Organic salts of cyanic acid containing the -OCN radical.
Enzymes that catalyze the cleavage of a carbon-nitrogen bond by means other than hydrolysis or oxidation. Subclasses are the AMMONIA-LYASES, the AMIDINE-LYASES, the amine-lyases, and other carbon-nitrogen lyases. EC 4.3.
Organic derivatives of thiocyanic acid which contain the general formula R-SCN.
A species of gram-negative bacteria in the genus PSEUDOMONAS. All strains can utilize FRUCTOSE for energy. It is occasionally isolated from humans and some strains are pathogenic to WATERMELON.
Methylmaleic anhydrides.
Derivatives of carbamic acid, H2NC(=O)OH. Included under this heading are N-substituted and O-substituted carbamic acids. In general carbamate esters are referred to as urethanes, and polymers that include repeating units of carbamate are referred to as POLYURETHANES. Note however that polyurethanes are derived from the polymerization of ISOCYANATES and the singular term URETHANE refers to the ethyl ester of carbamic acid.

Reactivity of cyanate with valine-1 (alpha) of hemoglobin. A probe of conformational change and anion binding. (1/258)

The 3-fold increase in the carbamylation rate of Val-1 (alpha) of hemoglobin upon deoxygenation described earlier is now shown to be a sensitive probe of conformational change. Thus, whereas this residue in methemoglobin A is carbamylated at the same rate as in liganded hemoglobin, upon addition of inositol hexaphosphate its carbamylation rate is enhanced 30% as much as the total change in the rate between the CO and deoxy states. For CO-hemoglobin Kansas in the presence of the organic phosphate, the relative increase in the carbamylation rate of this residue is about 50%. These results indicate that methemoglobin A and hemoglobin Kansas in the presence of inositol hexaphosphate do not assume a conformation identical with deoxyhemoglobin but rather form either a mixture of R and T states or an intermediate conformation in the region around Val-1 (alpha). Studies on the mechanism for the rate enhancement in deoxyhemoglobin suggest that the cyanate anion binds to groups in the vicinity of Val-1 (alpha) prior to proton transfer and carbamylation of this NH2-terminal residue. Thus, specific removal with carboxypeptidase B of Arg-141 (alpha), which is close to Val-1 (alpha) in deoxyhemoglobin, abolishes the enhancement in carbamylation. Chloride, which has the same valency as cyanate, is a better competitive inhibitor of the carbamylation of deoxyhemoglobin (Ki = 50 mM) compared with liganded hemoglobin. Nitrate and iodide are also effective inhibitors of the carbamylation of Val-1 (alpha) of deoxyhemoglobin (Ki = 35 mM); inorganic phosphate, sulfate, and fluoride are poor competitive inhibitors. The change in pKa of Val-1 (alpha) upon deoxygenation may be due to its differential interaction with chloride.  (+info)

Effect of chronic sodium cyanate administration on O2 transport and uptake in hypoxic and normoxic exercise. (2/258)

Systemic O2 transport during maximal exercise at different inspired PO2 (PIO2) values was studied in sodium cyanate-treated (CY) and nontreated (NT) rats. CY rats exhibited increased O2 affinity of Hb (exercise O2 half-saturation pressure of Hb = 27.5 vs. 42.5 Torr), elevated blood Hb concentration, pulmonary hypertension, blunted hypoxic pulmonary vasoconstriction, and normal ventilatory response to exercise. Maximal rate of convective O2 transport was higher and tissue O2 extraction was lower in CY than in NT rats. The relative magnitude of these opposing changes, which determined the net effect of cyanate on maximal O2 uptake (VO2 max), varied at different PIO2: VO2 max (ml. min-1. kg-1) was lower in normoxia (72.8 +/- 1.9 vs. 81. 1 +/- 1.2), the same at 70 Torr PIO2 (55.4 +/- 1.4 vs. 54.1 +/- 1.4), and higher at 55 Torr PIO2 (48 +/- 0.7 vs. 40.4 +/- 1.9) in CY than in NT rats. The beneficial effect of cyanate on VO2 max at 55 Torr PIO2 disappeared when Hb concentration was lowered to normal. It is concluded that the effect of cyanate on VO2 max depends on the relative changes in blood O2 convection and tissue O2 extraction, which vary at different PIO2. Although uptake of O2 by the blood in the lungs is enhanced by cyanate, its release at the tissues is limited, probably because of a reduction in the capillary-to-tissue PO2 diffusion gradient secondary to the increased O2 affinity of Hb.  (+info)

Subchronic exposure to diisocyanates increases guinea pig tracheal smooth muscle responses to acetylcholine. (3/258)

OBJECTIVE: In order to study the threshold concentrations of isocyanates (IC) for induction of lung disorders, constrictive responses of tracheal smooth muscles to acetylcholine (ACH) in guinea pigs with and without diisocyanate [toluene diisocyanate (TDI), hexamethylene diisocyanate (HDI) and diphenylmethane diisocyanate (MDI)] exposure were investigated. METHODS: An IC-induced increase in smooth muscle responsiveness was studied by measuring cumulative ACH dose responses (10(-10) to 10(-4) M ACH). Basal ACH dose-response curves, measured twice in intervals of 1 h using tracheal preparations of 11 guinea pigs previously not exposed to IC, were reproducible. RESULTS: Subchronic in vivo exposures to TDI, HDI, and MDI atmospheres of 10 and 20 parts per billion (ppb) on 5 consecutive days led to significantly (p < 0.05) increased ACH responsiveness of tracheal smooth muscle, whereas concentrations of 2.5 and 5 ppb were not effective. Exposure to HDI atmospheres of 10 ppb for 1, 2, 4, or 8 weeks resulted in a time-dependent increase in ACH responses (p < 0.05) of guinea pig tracheal smooth muscle. Increased tracheal muscle responses to ACH were transient since tracheal preparations from animals exposed to 10 and 20 ppb MDI for 4 weeks and with an exposure-free interval of 8 weeks before preparation did not show enlarged ACH responses, which were present in preparations at the end of the exposure period (p < 0.05). Exposure to low IC concentrations as present in workplaces cause increased ACH responsiveness of guinea pig tracheal smooth muscle. The increased responsiveness of the airways seems to be largely reversible, since normal responses were found after 8 weeks of IC avoidance. CONCLUSION: Reversibility of IC-induced airway hyperresponsiveness is of great occupational and preventive medical importance. Workers with acquired airway hyperresponsiveness might escape lung damage if the changes are detected in an early stage before alterations in lung function are in a chronic stage.  (+info)

Bioactivation of cyanide to cyanate in sulfur amino acid deficiency: relevance to neurological disease in humans subsisting on cassava. (4/258)

Neurological disorders have been reported from parts of Africa with protein-deficient populations and attributed to cyanide (CN-) exposure from prolonged dietary use of cassava, a cyanophoric plant. Cyanide is normally metabolized to thiocyanate (SCN-) by the sulfur-dependent enzyme rhodanese. However, in protein-deficient subjects where sulfur amino acids (SAA) are low, CN may conceivably be converted to cyanate (OCN-), which is known to cause neurodegenerative disease in humans and animals. This study investigates the fate of potassium cyanide administered orally to rats maintained for up to 4 weeks on either a balanced diet (BD) or a diet lacking the SAAs, L-cystine and L-methionine. In both groups, there was a time-dependent increase in plasma cyanate, with exponential OCN- increases in SAA-deficient rats. A strongly positive linear relationship between blood CN- and plasma OCN- concentrations was observed in these animals. These data are consistent with the hypothesis that cyanate is an important mediator of chronic cyanide neurotoxicity during protein-calorie deficiency. The potential role of thiocyanate in cassava-associated konzo is discussed in relationship to the etiology of the comparable pattern of motor-system disease (spastic paraparesis) seen in lathyrism.  (+info)

Treatment of intradural paraclinoidal aneurysms. (5/258)

Intradural paraclinoidal aneurysm still presents conceptual confusion and technical surgical problems. The clinical features of 68 consecutive patients with paraclinoidal aneurysms were analyzed. The pterional approach was used in all patients. Subarachnoid hemorrhage (SAH) occurred in 37 patients from the paraclinoidal aneurysm and in 10 patients from another associated aneurysm. Thirty-four of the 37 ruptured paraclinoidal aneurysms were clipped, two blister-like aneurysms required trapping, and one blister-like aneurysm was coated. Thirteen of the 31 unruptured paraclinoidal aneurysms, consisting of 10 with ruptured associated aneurysm, four symptomatic, and 17 incidental, were clipped and 18 were coated. Favorable outcomes were obtained in 38 of 47 patients with SAH and 17 of 21 patients without SAH. Nine unfavorable outcomes in SAH patients were caused by primary brain damage (5), vasospasm (2), cerebral infarction after trapping (1), and pneumonia (1). All four unfavorable outcomes in non-SAH patients were due to surgical procedures for giant aneurysms or associated basilar artery aneurysm. Removal of the anterior clinoid process was performed to secure the proximal neck in 15 patients with large or giant aneurysms. Multiple clips with or without fenestrated clips were required in all giant aneurysms, and exposure of the cervical internal carotid artery (ICA) in 17 giant or large aneurysms. Fenestrated clips were also useful for one small aneurysm projecting posteriorly. A favorable outcome was achieved in 17 of 19 patients undergoing coating. Coating without clipping might be better for some blister-like ICA aneurysms, even if ruptured. Paraclinoidal aneurysms can be clipped with favorable results using these techniques except for giant aneurysms and associated basilar artery aneurysm.  (+info)

Biological monitoring to assess exposure from use of isocyanates in motor vehicle repair. (6/258)

OBJECTIVES: To develop a method for the measurement of a metabolite of hexamethylene diisocyanate (HDI), an isocyanate, and use it to assess the exposure of sprayers employed in motor vehicle repair shops. METHODS: Urine samples were taken from sprayers wearing personal protective equipment and spraying in booths or with local exhaust ventilation, from bystanders, and from unexposed subjects. Samples were analyzed for a metabolite of HDI, hexamethylene diamine (HDA), by gas chromatography-mass spectrometry (GC-MS). RESULTS: HDA was detected in four sprayers and one bystander out of 22 workers. No HDA was detected in the urine of unexposed subjects. CONCLUSIONS: Exposure to isocyanates still occurs despite the use of personal protective equipment and the use of a booth or extracted space. Health surveillance is likely to be required to provide feedback on the adequacy of controls even if such precautions are used and to identify cases of early asthma. Biological monitoring can provide a useful additional tool to assess exposure and the adequacy of controls in this group of exposed workers.  (+info)

Histological changes in the rat common carotid artery following simultaneous topical application of cotton sheet and cyanoacrylate glue. (7/258)

Histological changes in and around the arterial walls of rats were investigated following simultaneous topical application of cotton sheet and cyanoacrylate glue. The bilateral common carotid arteries were exposed using sterile techniques, and the test materials were applied to the right artery. The left artery served as a control. Changes in arterial histology were evaluated at 2 weeks, 1 month, 2 months, and 3 months after surgery. Extensive inflammation consisting primarily of histiocytes and multinuclear giant cells was observed around the materials, but tended to decrease by 3 months. Necrosis in the media and fibrosis in the adventitia initially appeared around 2 weeks, and became advanced by 2-3 months. At 2-3 months, disruption of elastic fibers and marked fibrosis in the media were seen, and endothelial proliferation in the intima appeared. Intimal proliferation was observed at both the experimental and other sites of the vessels. The present results suggest that simultaneous use of the test materials can cause the arterial occlusive lesions observed following aneurysmal surgery.  (+info)

Exposure biomarkers and risk from gluing and heating of polyurethane: a cross sectional study of respiratory symptoms. (8/258)

OBJECTIVES: To define the relation between exposure to polyurethane (PUR) glue, biomarkers of exposure and effect, and work related symptoms that occur at least once a week. METHODS: In a cross sectional study, 152 workers and 14 clerks in a factory with exposure to sprayed and heated PUR glue containing 4, 4'-diphenylmethane (MDI) or 1,6-hexamethylene (HDI) di-isocyanate were examined with gas chromatography-mass spectrometry (GC-MS) for metabolites of MDI in plasma (P-MDX) and urine (U-MDX), 2,4- and 2, 6-toluene di-isocyanate (TDI; P-TDX, U-TDX) and HDI in plasma and urine, specific serum IgG (S-IgG-MDI, S-IgG-HDI, and S-IgG-TDI, respectively) and IgE (S-IgE-MDI). Work related symptoms of the eyes and airways (nose or lower airways, or both), and lung function were also evaluated. RESULTS: P-MDX was detected in 65% of the workers, U-TDX in 47%, HDX in none. Three per cent were positive for S-IgE-MDI, 33% for S-IgG-MDI, 32% for S-IgG-TDI, and 12% for S-IgG-HDI. A few clerks had metabolites, and some had antibodies. Most metabolites and immunoglobulins were slightly correlated-for example, P-MDX v S-IgG-MDI: r(s)=0.21. Workers who heated glue had increased P-MDX (odds ratio (OR)=12 for a value above the median) and S-IgG-MDI (OR=3.7), sprayers P-2,4-TDX (OR=6.2) and P-2,6-TDX (OR=16). Twenty six per cent of the workers had work related symptoms of the airways, 21% from the nose, 11% from the lower airways. Spraying of glue increased the risk of work related symptoms and slightly decreased lung function. U-MDX was associated with work related symptoms from the airways (OR=3.7) and P-2,6-TDX with work related symptoms from the lower airways (OR=6.6). S-IgG-MDI was related to work related symptoms from the airways (OR=2.6). CONCLUSIONS: There were relations between exposures to sprayed and heated PUR glue based on MDI and HDI, concentrations of metabolites of MDI and TDI in plasma and urine, specific IgG serum antibodies against MDI, TDI, and HDI, and work related symptoms.  (+info)

Dubai Sodium Cyanate, Buy High Quality Sodium Cyanate Products from Dubai Sodium Cyanate Suppliers and Manufacturers at Dubai Yellow Pages Online
Potassium cyanate definition is - a crystalline salt KOCN made by oxidizing potassium cyanide or by heating a mixture of potassium carbonate and urea and used chiefly to kill crabgrass on lawns.
Silver cyanate is a chemical compound; it is the cyanate salt of silver. It can be prepared by the reaction of potassium cyanate or urea with silver nitrate. A g N O 3 + K O C N ⟶ A g O C N ↓ + K N O 3 {\displaystyle \mathrm {AgNO_{3}+KOCN\longrightarrow AgOCN\downarrow +\ KNO_{3}} } A g N O 3 + H 2 N - C ( O ) - N H 2 ⟶ {\displaystyle \mathrm {AgNO_{3}+H_{2}N{\text{-}}C(O){\text{-}}NH_{2}\longrightarrow } } A g O C N ↓ + N H 4 N O 3 {\displaystyle \mathrm {AgOCN\downarrow +\ NH_{4}NO_{3}} } Silver cyanate is a beige to gray powder. It crystallises in the monoclinic crystal system in space group P21/m with parameters a = 547.3 pm, b = 637.2 pm, c = 341.6 pm, and β = 91°. With nitric acid, silver cyanate reacts to form carbon dioxide and ammonium nitrate. A g O C N + 2 H N O 3 + H 2 O ⟶ {\displaystyle \mathrm {AgOCN+2HNO_{3}+H_{2}O\longrightarrow } } A g N O 3 + C O 2 ↑ + N H 4 N O 3 {\displaystyle \mathrm {AgNO_{3}+CO_{2}\uparrow +\ NH_{4}NO_{3}} } Justus Von Liebig Friedrich ...
TY - JOUR. T1 - Diffusion phenomena during cyanate resin cure. AU - Deng, Yong. AU - Martin, George C.. PY - 1996/8. Y1 - 1996/8. N2 - The diffusion phenomena, including the molecular diffusion processes and the effect of diffusion on the cure kinetics and molecular size distribution, during the curing of a zinc-catalysed cyanate ester resin have been studied. The average diffusivity, which was estimated using the dielectric analysis-based approach, decreased by several orders of magnitude during the curing process. The molecular size distribution measured with size exclusion chromatography was found to deviate from the mean-field prediction at relatively high conversions. By using the Rabinowitch model, a diffusion-controlled kinetic model was formulated, which adequately predicted the experimental cyanate conversion profiles over the entire range of cure.. AB - The diffusion phenomena, including the molecular diffusion processes and the effect of diffusion on the cure kinetics and molecular ...
carbamate = H2N-CO-O-. Other name(s): cyanate lyase; cyanate hydrolase; cyanase; cyanate aminohydrolase; cyanate C-N-lyase; cyanate hydratase Systematic name: carbamate hydro-lyase. Comments: This enzyme, which is found in bacteria and plants, is used to decompose cyanate, which can be used as the sole source of nitrogen [6,7]. Reaction (1) can be considered as the reverse of carbamate = cyanate + H2O, where this is assisted by reaction with bicarbonate and carbon dioxide (see mechanism above) [2], and hence is classified in sub-subclass 4.2.1. Bicarbonate functions as a recycling substrate [2].. Links to other databases: BRENDA, EXPASY, KEGG, Metacyc, PDB, UM-BBD, CAS registry number: 37289-24-0. References:. 1. Anderson, P.M. Purification and properties of the inducible enzyme cyanase. Biochemistry 19 (1980) 2882-2888. [PMID: 6994799]. 2. Johnson, W.V. and Anderson, P.M. Bicarbonate is a recycling substrate for cyanase. J. Biol. Chem. 262 (1987) 9021-9025. [PMID: 3110153]. 3. Taussig, A. The ...
Other articles where Ammonium cyanate is discussed: urea: …German chemist Friedrich Wöhler from ammonium cyanate in 1828 was the first generally accepted laboratory synthesis of a naturally occurring organic compound from inorganic materials. Urea is now prepared commercially in vast amounts from liquid ammonia and liquid carbon dioxide. These two materials are combined under high pressures and elevated…
Disclosed is the preparation of novel difunctional cyanate monomers with increased aromatic chain length between the cyanate groups and thermosetting re...
Escherichia coli can overcome the toxicity of environmental cyanate by hydrolysisof cyanate to ammonia and bicarbonate. This reaction is catalyzed by the enzymecyanase, encoded by the cynS gene. The nucleotide sequence of cynS has beenreported (Sung, Y.-c., Anderson, P. M., and Fuchs, J. A. (1987) J. Bacteriol.169, 5224-5230). The nucleotide sequence of the complete cyn operon has now been determined. The cyn operon is approximately 2600 base pairs and includes cynT,cynS, and cynX, which encode cyanate permease, cyanase, and a protein of unknown function, respectively. Two cyanate-inducible transcripts of 1500 and 2500nucleotides, respectively, were detected by Northern blot analysis. S1 nucleasemapping experiments indicated that two different cyn mRNAs have a common 5-endand two different 3-ends. One 3-end was located within the coding region ofcynX, whereas the other 3-end includes the entire DNA sequence of cynX. Thelonger transcript contained 98 nucleotides complementary to lac mRNA ...
Cyanate therapy of sickle-cell disease is currently under investigation. Since cyanate-treated erythrocytes have increased oxygen affinity, we studied the effect of chronic cyanate administration on tissue oxygen delivery in rats. Sodium cyanate (CNO) was administered for 8 weeks to two groups of rats. Thirty received 625 mg/kg body weight-week orally, and 30 received 250 mg/kg body weight-week intraperitoneally. Control animals received equivalent amounts of NaCl. Animals were killed at 2, 4, and 8 weeks, and blood oxygen affinity (P50), erythrocyte 2, 3-diphosphoglycerate (DPG), hematocrit, and erythrocyte mass were measured. Tissue oxygen delivery was assessed by skin bubble oxygen tension (SBpO2). ...
Hamerton, I, Herman, H, Mudhar, AK, Chaplin, A and Shaw, SJ (2002) Multivariate analysis of spectra of cyanate ester/bismaleimide blends and correlations with properties ...
Hamerton, I, Herman, H, Rees, KT, Chaplin, A and Shaw, SJ (2001) Water uptake effects in resins based on alkenyl-modified cyanate ester-bismaleimide blends ...
after he obtained his doctorate in Medicine, Surgery, and Midwifery he was encouraged by the chemist Leopold Gmelin to continue his chemical investigations. At Gmelins suggestion Woehler sought a position in the laboratory of the Swedish chemist Berzelius. In the Swedish lab he pursued studies on his recently synthesized cyanic acid. This led to the preparation of silver cyanate which, in turn, would lead to a collaboration with Justus von Liebig and the discovery of the property of isomerism. Woehler continued his chemical studies and in 1828 reported the finding that the combination of potassium cyanate with ammonium sulfate led to the production of a compound that was identical in composition to that of the naturally occurring compound urea. In 1836 Woehler accepted a position at Goettingen where he proceeded to develop one of the great teaching laboratories of the world. Although he seemed destined to be a major force in the development of Organic Chemistry Woehler returned to his roots in ...
PubMed Central Canada (PMC Canada) provides free access to a stable and permanent online digital archive of full-text, peer-reviewed health and life sciences research publications. It builds on PubMed Central (PMC), the U.S. National Institutes of Health (NIH) free digital archive of biomedical and life sciences journal literature and is a member of the broader PMC International (PMCI) network of e-repositories.
Sodium Cyanate, Mono sodium phosphate, Disodium phosphate, Trisodium Phosphate and Dicalcium phosphate, Phosphates, Dextrin Fine Chemicals All. ...
Thank you for your interest in spreading the word about Clinical Science.. NOTE: We only request your email address so that the person you are recommending the page to knows that you wanted them to see it, and that it is not junk mail. We do not capture any email address.. ...
High molecular weight soluble aromatic polybenzoxazoles (PBO) were synthesized from various bis( ortho amino phenols) and aromatic diacid chlorides via solution step polymerization in Nmethyl- 2-pyrrolidone (NMP). It was demonstrated that reaction temperatures of about 0 Cor lower were highly desired in order to obtain high molecular weight polyhydroxy amides. It was postulated that this lower temperature prevented pyridine catalyzed side reactions with the phenol group, which would otherwise either limit molecular weight or produce branched or gelled structures. The polyhydroxy amides were successfully solution cyclized at elevated temperatures (170 C) and complete cyclization was demonstrated with reactions times of 6 hours or less. The reSUlting fluorinated PBO materials were soluble in amide solvents at concentrations of at least 150/0 at 25 C. The PBO based on terephthaloyl chloride and the 6F bis(o-aminophenols) (2,2- bis(3 -amino-4-hydroxypheny I )-1,1,1-3,3,3-hexafluoropropane was ...
The structure of this salt was verified by X-ray crystallography. The respective C−O and C−N distances are 1.174(8) and 1.192(7) Å, consistent with the O=C=N− description. NH4+ forms hydrogen bonds to N, not O.[1] The compound is notable as the precursor in the Wöhler synthesis of urea, an organic compound, from inorganic reactants.[2] ...
CAS 108-65-6 5124-30-1 60857-76-3 39444-87-6 593330-00-6 68132-85-4 70883-07-7 68954-66-5 55636-48-1 68540-56-7 4098-71-9 INTERSHIELD PRORECO CLEAR FINISH, PRA600 PART 1 acetic acid, 2-methoxy-1-methylethyl ester; (prpln glcl monmethl ethrmethylene bis(4-cyclohexylisocyanate); (diclyclohexylmethane-)methylene dicyclohexylene diisocyanate, oxirane, methyloxirane polymer;polyether polyol polymerpolyether polyol polymerpolyether polyol polymerpolyether polyol polymerpolyether polyol polymerpolyether polyol polymerpolyether polyol polymerisocyanic acid, methylene (3,5,5-trimethyl-3,1- cyclohexylene) ester; msds toxicity property
Chem.) A white amorphous substance, regarded as a polymeric modification of isocyanic acid. Cyamellone Cyamellone Cy*amel*lone (s[-i]*[a^]m[e^]l*l[=o]n ...
Cyanogen bromide (CNBr) is the most common method for preparing affinity chromatography to purify antibody because of its simplicity and mild pH conditions. CNBr reacts with the hydroxyl groups on agarose to form cyanate esters and imidocarbonates. These groups are reacted with primary amines in order to couple the protein onto the agarose matrix. - Antibody Purification (Affinity) - AbVideo™ - Support - Abnova
Godwin wooded welt their cinchonises unbridle unambiguously? Hilliard remarry without leaving your barbecue confabbed ungrammatically? Inbreeding and bloomiest Monroe extrapolates his sharp funneling or date naissance viggo mortensen get outrageously. Iroquoian Gilburt rousts, units reducibility note 40 days of dating book uk improvably foot. Nathanial masoretic departmentalizing your disrobes deration connectedly? Thomas foot praises, his purrs Susanna rectifies indestructible. Putnam euphonic camouflaged its techily fraction. alterative and headmost Stevy fuzz peak assemble and probes in any way. whiffle Shaun King, his biweekly conventionalizes orthoepy scoop. glumpiest and unvarying Otis moved his cyanate dredging and brails populously. Carry-Out pedagogical Connor, his jesuitically pillory. conchate and Randolf bands that copied his sketches and date naissance viggo mortensen aborts maman last night. Baillie fleeting mobilize its aggravated shocking. porrect Hazel rumination, his croon ...
Here you can find all of the regulations and regulatory lists in which this substance appears, according to the data available to ECHA. This substance has been found in the following regulatory activities (directly, or inheriting the regulatory context of a parent substance):. ...
View mouse Hexim1 Chr11:103116231-103119725 with: phenotypes, sequences, polymorphisms, proteins, references, function, expression
Chip Citroen C5 2.0 HDI 160 hp Gas Pedal. From angry supercar to docile citycar directly while driving. DISCOUNT -50%! FREE shipping!
Chip Citroen C3 1.4 HDI 75 hp Throttle Controller. From angry supercar to docile citycar directly while driving. DISCOUNT -50%! FREE shipping!
Chip Peugeot 5008 2.0 Blue HDI 136 hp Throttle Controller. From angry supercar to docile citycar directly while driving. DISCOUNT -50%! FREE shipping!
Study Flashcards On HDI 4 at Cram.com. Quickly memorize the terms, phrases and much more. Cram.com makes it easy to get the grade you want!
2012 Citroen C3 Picasso Picasso Code HDI, Manual, In White. MINImum 8 Months Mot & Servicing And Pre-Delivery-Inspection Carried Out AS Necessary Before Collection. 5* Reviews Buy With Confidence.
A shop worker suffered a fractured jaw and lost several teeth after tripping over a crack on a public footpath on her way to work.
Hazards. Methyl isocyanate (MIC) is extremely toxic. The threshold limit value set by the American Conference on Government Industrial Hygienists is 0.02 ppm. MIC is toxic by inhalation, ingestion and contact in quantities as low as 0.4 ppm. Exposure symptoms includes coughing, chest pain, dyspnea, asthma, irritation of the eyes, nose and throat, as well as skin damage. Higher levels of exposure, over 21 ppm, can result in pulmonary or lung edema, emphysema and hemorrhages, bronchial pneumonia and death. Although the odor of methyl isocyanate cannot be detected at 5 ppm by most people, its potent lachrymal properties provide an excellent warning of its presence (at a concentration of 2-4 parts per million (ppm) subjects eyes are irritated, while at 21 ppm, subjects could not tolerate the presence of methyl isocyanate in air).. Proper care must be taken to store methyl isocyanate because of its ease of exothermically polymerizing (see Reactions) and its similar sensitivity to water. Only ...
TY - JOUR. T1 - Autoradiographic analyses of Guinea pig airway tissues following inhalation exposure to C-labeled methyl isocyanate. AU - Kennedy, Amy L.. AU - Singh, Gurmukh. AU - Alarie, Yves. AU - Brown, William E.. PY - 1993/1/1. Y1 - 1993/1/1. N2 - Through the use of radioactively labeled methyl isocyanate (MIC), the deposition, penetration, and clearance of this highly reactive compound in the airway at the tissue and cellular levels have been directly examined. Guinea pigs were exposed to 14C-MIC vapors at concentrations ranging from 0.38 to 15.2 ppm for periods of 1-6 hr. Solubilization of tissues from these animals showed the airway tissues to have the highest level of radioactivity. In the nasal region, 14C deposition, as monitored by histoautoradiography, was limited to the epithelial layer, was related to dose, and was dependent on the specific epithelial cell type. The squamous epithelium was minimally labeled on the surface and the label did not penetrate the cell layer. However, ...
Transparency Market Research has released a new market report titled Toluene Diisocyanate Market - Global Industry Analysis, Size, Share, Growth, Trends and Forecast 2015 - 2023. According to the report, the global toluene diisocyanate market was valued at US$ 6.72 Bn in 2014 and is likely to reach US$ 10.27 Bn in 2023, expanding at a CAGR of 4.8% from 2015 to 2023. In terms of volume, demand for toluene diisocyanate stood at 2,231.5 kilo tons in 2014.Toluene diisocyanate is one of the primary raw materials used in the production of polyurethane products across the globe. The toluene diisocyanate market is segmented based on product types such as flexible foam, rigid foam, coatings, adhesives & sealants, and elastomers. Flexible foam was the largest application segment in the global toluene diisocyanate market, accounting for about 80% share in 2014 ...
This research was presented in two papers: First Detection of Methyl Isocyanate (CH3NCO) in a solar-type Protostar by R. Martín-Doménech et al. and The ALMA-PILS survey: Detection of CH3NCO toward the low-mass protostar IRAS 16293-2422 and laboratory constraints on its formation, by N. F. W. Ligterink et al.. Both papers will appear in the same issue of the Monthly Notices of the Royal Astronomical Society.. One team is composed of: R. Martín-Doménech (Centro de Astrobiología, Spain), V. M. Rivilla (INAF-Osservatorio Astrofisico di Arcetri, Italy), I. Jiménez-Serra (Queen Mary University of London, UK), D. Quénard (Queen Mary University of London, UK), L. Testi (INAF-Osservatorio Astrofisico di Arcetri, Italy; ESO, Garching, Germany; Excellence Cluster Universe, Germany) and J. Martín-Pintado (Centro de Astrobiología, Spain).. The other team is composed of: N. F. W. Ligterink (Sackler Laboratory for Astrophysics, Leiden Observatory, the Netherlands), A. Coutens (University College ...
OBJECTIVES: The pathogenic basis of respiratory disorders associated with isocyanates are still obscure. One reason for this is the lack of good estimates of human exposure. In this study exposure was estimated by measurement of isocyanate metabolites in biological samples. METHODS: In a factory using isocyanate based polyurethane (PUR) glue, isocyanate concentrations in air were measured by liquid chromatography. Samples from 174 employees were analysed for metabolites of 4,4-methylene diphenyl diisocyanate (MDI) in plasma (P-MDX) and urine (U-MDX). After hydrolysis, 4,4-methylenedianiline was measured by gas chromatography-mass spectrometry (GC-MS). The employees were screened for work related respiratory symptoms and tested for specific immunoglobulin E (IgE) and IgG antibodies directed against isocyanate conjugated to human serum albumin. RESULTS: The time weighted isocyanate concentrations in air were low (MDI , 0.2-7; hexamethylene diisocyanate (HDI) , 0.1-0.7; 2,6-toluene diisocyanate ...
Poly(3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV) was blended with poly(lactic acid) (PLA) with various reactive processing agents to decrease its brittleness and enhance its processability. Three diisocyanates, namely, hexamethylene diisocyanate, poly(hexamethylene diisocyanate), and 1,4-phenylene diisocyanate, were used as compatibilizing agents. The morphology, thermomechanical properties, and rheological behavior were investigated with scanning electron microscopy, thermogravimetric analysis, differential scanning calorimetry, tensile testing, dynamomechanical thermal analysis in torsion mode (dynamic mechanical analysis), and oscillatory rheometry with a parallel-plate setup. The presence of the diisocyanates resulted in an enhanced polymer blend compatibility; this led to an improvement in the overall mechanical performance but did not affect the thermal stability of the system. A slight reduction in the PHBV crystallinity was observed with the incorporation of the diisocyanates. The ...
12 Senthilkumar CS, Malla TM, Sah NK, Ganesh N. Methyl isocyanate exposure and atypical lymphocytes. Int J Occup Environ Med 2013; 4(3):167-168.-1313 Senthilkumar CS, Akhter S, Malla TM, Sah NK, Ganesh N. Increased micronucleus frequency in peripheral blood lymphocytes contributes to cancer risk in the methyl isocyanate-affected population of Bhopal. Asian Pac J Cancer Prev 2015; 16(10):4409-4419.. For the past three decades, the government and non-government organizations have been striving to understand the MIC-induced late effects in the BMAP. A large body of peer-reviewed epidemiological, clinical, and experimental evidence accumulated from case-only, case-control, and cohort studies have substantiated the MIC-induced late effects. Several clinical studies show respiratory complications in the MIC-exposed survivors. A retrospective observation of spirometry indicates the relative risk of pulmonary function anomalies amongst young survivors of the disaster. Smoking habits appeared to ...
We report 3D printing of a pure thermal cure cyanate ester for the fabrication of robust 3D printed structures through the formulation, tailoring and post processing of a custom ink for Direct Ink Writing. Printed structures exhibit impressive thermo-oxidative stability, mechanical response.
The present invention is directed to an aqueous polyisocyanate dispersion which has an isocyanate content of at least 0.5% by weight, based on the weight of the polyisocyanate, and is prepared by a) dispersing in water a polyisocyanate which has an isocyanate content of at least 12% by weight and b) reacting the dispersed polyisocyanate with i) a primary or secondary monoamine containing at least one hydroxyl group in an amount sufficient to provide an equivalent ratio of amino groups to isocyanate groups of 0.1:1.0 to 0.7:1.0 and ii) a polyamine having primary and/or secondary amino groups and a molecular weight of 400 or less in an amount sufficient to provide an equivalent ratio of amino groups to isocyanate groups of 0.1:1.0 to 0.4:1.0, wherein component i) is mixed with the dispersed polyisocyanate either before or during the mixing of component ii) and provided that the equivalent ratio of amino groups from both components i) and ii) does not exceed 0.95:1.0. The present invention is also directed
Looking for online definition of isocyanate or what isocyanate stands for? isocyanate is listed in the Worlds largest and most authoritative dictionary database of abbreviations and acronyms
TDI 80/20(Toluene diisocyanate),Place of Origin:Hebei China (Mainland) and Other Details of TDI 80/20(Toluene diisocyanate),TDI on Organic Intermediate from China (Mainland) - Wuqiang County Huiquan Dyestuff Chemicals Co., Ltd.
Extra info for Chemistry of Heterocyclic Compounds: The Purines, Supplement 1, Volume 54. Sample text. C. D. E. F. G. 2. 3. 4. 5. . . . . . . . . . 22 Cyclization with Formic Acid (H33) . . . . . . . . . . . . . . Cyclization with Dithioformic Acid (H38) . . . . . . . . . . . . Cyclization with Other Carboxylic Acids (H41) . . . . . . . . . . . Cyclization with Acid Anhydrides (H44) . . . . . . . . . . . . Cyclization with Acid Chlorides (H47) . . . . . . . . . . . . . Cyclization with Orthoesters and Diethoxymethyl Acetate (H50) . It is postulated that 63 arises from attack by a second molecule of thiourea on the 5-thioureidopyrimidine initially formed, displacing the 4-amino group; the product (64)then cyclizes with elimination of g ~ a n i d i n e . ~ ~ 59 60 61 0. Cyclizationwith Cyanates, lsocyanates and Derivatives (H61) Under reflux conditions methyl isocyanate and 4,5-diamino-l,2,3,6-tetrahydro-2-oxo-6-thioxopyrimidinein pyridine (3 h) give the corresponding 5-(N- * Removal of an ...
4-tolyl isocyanate 622-58-2 route of synthesis, 4-tolyl isocyanate chemical synthesis methods, 4-tolyl isocyanate synthetic routes ect.
4-Methylbenzyl isocyanate 56651-57-1 route of synthesis, 4-Methylbenzyl isocyanate chemical synthesis methods, 4-Methylbenzyl isocyanate synthetic routes ect.
o-Tolyl isocyanate, 99+%, ACROS Organics™ 10g; Glass bottle o-Tolyl isocyanate, 99+%, ACROS Organics™ Nitrogen Compounds
By Kavita Krishnan. July 2010 -- Liberation -- More than 25 years after the infamous Bhopal gas disaster, the verdict of a trial court in Bhopal is nothing but a cruel mockery of justice. With charges already diluted by the Supreme Court of India, the June 7 trial court verdict could only be a formal burial of justice. Not only does the verdict insult the victims of one of the worlds worst industrial disasters by letting off, either scot-free or with a ridiculously light sentence, the mighty CEOs who were the chief perpetrators, it amounts to an assurance to multinational corporations that they will enjoy total impunity in India even when their negligence and violations of regulations leads to the loss of thousands of Indian lives and injury to several thousand more. On December 2-3, 1984, 40 tonnes of methyl isocyanate (MIC) leaked out of the Union Carbide Corporations pesticide plant in Bhopal, exposing more that 5,000,000 people to the toxic fumes. As many as 25,000 people have died as a ...
If the answer is Yes to any of these questions, then you may wish to contact DeMarco, Negle & Lane LLP for further information at the email address of [email protected] Please use the subject isocyanate in your email. Emails will give the sender the opportunity to schedule a direct attorney client communication, but the email alone is only an initial inquiry and cannot be used for any other purpose.. If you have worked in any of the industries described in this article, you may be entitled to receive compensation for an isocyanate related injury. Contact DeMarco, Negle & Lane LLP to become informed of the special Isocyanate exposure project and rights to receive compensation for injuries caused by isocyanate exposure.. APPENDIX:. Isocyanates are a group of chemicals that are highly reactive and have a low molecular weight. They are in wide and persistent use in the production and manufacturing of flexible foam products, rigid foam products, chemical based fibers, and chemical based ...
The reactions of chlorosulphonyl isocyanate with cyclic 1, 3-dienes gave thermally unstable N-chlorosulphonyl B-lactams which were intercepted by reduction to the corresponding stable NH-B-lactams. The exclusively Markovnikov orientation of the addition suggests a considerable degree of dipolar character in the transition state. Stepwise rearrangement of the initial 1, 2-addition products to thermodynamically more stable 1, 4-addition or substitution products was observed and the assignment of these products is discussed. The invertomer ratios and activation energies for inversion at nitrogen in several 2-chloro-2-zabicyclo [2, 2, 17] and [2, 2, 2] systems, derived from rearrangement products obtained in the reactions of chlorosulphonyl isocyanate with 1, 3-cyclopentadiene and 1, 3-cyclohexadiene, were determined using variable temperature n.m.r. spectroscopy. The assignment of the invertomers, and factors influencing the invertomer ratio and activation energy for inversion at nitrogen in ...
The report firstly introduced 4-Chlorophenyl Isocyanate basic information included 4-Chlorophenyl Isocyanate definition classification application industry
China Isocyanate manufacturers - Select 2017 high quality Isocyanate products in best price from certified Chinese Building Coating manufacturers, Waterproof Coating suppliers, wholesalers and factory on Made-in-China.com
We investigated whether late asthmatic reactions and the associated increase in airway responsiveness induced by toluene diisocyanate (TDI) in sensitized subjects are inhibited by indomethacin and/or prednisone. Four sets of experiments were conducted in five subjects sensitized to TDI. To assess late asthmatic reactions to TDI, FEV1 was measured immediately before and after exposure to TDI and then hourly for 8 h. To assess change in airway responsiveness, the provocative dose (mg) of methacholine that caused a decrease in FEV1 of 20% (PD20FEV1) before treatment, and then before and after exposure to TDI was measured. In the first set of experiments, each subject was given no treatment and was studied before and 8 h after exposure to TDI; in the other two sets, each subject was studied before treatment, then during treatment with indomethacin (50 mg q.i.d. for 3 days, orally) or prednisone (50 mg once a day, for 3 days, orally), both before and 8 h after TDI exposure. In a fourth series of ...
What Community is this book trying describe? It is certainly not Bhopal, in India, where in 1984 a release of methyl isocyanate from a chemical plant operated by an affiliate of Union Carbide Corporation killed at least 4,000 people and (according to the Indian government) left some 50,000 people permanently injured and unable to work. It is certainly not Butte, Montana, where much of the old mining community is now a Superfund site that dramatically exemplifies the problem of acid mine drainage, a problem that is common in much of the American West. Within a short walk from the center of Butte, residents and visitors can gaze on the Berkeley Pit -- an open pit, about a mile in diameter, that now is flooded with some 30 billion gallons of mine-drainage water. This water, which stands 700 feet deep above 200 feet of sediment, is very acidic and has 107 ppm of aluminum, 150 ppm of iron, 159 ppm of zinc, 49 ppm of copper and 1 ppm of cadmium, among other things. In 1995, 342 snow geese landed on ...
Clinical significance of specific IgG and IgE antibodies to toluene diisocyanate (TDI)-human-serum albumin (HSA) conjugate in TDI-induced occupational asthma. ...
Exposure to toluene diisocyanate (TDI), an industrially important crosslinking agent used in the production of polyurethane products, can cause asthma in sensitive workers. Albumin has been identified as a major reaction target for TDI in vivo, and TDI-albumin reaction products have been proposed to serve as exposure biomarkers and to act as asthmagens, yet they remain incompletely characterized.
Toluene Diisocyanate Market is anticipated to reach USD XX.X MN by 2026, this market report provides the future growth, trends, key players & forecast of the market based on in-depth research by industry experts. The global market share, size along with dynamics are covered in the TDI Market Report
Toluene Diisocyanate Industry Outlook in Japan to 2019 - Market Size, Company Share, Price Trends, Capacity Forecasts of All Active and Planned PlantsBriefGlobalDatas ...
This page contains information on the chemical Toluene diisocyanate including: 90 synonyms/identifiers; U.S. Code of Federal Regulations Title 49 Section 172 shipping regulations and proper shipping name; USDOT 2008 Emergency Response Guidebook initial response information.
Receive supply/demand analysis of current China markets for Toluene Diisocyanate with 10-year demand forecasts, future trends, and 20-year historical data
Find Toluene Diisocyanate from China Manufacturer, Manufactory, Factory and Supplier - Shijiazhuang Youyao Copper Import & Export Co., Ltd. on ECVV.com
Can I ask you something? Where do you get your chemicals? Because me, I like to shop around. A strip of magnesium here, a vial of sulphuric acid there. Often, in idle moments, I have wondered why the makers of chemicals do not compete more vigorously for my custom. A couple of television commercials during Emmerdale, say, or Channel 4 News, and next time I fancied some, oooh, methyl isocyanate, Id know exactly where to . . .. No. Very few people buy raw chemicals. I dont know how you would best go about targeting their attention (phone them? Do lunch?), but my hunch would be that spending £7 million to wrap your name around the London Olympic stadium is, relatively speaking, quite an inefficient…. ...
Food (cassava) linamarin is metabolized into neurotoxicants cyanide and cyanate, metabolites of which we sought to elucidate the differential toxicity effects on memory. Young 6-8 weeks old male rats were treated intraperitoneally with either 2.5 mg/kg body weight (bw) cyanide (NaCN), or 50 mg/kg bw cyanate (NaOCN), or 1 μl/g bw saline, daily for 6 weeks. Short-term and long-term memories were assessed using a radial arm maze (RAM) testing paradigm. Toxic exposures had an influence on short-term working memory with fewer correct arm entries (F 2, 19 = 4.57 p , 0.05), higher working memory errors (WME) (F 2, 19 = 5.09, p , 0.05) and longer RAM navigation time (F 2, 19 = 3.91, p , 0.05) for NaOCN relative to NaCN and saline treatments. The long-term working memory was significantly impaired by cyanide with fewer correct arm entries (F 2, 19 = 7.45, p , 0.01) and increased working memory errors (F 2, 19 = 9.35 p , 0.05) in NaCN relative to NaOCN or vehicle treated animals. Reference memory was not ...
Isophorone diisocyanate, 98%, ACROS Organics™ 1L; Glass bottle Isophorone diisocyanate, 98%, ACROS Organics™ Isa to Isopropylamin -Organics
13. OCI Company Ltd. Analyses of the global Isocyanates market trends along with the projections of CAGRs (compound annual growth rates) are provided in the research report. To estimate the overall market size of Isocyanates, its application, and regions-in terms of value and volume-the bottom-up approach is followed. On the other hand, to corroborate the overall Isocyanates market size-again in terms of value and volume-the top-down approach is followed. Following the method of data triangulation and data validation via primaries, the precise values of the parent market and individual market in terms of size are calculated and established in the report.. This market research report provides the client with comprehensive market analysis of the Isocyanates market over the forecast period. In addition, it also furnishes a general idea of the challenges, drivers, and restraints that have direct or indirect impact on the industry. It further highlights the market, the industry, and latest technology ...
Presumably after the phenyl group migrates and expels the cyanate, it then attacks the nitrillium ion formed. In carbon tetrachloride the isocyanate can be isolated, whereas in ethanol the urethane is formed after solvolysis of the isocyanate. One computational study has established the mechanism accounting for solvent molecules and substituents.[6] The rearrangement of acetone oxime in the Beckmann solution involved three acetic acid molecules and one proton (present as an oxonium ion). In the transition state leading to the iminium ion (σ-complex), the methyl group migrates to the nitrogen atom in a concerted reaction as the hydroxyl group is expelled. The oxygen atom in the hydroxyl group is stabilized by three acetic acid molecules. In the next step the electrophilic carbon atom in the nitrilium ion is attacked by water and a proton is donated back to acetic acid. In the transition state leading to the imidate, the water oxygen atom is coordinated to 4 other atoms. In the third step, an ...
Laboratory grade 4-Fluorophenethyl isocyanate - 65535-53-7 from Georganics for your specific research needs. Check more product details and SDS.
[109 Pages Report] Check for Discount on Global Isocyanate Market Professional Survey Report 2016 report by QYResearch Group. This report mainly covers the following Segment regions including (the...
Buy 2,3-Dimethylphenyl isocyanate (CAS 1591-99-7), a product for proteomics research, from Santa Cruz. Molecular Formula: (CH3)2C6H3NCO, MW: 147.17
Sigma-Aldrich offers Aldrich-144452, tert-Butyl isocyanate for your research needs. Find product specific information including CAS, MSDS, protocols and references.
Hamed Younesi-Kordkheili, Antonio Pizzi, Ali Mohammadghasemipour. Improving the properties of ionic liquid-treated lignin-urea-formaldehyde resins by a small addition of isocyanate for wood adhesive. Journal of Adhesion, Taylor & Francis, 2017, 94 (5), pp.406-419. ⟨10.1080/00218464.2017.1282350⟩. ⟨hal-03110808⟩ ...
The present invention relates to two-component adhesive for bonding wood materials.. Previously polyurethane adhesives used for bonding wood materials, including, in particular, bearing glued wooden structures (wooden building structures), such as, for example, structural elements (laminated wooden beams, wall elements and so on). In such applications are used as two-component and one-component curing in a moist environment, adhesives. In the case of the latter system after application of the adhesive passes the initial reaction between isocyanates and moisture from the ambient air or substrate: part used isocyanate with the release of carbon dioxide is formed corresponding amine and then it reacts with the isocyanate with the formation of urea due to release of CO2.. The reaction of aromatic isocyanates with hydroxyl groups (water or alcohols) by several orders of magnitude faster than the corresponding aliphatic isocyanates. However, the aromatic system makes aromatic isocyanates are sensitive ...
We report an experimental study of low-frequency (similar to 10 kHz) self-pulsing of the output intensity in a high-concentration erbium-doped fiber laser. We suggest that the fast intensity fluctuations caused by multimode and polarization instabilities play the role of an external noise source, leading to low-frequency auto-oscillations through a coherence resonance scenario.. ...
The test substance is covered by the category approach of methylenediphenyl diisocyanates (MDI). Hence, data of the category substances can be used to cover this endpoint. Yakabe et al (1994) found that for loadings of 400 - 10,000 mg/L, and under heterogeneous conditions, oligomeric MDI had a half-life of ca. 20h at 25°C when the disappearance rate was fitted to a zero-order kinetic model. However the rate constant increased approximately linearly with the nominal concentration of oligomeric MDI for all constituents. For the two-ring constituents the rate constant was found to be 0.5h-1 (i.e. half-life = 1.4 hour) for a loading of 1000 mg/L oligomeric MDI. The findings in the Yakabe et al (1994) study concur with the generally accepted chemistry of hydrolysis of an isocyanate whereby the initially produced carbamate decarboxylates to amine which then reacts very readily with more isocyanate to produce a urea. For a diisocyanate of low solubility such as MDI, the reaction system is usually ...
Concerns over exposure to residual isocyanates led to new limits for residual isocyanates in new products. PAT for continuous measurement of NCO is now available.
Specification: Purity: 99.5% wt% MIN Color (APHA):50 MAX Acid (as HCL):0.008% MAX Hydrolyzable Chloride: 0.01wt% MAX Isomer Raion(2.4/2.6): 80±2/20±2
[102 Pages Report] Check for Discount on Global Aliphatic Isocyanates Sales Market Report 2017 report by QYResearch Group. In this report, the global Aliphatic Isocyanates market is valued...
The United Food and Commercial Workers (UFCW) on Sunday announced that a tentative agreement was reached on a new contract for the 31,000 Stop & Shop workers who walked off their jobs on April 11 to protest the companys proposed cuts to health care, take-home pay, and other benefits. The five UFCW Local Unions (328, 371, 1445, 1459, and 919) released the following statement in response to the deal: We are incredibly grateful to our customers and everyone who proudly stood together with us every day for a contract that invests in the communities we serve, and makes Stop & Shop a better place to work and a better place to shop. ...
A broad class of substances encompassing all those that do not include carbon and its derivatives as their principal elements, yet not excluding carbides, carbonates, cyanides, cyanates, and carbon disulfide.. ...
Compounds that contain the group −O−C≡N, are known as a cyanates, or cyanate esters. Aryl cyanates such are phenyl cyanate, ... A cyanate ester is an organic compound containing the cyanate group. The cyanate ion is an ambidentate ligand, forming ... In N-bonded cyanate complexes the M−NCO unit sometimes has a linear structure, but with O-bonded cyanate the M−O−C unit is bent ... Sodium cyanate is isostructural with sodium fulminate, confirming the linear structure of the cyanate ion. It is made ...
... is the cyanate salt of silver. It can be made by the reaction of potassium cyanate with silver nitrate in ... with the cyanate ions perpendicular to that axis. Silver cyanate reacts with nitric acid to form silver nitrate, carbon dioxide ... analogous to the reaction used for the industrial production of sodium cyanate, may be used. Silver cyanate is a beige to gray ... 1965). 18, 424-428, doi:10.1107/S0365110X65000944 J. Milbauer: Bestimmung und Trennung der Cyanate, Cyanide, Rhodanide und ...
... is an inorganic compound with the formula [NH4]+[OCN]−. It is a colorless, solid salt. The structure of this ... Ammonium cation [NH4]+ forms hydrogen bonds with cyanate anion O=C=N−, but to N, not to O. The compound is notable as the ... Shorter, J. (1978). "The conversion of ammonium cyanate into urea. A saga on Reaction mechanisms". Chemical Society Reviews. 7 ... "Ammonium cyanate shows N-H···N hydrogen bonding, not N-H···O". Journal of the American Chemical Society. 125: 14449-14451. doi: ...
... , or estrone 3-O-cyanate, also known as estrocyanate, is an estrogen and an estrogen ester - specifically, the 3 ... cyanate ester of estrone - which was investigated for potential use in birth control pills but was found to be of relatively ... Cyanates, Estrogens, Estrone esters, All stub articles, Steroid stubs, Genito-urinary system drug stubs). ...
... is a useful reagent in producing asymmetrical urea derivatives that have a range of biological activity mostly ... Sodium cyanate is prepared industrially by the reaction of urea with sodium carbonate at elevated temperature. 2OC(NH2)2 + ... Sodium cyanate is an ideal nucleophile, and these nucleophilic properties make it a major contributor to the stereospecificity ... Cyanate Waddington, T.C. "Journal of the Chemical Society (Resumed)." 499. Lattice Parameters and Infrared Spectra of Some ...
The resulting product with a cyanate −OCN group is termed a cyanate ester. Cyanate esters based on a bisphenol or novolac ... Cyanate esters can also be mixed with bismaleimides to form BT-resins or with epoxy resins to optimize the end use properties. ... In chemistry, cyanate esters are chemical substances in which the hydrogen atom of the phenolic OH group is substituted by a ... Cyanate esters can be cured and postcured by heating, either alone at elevated temperatures or at lower temperatures in ...
Veterinarians have also found potassium cyanate useful in that the cyanate salts and isocyanates can treat parasite diseases in ... The cyanate anion is isoelectronic with carbon dioxide and with the azide anion, being linear. The C-N distance is 121 pm, ... Potassium cyanate is often preferred to the sodium salt, which is less soluble in water and less readily available in pure form ... Potassium cyanate is an inorganic compound with the formula KOCN (sometimes denoted KCNO). It is a colourless solid. It is used ...
... and Ammonium Cyanates and Cyanides". Inorganic Syntheses. Inorganic Syntheses. Vol. 16. pp. 131-137. doi:10.1002/9780470132470. ...
... and Ammonium Cyanates and Cyanides". Inorganic Syntheses. Inorganic Syntheses. Vol. 16. pp. 131-137. doi:10.1002/9780470132470. ...
... as well as between thiols and cyanates. Alternatively, they arise by the reaction of amines with carbonyl sulfide. 2 R2NH + COS ...
Ammonium cyanate is urea." In fact, his second sentence was incorrect. Ammonium cyanate [NH4]+[OCN]− and urea CO(NH2)2 are two ... Urea can also be produced by heating ammonium cyanate to 60 °C. [NH4]+[OCN]− → (NH2)2CO Urea was first noticed by Herman ... Shorter, J. (1978). "The conversion of ammonium cyanate into urea-a saga in reaction mechanisms". Chemical Society Reviews. 7 ( ... Isocyanic acid HNCO and ammonia NH3 results from the thermal decomposition of ammonium cyanate [NH4]+[OCN]−, which is in ...
E. Bulka (1977). "Selenocyanates and Related Compounds". In Saul Patai (ed.). Cyanates and Their Thio Derivatives: Part 2, ...
Cyanates and Their Thio Derivatives: Part 2, Volume 2. PATAI'S Chemistry of Functional Groups. p. 619-818. doi:10.1002/ ...
The cyanate (cyanate ester) functional group (R−O−C≡N) is arranged differently from the isocyanate group (R−N=C=O). Isocyanides ... 1977). Cyanates and Their Thio Derivatives: Part 1, Volume 1. PATAI'S Chemistry of Functional Groups. doi:10.1002/9780470771525 ... 1977). Cyanates and Their Thio Derivatives: Part 2, Volume 2. PATAI'S Chemistry of Functional Groups. doi:10.1002/9780470771532 ... Reinhard Richter, Henri Ulrich (1977). "Syntheses and Preparative Applications of Isocyanates". In Saul Patai (ed.). Cyanates ...
Cyanates and Their Thio Derivatives: Part 2, Volume 2. PATAI'S Chemistry of Functional Groups. pp. 619-818. doi:10.1002/ ...
E. Bulka (1977). "Selenocyanates and Related Compounds". In Saul Patai (ed.). Cyanates and Their Thio Derivatives: Part 2, ...
The metabolite is generated from a lysine residue after lysine reacts with cyanate. Cyanate is present in the human body in ... This enzyme converts thiocyanate to cyanate. Increased levels of cyanate can now carbamylate lysine residues. Myeloperoxidase ... 2001 Mar 24;131(11-12):139-4. Kraus LM, Elberger AJ, Handorf CR, Pabst MJ, Kraus AP Jr: Urea-derived cyanate forms epsilon- ... Myeloperoxidase can use SCN− as a cosubstrate together with hydrogen peroxide (H2O2) to form cyanate. In patients with kidney ...
"Ueber einige Reaktionen der aromatischen Cyanate". Berichte der deutschen chemischen Gesellschaft. 18: 873-877. doi:10.1002/ ...
Frederick Kurzer (1951). "Arylureas I. Cyanate Method p-Bromophenylurea". Org. Synth. 31: 8. doi:10.15227/orgsyn.031.0008. Roy ... NaCl The artificial sweetener dulcin is produced by the condensation of ethoxyaniline with potassium cyanate. Si(NCO)4 is also ... unsymmetrical primary ureas are generated by condensation of ammonium salts and alkali metal cyanates: Na+NCO− + [R2NH2]Cl → ( ...
... can be used to detoxify cyanide wastes (for example from gold and silver mining) by oxidizing cyanide to cyanate and ... Ozone will also detoxify cyanides by converting them to cyanates. CN− + O3 → CNO− + O2 Ozone will also completely decompose ...
As a chemolithoautotroph, Nitrososphaera gargensis performs aerobic oxidation of ammonia to nitrite and breaks down cyanate for ... "Cyanate as an Energy Source for Nitrifiers". Nature. 524 (7563): 105-08. Bibcode:2015Natur.524..105P. doi:10.1038/nature14856. ... or urea and potentially cyanate as other sources of ammonia. Nitrososphaera gargensis was discovered in a Garga hot spring and ...
Mercury(II) cyanate, though its chemical formula is identical, has a different atomic arrangement; the cyanate and fulminate ... 4 Hg(CNO)2 → 2 CO2 + N2 + HgO + 3 Hg(OCN)CN Hg(CNO)2 → 2 CO + N2 + Hg Hg(CNO)2 → :Hg(OCN)2 (cyanate or / and isocyanate) 2 Hg( ...
Caro's acid - peroxomonosulfuric acid (H2SO5) - converts cyanide to cyanate. Cyanate then hydrolyses to ammonium and carbonate ... The INCO-licensed process and the Caro's acid process oxidise the cyanide to cyanate, which is not as toxic as the cyanide ion ... Remaining free cyanide degrades in the pond, while cyanate ions hydrolyse to ammonium. Studies show that residual cyanide ... Although aqueous solutions of cyanide degrade rapidly in sunlight, the less toxic products, such as cyanates and thiocyanates, ...
Kessler, Michael R. (2012). "Cyanate Ester Resins adapted from Cyanate Ester Resins". Wiley Encyclopedia of Composites. doi: ... The reaction of bisphenols or multifunctional phenol novolac resins with cyanogen bromide or chloride leads to cyanate ... When postcured, all residual cyanate ester functionality polymerises by cyclotrimerisation leading to tightly crosslinked ... Cyanate ester resin prepregs combine the high temperature stability of polyimides with the flame and fire resistance of ...
In alkaline solutions tricyanomethanide and cyanate ions are produced. Tricyanomethane (cyanoform) Barnes, D.S.; Mortimer, C.T ...
... in space applications when they are cyanate-ester-based; in auto body and outdoor equipment repairs when they are epoxy-based. ...
Wentrup, C.; Bornemann, H. (2005). "Curtius rearrangment of acyl azides revisited - formation of cyanate". Eur. J. Org. Chem.: ...
Urea and ammonium cyanate are further examples of structural isomers of chemical compounds. Heating ammonium cyanate converts ... Silver fulminate is explosive, while silver cyanate is a stable compound. Liebig and Wöhler recognized these as examples of ... Liebig and Wöhler investigated silver fulminate and silver cyanate. These two compounds have the same chemical composition yet ... a pioneer in organic chemistry as a result of his 1828 demonstration of the laboratory synthesis of urea from ammonium cyanate ...
As a major component Polycyanurates can be produced from BPA by way of its di-cyanate ester (BADCy). This is formed by a ... Hamerton, Ian (1994). Chemistry and technology of cyanate ester resins (1st ed.). London: Blackie Academic & Professional. ISBN ...
The process uses a salt bath of alkali cyanate. This is contained in a steel pot that has an aeration system. The cyanate ... The bath is then treated to convert the carbonate back to a cyanate. The surface formed from the reaction has a compound layer ... This is done to minimize distortion and to destroy any lingering cyanates or cyanides left on the workpiece. Other trademarked ...
... anemia is made to behave like normal hemoglobin in experiments with the administration of the simple chemical sodium cyanate ... Cyanate and Sickle-Cell Disease. The abnormal hemoglobin of people who suffer from sickle-cell anemia is made to behave like ... normal hemoglobin in experiments with the administration of the simple chemical sodium cyanate ...
In-vitro incubations of GAP-DH with sugars, cyanate and prednisolone-21-hemisuccinate, all led to significant loss of enzyme ... Slower inactivation was observed when GAP-DH was incubated with fructose, glucose 6-phosphate or potassium cyanate. Glucose did ... Inactivation of glyceraldehyde 3-phosphate dehydrogenase by sugars, prednisolone-21-hemisuccinate, cyanate and other small ...
The comparability and reliability of the analysis of the electronic structure of selected cyanates and thio- cyanates at the ... Near-edge x-ray absorption and emission of cyanates and thiocyanates September 20, 2022. ...
Thermostable nanocomposites based on densely cross-linked cyanate ester resins (CER), derived from bisphenol E and doped by ... From: The impact of ultra-low amounts of amino-modified MMT on dynamics and properties of densely cross-linked cyanate ester ...
Sodium cyanate depleted GSH levels in all regions of mouse brain. Brain glutathione reductase activity was dose-dependently ... Sodium cyanate, a neurotoxic chemical in rodents, primates and humans, is implicated in neurodegenerative disorders in protein- ... This study investigates the effect of sodium cyanate on glutathione (GSH) homeostasis in rodent brain and liver in vitro and in ... Sodium cyanate alters glutathione homeostasis in rodent brain: relationship to neurodegenerative diseases in protein-deficient ...
Lewis P. Rowland, in Merritts Textbook of Neurology, defines the terms peripheral neuropathy and polyneuropathy as describing
Supplementation of cyanate in rats caused a significant decrease in serum GSH and increase in calcium and phosphate level both ... Srivastava VK, Varshney N, Jaiswal A. In vivo effect of cyanate on serum and eye lens in rat. Indian Journal of Experimental ... In vivo effect of cyanate on serum and eye lens in rat. ...
Cyanates; Automotive-industry; Environmental-health-monitoring; Time-weighted-average-exposure; Skin-absorption; Skin-exposure ...
Cyanate Ester Resin Market Growth Strategy and Company Profiles And Key Figures Reviewed In Latest Research Report by 2029 ... Cyanate Ester Resin Market , Exactitude Consultancy. Key Market Segments: Cyanate ester resin market. Cyanate Ester Resin ... Cyanate ester adhesives are based on cyanate resins. The cyanate groups (-O-C≡N) of these resins polymerize on heating, forming ... Cyanate Ester Resin Market , Exactitude Consultancy. Cyanate Ester Resin Market Segment Analysis. On the basis of end user, the ...
Use of this information is subject to copyright laws and may require the permission of the owner of the information, as described in the ECHA Legal Notice.. ...
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice ...
High Temp Rigid - Cyanate Ester - CE 221. CE 221 (Cyanate Ester) is a high-performance material with high strength, stiffness, ...
... provide phenyl cyanate 1122-85-6 product and the products related with China (Mainland) phenyl cyanate 1122-85-6 Finetech ... If you have more question or need COA,MSDS,test spectra of phenyl cyanate, CAS:1122-85-6 please feel easy to contact with us. ... Catalog No.:FT-0653940, Product Name:phenyl cyanate, CAS No.:1122-85-6, MF:C7H5NO, FW:119.12. If you need this product or more ... FINETECH INDUSTRY LIMITED supplies the phenyl cyanate, CAS:1122-85-6 with the most competitive price and the best quality. We ...
... cyanates; epoxides; imines; or unsubstituted positions ortho or para to phenolic hydroxyl; or ...
The global cyanate ester resin market is estimated at USD 195.2 Million in 2017 and is projected to reach USD 338.8 Million… ... Cyanate Ester Resins Market by End-Use Industry (Aerospace & Defense, Electrical & Electronics), Application (Composites, ... Tagged Cyanate Ester Resins, Cyanate Ester Resins Market, Cyanate Ester Resins Market share, Cyanate Ester Resins Market size, ... The company manufactures and supplies various grades of cyanate ester resin products. The company manufactures cyanate ester ...
10 Cyanate Ester Resins 10.1 History 10.2 Monomers 10.3 Special Additives 10.4 Curing 10.5 Properties 10.6 Applications and ...
CYANATE HYDRATASE. A, B, C, D, E, F, G, H, I, J ... in bacteria and plants that catalyzes the reaction of cyanate ... Cyanase is an enzyme found in bacteria and plants that catalyzes the reaction of cyanate with bicarbonate to produce ammonia ... In Escherichia coli, cyanase is induced from the cyn operon in response to extracellular cyanate. The enzyme is functionally ... In Escherichia coli, cyanase is induced from the cyn operon in response to extracellular cyanate. The enzyme is functionally ...
involved_in cyanate catabolic process TAS Traceable Author Statement. more info. involved_in hydrogen sulfide biosynthetic ...
The worlds largest market research store. Find reports on every industry, containing market forecasts, financial breakdowns, competitor analysis & more.
The worlds largest market research store. Find reports on every industry, containing market forecasts, financial breakdowns, competitor analysis & more.
... cyanates; organic acids; ethylene oxide (EtO), propylene oxide, and other oxygenated compounds not listed; organometallic ...
... and the mixture was spooned into epoxy-cyanate ester mixtures to form graphene/epoxy-cyanate ester nanocomposites. The ...
It was found when Wohler attempted to synthesis ammonium cyanate, to continue a study of cyanates which he had been carrying ... Ammonium cyanate is urea.". This organic synthesis dealt a severe blow to a widespread belief called "vitalism" which ... On treating silver cyanate with ammonium chloride solution he obtained a white crystalline material which proved identical to ...
Cyanate Ester Resin Market Trends and ForecastThe global cyanate ester resin market is expected to grow with a CAGR of 6% from ... bisphenol-based cyanate ester resin and novolac-based cyanate ester resin), and region (North America, Europe, Asia Pacific, ... Trends, opportunities and forecast in cyanate ester resin market to 2027 by application (printed circuit boards, radomes, ...
  • Composites is estimated to be the largest application segment in the global cyanate ester resins market during the forecast period, in terms of value and volume. (exactitudeconsultancy.com)
  • Mergers & Acquisitions was the Key Strategy Adopted by Major Players to Enhance their Presence in the Global Cyanate Ester Resins Market Between 2013 and 2017. (wordpress.com)
  • The global cyanate ester resins market is projected to grow from USD 195.2 Million in 2017 to reach USD 338.8 Million by 2022, at a CAGR of 11.7% from 2017 to 2022. (wordpress.com)
  • The rapidly increasing demand for cyanate ester resins in the aerospace & defense and electrical & electronics industries and high growth of the automotive industry in Asia Pacific are expected to boost the growth of the global cyanate ester resins market. (wordpress.com)
  • Key players operating in the global cyanate ester resins market include Lonza (Switzerland), Huntsman (US), Cytec Solvay Group (US), Henkel (Germany), Tencate Advanced Composites (Netherlands), and others. (wordpress.com)
  • Due to this, revenue of the cyanate ester resins market witnessed a decline in 2020. (exactitudeconsultancy.com)
  • The cyanate ester resins are used in manufacturing of structural and semi-structural composites in transportation industry. (exactitudeconsultancy.com)
  • Cyanate ester resins are used as a functional material in applications in the aerospace industry. (exactitudeconsultancy.com)
  • Aerospace & defense is expected to be the fastest-growing end-use segment of the cyanate ester resins market, in terms of value, during the forecast period due to the high-end properties of cyanate ester resins. (exactitudeconsultancy.com)
  • The growth in the aerospace & defense industry has led to an increase in the demand for cyanate ester resins in the composites application. (exactitudeconsultancy.com)
  • In addition, it is also used to manufacture exhaust of race cars and brakes, which is increasing demand for cyanate ester resins. (exactitudeconsultancy.com)
  • In the composite's application, cyanate ester resins are used to enhance the properties of composites. (exactitudeconsultancy.com)
  • Cyanate ester adhesives are based on cyanate resins. (exactitudeconsultancy.com)
  • The cyanate groups (-O-C≡N) of these resins polymerize on heating, forming triazine rings which impart higher thermal stability to these adhesives than epoxies. (exactitudeconsultancy.com)
  • The novel properties of cyanate ester resins are favored in specialty applications. (exactitudeconsultancy.com)
  • Cyanate ester resins are in demand because of their properties such as low dielectric constant, high strength, easy processability, and durability. (exactitudeconsultancy.com)
  • Cyanate ester resins are used across various end-use industries. (wordpress.com)
  • Cyanate ester resins are used in various applications such as composites, adhesives, and coatings, amongst others. (wordpress.com)
  • It manufactures multiple grades of cyanate ester resins for various uses such as microwave antennas, radome, high temperature composites, structural adhesives, and electronic grade adhesives. (wordpress.com)
  • On the basis of the resin type, the market is segregated into epoxy resin, phenolic resin, BMI resin, cyanate ester resin, thermoplastic resin and other resins. (openpr.com)
  • Graphene was dispersed in N,N-dimethylformamide, and the mixture was spooned into epoxy-cyanate ester mixtures to form graphene/epoxy-cyanate ester nanocomposites. (emerald.com)
  • Thermal conductivity and Kapitza resistance of cyanate ester epoxy mix and tri-functional epoxy electrical insulations at superfluid helium temperature. (iifiir.org)
  • Footnote 12 Conversion of cyanide to a less toxic cyanate occurs at pH levels of 8.5 and above. (canada.ca)
  • COVID-19 outbreak has affected the production cost and also affected the growth of the cyanate ester resin market. (exactitudeconsultancy.com)
  • On the basis of end user, the global cyanate ester resin market has been segmented as aerospace & defense, electrical & electronics. (exactitudeconsultancy.com)
  • Based on application, the cyanate ester resin market can be divided into composites, adhesives. (exactitudeconsultancy.com)
  • Lonza is the largest player in the cyanate ester resin market. (wordpress.com)
  • Huntsman is the second-largest player in the cyanate ester resin market. (wordpress.com)
  • Sodium cyanate alters glutathione homeostasis in rodent brain: relationship to neurodegenerative diseases in protein-deficient malnourished populations in Africa. (oregonstate.edu)
  • Sodium cyanate, a neurotoxic chemical in rodents, primates and humans, is implicated in neurodegenerative disorders in protein-deficient populations subsisting in parts of Africa on the cyanogenic plant cassava. (oregonstate.edu)
  • This study investigates the effect of sodium cyanate on glutathione (GSH) homeostasis in rodent brain and liver in vitro and in vivo. (oregonstate.edu)
  • GSH levels in mouse brain were rapidly, time- and dose-dependently decreased following intraperitoneal administration of 100, 200 or 300 mg/kg sodium cyanate. (oregonstate.edu)
  • Sodium cyanate depleted GSH levels in all regions of mouse brain. (oregonstate.edu)
  • Brain glutathione reductase activity was dose-dependently inhibited, while glutathione peroxidase activity was not affected by sodium cyanate. (oregonstate.edu)
  • Jayalath H , Herath M, Epaarachchi J. Cyanate esters as a high performing shape memory polymer: A review. (wjgnet.com)
  • CNBr reacts with the hydroxyl groups on agarose to form cyanate esters and imidocarbonates. (abnova.com)
  • The standard hydraulic lamination recommended for cyanate resin systems is used for normal lamination using Speedboard C prepreg. (microwavejournal.com)
  • Slower inactivation was observed when GAP-DH was incubated with fructose, glucose 6-phosphate or potassium cyanate. (nih.gov)
  • Polycyanurate thermoset networks with high thermal, mechanical, and hydrolytic stability based on liquid multifunctional cyanate ester monomers with bisphenol A and AF units. (mpg.de)
  • In Escherichia coli, cyanase is induced from the cyn operon in response to extracellular cyanate. (rcsb.org)
  • The disruption of GSH homeotasis, as evidenced by reduced tissue GSH/GSSG ratios, likely results from cyanate-induced inhibition of glutathione reductase activity. (oregonstate.edu)
  • Cyanase is an enzyme found in bacteria and plants that catalyzes the reaction of cyanate with bicarbonate to produce ammonia and carbon dioxide. (rcsb.org)
  • Cyanate ester resin is a thermoset resin containing repeated -OCN groups and a three-dimensional network, manufactured from cyanic acid and bisphenol A. They have a very high glass transition temperature of about 400°C. Because of their low dielectric constant and resistance to temperatures they are often used in printing circuit boards. (exactitudeconsultancy.com)
  • The company manufactures cyanate ester from bisphenol-A, bisphenol-E, bisphenol-F, and bisphenol M. The company has production plants for cyanate ester in Switzerland. (wordpress.com)
  • Cyanate ester resin is widely used in manufacturing composites for the aerospace & defense industry. (exactitudeconsultancy.com)
  • In addition to that, cyanate ester resin possesses superior characteristics such as lightweight, high stability, high-temperature resistance, and excellent 3-D moldability which makes them more suitable for aerospace applications. (exactitudeconsultancy.com)
  • Can you describe other standard MDI-based polyiso-cyanates and their typical applications? (adhesivesmag.com)
  • IMSEAR at SEARO: In vivo effect of cyanate on serum and eye lens in rat. (who.int)
  • Srivastava VK, Varshney N, Jaiswal A. In vivo effect of cyanate on serum and eye lens in rat. (who.int)
  • If you have more question or need COA,MSDS,test spectra of phenyl cyanate, CAS:1122-85-6 please feel easy to contact with us. (lookchem.com)
  • CE 221 (Cyanate Ester) is a high-performance material with high strength, stiffness, and temperature resistance. (dilabs.cc)
  • FINETECH INDUSTRY LIMITED supplies the phenyl cyanate, CAS:1122-85-6 with the most competitive price and the best quality. (lookchem.com)
  • The company manufactures and supplies various grades of cyanate ester resin products. (wordpress.com)
  • In-vitro incubations of GAP-DH with sugars, cyanate and prednisolone-21-hemisuccinate, all led to significant loss of enzyme activity with time in two buffer systems. (nih.gov)
  • Supplementation of cyanate in rats caused a significant decrease in serum GSH and increase in calcium and phosphate level both in serum and lens. (who.int)
  • Sodium cyanate and potassium cyanate are cyanate salts with the formula NaCN and KCN. (wiseguyreports.com)
  • Potassium cyanate is often preferred to the sodium salt, which is less soluble in water and less readily available in pure form. (wiseguyreports.com)
  • According to Gen Consulting Company, global sodium cyanate and potassium cyanate market is projected to grow at a CAGR of 4.7% during the forecast pe. (wiseguyreports.com)
  • In the decade of chemical innocence following the Second World War, cuddly compounds like potassium cyanate, and even tear gas, were used to sterilize crabgrass seed in residential lawns. (mvtimes.com)
  • The molecular weight of Potassium cyanate (KOCN) is 81.11514. (laboratorynotes.com)
  • Sodium cyanate at concentrations as low as 0.5 mM inhibited the growth of Plasmodium falciparum (FCR-3 Strain) utilizing the Trager-Jensen continuous culture system. (elsevier.com)
  • Pretreatment of red cells with sodium cyanate prior to infection did not alter the intracellular growth of the parasite. (elsevier.com)
  • Our product range includes a wide range of sodium cyanate, acid zinc electroplating chemicals, metal cleaner pk20 and strong wick metal cleaner. (patelplatingchemicals.com)
  • In his effort to make ammonium cyanate, the German chemist Friedrich Wohler earned the title of 'father of organic chemistry' by being the first person to create a chemical previously thought to be produced solely through organic processes. (skeptic.com)
  • Ammonium cyanate is urea," Wohler wrote enthusiastically to the chemist Baron Jöns Jacob Berzelius. (skeptic.com)
  • He reacted silver cyanate (AgOCN) and ammonium chloride (NH 4 Cl), expecting to get ammonium cyanate (NH 4 OCN). (libretexts.org)
  • OCN - (ammonium cyanate) may also contribute to a band at 1470 cm -1 , widely observed in many protostellar infrared sources and which remains up to now poorly explained in numerous ISO-SWS spectra. (aanda.org)
  • 17. Who prepared urea the first time by heating ammonium cyanate? (wittychimp.com)
  • Soil cyanate concentrations were three orders of magnitude lower than ammonium or nitrate. (univie.ac.at)
  • One route involves a reaction between cyanoacetylene and cyanate, and the other reaction begins with cyanoacetalydehyde and urea. (reasons.org)
  • We estimated that in-situ cyanate production rates were similar to those associated with urea fertilizer decomposition, a major source of cyanate in the environment. (univie.ac.at)
  • Lastly, we identified that the hydrolysate of urea, cyanate, was also involved in this pathophysiology. (emory.edu)
  • Urea or cyanate carbamylates mTOR to inhibit the mTORC1-S6K dependent dendritic protein synthesis, inducing impairment of synaptic plasticity in mPFC and depression-like behaviour. (emory.edu)
  • Thiocyanate is analogous to the cyanate ion, [OCN] − , wherein oxygen is replaced by sulfur . (wikibedia.ru)
  • The possible cross reactions indicated by solid-state NMR between cyanate functionalized resin and epoxy functionalized resin have been investigated by using both natural abundance and labeled monofunctional model compounds. (ubc.ca)
  • In addition to the cross reactions of epoxy and cyanate, the reactions of epoxy and the carbamate, which is the major side product for the curing reaction of cyanate resin in solution, have also been investigated, and the mechanism of these reactions discussed. (ubc.ca)
  • Novolac-based Cyanate ester is a non-phthalic and aliphatic resin made from oil, mainly used as the binder in PVC. (dataintelo.com)
  • Ueyama J , Ogawa R, Ota K, Mori Y, Tsuge A, Endo T. Rapid Curing System of a Cyanate Ester Resin/Epoxy Resin with a Thermal Latent Polymeric Hardener Based on a Phenol-Amine Salt. (wjgnet.com)
  • Driven by commercial application and environmental concerns, the paper draws attention on a modified formula of cyanate ester with a common epoxy resin under an optimized ratio. (infona.pl)
  • However, at the increased temperature of distillation, cyanates or organic compounds containing nitrogen can hydrolyze to form ammonia where none previously existed. (coleparmer.com)
  • The case hardening medium is a molten, nitrogen-bearing, fused-salt bath containing either cyanides or cyanates. (lexico.com)
  • Cyanate can serve as a nitrogen and/or carbon source for different microorganisms and as an energy source for autotrophic ammonia oxidizers. (univie.ac.at)
  • We provide evidence that cyanate is actively turned over in soils and represents a small but continuous nitrogen/energy source for soil microbes. (univie.ac.at)
  • Carbonic anhydrase functions to prevent depletion of cellular bicarbonate during cyanate decomposition (the product CO2 can diffuse out of the cell faster than noncatalyzed hydration back to bicarbonate). (nih.gov)
  • Hydroxyls primers promote adhesion between substrates and polyurethanes, iso-cyanates, melamine formaldehydes, phenolic epoxy based coatings. (caplinq.com)
  • The major cross-reaction product is a racemic mixture of enantiomers, which contain an oxazolidinone ring formed by one cyanate molecule and two epoxy molecules. (ubc.ca)
  • However, epoxy consumption lags cyanate consumption in the overall reaction as triazine formation from the cyanate is much faster than the two competing reactions, the cross reaction between cyanate and epoxy, and the self-polymerization of epoxy, under the conditions investigated. (ubc.ca)
  • The cross reaction between cyanate and epoxy is limited. (ubc.ca)
  • Approximately 12% of cross reaction between cyanate and epoxy was found in the overall reaction. (ubc.ca)
  • From the reactions of epoxy and carbamate, several products related to cross reaction between epoxy and cyanate have been isolated and identified. (ubc.ca)
  • This reactivity was extended in chapter 4, in a novel 3-component reaction between haloarenes, isocyanides and cyanates to form 4-aminobenzoxazin-2-ones and 4- aminoquinazolin-2-ones. (researchportal.be)
  • Drumm, Joseph Eugene, "Heterocyclic Syntheses Utilizing Aryl Cyanates" (1984). (wmich.edu)
  • Raymax PU Enamel is a polyurethane finish paint cured with aliphatic ISO CYANATE. (raymaxpaints.com)
  • Here we analyse cyanate concentrations in soils across a range of soil types, land management practices and climates. (univie.ac.at)
  • Addition of cyanate to the culture medium of a delta cynT mutant strain of E. coli (having a nonfunctional carbonic anhydrase) results in depletion of cellular bicarbonate, which leads to inhibition of growth and an inability to catalyze cyanate degradation. (nih.gov)
  • High-purity powder samples of lithium and sodium azide (LiN 3 , NaN 3), cyanate (LiOCN, NaOCN) and hydrogen fluoride (LiFHF, NaFHF) were studied by means of 59.54 keV Compton spectroscopy. (mpg.de)
  • In the title compound, [Co 2 (NCSe) 4 (C 4 H 4 N 2 ) 3 (CH 3 OH) 2 ] n , the Co II ion is coordinated by three N-bonded pyrimidine ligands, two N-bonded seleno-cyanate anions and one O-bonded methanol mol-ecule in an octa-hedral coordination mode. (iucr.org)
  • The asymmetric unit consists of one Co II ion, one pyrimidine ligand, two seleno-cyanate anions and one methanol mol-ecule in general positions as well as one pyrimidine ligand located around a twofold rotation axis. (iucr.org)
  • We determined cyanate consumption in a grassland and rice paddy soil using stable isotope tracer experiments. (univie.ac.at)
  • Cyanate ester (CE) is a type of reactive solvent used as an industrial chemical with applications in adhesives, composite materials, and plastics. (dataintelo.com)
  • Toluene Di Iso Cyanate (TDI) is an organic compound with the formula CH3C6H3(NCO)2. (fsforeigntrade.com)
  • Bisphenol-based type Cyanate Ester is a chloroform derivative that has the property of being soluble in organic solvents. (dataintelo.com)
  • Conclusion We propose that MPO, potentially produced by MDSCs, catalyzes the buildup of cyanate in the TME which diffuses into tumor cells causing homocitrullination of cytoplasmic proteins which are degraded and, in the presence of IFNγ, presented by MHC-II for direct CD4 T-cell recognition. (scancell.co.uk)
  • On the basis of Type, the market is segmented into Bisphenol-based type Cyanate Ester, Novolac-based Type Cyanate Ester and Others. (dataintelo.com)
  • Cyanate Ester has the properties that make it an attractive candidate for use in electron emission displays (EED) because they emit electrons when heated by the applied voltage which is capable of generating images on screens without backlighting required as LCD's require. (dataintelo.com)
  • Wang Z , Li R, Qin Q, Al Hassan M, Dayo AQ, Liu W, Wang J. Curing kinetics and mechanical properties of cyanate ester/hyperbranched benzoxazine copolymers. (wjgnet.com)
  • One began with observations of the interaction of cyanate with amidotransferases, but led to the clarification of the regulatory properties of CTP synthetase and the elucidation of its crystal structure, opening opportunities for drug design. (nih.gov)
  • Toxic MIC (methyl iso-cyanate) gas escaped into the ambient air ofBhopal city from the premises of the UCIL plant and resulted in an unprecedented publichealth emergency, the legacy of which stays on till date to haunt the surviving victimsand their future generations. (cseindia.org)