Chromium
Potassium Dichromate
Chromic acid (H2Cr2O7), dipotassium salt. A compound having bright orange-red crystals and used in dyeing, staining, tanning leather, as bleach, oxidizer, depolarizer for dry cells, etc. Medically it has been used externally as an astringent, antiseptic, and caustic. When taken internally, it is a corrosive poison.
Ochrobactrum
Chromium Isotopes
Tungsten
Tungsten. A metallic element with the atomic symbol W, atomic number 74, and atomic weight 183.85. It is used in many manufacturing applications, including increasing the hardness, toughness, and tensile strength of steel; manufacture of filaments for incandescent light bulbs; and in contact points for automotive and electrical apparatus.
Shewanella
Lead
Drug Contamination
Flavin Mononucleotide
Biodegradation, Environmental
Perissodactyla
Alcaligenes
Oxidation-Reduction
A chemical reaction in which an electron is transferred from one molecule to another. The electron-donating molecule is the reducing agent or reductant; the electron-accepting molecule is the oxidizing agent or oxidant. Reducing and oxidizing agents function as conjugate reductant-oxidant pairs or redox pairs (Lehninger, Principles of Biochemistry, 1982, p471).
Chemical Industry
Spiro Compounds
Drug Antagonism
Pseudomonas putida
Vanadium
Oxidoreductases
The class of all enzymes catalyzing oxidoreduction reactions. The substrate that is oxidized is regarded as a hydrogen donor. The systematic name is based on donor:acceptor oxidoreductase. The recommended name will be dehydrogenase, wherever this is possible; as an alternative, reductase can be used. Oxidase is only used in cases where O2 is the acceptor. (Enzyme Nomenclature, 1992, p9)
Arthrobacter
Chromosomal Instability
Metals, Heavy
Sulfur
Nickel
Glutathione Reductase
Guanosine
Molybdenum
Metals
Escherichia coli K12
Mutagenicity Tests
Riboflavin
Nutritional factor found in milk, eggs, malted barley, liver, kidney, heart, and leafy vegetables. The richest natural source is yeast. It occurs in the free form only in the retina of the eye, in whey, and in urine; its principal forms in tissues and cells are as FLAVIN MONONUCLEOTIDE and FLAVIN-ADENINE DINUCLEOTIDE.
Substance Abuse Detection
Ascorbic Acid
A six carbon compound related to glucose. It is found naturally in citrus fruits and many vegetables. Ascorbic acid is an essential nutrient in human diets, and necessary to maintain connective tissue and bone. Its biologically active form, vitamin C, functions as a reducing agent and coenzyme in several metabolic pathways. Vitamin C is considered an antioxidant.
Singlet Oxygen
NAD
A coenzyme composed of ribosylnicotinamide 5'-diphosphate coupled to adenosine 5'-phosphate by pyrophosphate linkage. It is found widely in nature and is involved in numerous enzymatic reactions in which it serves as an electron carrier by being alternately oxidized (NAD+) and reduced (NADH). (Dorland, 27th ed)
Mutagens
Bronchi
Metal Nanoparticles
Electron Spin Resonance Spectroscopy
A technique applicable to the wide variety of substances which exhibit paramagnetism because of the magnetic moments of unpaired electrons. The spectra are useful for detection and identification, for determination of electron structure, for study of interactions between molecules, and for measurement of nuclear spins and moments. (From McGraw-Hill Encyclopedia of Science and Technology, 7th edition) Electron nuclear double resonance (ENDOR) spectroscopy is a variant of the technique which can give enhanced resolution. Electron spin resonance analysis can now be used in vivo, including imaging applications such as MAGNETIC RESONANCE IMAGING.
Drug Resistance, Bacterial
DNA Damage
Injuries to DNA that introduce deviations from its normal, intact structure and which may, if left unrepaired, result in a MUTATION or a block of DNA REPLICATION. These deviations may be caused by physical or chemical agents and occur by natural or unnatural, introduced circumstances. They include the introduction of illegitimate bases during replication or by deamination or other modification of bases; the loss of a base from the DNA backbone leaving an abasic site; single-strand breaks; double strand breaks; and intrastrand (PYRIMIDINE DIMERS) or interstrand crosslinking. Damage can often be repaired (DNA REPAIR). If the damage is extensive, it can induce APOPTOSIS.
Spectrum Analysis, Raman
Gene Expression Regulation, Bacterial
Gold
Culture Media
Any liquid or solid preparation made specifically for the growth, storage, or transport of microorganisms or other types of cells. The variety of media that exist allow for the culturing of specific microorganisms and cell types, such as differential media, selective media, test media, and defined media. Solid media consist of liquid media that have been solidified with an agent such as AGAR or GELATIN.
Lung
Colorimetry
Cricetinae
Coloring Agents
Glutathione
Carcinogens
Electrophoresis, Capillary
Occupational Exposure
Aneuploidy
The chromosomal constitution of cells which deviate from the normal by the addition or subtraction of CHROMOSOMES, chromosome pairs, or chromosome fragments. In a normally diploid cell (DIPLOIDY) the loss of a chromosome pair is termed nullisomy (symbol: 2N-2), the loss of a single chromosome is MONOSOMY (symbol: 2N-1), the addition of a chromosome pair is tetrasomy (symbol: 2N+2), the addition of a single chromosome is TRISOMY (symbol: 2N+1).
Environmental Monitoring
Regulatory Elements, Transcriptional
Bacillus cereus
Cricetulus
Operon
Radiometry
Plasmids
Centrosome
The cell center, consisting of a pair of CENTRIOLES surrounded by a cloud of amorphous material called the pericentriolar region. During interphase, the centrosome nucleates microtubule outgrowth. The centrosome duplicates and, during mitosis, separates to form the two poles of the mitotic spindle (MITOTIC SPINDLE APPARATUS).
DNA
A deoxyribonucleotide polymer that is the primary genetic material of all cells. Eukaryotic and prokaryotic organisms normally contain DNA in a double-stranded state, yet several important biological processes transiently involve single-stranded regions. DNA, which consists of a polysugar-phosphate backbone possessing projections of purines (adenine and guanine) and pyrimidines (thymine and cytosine), forms a double helix that is held together by hydrogen bonds between these purines and pyrimidines (adenine to thymine and guanine to cytosine).
Solubility
Ultracentrifugation
Hydrogen-Ion Concentration
Escherichia coli
A species of gram-negative, facultatively anaerobic, rod-shaped bacteria (GRAM-NEGATIVE FACULTATIVELY ANAEROBIC RODS) commonly found in the lower part of the intestine of warm-blooded animals. It is usually nonpathogenic, but some strains are known to produce DIARRHEA and pyogenic infections. Pathogenic strains (virotypes) are classified by their specific pathogenic mechanisms such as toxins (ENTEROTOXIGENIC ESCHERICHIA COLI), etc.
Molecular Sequence Data
Descriptions of specific amino acid, carbohydrate, or nucleotide sequences which have appeared in the published literature and/or are deposited in and maintained by databanks such as GENBANK, European Molecular Biology Laboratory (EMBL), National Biomedical Research Foundation (NBRF), or other sequence repositories.
Cell Survival
Zinc
A metallic element of atomic number 30 and atomic weight 65.38. It is a necessary trace element in the diet, forming an essential part of many enzymes, and playing an important role in protein synthesis and in cell division. Zinc deficiency is associated with ANEMIA, short stature, HYPOGONADISM, impaired WOUND HEALING, and geophagia. It is known by the symbol Zn.
Hydrogen Peroxide
Cloning, Molecular
Cell Transformation, Neoplastic
Copper
Biotransformation
The chemical alteration of an exogenous substance by or in a biological system. The alteration may inactivate the compound or it may result in the production of an active metabolite of an inactive parent compound. The alterations may be divided into METABOLIC DETOXICATION, PHASE I and METABOLIC DETOXICATION, PHASE II.
Spectrometry, Mass, Electrospray Ionization
A mass spectrometry technique used for analysis of nonvolatile compounds such as proteins and macromolecules. The technique involves preparing electrically charged droplets from analyte molecules dissolved in solvent. The electrically charged droplets enter a vacuum chamber where the solvent is evaporated. Evaporation of solvent reduces the droplet size, thereby increasing the coulombic repulsion within the droplet. As the charged droplets get smaller, the excess charge within them causes them to disintegrate and release analyte molecules. The volatilized analyte molecules are then analyzed by mass spectrometry.
CHO Cells
Drug Resistance, Microbial
Dose-Response Relationship, Drug
Temperature
Sequence Analysis, DNA
Molecular Structure
Base Sequence
Fibroblasts
Chromatography, High Pressure Liquid
Amino Acid Sequence
Biological Transport
Pseudomonas aeruginosa
DNA-Binding Proteins
Oxidative Stress
Transcription, Genetic
Reproducibility of Results
The statistical reproducibility of measurements (often in a clinical context), including the testing of instrumentation or techniques to obtain reproducible results. The concept includes reproducibility of physiological measurements, which may be used to develop rules to assess probability or prognosis, or response to a stimulus; reproducibility of occurrence of a condition; and reproducibility of experimental results.
Chromate efflux by means of the ChrA chromate resistance protein from Pseudomonas aeruginosa. (1/216)
Everted membrane vesicles of Pseudomonas aeruginosa PAO1 harboring plasmid pCRO616, expressing the ChrA chromate resistance protein, accumulated four times more (51)CrO(4)(2-) than vesicles from plasmidless cells, indicating that a chromate efflux system functions in the resistant strain. Chromate uptake showed saturation kinetics with an apparent K(m) of 0.12 mM chromate and a V(max) of 0. 5 nmol of chromate/min per mg of protein. Uptake of chromate by vesicles was dependent on NADH oxidation and was abolished by energy inhibitors and by the chromate analog sulfate. The mechanism of resistance to chromate determined by ChrA appears to be based on the active efflux of chromate driven by the membrane potential. (+info)Mortality among aircraft manufacturing workers. (2/216)
OBJECTIVES: To evaluate the risk of cancer and other diseases among workers engaged in aircraft manufacturing and potentially exposed to compounds containing chromate, trichloroethylene (TCE), perchloroethylene (PCE), and mixed solvents. METHODS: A retrospective cohort mortality study was conducted of workers employed for at least 1 year at a large aircraft manufacturing facility in California on or after 1 January 1960. The mortality experience of these workers was determined by examination of national, state, and company records to the end of 1996. Standardised mortality ratios (SMRs) were evaluated comparing the observed numbers of deaths among workers with those expected in the general population adjusting for age, sex, race, and calendar year. The SMRs for 40 cause of death categories were computed for the total cohort and for subgroups defined by sex, race, position in the factory, work duration, year of first employment, latency, and broad occupational groups. Factory job titles were classified as to likely use of chemicals, and internal Poisson regression analyses were used to compute mortality risk ratios for categories of years of exposure to chromate, TCE, PCE, and mixed solvents, with unexposed factory workers serving as referents. RESULTS: The study cohort comprised 77,965 workers who accrued nearly 1.9 million person-years of follow up (mean 24.2 years). Mortality follow up, estimated as 99% complete, showed that 20,236 workers had died by 31 December 1996, with cause of death obtained for 98%. Workers experienced low overall mortality (all causes of death SMR 0.83) and low cancer mortality (SMR 0.90). No significant increases in risk were found for any of the 40 specific cause of death categories, whereas for several causes the numbers of deaths were significantly below expectation. Analyses by occupational group and specific job titles showed no remarkable mortality patterns. Factory workers estimated to have been routinely exposed to chromate were not at increased risk of total cancer (SMR 0.93) or of lung cancer (SMR 1.02). Workers routinely exposed to TCE, PCE, or a mixture of solvents also were not at increased risk of total cancer (SMRs 0.86, 1.07, and 0.89, respectively), and the numbers of deaths for specific cancer sites were close to expected values. Slight to moderately increased rates of non-Hodgkin's lymphoma were found among workers exposed to TCE or PCE, but none was significant. A significant increase in testicular cancer was found among those with exposure to mixed solvents, but the excess was based on only six deaths and could not be linked to any particular solvent or job activity. Internal cohort analyses showed no significant trends of increased risk for any cancer with increasing years of exposure to chromate or solvents. CONCLUSIONS: The results from this large scale cohort study of workers followed up for over 3 decades provide no clear evidence that occupational exposures at the aircraft manufacturing factory resulted in increases in the risk of death from cancer or other diseases. Our findings support previous studies of aircraft workers in which cancer risks were generally at or below expected levels. (+info)Purification to homogeneity and characterization of a novel Pseudomonas putida chromate reductase. (3/216)
Cr(VI) (chromate) is a widespread environmental contaminant. Bacterial chromate reductases can convert soluble and toxic chromate to the insoluble and less toxic Cr(III). Bioremediation can therefore be effective in removing chromate from the environment, especially if the bacterial propensity for such removal is enhanced by genetic and biochemical engineering. To clone the chromate reductase-encoding gene, we purified to homogeneity (>600-fold purification) and characterized a novel soluble chromate reductase from Pseudomonas putida, using ammonium sulfate precipitation (55 to 70%), anion-exchange chromatography (DEAE Sepharose CL-6B), chromatofocusing (Polybuffer exchanger 94), and gel filtration (Superose 12 HR 10/30). The enzyme activity was dependent on NADH or NADPH; the temperature and pH optima for chromate reduction were 80 degrees C and 5, respectively; and the K(m) was 374 microM, with a V(max) of 1.72 micromol/min/mg of protein. Sulfate inhibited the enzyme activity noncompetitively. The reductase activity remained virtually unaltered after 30 min of exposure to 50 degrees C; even exposure to higher temperatures did not immediately inactivate the enzyme. X-ray absorption near-edge-structure spectra showed quantitative conversion of chromate to Cr(III) during the enzyme reaction. (+info)Apoptosis and P53 induction in human lung fibroblasts exposed to chromium (VI): effect of ascorbate and tocopherol. (4/216)
Some forms of hexavalent chromium [Cr(VI)] are known to cause damage to respiratory tract tissue, and are thought to be human lung carcinogens. Because Cr(VI) is mutagenic and carcinogenic at doses that evoke cell toxicity, the objective of these experiments was to examine the effect of Cr(VI) on the growth, survival, and mode of cell death in normal human lung fibroblasts (HLF cells). DNA adduct formation was monitored as a marker for bioavailability of genotoxic chromium. We also examined the modulation of these endpoints by vitamins C and E. Long-term Cr(VI) exposures were employed, which decreased clonogenic cell survival by 25% to 95% in a dose-dependent manner. The predominant cellular response to Cr(VI) was growth arrest. We found that Cr(VI) caused up to 20% of HLF cells to undergo apoptosis, and documented apoptotic morphology and the phagocytosis of apoptotic bodies by neighboring cells. P53 levels increased 4- to 6-fold in chromium-treated cells. In contrast with previous studies using CHO cells, the present study using HLFs found that pretreatment with either vitamin C or E did not exhibit a significant effect on Cr-induced apoptosis or clonogenic survival. In addition, pretreatment with vitamin C did not affect the p53 induction observed after chromium treatment. Neither vitamin had any effect on Cr-DNA adduct formation. These data indicate that although pretreatment with vitamin C or E alters the spectrum of cellular and/or genetic lesions induced by chromium(VI), neither vitamin altered the initiation or progression of apoptosis in diploid human lung cells. (+info)Organization-dependent effects of toxic bivalent ions microtubule assembly and glycolysis. (5/216)
The effects of bivalent ions on tubulin dynamics and the upper phase of glycolysis were investigated at different organization levels in vitro. Cu2+, Cd2+, Hg2+ and CrO4(2-) inhibit the tubulin polymerization at an IC50 of 14-24 microM with high cooperativity and also induce microtubule disassembly. The apparent binding constants of the ions to tubulin, estimated by fluorescence quenching, vary between 6 and 28 microM. BIAcore measurements for tubulin-tubulin interaction suggest that the presence of Cu2+ affects neither koff nor kon, but the amount of the bound tubulin. While the inhibitory effect of Cu2+ on tubulin polymerization is partially abolished by cross-linking of microtubules with substoichiometric amounts of phosphofructokinase or decoration of tubules with cytosolic proteins, in the presence of kinase but not with cytosolic proteins the tubules are resistant to CrO4(2-). No inhibitory effect of Cu2+ or CrO4(2-) on microtubule assembly was detected in the MAP-containing cytosolic fraction. Electron microscopy revealed that tubules assembled in the presence of Cu2+ or CrO4(2-) ions contain aggregates of thread-like oligomers that are less conspicuous in the presence of cytosolic proteins. Cu2+, Cd2+, and Hg2+ inhibit the glycolytic flux in the cytosolic fraction characterized at equilibrium by an IC50 of 10-14 microM with high cooperativity. Tubulin diminishes the inhibitory effect of the cations. These data indicate that the responses elicited by the bivalent ions are highly dependent on the supramolecular organization of the systems. (+info)Activation of JNK, p38 and ERK mitogen-activated protein kinases by chromium(VI) is mediated through oxidative stress but does not affect cytotoxicity. (6/216)
In this study we have explored the involvement of oxidative stress in Cr(VI)-induced JNK, p38 and ERK signaling pathways and their effects on Cr(VI) cytotoxicity in human non-small cell lung carcinoma CL3 cells. Exposure to K(2)Cr(2)O(7) markedly activated JNK and p38 and moderately activated ERK in a dose- (10-80 microM) and time-dependent (1-12 h) manner. The activated p38 decreased markedly and rapidly and the activated JNK decreased gradually when Cr(VI) was removed from the medium. Post-incubation of Cr(VI)-treated cells with H(2)O(2) increased the activities of JNK and p38, but not ERK. Co-administering Cr(VI) with 3-amino-1,2, 4-triazole (3AT), a catalase inhibitor, enhanced p38 activation, but did not influence JNK and ERK activation by Cr(VI). Conversely, co-administering Cr(VI) with mannitol, a hydroxyl radical scavenger and a Cr(V) chelator, reduced p38 activation and increased JNK and ERK activation by Cr(VI). These results indicate that p38 activation by Cr(VI) is positively correlated with oxidative stress, while JNK activity can be enhanced by either a quencher (mannitol) or activator (H(2)O(2)) of redox reactions in Cr(VI)-exposed CL3 cells. However, both 3AT and mannitol reduced the cytotoxicity of Cr(VI), but H(2)O(2) did not. The JNK activated by Cr(VI) was decreased (approximately 50%) by expression of a kinase-defective form of MKK7 (MKK7A) but not that of MKK4 (MKK4KR), suggesting that activation of JNK by Cr(VI) is mediated through MKK7. SB202190, a specific inhibitor of p38, markedly decreased JNK but did not change ERK activation by Cr(VI). PD98059, a specific inhibitor of ERK kinases MKK1/2, blocked ERK and p38 but did not alter JNK activation by Cr(VI). Neither the specific kinase inhibitors nor expression of MKK7A altered Cr(VI)-induced cytotoxicity. Together, these results suggest that activation of the JNK, p38 and ERK pathways by Cr(VI) is mediated through diverse redox mechanisms, yet their activation does not correlate with Cr(VI) cytotoxicity. (+info)Cyclosporin A inhibits chromium(VI)-induced apoptosis and mitochondrial cytochrome c release and restores clonogenic survival in CHO cells. (7/216)
A variety of key events in the molecular apoptotic pathway involve the mitochondria. Cyclosporin A (csA) affects the mitochondria by inhibiting the mitochondrial permeability transition (MPT), thereby preventing disruption of the transmembrane potential. The role of the MPT in apoptosis is not fully understood, but inhibition of the MPT may prevent the release of mitochondrial caspase activators, such as cytochrome c (cyt c), into the cytosol. Certain hexavalent chromium [Cr(VI)] compounds are known occupational respiratory tract toxins and carcinogens. We have previously shown that these compounds induce apoptosis as a predominant mode of cell death and that this effect can be observed in cell culture using soluble Cr(VI). We show here that Cr(VI)-induced apoptosis in Chinese hamster ovary (CHO) cells involves disruption of mitochondrial stability. Using a cyt c-specific monoclonal antibody, we observed a dose-dependent release of mitochondrial cyt c in cytosolic extracts of CHO cells exposed to apoptogenic doses of sodium chromate. Co-treatment of these cells with csA inhibited the release of cyt c and abrogated Cr(VI)-induced apoptosis as determined by a reduction in internucleosomal DNA fragmentation. Co-treatment with csA also markedly increased clonogenic survival of Cr(VI)-treated CHO cells. In contrast, the general caspase inhibitor Z-VAD-FMK markedly inhibited most of the morphological and biochemical parameters of apoptosis but did not prevent cyt c release and did not increase clonogenic survival. These results suggest that the MPT plays an important role in the regulation of mitochondrial cyt c release and that this may be a critical point in the apoptotic pathway in which cells are irreversibly committed to death. (+info)Chromate reduction by a pseudomonad isolated from a site contaminated with chromated copper arsenate. (8/216)
A pseudomonad (CRB5) isolated from a decommissioned wood preservation site reduced toxic chromate [Cr(VI)] to an insoluble Cr(III) precipitate under aerobic and anaerobic conditions. CRB5 tolerated up to 520 mg of Cr(VI) liter(-1) and reduced chromate in the presence of copper and arsenate. Under anaerobic conditions it also reduced Co(III) and U(VI), partially internalizing each metal. Metal precipitates were also found on the surface of the outer membrane and (sometimes) on a capsule. The results showed that chromate reduction by CRB5 was mediated by a soluble enzyme that was largely contained in the cytoplasm but also found outside of the cells. The crude reductase activity in the soluble fraction showed a K(m) of 23 mg liter(-1) (437 microM) and a V(max) of 0.98 mg of Cr h(-1) mg of protein(-1) (317 nmol min(-1) mg of protein(-1)). Minor membrane-associated Cr(VI) reduction under anaerobiosis may account for anaerobic reduction of chromate under nongrowth conditions with an organic electron donor present. Chromate reduction under both aerobic and anaerobic conditions may be a detoxification strategy for the bacterium which could be exploited to bioremediate chromate-contaminated or other toxic heavy metal-contaminated environments. (+info)
PARTICULATE CR(VI) TOXICOLOGY IN HUMAN LUNG EPITHELIAL CELLS AND FIBROBLASTS
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Chromic Acid
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Chromic acid - Wikipedia
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Estimating historical occupational exposure to airborne hexavalent chromium in a chromate production plant: 1940-1972 -...
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Pyridinium Chlorochromate
ZINC CHROMATE
(13530-65-9)
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Lead
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Sulfate minerals
Class: chromatesEdit. *07.F Chromates *07.FA Without additional anions: 05 Tarapacaite, 10 Chromatite, 15 Hashemite, 20 ... The chromate and manganate minerals have a similar structure and are often included with the sulfates in mineral classification ...
Molybdenum
Lead molybdate (wulfenite) co-precipitated with lead chromate and lead sulfate is a bright-orange pigment used with ceramics ... Molybdates are weaker oxidants than chromates. They tend to form structurally complex oxyanions by condensation at lower pH ...
Coordination complex
chromate vanadium vanadate copper cuprate iron ferrate [Cu(H2O)6] 2+ → hexaaquacopper(II) ion. [NiCl4]2− → ...
Diphenylcarbazide
Chromates and molybdates produce the same reaction. The major drawback of the test is the deterioration of stock solution of ... Reacting a Diphenylcarbazide with Chromium (VI) compounds, such as chromates or dichromates produces diphenylcarbazone, which ...
Stool guaiac test
Chromate blood loss studies". Am. J. Med. 31 (2): 259-65. doi:10.1016/0002-9343(61)90114-0. PMID 13735596. Norfleet RG (April ...
IUPAC nomenclature of inorganic chemistry
4 chromate. Cr. 2O2−. 7 dichromate. BO3−. 3 borate. AsO3−. 4 arsenate. C. 2O2−. 4 oxalate. CN−. cyanide. SCN−. thiocyanate. MnO ...
Pyrotechnic composition
Barium chromate - used in delay compositions, e.g. in fireworks rockets Lead chromate - used in delay compositions Potassium ... Other possibilities include permanganates, chromates, and some oxides. Generally, the less the oxidizer, the slower the burning ...
Leucobacter aridicollis
nov., a chromate-resistant strain." International Journal of Systematic and Evolutionary Microbiology 61.4 (2011): 956-960. ...
Karin Aurivillius
"Studies on sulphates, selenates and chromates of mercury (II)." Acta Chem. Scand 15.9 (1961): 1932-1938. Aurivillius, K. A. R. ...
Delay composition
... manganese with lead chromate and barium chromate (lead chromate is the principal oxidizer, barium chromate acts as burning rate ... Oxidizers: lead dioxide, iron oxides, barium chromate, lead chromate, tin(IV) oxide, bismuth(III) oxide, barium sulfate (for ... zirconium-nickel alloy with barium chromate and potassium perchlorate. boron with barium chromate [5] "PYROTECHNIC CHEMISTRY". ... modifier, the more of it the slower the reaction) [3] Tungsten Delay Composition: tungsten with barium chromate and potassium ...
Chrome yellow
... is lead(II) chromate (PbCrO4). It occurs naturally as the mineral crocoite but the mineral ore was never used as ... List of colors List of inorganic pigments School bus yellow Kühn, H. and Curran, M., Chrome Yellow and Other Chromate Pigments ... Chrome yellow had been commonly made by mixing solutions of lead nitrate and potassium chromate and filtering off the lead ... After the French chemist Louis Vauquelin discovered the new element chromium in 1797 lead chromate was synthesized in the ...
Langbeinites
Chromate based langbeinites include dicaesium dimanganese chromate. Molybdates include Rb 2Co 2(MoO 4) 3. Potassium members are ... chromate (CrO2− 4), molybdate (MoO2− 4), or tungstates. Although monofluorophosphates are predicted, they have not been ...
Donald Lewis Sparks
Fendorf, S.E.; M.J. Eick; P.R. Grossl; D.L. Sparks (February 1997). "Arsenate and Chromate Retention Mechanisms on Goethite. 1 ...
Dolly Cohen
She makes the grills with chromium chromate. She makes a print and a plat, then sculpts a mold out of alginate. She uses yellow ...
Arsenate mineral
Chromates(VI) (IDs 7.F). *Molybdates, wolframates, niobates(VI) (IDs 7.G-H) ...
Cantonnier Lode
The chromates and copper are rather unusual and pose a problem. Normally chromates are associated with oceanic and ultramafic ... Amongst these galena-derived lead minerals we find chromates (crocoite, embreyite and vauquelinite), arsenates (mimetesite) and ...
Liesegang rings
Chromates, metal hydroxides, carbonates, and sulfides, formed with lead, copper, silver, mercury and cobalt salts are sometimes ... Swami, S.N.; Kant, K. (March 1966). "Liesegang Rings of Copper Chromate in Gelatin Gel". Colloid and Polymer Science. 209 (1): ...
Galvanization
Magalhães, A. A. O; Margarit, I. C. P; Mattos, O. R (1999-07-31). "Electrochemical characterization of chromate coatings on ... Additional electroplating such as a chromate conversion coating may be applied to provide further surface passivation to the ...
Oxidation with chromium(VI) complexes
1) Chromate esters are implicated in these reactions. The chromate ester decomposes to the aldehyde or carbonyl by transfer of ... Acidic reagents such as PCC may cause ionization and recombination of the chromate ester (path A), while the basic reagents ( ... Insights into the mechanism is provided by structure-reactivity, implicating direct epoxidation by the chromate ester. ...
Osmium tetroxide
This is isoelectronic with permanganate and chromate ions. OsO4 is formed slowly when osmium powder reacts with O2 at ambient ...
Shewanella oneidensis
... nitrates and chromates when grown anaerobically. This species is referred to as S. oneidensis MR-1, indicating "manganese ...
Hexavalent chromium
Chromate-dyed textiles or chromate-tanned leather shoes can cause skin sensitivity. In the U.S., the OSHA PEL for airborne ... Yet, soluble chromates are a confirmed carcinogen so it would be prudent to consider all chromates carcinogenic. Chronic ... Both insoluble salts of lead and barium chromates as well as soluble chromates were negative in the implantation model of lung ... Industrial uses of hexavalent chromium compounds include chromate pigments in dyes, paints, inks, and plastics; chromates added ...
Lithium sulfate
... and Chromates. NSRDS. 1975, 56, 2-12 Fordland, T.; Keogh, M. J. The structure of the High temperature Modification of lithium ...
Lead-based paint in the United Kingdom
However lead chromate continued to be used in yellow road markings up to the present day. Its use was supposed to cease on 21 ... Until the early 1970s red, yellow, orange and green lead-based pigments (lead chromate) were added to a limited number of ... "Comment: End of the road for lead chromate pigments?", Highways Magazine, Sevenoaks, England, November 2014. Retrieved on 2015- ...
Iron
It is also used to reduce chromate in cement. It is used to fortify foods and treat iron deficiency anemia. Iron(III) sulfate ...
Glossary of engineering
Chromate Chromate salts contain the chromate anion, CrO2− 4. Dichromate salts contain the dichromate anion, Cr 2O2− 7. They are ... In an aqueous solution, chromate and dichromate ions can be interconvertible. Circular motion In physics, circular motion is a ...
A. C. Matin
"TARGETS OF IMPROVEMENT IN BACTERIAL CHROMATE BIOREMEDIATION" (PDF). "Mechanism of chromate reduction by the Escherichia coli ... and the role of different chromate reductases in minimizing oxidative stress during chromate reduction". Ackerley, D. F.; Barak ... Barak Y, Ackerley DF, Dodge CJ, Banwari L, Alex C, Francis AJ, Matin A (November 2006). "Analysis of novel soluble chromate and ... Matin has also studied bacterial bioremediation of the carcinogens chromate Cr(VI) and uranyl U(VI), which are wide-spread ...
Pyrotechnic heat source
One uses a fuze strip (containing barium chromate and powdered zirconium metal in a ceramic paper) along the edge of the heat ... Another mixture is 46.67 wt.% of titanium, 23.33% of amorphous boron, and about 30% barium chromate. Yet another one is 45 wt ... Another composition in use is zirconium with barium chromate. ... tungsten, 40.5% barium chromate, 14.5% potassium perchlorate, ...
Ammeline
2 C2H4N4 + C2H5N3O2 → 2C3H5N5O + NH3 Ammeline is weakly acidic with pKa ~9. It can form nitrate, sulfate, chromate, and oxalate ...
Sodium dichromate
Dichromate and chromate salts are oxidizing agents. For the tanning of leather, sodium dichromate is first reduced with sulfur ...
Chromic acid and chromates (2005-110) | NIOSH | CDC
ICSC 1770 - POTASSIUM CHROMATE
Repeated or prolonged contact may cause skin sensitization. Repeated or prolonged inhalation may cause asthma. Repeated or prolonged inhalation may cause nasal ulceration. This may result in perforation of the nasal septum. The substance may have effects on the kidneys. This may result in kidney impairment. This substance is carcinogenic to humans. Animal tests show that this substance possibly causes toxicity to human reproduction or development ...
Category:Sodium chromate - Wikimedia Commons
Butyl chromate, tert- (2005-110) | NIOSH | CDC
Barium chromate
The National Institute of Standards and Technology (NIST) uses its best efforts to deliver a high quality copy of the Database and to verify that the data contained therein have been selected on the basis of sound scientific judgment. However, NIST makes no warranties to that effect, and NIST shall not be liable for any damage that may result from errors or omissions in the Database ...
Chromate - Wikipedia
Chromate or chromat, and their derived terms, may refer to: Chromate and dichromate, ions Monochromate, an ion Trichromate, an ... This disambiguation page lists articles associated with the title Chromate. If an internal link led you here, you may wish to ... ion Tetrachromate, an ion Chromate conversion coating, a method for passivating metals Monochromacy (monochromate) having one ...
ICSC 0811 - ZINC CHROMATE
The substance may have effects on the blood, bone marrow, central nervous system, peripheral nervous system and kidneys. Repeated or prolonged inhalation may cause nasal ulceration. This may result in perforation of the nasal septum. Repeated or prolonged contact may cause skin sensitization. This substance is carcinogenic to humans. May cause toxicity to human reproduction or development ...
Calcium chromate - Wikipedia
Calcium chromate is an inorganic compound with the formula CaCrO4, i.e. the chromate salt of calcium. It is a bright yellow ... Calcium chromate is formed from the salt metathesis reaction of sodium chromate and calcium chloride: Na2CrO4 + CaCl2 → CaCrO4 ... The compound is occasionally used as a yellow inorganic pigment, or a corrosion inhibitor as part of the chromate conversion ... Chromium (VI) compounds are carcinogenic to humans (Group 1). "Calcium chromate 10827-V". ntp.niehs.nih.gov. National ...
Sodium Chromate (⁵¹ Cr) Injection - Drugs.com
A list of US medications equivalent to Sodium Chromate (⁵¹ Cr) Injection is available on the Drugs.com website. ... Sodium Chromate (⁵¹ Cr) Injection is a medicine available in a number of countries worldwide. ... Sodium Chromate Cr-51. Sodium Chromate (⁵¹ Cr) Injection (JAN) is known as Sodium Chromate Cr-51 in the US. ... Sodium Chromate (⁵¹ Cr) Injection. Sodium Chromate (⁵¹ Cr) Injection may be available in the countries listed below. ...
Silver chromate 98% | Sigma-Aldrich
Barium chromate - Wikipedia
Using zinc chromate as a standard, it was discovered that barium chromate is both genotoxic and cytotoxic. The cytotoxicity was ... Barium chromate, named barium tetraoxochromate(VI) by the IUPAC, is a yellow sand like powder with the formula BaCrO4. It is a ... Barium chromate has been found to be useful in many capacities. The compound is often used as a carrier for the chromium ions. ... Barium chromate is an oxidizing agent, making it useful as a burn rate modifier in pyrotechnic compositions. It is especially ...
FDA Alert: Mallinckrodt Sodium Chromate Cr-51 Injection
Sodium Chromate Cr-51 Injection is a radiopharmaceutical agent used in a diagnostic test to determine the presence of a disease ... Covidien and FDA announced the recall of one lot [#370-9004] of Mallinckrodt Sodium Chromate Cr-51 Injection as a result of ... Mallinckrodt Sodium Chromate Cr-51 Injection. July 10, 2009. Audience: Hematology and Nuclear Medical healthcare professionals ...
Skip to Properties
Thallium Chromate Tl2CrO4 bulk & research qty manufacturer. Properties, SDS, Applications, Price. Free samples program. Term ... About Thallium Chromate. Thallium Chromate is generally immediately available in most volumes. High purity, submicron and ... Related Applications, Forms & Industries for Thallium Chromate. Chemical Manufacturing. Chromates. Research & Laboratory. ... Adsorption mechanisms of chromate and phosphate on hydrotalcite: A combination of macroscopic and spectroscopic studies. ...
Sodium chromate tetrahydrate M88034
Potassium chromate - Registration Dossier - ECHA
Once released into soil, it is likely that much of the chromium (VI) present will be reduced to chromium (III). Toxicity data are available for chromium (VI) in soil, but it is also likely that in these experiments the majority of the chromium present will be converted to chromium (III) during the test. Chromium (III) has generally been shown to be less toxic than chromium (VI) to soil organisms. For Cr(VI) LC50 and EC50 values were 146 and 792 mg Cr(VI)/kg dry soil. An NOEC value of 32 mg Cr(III)/kg dry soil was observed. ...
Potassium chromate - Registration Dossier - ECHA
Chromate(1-),... - Substance Information - ECHA
Sodium chromate - Simple English Wikipedia, the free encyclopedia
Sodium chromate is a chemical compound composed of sodium ions and chromate ions. It is a bright yellow crystal chemical. It is ... similar to potassium chromate. It is a strong oxidizing agent. It is toxic because it contains chromium in the +6 oxidation ... Retrieved from "https://simple.wikipedia.org/w/index.php?title=Sodium_chromate&oldid=6191181" ...
Potassium chromate - Simple English Wikipedia, the free encyclopedia
It can also be used to make lead chromate for paint. Safety[change , change source]. Potassium chromate is very toxic. It is a ... Potassium chromate is a chemical compound. Its chemical formula is K2CrO4. It has potassium and chromate ions. ... Potassium chromate is found very rarely as a mineral. It dissolves easily in water. It is only found in very dry places. ... It reacts with lead nitrate to make lead chromate, a yellow pigment. ...
Sodium chromate, 98+%, anhydrous, Acros Organics
| Fisher Scientific
Chromate
Determination of Chlorinity of Water without the Use of Chromate Indicator
... was developed in order to improve the old method by alleviating the environmental problems associated with the toxic chromate. ... Determination of Chlorinity of Water without the Use of Chromate Indicator. Tae-Kee Hong. ,1 Myung-Hoon Kim,2 and Myung-Zoon ... Determination of Chlorinity of Water without the Use of Chromate Indicator,. International Journal of Analytical Chemistry,. ... Titration of halides, iodate, chromate, and secondary phosphate," Bunseki Kagaku, vol. 20, p. 522, 1971. View at: Google ...
Chromate | definition of chromate by Medical dictionary
... chromate explanation free. What is chromate? Meaning of chromate medical term. What does chromate mean? ... Looking for online definition of chromate in the Medical Dictionary? ... chro·mate. (krōmāt), A salt of chromic acid.. chromate. /chro·mate/ (kro´māt) any salt of chromic acid.. chromate (CrO4 2-). ... chromate. Also found in: Dictionary, Thesaurus, Encyclopedia, Wikipedia.. Related to chromate: lead chromate, Barium chromate, ...
Reaction mass of Chromate(1-),... - Registration Dossier - ECHA
29 CFR 1910.1000, Table Z-2 Citation Policy for Chromates and Chromic Acids | Occupational Safety and Health Administration
2. Cite violations resulting from employee exposure to zinc chromate and dichromate as well as other chromates and dichromates ... the permissible exposure to lead chromate is, in effect, lowered to less than 25 percent of what the chromates standard (29 CFR ... and would provide greater protection to workers exposed to lead chromate than would be provided under the chromates standard. ... 2. Certain chromate compounds are suspected to be carcinogenic, and since no safe levels of exposure to carcinogenic substance ...
Potassium chromate | definition of potassium chromate by Medical dictionary
What is potassium chromate? Meaning of potassium chromate medical term. What does potassium chromate mean? ... Looking for online definition of potassium chromate in the Medical Dictionary? potassium chromate explanation free. ... potassium chromate. Also found in: Dictionary, Thesaurus, Encyclopedia, Wikipedia. potassium chromate. K2CrO4, carcinogenic ... Potassium chromate , definition of potassium chromate by Medical dictionary https://medical-dictionary.thefreedictionary.com/ ...
Potassium Chromate | Sargent Welch
Dipotassium Chromate, Neutral Potassium chromate
Shelf Life (months): 36
Storage: Blue ... Synonyms: Dipotassium Chromate, Neutral Potassium chromate. Shelf Life (months): 36. Storage: Blue. ... Potassium Chromate Reagent. 100 g. Crystal. Each (100g). Retrieving. Clearance . Act quickly! These items have limited quantity ... Potassium Chromate Reagent. 500 g. Crystal. Each (500g). Retrieving. Clearance . Act quickly! These items have limited quantity ...
Shelf Life (months): 36
Storage: Blue ... Synonyms: Dipotassium Chromate, Neutral Potassium chromate. Shelf Life (months): 36. Storage: Blue. ... Potassium Chromate Reagent. 100 g. Crystal. Each (100g). Retrieving. Clearance . Act quickly! These items have limited quantity ... Potassium Chromate Reagent. 500 g. Crystal. Each (500g). Retrieving. Clearance . Act quickly! These items have limited quantity ...
Potassium chromate | K2CrO4 - PubChem
Chromate Adsorption by Kaolinite
Abstract: Chromate (CrO42-) adsorption was investigated on kaolinite (0.2-2 µm) saturated with NaClO4 over a range of pH. ... Key Words: Adsorption • Chromate • Kaolinite • Sulfate • Surface complex. Clays and Clay Minerals; August 1988 v. 36; no. 4; p ... The adsorption of both chromate and sulfate can be described in terms of a site-binding model of the kaolinite edge, in which ... Chromate Adsorption by Kaolinite. J. M. Zachara, C. E. Cowan, R. L. Schmidt and C. C. Ainsworth ...
Concomitant microbial generation of palladium nanoparticles and hydrogen to immobilize chromate | RTI
SodiumHexavalent chromiumPigmentZincBariumChromic acidIron ChromatePigmentsCarcinogenicInorganicIonsDichromateSaltsCoatingsSulfateResponse to chromateToxicAdsorptionSolubilityCalcium chromateStrontiumParticulateChlorideFormulaCompoundsTrivalentPhosphate2016Aqueous SolutionsExposureBacteriaMicrobialInhibitionLeucobacterPassivatesChemical compoundReduced to chromiumAnionK2CrO4Na2CrO4LemonAnticorrosiveSpeciesReduction
Sodium18
- Sodium Chromate (⁵¹ Cr) Injection may be available in the countries listed below. (drugs.com)
- Sodium Chromate (⁵¹ Cr) Injection (JAN) is known as Sodium Chromate Cr-51 in the US. (drugs.com)
- Alternatively, it can be created by the interaction of barium chloride with sodium chromate . (wikipedia.org)
- It can react with barium hydroxide in the presence of sodium azide to create barium chromate(V) . The reaction releases oxygen and water. (wikipedia.org)
- Covidien and FDA announced the recall of one lot [#370-9004] of Mallinckrodt Sodium Chromate Cr-51 Injection as a result of routine post-market testing in which the product was found to be subpotent. (drugs.com)
- Sodium Chromate Cr-51 Injection is a radiopharmaceutical agent used in a diagnostic test to determine the presence of a disease known as Polycythemia rubra vera. (drugs.com)
- Sodium chromate is a chemical compound composed of sodium ions and chromate ions. (wikipedia.org)
- We offer our customers an excellent quality range of Sodium Bi Chromate. (tradeindia.com)
- We provide independent and unbiased information on manufacturers, prices, production news and consumers for the global and regional (North America, Asia and Europe) market of Sodium chromate. (reportsnreports.com)
- Sodium chromate Cr 51 (Chromitope®) injections were withdrawn from the US market by Bracco Diagnostics on July 15, 2012. (stlukes-stl.com)
- You should not receive this medicine if you have had an allergic reaction to sodium chromate Cr 51. (stlukes-stl.com)
- This study covers the world outlook for chromium compounds excluding sodium bichromate and sodium chromate across more than 190 countries. (marketresearch.com)
- This study gives, however, my estimates for the worldwide latent demand, or the P.I.E., for chromium compounds excluding sodium bichromate and sodium chromate. (marketresearch.com)
- This study investigated the performance of potassium dichromate and potassium chromate inhibitors on the corrosion of steel rebar in concrete partially immersed in sulfuric acid and sodium chloride medium. (springer.com)
- In the inhibitor concentrations used, the statistically analyzed experimental results identified 0.145 M potassium chromate as exhibiting the best inhibiting quality in sulfuric acid whereas the synergetic admixture of 0.032 M potassium dichromate and 0.097 M potassium chromate was predicted as showing the lowest probability of corrosion risk in sodium chloride solution. (springer.com)
- Afolabi, A.S.: Synergistic Inhibition of Potassium Chromate and Sodium Nitrite on Mild Steel in Chloride Sulphide Media (2008). (springer.com)
- Other properties identical to those of unlabeled sodium chromate. (drugfuture.com)
- Iron III Nitrate with Sodium Chromate. (rebelwithoutacarproductions.com)
Hexavalent chromium4
- However, the argentometry with the Mohr or Mohr-Knudsen method [ 1 , 5 , 7 ], which is based on appearance of the red color of silver chromate precipitate at the equivalence point raises concerns with environment problems because of the toxicity of the chromate with a hexavalent chromium. (hindawi.com)
- Over the years, the most widely used conversion coatings for magnesium alloys have been based on hexavalent chromium, also known as hex-chrome or chromate. (energy.gov)
- Metrohm Process Analytics is pleased to present a solution for the online monitoring of chromate (hexavalent chromium) in industrial wastewater streams. (labmate-online.com)
- López-Bucio, José 2014-06-14 00:00:00 Soil contamination by hexavalent chromium [Cr(VI) or chromate] due to anthropogenic activities has become an increasingly important environmental problem. (deepdyve.com)
Pigment7
- The compound is occasionally used as a pigment, but this usage is limited due to the very toxic and carcinogenic nature of haxavalent chromium compounds such as chromate salts. (wikipedia.org)
- The compound is occasionally used as a yellow inorganic pigment, or a corrosion inhibitor as part of the chromate conversion coating procedure. (wikipedia.org)
- Barium chromate is used as a corrosion inhibitive pigment when zinc-alloy electroplating surfaces. (wikipedia.org)
- The pigment known as lemon yellow often contained barium chromate mixed with lead sulfate. (wikipedia.org)
- It reacts with lead nitrate to make lead chromate , a yellow pigment. (wikipedia.org)
- Major studies pinpointing Cr(VI) as a human lung carcinogen have been performed on workers involved in chromate production, chromate pigment production and chromium plating. (thefreedictionary.com)
- Chromium (VI) compounds are … Iron(III) chromate, a yellow powder used as a pigment in paints, contains 24.3% Fe, 33.9% Cr, and 41.8% O. It is commonly presents in its hydrated … Use the Common Ion Table to find the formula and charge for the sulfate ion. (rebelwithoutacarproductions.com)
Zinc8
- It still has the telltale green of aviation zinc chromate paint on one side. (thefreedictionary.com)
- 2. Cite violations resulting from employee exposure to zinc chromate and dichromate as well as other chromates and dichromates under 29 CFR 1910.1000, Table Z-2 (PEL 0.1 mg/m3). (osha.gov)
- E-Chrome Ultra is a high-quality line of corrosion-inhibiting chromates for zinc that produces exceptional colors, superior salt spray protection, and fade resistance. (epi.com)
- While it may be somewhat confusing in that it is sometimes used with another finish when masked off, such as either hardcoat or sulfuric anodize, but when we say secondary post treatment it is meant as a chromate over another finish such as Zinc or Cadmium. (anoplate.com)
- Chromates are what give the color options such as yellow, black, or olive drab to Zinc or Cadmium finishes. (anoplate.com)
- IES pigments were originally developed and introduced in the 1980s (8), (9) as nonhazardous, environmentally compliant alternatives to traditional anticorrosive pigments, such as chromates and lead pigments, as well as the existing zinc phosphate anticorrosive pigments. (freethesaurus.com)
- Animal studies illustrate that slightly soluble and highly insoluble Cr(VI) particulates such as chromates of zinc, lead, strontium, barium, and sintered calcium consistently induced a tumor response, albeit with variable efficacy (reviewed by IARC 1990). (freethesaurus.com)
- SrCrO 4 (203.612) Zinc Chromate … Properties. (rebelwithoutacarproductions.com)
Barium16
- Barium chromate , named barium tetraoxochromate(VI) by the IUPAC , is a yellow sand like powder with the formula BaCrO 4 . (wikipedia.org)
- The first naturally occurring barium chromate was found in the country of Jordan. (wikipedia.org)
- The hashemite crystals are not composed of pure barium chromate but instead contain some small sulfur content as well. (wikipedia.org)
- It can be synthesized by reacting barium hydroxide or barium chloride with potassium chromate . (wikipedia.org)
- Barium chromate has been found to be useful in many capacities. (wikipedia.org)
- One such case is the use of barium chromate as a sulfate scavenger in chromium electroplating baths. (wikipedia.org)
- Adding barium chromate enhances the life of the bath by adding to the chromic acid concentration. (wikipedia.org)
- Barium chromate is an oxidizing agent, making it useful as a burn rate modifier in pyrotechnic compositions. (wikipedia.org)
- When mixed with solid fumaric acid , barium chromate can be used in the removal of impurities and residual moisture from organic dry-cleaning solvents or from petroleum fuels. (wikipedia.org)
- Barium chromate is also used in the composition of a catalyst for alkane dehydrogenation. (wikipedia.org)
- Barium chromate (CAS 10294-40-3) Market Research Report 2018 aims at providing comprehensive data on barium chromate market globally and regionally (Europe, Asia, North America, Latin America etc. (marketpublishers.com)
- It captures barium chromate market trends, pays close attention to barium chromate manufacturers and names suppliers. (marketpublishers.com)
- Besides, the report provides barium chromate prices in regional markets. (marketpublishers.com)
- In addition to the above the report determines barium chromate consumers. (marketpublishers.com)
- Barium chromate (CAS 10294-40-3) Market Research Report 2018 contents were worked out and placed on the website in February, 2018. (marketpublishers.com)
- Please note that Barium chromate (CAS 10294-40-3) Market Research Report 2018 is a half ready publication and contents are subject to change. (marketpublishers.com)
Chromic acid2
- This instruction provides guidance for citing violations resulting from employee exposure to chromates, dichromates and chromic acid mist. (osha.gov)
- 1. OSHA has been citing all violations resulting from employee exposure to chromic acid mist, or dust from chromates and dichromates under 29 CFR 1910.1000, Table Z-2. (osha.gov)
Iron Chromate1
- Iron Chromate is generally immediately available in most volumes, including bulk quantities.American Elements can produce materials to custom specifications by request, in addition to custom compositions for commercial and research applications and new proprietary technologies. (rebelwithoutacarproductions.com)
Pigments4
- thus, declines in chromate pigments will slow as they are replaced by various organic and complex inorganic types. (thefreedictionary.com)
- Four years ago, the EU Commission granted the Canada-based paint manufacturer Dominion Colour Corporation (DCC) authorisation to use toxic lead chromates in red and yellow paint pigments. (chemsec.org)
- LINK: [http://www.cdc.gov/niosh/ipcsneng/neng0003.html International Chemical Safety Card] == Additional Information == H. Kuhn, M.Curran, "Chrome Yellow and Other Chromate Pigments", ''Artists Pigments, Volume 1, R. Feller (ed. (mfa.org)
- Chromate is useful in many industries - in the production of pigments and dyes for textiles, paints and colored glass, anodized or plated onto metals for surface finishing applications, as an oxidizing agent to tan and process leather, and as a corrosion inhibitor in industrial cooling towers. (labmate-online.com)
Carcinogenic4
- 2. Certain chromate compounds are suspected to be carcinogenic, and since no safe levels of exposure to carcinogenic substance have been demonstrated, it has been OSHA's policy to attempt to minimize worker exposure to them to the greatest extent feasible. (osha.gov)
- Fourier transform infrared and Raman microspectroscopy, as well as other techniques have been used to test a putative, non-carcinogenic metal coating material based on molybdate to replace chromate for corrosion protection of aluminium in the automobile, aerospace and engineering industries. (spectroscopynow.com)
- Carcinogenic chromates are now banned in consumer and automotive products, but their use in the defence and aerospace industries is exempted in the absence of viable alternatives. (spectroscopynow.com)
- The particulate form, for example lead chromate, has been determined to be the most toxic and carcinogenic form. (aacrjournals.org)
Inorganic3
- Calcium chromate is an inorganic compound with the formula CaCrO4, i.e. the chromate salt of calcium. (wikipedia.org)
- By contrast, the chromate-responsive proteome derived under defined minimal growth conditions was characterized predominantly by up-regulated proteins related to cell envelope biogenesis, inorganic ion transport, and motility. (biomedcentral.com)
- Comparative analysis indicated that the core molecular response to chromate, irrespective of the nutritional conditions tested, comprised seven up-regulated proteins belonging to six different functional categories including transcription, inorganic ion transport/metabolism, and amino acid transport/metabolism. (biomedcentral.com)
Ions1
- It has potassium and chromate ions . (wikipedia.org)
Dichromate2
- 1. Cite violations resulting from employee exposure to lead chromate and dichromate under the lead standard, 29 CFR 1910.1025. (osha.gov)
- However, the overall probabilistic results rated potassium chromate as the best inhibitor compared to potassium dichromate in most of the other concentrations investigated in the study, especially in concrete structures exposed to saline environments. (springer.com)
Salts2
- Most of be emphasis is centered on the traditional metal oxides, such as chromate or permanganate salts, in spite of the hazards and waste management concerns associate with them. (thefreedictionary.com)
- Exposure to chromate salts has been reported to produce skin and nasal ulcerations with continued exposure leading to perforation of the nasal septa. (espimetals.com)
Coatings11
- The coating could replace chromate coatings, which have been used in aerospace and other applications for more than half a century. (spectroscopynow.com)
- Materials scientists have been attempting to find ways to replace chromate coatings with non-toxic alternatives since the 1980s. (spectroscopynow.com)
- The main obstacle until now for finding a viable replacement is that chromate coatings can "self heal" if they are damaged or scratched whereas no previous alternative has had that property. (spectroscopynow.com)
- Now, Chidambaram and colleagues have demonstrated how a new molybdate-based formulation can perform comparably well to chromate coatings and undergo self-healing. (spectroscopynow.com)
- The objective of this research project was to develop a chromium-free zeolite coating that has comparable thickness to chromate conversion and anodization coatings and equivalent or superior performance in coating adhesion, corrosion protection, abrasion resistance, and paint adhesion. (epa.gov)
- We have shown that high-silica zeolite ZSM-5 coatings on aluminum alloy 2024-T3 (AA-2024-T3) and other metals offer remarkably better corrosion resistance than chromate conversion coating and anodization coating in strong acids and bases (0.5 M NaOH), and pitting aggressive environments (Cheng, et. (epa.gov)
- Although chromate free conversion coatings are available, the corrosion resistance they offer, in the absence of the ability to self-heal, does not match that of the CCC. (energy.gov)
- Describes methods for the determination of: - the presence of colourless chromate conversion coatings. (saiglobal.com)
- For ease of explanation we are going to further sub-divide this category into steel conversion coatings, chromate conversion coatings, and anodize which is covered elsewhere. (anoplate.com)
- Chromate conversion coatings are a varying group that can be done as a stand alone finish, used by itself, or as a secondary post finish treatment, used over a metal plating. (anoplate.com)
- AnoChem TCP replaces hexavalent chromate conversion coatings used for aluminum alloys without sacrificing corrosion resistance, electrical contact resistance or organic topcoat adhesion properties while meeting regulatory requirements of ROHS, WEEE and ELV legislation. (anoplate.com)
Sulfate1
- The adsorption of both chromate and sulfate can be described in terms of a site-binding model of the kaolinite edge, in which the edge is viewed as composite layers of Al and Si oxide. (clays.org)
Response to chromate2
Toxic4
- Potassium chromate is very toxic. (wikipedia.org)
- A new method for determining chlorinity of water was developed in order to improve the old method by alleviating the environmental problems associated with the toxic chromate. (hindawi.com)
- Moreover, chromate is reduced intracellularly to the less-toxic Cr(III). (nih.gov)
- IMPORTANCE Chromate is a highly toxic oxyanion. (nih.gov)
Adsorption7
- Chromate (CrO 4 2- ) adsorption was investigated on kaolinite (0.2-2 µm) saturated with NaClO 4 over a range of pH. (clays.org)
- Adsorption increased with decreasing pH because of protonation of chromate and/or variable charge sites on kaolinite. (clays.org)
- Chromate adsorption at different sorbate and sorbent concentrations increased below the pH zpc for the kaolinite edge, suggesting the formation of weak surface complexes. (clays.org)
- Surface complexation constants for CrO 4 2- on kaolinite were similar to those for alumina, pointing to the importance of Al-OH edge sites in chromate adsorption. (clays.org)
- Different models were tested to access the sorption maxima and to probe into the chromate adsorption mechanism. (thefreelibrary.com)
- Though, the adsorption of chromate on carbon materials has been studied previously. (thefreelibrary.com)
- The present study not only focuses to probe into the mechanism of chromate adsorption onto activate carbon but also to evaluate the thermodynamic feasibility of the process. (thefreelibrary.com)
Solubility3
- a property which is enhanced by the high solubility of chromate and its affinity for leaching. (labmate-online.com)
- What is the solubility (in mol/L) of silver chromate in 1.4 M potassium chromate aqueous solution? (jiskha.com)
- A saturated solution of lead chromate, pbcro4 has a lead ion concentration of 1.4 x 10^-7 m. what is the value of the solubility product ksp for lead chromate? (jiskha.com)
Calcium chromate3
- Solid calcium chromate will react explosively with hydrazine. (wikipedia.org)
- http://www.mindat.org Occupational Safety And Health Guideline For Calcium Chromate Archived August 8, 2007, at the Wayback Machine IARC (2012) [17-24 March 2009]. (wikipedia.org)
- Calcium chromate 10827-V". ntp.niehs.nih.gov. (wikipedia.org)
Strontium1
- Anti-corrosive, strontium chromate primer semi matt green, used on its own, or as a base for use with either the IP3 or IP9064 epoxy or IP6 polyurethane ranges. (indestructible.co.uk)
Particulate2
- CONCLUSIONS: These data illustrate that repetitive exposure to particulate chromate induces chronic injury and an inflammatory microenvironment that may promote Cr(VI) carcinogenesis. (thefreedictionary.com)
- Studies have not been done of particulate Cr(VI) after oral exposure, but given the low pH of the stomach, it is likely that these exposures would ultimately become exposures to soluble Cr(VI) as particulate chromates dissolve at low pH. (freethesaurus.com)
Chloride4
- The analytical methods recommended in the Standard Method for the Examination of Water and Waste Water [ 15 ] and the Official and Standardized Method of Analysis [ 16 ] are: (1) argentometric titration with silver nitrate using potassium chromate indicator, (2) titration with mercuric nitrate using s-diphenylcarbazone indicator, and (3) potentiometric titration using a glass and a silver-silver chloride electrode. (hindawi.com)
- The suspended NH3 and hydrogen chloride can recombine in the atmosphere and form small particles of ammonium chloride which can settle on and contaminate the chromate bath or the water used for quenching stages as well as all galvanized pieces lying on the floor. (thefreedictionary.com)
- as long as there is chloride present, any silver chromate that forms will disappear as the silver gets taken out of solution by the silver chloride. (rebelwithoutacarproductions.com)
- Potassium Chromate Indicator for Silver - Chloride Titrations. (suratchemical.com)
Formula3
- The chemical formula for iron (III) chromate is Fe2(CrO4)3. (rebelwithoutacarproductions.com)
- Safety … Home / Uncategorized / iron iii chromate formula. (rebelwithoutacarproductions.com)
- Solution for Which represents the formula for iron (III) chromate? (rebelwithoutacarproductions.com)
Compounds1
- From the results we have so far, I am certain that we can develop a viable treatment for former industrial sites where chromate compounds are a problem," said Dr Stewart. (thefreedictionary.com)
Trivalent7
- Are Trivalent Chromates really Hexavalent Chromates? (epi.com)
- Are Trivalent Chromates really Hexavalent Chromates after Salt Spray Testing? (epi.com)
- The latest Plating Surface Finishing magazine has an article by Tom Rochester that states that trivalent chromates under salt spray testing result in hexavalent chrome when using the diphenyl carbizide indicator test. (epi.com)
- Do they certify that the salt spray cabinet has no hexavalent chrome in that cabinet while they are doing salt spray of trivalent chromates? (epi.com)
- I remember one time we were doing testing on a trivalent chromate and we put some panels in and my chemist Mark Kulas informed me that we had an unusual failure after 24 hours. (epi.com)
- EPi has created two product lines for trivalent chromates that will help a variety of metal pass salt spray tests: E-Chrome Ultra and E-PASSivate. (epi.com)
- EPi's environmentally friendly lines of trivalent yellow chromate and trivalent blue chromate processes meet many European Union initiatives. (epi.com)
Phosphate1
- All units are phosphate washed, caulked with polyurethane sealant to prevent rust in seams, and painted with an epoxy primer using an acrylic enamel paint that is lead and chromate free. (thefreedictionary.com)
20161
- The report then estimates 2016-2021 market development trends of Potassium Chromate. (researchbeam.com)
Aqueous Solutions2
- Anion Exchange Sorption of Chromate from Aqueous Solutions by Activated Carbon. (thefreelibrary.com)
- Silver chromate is sparingly soluble in aqueous solutions. (jiskha.com)
Exposure4
- occurs accidentally as a result of exposure to chromate residues. (thefreedictionary.com)
- 3. The comprehensive standard for occupational exposure to lead is also applicable to lead chromate, and would provide greater protection to workers exposed to lead chromate than would be provided under the chromates standard. (osha.gov)
- By instructing compliance officers to cite violations under the new lead standard, 29 CFR 1910.1025 (PEL 50 ug/m3), the permissible exposure to lead chromate is, in effect, lowered to less than 25 percent of what the chromates standard (29 CFR 1910.1000, PEL 0.1mg/m3) would allow. (osha.gov)
- protective provisions not found in the provisions applicable to chromates, such as exposure monitoring, medical surveillance, medical removal protection, and worker training and education. (osha.gov)
Bacteria2
- To further understand the mechanisms developed by these bacteria to tolerate chromate, a proteomic analysis was performed to identify proteins involved in chromate stress response of Staphylococcus saprophyticus isolated from a fly ash dumping site. (ajol.info)
- Pure culture of bacteria using chromates and bichromates as hydrogen acceptors during development under anaerobic conditions]. (semanticscholar.org)
Microbial3
- Our results suggest a novel process where the in situ microbial production of hydrogen is directly coupled to the catalytic bio-Pd mediated reduction of chromate. (rti.org)
- The extreme chromate tolerance and the unique set of resistance factors suggest the use of L. chromiiresistens as a new model organism to study microbial chromate resistance. (nih.gov)
- These proteins might potentially serve as indicators of chromate stress in natural microbial communities. (biomedcentral.com)
Inhibition1
- Inhibition of biofilm formation leads to drastically decreased chromate tolerance. (nih.gov)
Leucobacter2
- Leucobacter chromiiresistens is a highly chromate-resistant strain, tolerating chromate concentrations in LB medium of up to 400 mM. (nih.gov)
- Reduction of high concentrations of chromate by Leucobacter sp. (semanticscholar.org)
Passivates1
- EPi offers high-quality chromates and passivates for a variety of metals. (epi.com)
Chemical compound1
- Potassium chromate is a chemical compound . (wikipedia.org)
Reduced to chromium1
- As they age, the small lead chromate particles are completely reduced to chromium oxide, while larger ones maintain a core of lead chromate that is coated in a shell of chromium oxide. (freethesaurus.com)
Anion2
- It was concluded that the anion exchange sorption was involved in removing the chromate anion from the aqueous system into the surface of activated carbon. (thefreelibrary.com)
- Activated carbon is a good choice to be used for the decontamination of water from chromate anion because of its high surface area and excellent performance as compared to its counterparts reported in the literature [20]. (thefreelibrary.com)
K2CrO41
- This series shows a progression as potassium chromate (K2CrO4) is added drop by drop to a test tube containing silver nitrate (AgNO3). (sciencephoto.com)
Na2CrO41
- calculate the minimum concentration of ag+ ion that must be added to (or built up in) a 0.140 m Na2CrO4 solution in order to initiate a precipitation of silver chromate. (jiskha.com)
Lemon1
- Lead chromate can range in shade from lemon yellow to orange depending on its particle size and hydration state. (mfa.org)
Anticorrosive1
- Specifies requirements for solvent-borne, lead and chromate free, anticorrosive metal primer applied to ships and equipment. (saiglobal.com)
Species3
- citation needed] All applications suffer from the high toxicity of chromium(VI) species to humans, with chromates listed as IARC Group 1 carcinogens while also very corrosive (e.g. capable of producing permanent eye damage) and genotoxic. (wikipedia.org)
- The chromate species is of particular concern because of its appreciable migratory potential and the resultant threat to groundwater supplies. (thefreedictionary.com)
- Staphylococci species resistant to chromate were previously isolated from a fly ash dumping site. (ajol.info)
Reduction1
- Potential detoxifying microorganisms are often not sufficient in their resistance characteristics to effectively perform, e.g., chromate reduction or biosorption. (nih.gov)