the 1 - and 2-chloropropenes to 3- and 2 ...

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You have your olive oil, you have your garlic and now you think youre ready to make garlic infused oil. Maybe you are. However, if youre like me, you might not really know what youre doing. You see, I used to think you simply put some cloves of garlic into some olive oil and let […]. ...

Lookup HS Codes for China vi 28.13.90 Other non-metallic sulfides, phosphorus trisulfide Goods. Avalara LandedCosts helps determine your duty rates and other import taxes for China.

Translation of Vidimo se daso by Ceca (Светлана Цеца Ражнатовић) from Serbian to English. Vidimo Se Daso This song is by Ceca and appears on the album Poziv (). Vece, guzva preko mosta Vidim svega ti je dosta Meni svega malo je Meni se i nocas zivi Ludilo u perspektivi Da spavam rano je Od svojih sam tajni gora Ne trebas mi da se slomim Meni treba neko Koga ne . See contact information and details about Ceca vidimo se Daso. Poziv Album by Ceca. Poziv Da raskinem sa njom 5 minuta Ime i prezime Mrzi me Brat Udaće se suze moje Vidimo se daso Dobro sam prošla Turbulentno External links Amazon: search for Ceca • Poziv sanctusmusic.com: search for Ceca • Poziv Wikipedia: search for Ceca • Poziv iTunes: buy Poziv AllMusic.Translation of Vidimo se daso by Ceca (Светлана Цеца Ражнатовић) from Serbian to English. Ceca - Vidimo se daso - (Audio ) HD - Duration: 3 minutes, 22 seconds. Svetlana Ceca Raznatovic. 8,, views; 5 years ago. Play next; Play ...

Title: Meta-Analysis of Anticancer Drug Structures - Significance of Their Polar Allylic Moieties. VOLUME: 7 ISSUE: 2. Author(s):Norman S. Radin. Affiliation:10150 Torre Ave., Apt. 115,Cupertino, CA 95014-2129, USA.. Keywords:Allylic anticancer drugs, thiol condensations, ceramide in cancer therapy, reactive oxygen species, ubiquinone interference, sphingolipids as coenzymes. Abstract: This meta-analysis examines a wide range of small molecule anticancer drugs to search for a structure common to all. Although they encompass a very wide range of structures, nearly all reveal the presence of an allylic O, N, or S atom. In some, the allylic oxygen is a carbonyl group, or an alcohol group, which can be substituted (ester, lactone, glycoside, ether) or replaced by an amino or imino nitrogen Some antineoplastic drugs do not exhibit this moiety but are converted in vivo to allylic derivatives. An allylic hydroxyl is also present in most sphingolipids, ubiquitous body components that control ...

5 ingredient quick recipe. Use this garlic chili oil in anything and everything. It will definitely bring your meals to another level. Yep!

The test agent in this study is a product of biphenylmethyl dicarboxylate (BDD) with garlic oil. The two components were confirmed to have complementary effects because of different operational mechanism in animal experiments, and were examined on humans in this study. Both BDD and garlic oil are expected to show better protection and treatment on hepatotoxicity caused by toxic substances, and the purpose of this study is to confirm efficacy of and safety on human body of the agent and to determine its optimal dose ...

- It helps with blood circulation -100% natural Preventive against fungi, bacteria and viruses - Rich in vitamins - With a high content of polyunsaturated fatty acids

From the kitchen of One Perfect Bite...Ive been trying to test a series of skillet suppers for quick and easy weeknight meals. It has been slow going because Ive overbooked my calendar, but I am slogging my way through the pile of recipes with the intent of of sharing the best of them with you. Hopefully, that will be before school starts. Tonights recipe is one of a series that I found in a BuzzFeed article that featured stovetop chicken dishes. The recipe is a keeper and I think all but the youngest members of your family will enjoy it. Feel free to substitute thigh meat for the breast meat specified in the recipe and use any type of pasta that you enjoy. I hope you will give this recipe a try. You can have this dish on the table in 30 minutes and it makes a lovely supper. Here is the recipe. ...

A model two-step synthesis of a saturated hyperbranched hydroxyl-terminated ester has been developed to show a synthesis route. Three different series of hyperbranched esters with different terminations have been synthesized to relate some of their properties to their structures. This route has then been used to synthesize three different allyl ether-maleate functional hyperbranched ester resins in a two-step procedure. The resins have been characterized with respect to rheology, structure, and properties, and the differences are discussed. The allyl ether-maleate functional resins have also been studied with respect to curing performance and final film properties.. ...

And like conventional antibiotics and anti-virals, youll have to take garlic for a minimum of one week or youll run the risk of having a relapse. I made that mistake when I used the same treatment for a viral infection. I was so convinced of the power of my garlic-honey-lime remedy that I used it to treat the swollen, painful lymph nodes that my kids developed. Because they also were running a high fever, indicative of a full-blown infection, I increased the dose to one clove/tsp. every three hours. Each time, I also smothered garlic oil on their necks below the ears where the nodes were sore, and on the soles of their feet twice a day as a trans-dermal therapy. The treatment was effective, but once the symptoms improved, I brought the dose down immediately to three times per day or every eight hours. The kids suffered a rebound. For a systemic, high-grade infection like that, I would recommend administering a dose six to eight times a day. Increase the time between doses by an hour as soon as ...

NTP Experiment-Test: 96003-05 INCIDENCE RATES OF NONNEOPLASTIC LESIONS BY ANATOMIC SITE (a) Report: PEIRPT03 Study Type: 39 WEEKS ALLYL BROMIDE Date: 03/26/01 Route: GAVAGE Time: 13:49:05 FINAL#1/MICE Facility: BIORELIANCE Chemical CAS #: 106-95-6 Lock Date: 10/18/00 Cage Range: All Reasons For Removal: All Removal Date Range: All Treatment Groups: Include All a Number of animals examined microscopically at site and number of animals with lesion Page 1 NTP Experiment-Test: 96003-05 INCIDENCE RATES OF NONNEOPLASTIC LESIONS BY ANATOMIC SITE (a) Report: PEIRPT03 Study Type: 39 WEEKS ALLYL BROMIDE Date: 03/26/01 Route: GAVAGE Time: 13:49:05 ____________________________________________________________________________________________________________________________________ MICE:P53+/-(C57BL/6) FEMALE VEHICLE 0.5 1 MG/KG 2 MG/KG 4 MG/KG 8 MG/KG CONTROL MG/KG ____________________________________________________________________________________________________________________________________ DISPOSITION ...

The product is the vinyl ether /allyl cationic/free-radical mixed curing monomer synthesized with diisocyanate of IPDI, with low toxicity, fast curing speed, curing thoroughly, low oxygen interference, little shrinkage, good strength of the cured coating and good toughness of the cured coating ...

Allyl benzoate/ACM583040 can be provided in Alfa Chemistry. We are dedicated to provide our customers the best products and services.

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Additives China, Manufacture Of Sodium Allyl Sulfonate Sas, 1)As the third monomer of acrylic fiber, this product can improve the dying properties, the heat resistance and flexibil...

If you Google health benefits of garlic, its pretty unbelievable to read some of the claims made. Most of the info is based on taking garlic that has been commercially prepared as a supplement but Ive always heard eating fresh garlic is good for you too. For sure it will keep the vampires away and probably the neighbors too if we eat enough of it.. Yesterday I browned some of the garlic, then removed it from the pan, cooked the other ingredients and was going to add the garlic back but, in the meantime, Vince came in and said Can I have some of it? I said Sure, take all you want! He did so I had to peel two more bulbs and start over with the garlic.. ...

Kemira Specialty, Inc., Northvale, NJ, has created Kemira NanoGel, an ingredient that produces a nanoemulsion at room temperature using only a blade propeller or even a spatula. When it is added at three times the amount of any oil or oil-soluble ing

Garlic (Allium sativum L.) has been used for culinary and medicinal purposes by many cultures for centuries (1). Garlic is a particularly rich source of organosulfur compounds, which are thought to be responsible for its flavor and aroma, as well as its potential health benefits (2). Consumer interest in the health benefits of garlic is strong enough to place it among the best-selling herbal supplements in the United States (3). Scientists are interested in the potential for organosulfur compounds derived from garlic to prevent and treat chronic diseases, such as cancer and cardiovascular disease.. Summary. * Garlic (Allium sativum L.) is a particularly rich source of organosulfur compounds, which are currently under investigation for their potential to prevent and treat disease. * Crushing or chopping garlic releases an enzyme called alliinase that catalyzes the formation of allicin. Allicin rapidly breaks down to form a variety of organosulfur compounds. * Since cooking can inactivate ...

The folk wisdom that eating garlic fights illness is ancient. In these more modern times, fruit and vegetable extracts that can inhibit the growth of pathogenic and spoilage microorganisms are actually being evaluated as food preservatives, in part because consumers are demanding fewer synthetic chemical food preservatives. Now, a team led by researchers from Washington State University, Pullman, has found, contrary to expectations, that a group of garlic-derived organosulfur compounds has greater antimicrobial activity than garlic-derived phenolic compounds. The research is published in the August 2011 issue of the journal Applied and Environmental Microbiology. 

Abstract. Sodium nitrite (NaNO2), a food color fixative and preservative, contributes to carcinogenesis. We investigated the protective role of garlic oil against NaNO2-induced abnormalities in metabolic biochemical parameters and oxidative status in male albino rats. NaNO2 treatment for a period of three months induced a significant increase in serum levels of glucose, aspartate aminotransferase (AST), alanine aminotransferase (ALT), alkaline phosphatase (ALP), bilirubin, urea and creatinine as well as hepatic AST and ALT. However, significant decrease was recorded in liver ALP activity, glycogen content, and renal urea and creatinine levels. In parallel, a significant increase in lipid peroxidation, and a decrease in glutathione content and catalase activity were observed in the liver and the kidney. However, garlic oil supplementation showed a remarkable amelioration of these abnormalities. Our data indicate that garlic is a phytoantioxidant with powerful chemopreventive properties against ...

Chelated enolates are versatile nucleophiles for palladium-catalysed allylic alkylations. Even with complex allylic substrates the reaction proceed without significant isomerisation. This allows the stereoselective introduction of polyhydroxylated allylic sidechains into amino acids and peptides with retention of the olefin geometry ...

0027] Suitable organosilane polysulfides include, but are not limited to, 3,3-bis(trimethoxysilylpropyl)disulfide, 3,3-bis(triethoxysilylpropyl)disulfide, 3,3-bis(triethoxysilylpropyl)tetrasulfide, 3,3-bis(triethoxysilylpropyl)octasulfide, 3,3-bis(trimethoxysilylpropyl)tetrasulfide, 2,2-bis(triethoxysilylethyl)tetrasulfide, 3,3-bis(trimethoxysilylpropyl)trisulfide, 3,3-bis(triethoxysilylpropyl)trisulfide, 3,3-bis(tributoxysilylpropyl)disulfide, 3,3-bis(trimethoxysilylpropyl)hexasulfide, 3,3-bis(trimethoxysilylpropyl)octasulfide, 3,3-bis(trioctoxysilylpropyl)tetrasulfide, 3,3-bis(trihexoxysilylpropyl)disulfide, 3,3-ibis(tri-2-ethylhexoxysilylpropyl)trisulfide, 3,3-bis(triisooctoxysilylpropyl)tetrasulfide, 3,3-bis(tri-t-butoxysilylpropyl)disulfide, 2,2-bis(methoxydiethoxysilylethyl)tetrasulfide, 2,2-bis(tripropoxysilylethyl)pentasulfide, 3,3-bis(tricycloneoxysilylpropyl)tetrasulfide, 3,3-bis(tricyclopentoxysilylpropyl)trisulfide, ...

EVALUATION OF THE EFFECT OF THE COMBINATION OF DIBENZYL DISULFIDE, DIBENZYL TRISULFIDE AND OCTADECENOIC ACID METHYL ESTER ON THE PROCESS OF OVOGENESIS IN ACARICIDE-RESISTANT RHIPICEPHALUS MICROPLUS

4. A resist underlayer composition comprising an organic solvent; and a polymer including a repeating unit represented by at least one of Chemical Formula 1 and Chemical Formula 2, ##STR00029## wherein, in Chemical Formulae 1 and 2, R1, R3, R4, R5, and R7 are each independently hydrogen, a hydroxy group, a halogen, a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group, a substituted or unsubstituted allyl group, a substituted or unsubstituted heteroaryl group, a substituted or unsubstituted alkoxy group, a substituted or unsubstituted carbonyl group, a substituted or unsubstituted amino group, a substituted or unsubstituted siloxane group, or a substituted or unsubstituted silane group, R2 and R6 are each independently hydrogen, a halogen, a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group, a substituted or unsubstituted allyl group, a substituted or unsubstituted heteroaryl group, a substituted or unsubstituted alkoxy group, a ...

The focus on upgrading petroleum has been on sulfur, but the ability to metabolize organonitrogen compounds may be particularly important because organonitrogen compounds are associated with the majority of metals in petroleum. Sulfur is present in crude oil almost exclusively as organic sulfur. While there are multiple types of organosulfur compounds, such as mercaptans, sulfides, disulfides, and thiophenes, the most abundant form of sulfur in petroleum is usually thiophenic. Thiophenic sulfur often comprises 50 to 95% of the sulfur in crude oil and petroleum products, and alkylated derivatives of dibenzothiophene (DBT) are the most common organosulfur compounds typically found in crude oil and diesel. Integrating a biodesulfurization process into a refinery is the only way to treat a product such as diesel. Biodesulfurization could fit well with current practices in the petroleum industry if performed in conjunction with desalting and dewatering operations. The removal of organically bound nitrogen

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Dipropyl Succinate (CAS 925-15-5) Market Research Report 2018 aims at providing comprehensive data on dipropyl succinate market globally and regionally

most thoroughly studied.. Margie The Arthritis Lady http://www.yoursuccesslinks.com. REFERENCES:. Abramovitz D, et al, Allicin-induced decrease in formation of fatty streaks (atherosclerosis) in mice fed a cholesterol-rich diet, Coronary Artery Diseases, 1999 Oct;10(7):515-9. Ankri S, Mirelman D, Antimicrobial properties of allicin from garlic, Microbes and Infection, 1999 Feb;1(2):125-129. Challier B, Perarnau JM, Viel JF, Garlic, onion, and cereal fibre as protective factors for breast cancer: a French case-control study, European Journal of Epidemiology, 1998 Dec;14(8):737-47. Ide N, Lau BH,Aged garlic extract attenuates intracellular oxidative stress, Phytomedicine, 1999 May;6(2):125-31. Koscielny J, et al, The antiatherosclerotic effect of Allium sativum, Atherosclerosis, 1999 May;144(1):237-49. Kumar M, Berwal JS, Sensitivity of food pathogens to garlic (Allium sativum), Journal of Applied Microbiology, 1998 Feb;84(2):213-5. Munday R, Munday CM, Low doses of diallyl disulfide, ...

The report generally describes diallyl dimethyl ammonium chloride(dadmac), examines its uses, production methods, patents. Diallyl dimethyl ammonium

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synthetic flavoring substances and adjuvants may be safely used in food in accordance with the following conditions. (a) They are used in the minimum quantity required to produce their intended effect, and otherwise in accordance with all the principles of good manufacturing practice. (b) They consist of one or more of the following, used alone or in combination with flavoring substances and adjuvants generally recognized as safe in food, prior-sanctioned for such use, or regulated by an appropriate section in this part. Acetal; acetaldehyde diethyl acetal. Acetaldehyde phenethyl propyl acetal. Acetanisole; 4-methoxyacetophenone. Acetophenone; methyl phenyl ketone. Allyl anthranilate. Allyl butyrate. Allyl cinnamate. Allyl cyclohexaneacetate. Allyl cyclohexanebutyrate. Allyl cyclohexanehexanoate. Allyl cyclohexaneproprionate. Allyl cyclohexanevalerate. Allyl disulfide. Allyl 2-ethylbutyrate. Allyl hexanoate; allyl caproate. Allyl [alpha]-ionone; ...

Compounds and methods for sorbing organosulfur compounds from fluids are provided. Generally, compounds according to the present invention comprise mesoporous, nanocrystalline metal oxides. Preferred metal oxide compounds either exhibit soft Lewis acid properties or are impregnated with a material exhibiting soft Lewis acid properties. Methods according to the invention comprise contacting a fluid containing organosulfur contaminants with a mesoporous, nanocrystalline metal oxide. In a preferred embodiment, nanocrystalline metal oxide particles are formed into pellets ( 14 ) and placed inside a fuel filter housing ( 12 ) for removing organosulfur contaminants from a hydrocarbon fuel stream.

This product contains the harmonious combination of garlic and ginger. Jarrow Formulas Garlic contains the original amino acids, vitamins and minerals, including selenium, and special sulphur compounds, including alliin, alliinase, allicin and diallyl disulfide compounds, naturally occurring in garlic. Jarrow Formulas Ginger is naturally dried and not subjected to any additional heat. This process ensures the presence of the active compounds that are beneficial to the gastrointestinal tract.* Keep out of the reach of children.

This thesis deals with the design of chiral ligands for asymmetric palladiumcatalysed allylic substitution reactions. The effect of the symmetry and the electronic properties of the ligands on the reactivity and selectivity of the resulting metal complexes were investigated. Preparation of ligands from the chiral pool is also described. Chiral 2-(1-hydroxyalkyl)pyridines and 2-(1-alkoxyalkyl)pyridines carrying a chiral pyrrolidine ring in the 6-position of the pyridine ring were synthesised. The effect of the conformational preferences of the ligands in the metal complexes on the reactivity and selectivity was studied. The performance of these ligands did not show a clear trend that could be rationalised by a general model. Chiral N,P-ligands with pseudo-C2 and pseudo-meso symmetry based upon pyrrolidines, pyridines, 1,1´-binaphthylazepines, phospholanes and 1,1´binaphthylphosphepines were synthesised. The performance of these ligands was compared to the performance of the corresponding ...

Close The Infona portal uses cookies, i.e. strings of text saved by a browser on the users device. The portal can access those files and use them to remember the users data, such as their chosen settings (screen view, interface language, etc.), or their login data. By using the Infona portal the user accepts automatic saving and using this information for portal operation purposes. More information on the subject can be found in the Privacy Policy and Terms of Service. By closing this window the user confirms that they have read the information on cookie usage, and they accept the privacy policy and the way cookies are used by the portal. You can change the cookie settings in your browser. ...

Garlic powder is ground, dehydrated garlic. It is a very common seasoning. Applications include pasta, pizza, ranch dressing and grilled chicken. Garlic salt is simply salt plus garlic powder.

A physiologically based pharmacokinetic model was used to determine the in vivo metabolic constants of the candidate chlorofluorocarbon replacement 1,1-dichloro-1-fluoroethane (HCFC-141b). Rats were exposed by inhalation to HCFC-141b concentrations ranging from 1,000 to 10,000 ppm. Uptake studies of HCFC-141b in the rat indicated the involvement of saturable and first-order components. The in vivo metabolic constants for HCFC-141b were: KM = 7.0 mg liter-1 (59.9 mumol liter-1), Vmax = 0.2 mg kg-1 hr-1 (1.71 mumol kg-1 hr-1), and k = 0.5 hr-1. In rats exposed to HCFC-141b, 2,2-dichloro-2-fluoroethanol was excreted in the urine as its glucuronide conjugate, and the rate of 2,2-dichloro-2-fluoroethanol excretion increased linearly with increasing HCFC-141b exposure concentrations. Diallyl sulfide, a selective, mechanism-based inhibitor of cytochrome P-450 2E1, inhibited the metabolism of HCFC-141b, as indicated by a decreased uptake of HCFC-141b and by a lowered urinary excretion of ...

BUSINESS WIRE)--Building on its foundational excellence of science-driven innovation, Dow turned to the power of the crowd to spearhead new application development and potential markets for UCON™ oil-soluble polyalkylene glycols (oil-soluble PAGs). Partnering with InnoCentive, the first of its kind Oil-Sol Challenge received more than 60 solutions from 43 countries. The Challenge called for industry leaders to collaborate, innovate and problem solve to validate new applications or markets where UCON™ oil-soluble PAGs could offer clear advantages to help solve some of the worlds most pressing challenges. Two winners-Joel Martin and Dmitriy Tipikin-clearly stepped up to the challenge, identifying potential applications for addressing eye disease globally and for providing better environmental and sustainable standards for oil/gas/mining operations. Each was awarded $15,000 for their winning ideas. Polyalkylene glycol synthetic lubricants have been around for more than 50 years, but have ...

A one-pot iron-catalyzed conversion of allylic alcohols to a-methyl ketones has been developed. This isomerization-methylation strategy utilized a (cyclopentadienone)iron(0) carbonyl complex as precatalyst and methanol as the C1 source. A diverse range of allylic alcohols undergo isomerization-methylation to form a-methyl ketones in good isolated yields (up to 84% isolated yield).. Analysis of reaction products from this methodology resulted in the following data:. 1H, 19F and 13C NMR raw data files. IR spectra. High resolution mass spectrometry spectra. Research results based upon these data are published at http://doi.org/10.1021/acs.orglett. ...

Due to its high refractive index of 2.45 and its large Knoop hardness compared to organic photoresists, As2S3 has been investigated for the fabrication of photonic crystals with a full-photonic band-gap. Advances in laser patterning techniques such as three-dimensional direct laser writing (3-D DLW) and chemical wet-etching chemistry, has allowed this material to be used as a photoresist to fabricate 3-D nanostructures.[13][14]. As2S3 has been investigated for use as a high resolution photoreist material since the early 1970s,[15][16] using aqueous etchants. Although these aqueous etchants allowed for low-aspect ratio 2-D structures to be fabricated, they do not allow for the etching of high aspect ratio structures with 3-D periodicity. Certain organic reagents, used in organic solvents, permit the high-etch selectivity required to produce high-aspect ratio structures with 3-D periodicity. ...

A particular advantage with the method of the invention is that a cheaper starting material, H-D-Pal-OH-2HC1, can be used instead of the ester H-Pal-OR-2HC1; the protective group of the starting material need not be removed. Therefore the synthesis of the invention is one step shorter and avoids that material is lost in the additional step. Another advantage is that the formation of impurities in the saponification step is avoided. The formation of such impurities is well known. For instance, the basic conditions at the ester hydrolysis step cause partial racemization of D-Pal. The other prior-art alternative of removing the ester group by catalytic hydrogenation (in the case of allyl or benzyl ester groups) risks to cause a loss of Cl from 4ClPhe producing Phe. While allyl groups may be removed by still other reagents the full removal is difficult to control. The invention will now be explained in more detail by reference to a preferred embodiment ...

TY - JOUR. T1 - 2-O-alkyl oligoribonucleotides as antisense probes. AU - Iribarren, A. M.. AU - Sproat, B. S.. AU - Neuner, P.. AU - Sulston, I.. AU - Ryder, U.. AU - Lamond, A. I.. PY - 1990/10/1. Y1 - 1990/10/1. N2 - 2-O-Methyl oligoribonucleotides have recently been introduced as antisense probes for studying RNA processing and for affinity purification of RNA-protein complexes. To identify RNA analogues with improved properties for antisense analysis, 2-O-alkyl oligoribonucleotides were synthesized in which the alkyl moiety was either the three-carbon linear allyl group or the five-carbon branched 3,3-dimethylallyl group. Both these analogues were found to be completely resistant to degradation by either DNA- or RNA-specific nucleases. Use of biotinylated derivatives of the probes to affinity-select ribonucleoprotein particles from crude HeLa cell nuclear extracts showed that the presence of the bulky 3,3-dimethylallyl group significantly reduces affinity selection, whereas the allyl ...

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Provided is a process for producing bisphenol A having a stable color tone at a high temperature and free from coloration, which comprises reacting phenol with acetone in the presence of an acid ion-exchange resin as a catalyst and an alkyl mercaptan as a cocatalyst, wherein a concentration of an organosulfur compound in a crystallization starting material obtained by conducting the reaction under conditions that a reaction temperature is between 60 and 100° C., a phenol to acetone molar ratio is between 6 and 13 and an acetone to alkyl mercaptan molar ratio is between 13 and 25, distilling off unreacted acetone, by-product water and the alkyl mercaptan as the cocatalyst and further distilling off excess phenol is measured, and maintained at 200 weight ppm or less.

Amidinates have a rich coordination chemistry32 as they can coordinate to a single metal center either in terminal (κ1), chelating (κ2) modes, and, less often they can even bind in η3 mode, like an allyl group. The amidinate can also bridge two metal centers, i.e., in μ2-κ1N, κ1N′ mode. On a metal surface one N-atom can bridge more than two metal atoms and thus a variety of coordination modes results. As the measurements on Pt NPs gave not satisfactory evidence for the bonding mode in 15N NMR spectroscopy we turned to different metals for 15N NMR spectral data. As ruthenium presents insignificant or no Knight shift, we synthesized Ru/ICy·(Ph)NCN NPs as reported before4 stabilized with 0.1, 0.2, 0.5 and 1 equiv. of the 15N labelled ligand and studied the coordination of the ligand by solid state 15N MAS NMR. The resulting Ru/ICy·(Ph)NC15N NPs have sizes between 1.0 and 1.3 nm, they are very well dispersed and show a narrow size distribution (see ESI, Fig. S11-S14†). As for Pt NPs, we ...

An efficient one-pot procedure was designed by integration of the pincer-complex-catalyzed borylation of allyl alcohols in the Petasis borono-Mannich reaction and in allylation of aldehydes and ketones. These procedures are suitable for one-pot synthesis of α-amino acids and homoallyl alcohols from easily available allyl alcohol, amine, aldehyde, or ketone substrates. In the presented transformations, the active allylating agents are in situ generated allyl boronic acid derivatives. These transient intermediates are proved to be reasonably acid-, base-, alcohol-, water-, and air-stable species, which allows a high level of compatibility with the reaction conditions of the allylation of various aldehyde/ketone and imine electrophiles. The boronate source of the reaction is diboronic acid or in situ hydrolyzed diboronate ester ensuring that the waste product of the reaction is nontoxic boric acid. The regio- and stereoselectivity of the reaction is excellent, as almost all products form as single ...

1. GELAPRO™ provides your body with proline and glycine, two important amino acids for cartilage producing cells (chondrocytes) and bone forming cells (osteoblasts) for making structural proteins. A lack or excess of physical activity, injury, age, or low availability of nutrients can negatively influence these functions. Gelatin has been shown to be supportive for joints health through several studies (1, 2, 3, 4), preventive for athletic injuries (5) and safe nutrient even for long use.. 2. ULTRA-MSM™ is organosulfur compound that occurs naturally in some primitive plants and is present in small amounts in many foods and beverages. Recently, MSM is shown to have some beneficial effects for milld-moderate joints pain both on animal and human models (6, 7).. 3. Glucosamine Sulfate is a precursor for glycosaminoglycans which a major component of joint cartilage.Recent study of 318 people has proven glucosamine sulfate effectiveness in relieving joints pain (8).. 4. Chondroitin Sodium Sulfate ...

Diastereoselective and enantioselective aldehyde addition-reactions of 2-allyl-1,3,2-dioxaborolane-4,5-dicarboxylic esters, a useful class of tartrate ester modified allylboronates ...

trigger cold sore treatment products on cold sore dead in its fight any type of sore. In severe cases, large-sized clusters around the affected part. Thus a cold drink to the affected skin severe cases tablets can damage the cell membrane and arginine in your diet. There are many people have come to realize that you can applying garlic oil in cold sore. Cold sores are MUCH more painful when you are prone to them. Lysine is a raised red bump on the skin to another. Some even suggest cold sore on the tip of my nose this for a couple of hours, if dosage has been as simple as taking a good idea to quicken the healing oxygen. Some symptoms with just one of the symptoms so there will definition, you will find that comes down to 3-4 days. quick way to get rid of cold lunch ideas Researchers are now convinced that applying the virus. But it is very important when you stop the area feel better? Commonly, folks claim applying garlic oil. Soy beans, oatmeal and wheat, nuts, grains, oysters, turkey and ...

The cholesterol-lowering effects of Kyolic were confirmed by two recent, well-designed, double-blind clinical studies. One reported in the American Journal of Clinical Nutrition,found a 7% reduction in cholesterol and 6% reduction in blood pressure following six months intake of Kyolic. It reported a 7% reduction in total cholesterol and a 10% reduction in LDL cholesterol following five months intake. It also reported that Kyolic improved platelet function in patients with high cholesterol levels by decreasing adhesion to fibrinogen (a blood thinning effect). Platelet adhesion is strongly related to the development of atherosclerosis and other cardiovascular diseases ...

Garlic powder makes a great substitute for fresh garlic - saves time and adds robust flavor to rubs, marinades, sauces, meats and baked goods. 16oz. size.

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Allyl isothiocyanate possesses antidiabetic, antioxidant, and anti-inflammatory activities in high-fat diet/streptozotocin-induced type 2 diabetes mellitus.

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Garlic powder can inspire a striking level of animosity. Once ground and sifted into a small jar, just popping the lid off this DIY version of the seasoning sealed the deal for me.

We moved from there to Kentwood in the Pines. I think it was close to Cuyamaca as Dad went back to work at C.A. Grays ranch. Lois [sister] had appendicitus while we were there and Russell [brother] was born. it was either for the appendicitis or to take mother to the hospital, that Mr. Gray lent father a new beaver tail (?) dodge to drive to the hospital. It had a velvet-like upholstery. It must have been a 1932. That was about the time of the first Roosevelt campaign which seems to have been tied up with prohibition. It could have been 1932 when we lived the the compound. I recall that Roosevelt and Repeal were spoken like expletives. I never again recall political discussions but I recall 1932 ...

Personal protection: filter respirator for organic gases and vapours adapted to the airborne concentration of the substance. Ventilation. Remove all ignition sources. Do NOT wash away into sewer. Cover the spilled material with dry earth, sand or other non-combustible material. Collect leaking and spilled liquid in sealable containers as far as possible ...

The National Institute of Standards and Technology (NIST) uses its best efforts to deliver a high quality copy of the Database and to verify that the data contained therein have been selected on the basis of sound scientific judgment. However, NIST makes no warranties to that effect, and NIST shall not be liable for any damage that may result from errors or omissions in the Database ...

In contrast to the trisulfides of the heavier alkali metals (Na-Cs) which were synthesized by Böttcher (1977, 1980a,b) under ammonothermalic conditions (130-400 °C, 500-3000 bar), [Li(NH3)4][Li(NH3)3S3] was formed in the reaction of lithium and sulfur in liquid ammonia. The crystal structure of [Li(NH3)4][Li(NH3)3S3] was determined in the course of investigations concerning the reactivity of sulfur containing components in solutions of alkali metals in liquid ammonia.. In the title compound, two crystallographically independent formula units represent the asymmetric unit (Fig. 1). The independent trisulfide anions S32- have an angled shape with angles of 110.43 (5)° and 109.53 (5)°. The average of the sulfur-sulfur distances is 2.083 Å and agrees with known S-S-distances of other trisulfides (Böttcher, 1977, 1980a,b). In contrast to the isolated Se32--anion in [Li(NH3)4]Se3, the two crystallographically different S32--anions build mono anionic [Li(NH3)3S3]--aggregates with triammine ...