Compounds based on a seven-membered ring fused to a five-membered ring. Heat can rearrange them to NAPHTHALENES which have two fused six-membered rings. They are similar to guaiazulenes which are SESQUITERPENES with a six-membered ring fused to a five-membered ring.
Naphthalene rings which contain two ketone moieties in any position. They can be substituted in any position except at the ketone groups.
Substances intended to be applied to the human body for cleansing, beautifying, promoting attractiveness, or altering the appearance without affecting the body's structure or functions. Included in this definition are skin creams, lotions, perfumes, lipsticks, fingernail polishes, eye and facial makeup preparations, permanent waves, hair colors, toothpastes, and deodorants, as well as any material intended for use as a component of a cosmetic product. (U.S. Food & Drug Administration Center for Food Safety & Applied Nutrition Office of Cosmetics Fact Sheet (web page) Feb 1995)
Liquid formulations for the nutrition of infants that can substitute for BREAST MILK.
The region of DNA which borders the 3' end of a transcription unit and where a variety of regulatory sequences are located.
A syndrome characterized by the acute onset of unilateral FACIAL PARALYSIS which progresses over a 2-5 day period. Weakness of the orbicularis oculi muscle and resulting incomplete eye closure may be associated with corneal injury. Pain behind the ear often precedes the onset of paralysis. This condition may be associated with HERPESVIRUS 1, HUMAN infection of the facial nerve. (Adams et al., Principles of Neurology, 6th ed, p1376)
Stable elementary particles having the smallest known negative charge, present in all elements; also called negatrons. Positively charged electrons are called positrons. The numbers, energies and arrangement of electrons around atomic nuclei determine the chemical identities of elements. Beams of electrons are called CATHODE RAYS.
The theory that the radiation and absorption of energy take place in definite quantities called quanta (E) which vary in size and are defined by the equation E=hv in which h is Planck's constant and v is the frequency of the radiation.
A group of adenine ribonucleotides in which the phosphate residues of each adenine ribonucleotide act as bridges in forming diester linkages between the ribose moieties.
A molecule that binds to another molecule, used especially to refer to a small molecule that binds specifically to a larger molecule, e.g., an antigen binding to an antibody, a hormone or neurotransmitter binding to a receptor, or a substrate or allosteric effector binding to an enzyme. Ligands are also molecules that donate or accept a pair of electrons to form a coordinate covalent bond with the central metal atom of a coordination complex. (From Dorland, 27th ed)
Colorless, odorless crystals that are used extensively in research laboratories for the preparation of polyacrylamide gels for electrophoresis and in organic synthesis, and polymerization. Some of its polymers are used in sewage and wastewater treatment, permanent press fabrics, and as soil conditioning agents.
Compounds formed by the joining of smaller, usually repeating, units linked by covalent bonds. These compounds often form large macromolecules (e.g., BIOPOLYMERS; PLASTICS).
Nanometer-sized particles that are nanoscale in three dimensions. They include nanocrystaline materials; NANOCAPSULES; METAL NANOPARTICLES; DENDRIMERS, and QUANTUM DOTS. The uses of nanoparticles include DRUG DELIVERY SYSTEMS and cancer targeting and imaging.
A change of a substance from one form or state to another.
A yellow metallic element with the atomic symbol Au, atomic number 79, and atomic weight 197. It is used in jewelry, goldplating of other metals, as currency, and in dental restoration. Many of its clinical applications, such as ANTIRHEUMATIC AGENTS, are in the form of its salts.
Common name for several daisy-like plants (MATRICARIA; TRIPLEUROSPERMUM; ANTHEMIS; CHAMAEMELUM) native to Europe and Western Asia, now naturalized in the United States and Australia.
Resin from wood of certain species of GUAIACUM. It is used as clinical reagent for occult blood.
Disorders of connective tissue, especially the joints and related structures, characterized by inflammation, degeneration, or metabolic derangement.
A class of disabling primary headache disorders, characterized by recurrent unilateral pulsatile headaches. The two major subtypes are common migraine (without aura) and classic migraine (with aura or neurological symptoms). (International Classification of Headache Disorders, 2nd ed. Cephalalgia 2004: suppl 1)
A genus in the family Myrtaceae sometimes known as "stoppers" in FOLK MEDICINE. Many species of the genus SYZYGIUM have synonymous names that begin with the Eugenia genus name.
The study of chemical changes resulting from electrical action and electrical activity resulting from chemical changes.
The location of the atoms, groups or ions relative to one another in a molecule, as well as the number, type and location of covalent bonds.
A mixture of liquid hydrocarbons obtained from petroleum. It is used as laxative, lubricant, ointment base, and emollient.
The application of drug preparations to the surfaces of the body, especially the skin (ADMINISTRATION, CUTANEOUS) or mucous membranes. This method of treatment is used to avoid systemic side effects when high doses are required at a localized area or as an alternative systemic administration route, to avoid hepatic processing for example.
Devices designed to provide personal protection against injury to individuals exposed to hazards in industry, sports, aviation, or daily activities.
An exocellulase with specificity for a variety of beta-D-glycoside substrates. It catalyzes the hydrolysis of terminal non-reducing residues in beta-D-glucosides with release of GLUCOSE.

Sex-related differences in urinary excretion of egualen sodium in rats. (1/33)

Egualen sodium (sodium 3-ethyl-7-isopropyl-1-azulenesulfonate 1/3 hydrate) is a new antiulcer drug. There has been no difference observed in absorption between male and female rats, the relative amount of metabolites in male plasma has been higher than that in females, and the excretion ratios of metabolites in males have been significantly higher than those in females. However, the plasma concentration profile of total radioactivity in males has been higher than that in females. To clarify this discrepancy, the renal clearances and plasma concentrations of the unchanged drug and its metabolites were determined. The renal clearance of the unchanged drug in males was 21 times lower than that in females, and the urinary excretions in males and females were 2.1 and 39.5% of dose, respectively. This indicates that the major factor in the sex-related difference observed in the plasma concentration of total radioactivity is due to the difference in the renal clearance of the unchanged drug between the sexes. The results of treatments with probenecid in normal and gonadectomized rats revealed that egualen sodium was mainly excreted into urine by secretion through the renal tubule. Furthermore, the results of treatments with testosterone in rats revealed that the excretion of egualen sodium was highly affected by androgens. These facts indicated that the sex-related difference observed in the plasma concentration of total radioactivity can be attributed to the inhibition of renal tubular secretion of the unchanged drug by androgens. This is the first example of sex-related differences in both metabolism and excretion.  (+info)

Bicarbonate enhances peroxidase activity of Cu,Zn-superoxide dismutase. Role of carbonate anion radical and scavenging of carbonate anion radical by metalloporphyrin antioxidant enzyme mimetics. (2/33)

Much evidence exists for the increased peroxidase activity of copper, zinc superoxide dismutase (SOD1) in oxidant-induced diseases. In this study, we measured the peroxidase activity of SOD1 by monitoring the oxidation of dichlorodihydrofluorescein (DCFH) to dichlorofluorescein (DCF). Bicarbonate dramatically enhanced DCFH oxidation to DCF in a SOD1/H(2)O(2)/DCFH system. Peroxidase activity could be measured at a lower H(2)O(2) concentration ( approximately 1 microm). We propose that DCFH oxidation to DCF is a sensitive index for measuring the peroxidase activity of SOD1 and familial amyotrophic lateral sclerosis SOD1 mutants and that the carbonate radical anion (CO(3)) is responsible for oxidation of DCFH to DCF in the SOD1/H(2)O(2)/bicarbonate system. Bicarbonate enhanced H(2)O(2)-dependent oxidation of DCFH to DCF by spinal cord extracts of transgenic mice expressing SOD1(G93A). The SOD1/H(2)O(2)/HCO(3)(-)-dependent oxidation was mimicked by photolysis of an inorganic cobalt carbonato complex that generates CO(3). Metalloporphyrin antioxidants that are usually considered as SOD1 mimetic or peroxynitrite dismutase effectively scavenged the CO(3) radical. Implications of this reaction as a plausible protective mechanism in inflammatory cellular damage induced by peroxynitrite are discussed.  (+info)

Synthesis of new azulene derivatives and study of their effect on lipid peroxidation and lipoxygenase activity. (3/33)

The relationship between free radicals and acute or chronic inflammation has been well established. We have previously reported the significant antioxidant activity of the natural azulene derivatives chamazulene and guaiazulene. Furthermore, some synthetic azulene analogues have been found to possess anti-inflammatory activity. In this investigation we report the synthesis of five 3-alkyl or 3-(hydroxy)alkylazulene-1-carboxylic acids and esters, from tropolone, via the corresponding furanone. The synthesised compounds were tested for their effect on the peroxidation of rat hepatic microsomal membrane lipids, applying the 2-thiobarbituric acid test. Their anti-inflammatory activity was evaluated in vitro by the offered inhibition of soybean lipoxygenase. All the tested molecules were found to inhibit lipid peroxidation by 100% at 1 mM. They were also found to considerably inhibit lipoxygenase activity. The above results are discussed in relation to the structure and physicochemical properties of the examined azulene derivatives.  (+info)

Cardiovascular effects of orally administered HNS-32, an originally synthesized azulene-1-carboxamidine derivative, assessed in the in vivo rat model. (4/33)

HNS-32, an azulene-1-carboxamidine derivative, is an originally synthesized antiarrhythmic compound. Its cardiovascular effects after oral administration (1-10 mg/kg) were assessed using the pentobarbital-anesthetized in vivo rat model in comparison with those of verapamil (3 mg/kg, p.o.). Verapamil decreased the heart rate and mean blood pressure and prolonged the PR interval without changing the QRS width (n = 6). Similar results were observed for HNS-32 except that the QRS width was prolonged by the highest dose and the effects occurred slowly and lasted longer. These results suggest that HNS-32 is an orally active slowly-acting calcium plus sodium channel blocker.  (+info)

Radiosensitization and DNA repair inhibition by the combined use of novel inhibitors of DNA-dependent protein kinase and poly(ADP-ribose) polymerase-1. (5/33)

The DNA repair enzymes, DNA-dependent protein kinase (DNA-PK) and poly(ADP-ribose) polymerase-1 (PARP-1), are key determinants of radio- and chemo-resistance. We have developed and evaluated novel specific inhibitors of DNA-PK (NU7026) and PARP-1 (AG14361) for use in anticancer therapy. PARP-1- and DNA-PK-deficient cell lines were 4-fold more sensitive to ionizing radiation (IR) alone, and showed reduced potentially lethal damage recovery (PLDR) in G(0) cells, compared with their proficient counterparts. NU7026 (10 micro M) potentiated IR cytotoxicity [potentiation factor at 90% cell kill (PF(90)) = 1.51 +/- 0.04] in exponentially growing DNA-PK proficient but not deficient cells. Similarly, AG14361 (0.4 micro M) potentiated IR in PARP-1(+/+) (PF(90) = 1.37 +/- 0.03) but not PARP-1(-/-) cells. When NU7026 and AG14361 were used in combination, their potentiating effects were additive (e.g., PF(90) = 2.81 +/- 0.19 in PARP-1(+/+) cells). Both inhibitors alone reduced PLDR approximately 3-fold in the proficient cell lines. Furthermore, the inhibitor combination completely abolished PLDR. IR-induced DNA double strand break (DNA DSB) repair was inhibited by both NU7026 and AG14361, and use of the inhibitor combination prevented 90% of DNA DSB rejoining, even 24-h postirradiation. Thus, there was a correlation between the ability of the inhibitors to prevent IR-induced DNA DSB repair and their ability to potentiate cytotoxicity. Thus, individually, or in combination, the DNA-PK and PARP-1 inhibitors act as potent radiosensitizers and show potential as tools for anticancer therapeutic intervention.  (+info)

Photomutagenicity of cosmetic ingredient chemicals azulene and guaiazulene. (6/33)

The photomutagenicity of the popular skin conditioning agents azulene and guaiazulene were tested in Salmonella typhimurium TA98, TA100 and TA102. Following irradiation with UVA and/or visible light, both azulene and guaiazulene exhibited mutagenicity 4-5-fold higher than the spontaneous background mutation. In contrary, naphthalene, a structural isomer of azulene, was not photomutagenic under the same conditions. Azulene was photomutagenic when irradiated with UVA light alone, visible light alone, or a combination of UVA and visible light. Azulene and guaiazulene are not mutagenic when the experiment is conducted with the exclusion of light. Therefore, extreme care must be taken when using cosmetic products with azulene/guaiazulene as ingredients since after applying these products on the skin, exposure to sunlight is inevitable.  (+info)

Anticancer chemosensitization and radiosensitization by the novel poly(ADP-ribose) polymerase-1 inhibitor AG14361. (7/33)

BACKGROUND: Poly(ADP-ribose) polymerase-1 (PARP-1) facilitates the repair of DNA strand breaks. Inhibiting PARP-1 increases the cytotoxicity of DNA-damaging chemotherapy and radiation therapy in vitro. Because classical PARP-1 inhibitors have limited clinical utility, we investigated whether AG14361, a novel potent PARP-1 inhibitor (inhibition constant <5 nM), enhances the effects of chemotherapy and radiation therapy in human cancer cell cultures and xenografts. METHODS: The effect of AG14361 on the antitumor activity of the DNA alkylating agent temozolomide, topoisomerase I poisons topotecan or irinotecan, or x-irradiation or gamma-radiation was investigated in human cancer cell lines A549, LoVo, and SW620 by proliferation and survival assays and in xenografts in mice by tumor volume determination. The specificity of AG14361 for PARP-1 was investigated by microarray analysis and by antiproliferation and acute toxicity assays in PARP-1-/- and PARP-1+/+ cells and mice. After intraperitoneal administration, the concentration of AG14361 was determined in mouse plasma and tissues, and its effect on PARP-1 activity was determined in tumor homogenates. All statistical tests were two-sided. RESULTS: AG14361 at 0.4 micro M did not affect cancer cell gene expression or growth, but it did increase the antiproliferative activity of temozolomide (e.g., in LoVo cells by 5.5-fold, 95% confidence interval [CI] = 4.9-fold to 5.9-fold; P =.004) and topotecan (e.g., in LoVo cells by 1.6-fold, 95% CI = 1.3-fold to 1.9-fold; P =.002) and inhibited recovery from potentially lethal gamma-radiation damage in LoVo cells by 73% (95% CI = 48% to 98%). In vivo, nontoxic doses of AG14361 increased the delay of LoVo xenograft growth induced by irinotecan, x-irradiation, or temozolomide by two- to threefold. The combination of AG14361 and temozolomide caused complete regression of SW620 xenograft tumors. AG14361 was retained in xenografts in which PARP-1 activity was inhibited by more than 75% for at least 4 hours. CONCLUSION: AG14361 is, to our knowledge, the first high-potency PARP-1 inhibitor with the specificity and in vivo activity to enhance chemotherapy and radiation therapy of human cancer.  (+info)

Novel poly(ADP-ribose) polymerase-1 inhibitor, AG14361, restores sensitivity to temozolomide in mismatch repair-deficient cells. (8/33)

PURPOSE: Mismatch repair (MMR) deficiency confers resistance to temozolomide, a clinically active DNA-methylating agent. The purpose of the current study was to investigate the reversal mechanism of temozolomide resistance by the potent novel poly(ADP-ribose) polymerase (PARP)-1 inhibitor, AG14361, in MMR-proficient and -deficient cells. EXPERIMENTAL DESIGN: The effects of AG14361, in comparison with the methylguanine DNA methyltransferase inhibitor, benzylguanine, on temozolomide-induced growth inhibition were investigated in matched pairs of MMR-proficient (HCT-Ch3, A2780, and CP70-ch3) and -deficient (HCT116, CP70, and CP70-ch2) cells. RESULTS: AG14361 enhanced temozolomide activity in all MMR-proficient cells (1.5-3.3-fold) but was more effective in MMR-deficient cells (3.7-5.2-fold potentiation), overcoming temozolomide resistance. In contrast, benzylguanine only increased the efficacy of temozolomide in MMR-proficient cells but was ineffective in MMR-deficient cells. The differential effect of AG14361 in MMR-deficient cells was not attributable to differences in PARP-1 activity or differences in its inhibition by AG14361, nor was it attributable to differences in DNA strand breaks induced by temozolomide plus AG14361. MMR-deficient cells are resistant to cisplatin, but AG14361 did not sensitize any cells to cisplatin. PARP-1 inhibitors potentiate topotecan-induced growth inhibition, but AG14361 did not potentiate topotecan in MMR-deficient cells more than in MMR-proficient cells. CONCLUSIONS: MMR defects are relatively common in sporadic tumors and cancer syndromes. PARP-1 inhibition represents a novel way of selectively targeting such tumors. The underlying mechanism is probably a shift of the cytotoxic locus of temozolomide to N(7)-methylguanine and N(3)-methyladenine, which are repaired by the base excision repair pathway in which PARP-1 actively participates.  (+info)

Azulene is a main component of chamomile extract which is used as a colouring agent (azul means blue in Spanish) in cosmetics and ointments and used as a folk medicine to treat migraine, arthritis, rheumatic diseases, and allergy. It has antioxidant and anti-inflammatory activities. Examples of common substituted azulenes obtained naturally are vetivazulene (4,8-dimethyl-2-isopropylazulene) from vetiver oil, and guaiazulene (1,4-dimethyl-7-isopropylazulene) from constituent of guaiac wood oil. Guaiazulene has been used as an antiulcer drug. Various biological activities such as antiphlogistic, antiallergic, bacteriostatic from azulen class compounds are expected. ...
Egualen is a medicine available in a number of countries worldwide. A list of US medications equivalent to Egualen is available on the Drugs.com website.
Cyclization of 4-(2-halophenyl)-1H-pyrazolo[3,4-b]quinolines 3a-b and 9a-9b provided two regioisomeric compounds: 6-phenyl-6H-5,6,7-triazadibenzo[f,h]naphtho[3,2,1-cd]azulenes 4,10 and 1,3-diphenyl-3H-indeno[1,2,3-de]pyrazolo[3,4-b]quinolines 2,11. All of them are considered as new building blocks for optoelectronic materials. The two-step synthesis utilized readily available starting materials ...
Other names: 1H-Cycloprop[e]azulene, decahydro-1,1,7-trimethyl-4-methylene-, [1aR-(1a«alpha»,4a«alpha»,7«alpha»,7a«beta»,7b«alpha»)]-; 1H-Cycloprop[e]azulene, decahydro-1,1,7-trimethyl-4-methylene-, (1aR,4aR,7R,7aR,7bS)-(+)-; (1aR,4aR,7R,7aR,7bS)-1,1,7-Trimethyl-4-methylenedecahydro-1H-cyclopropa[e]azulene; Aromadendr-7(15)-ene; (+)-Aromadendrene; Aromadendrene, (+)-; 1,1,7-Trimethyl-4-methylenedecahydro-1H-cyclopropa[e]azulene-, [1aR-(1a«alpha»,4a«alpha»,7«alpha»,7a«beta»,7b«alpha»)]-; [1aR-(1a«alpha»,4a«alpha»,7«alpha»,7a«beta»,7b«alpha»)]-decahydro-1,1,7-trimethyl-4-methylene-1H-cycloprop[e]azulene ...
BioAssay record AID 735304 submitted by ChEMBL: Inhibition of iNOS-mediated nitric oxide production in LPS-stimulated mouse RAW264.7 cells after 24 hrs by Griess reaction analysis.
BioAssay record AID 418268 submitted by ChEMBL: Inhibition of COX2-mediated PGE2 production in LPS-stimulated mouse RAW264.7 cells by enzyme immunoassay.
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Compounds of formula (I): |p||chemistry id=CHEM-US-00001 num=00001||img id=EMI-C00001 he=33.70mm wi=69.85mm file=US20100105666A1-20100429-C00001.TIF img-content=chem img-format=tif ori
Beyond providing Skin Deep® as an educational tool for consumers, EWG offers its EWG VERIFIED™ mark as a quick and easily identifiable way of conveying personal care products that meet EWGs strict health criteria. Before a company can use EWG VERIFIEDTM on such products, the company must show that it fully discloses the products ingredients on their labels or packaging, they do not contain EWG ingredients of concern, and are made with good manufacturing practices, among other criteria. Note that EWG receives licensing fees from all EWG VERIFIED member companies that help to support the important work we do. Learn more , Legal Disclaimer ...
1. Yonghai Li, Masoud Baghernejad, Al-Galiby Qusiy, David Zsolt Manrique, Guanxin Zhang, Joseph Hamill, Yongchun Fu, Peter Broekmann, Wenjing Hong,* Thomas Wandlowski, Deqing Zhang,* and Colin Lambert*,Three-State Single-Molecule Naphthalenediimide Switch: Integration of a Pendant Redox Unit for Conductance Tuning,Angew. Chem. Int. Ed. 2015, 54, 13586 -13589。出版年: NOV 9 2015 1433-7851. 2. Guanxin Zhang, Fang Hu, and Deqing Zhang*,Manipulation of the Aggregation and Deaggregation of Tetraphenylethylene and Silole Fluorophores by Amphiphiles: Emission Modulation and Sensing Applications,LANGMUIR 2015,31(16). 4593-4604 出版年: APR 28 2015 0743-7463. 3. Jingjing Yao, Zhengxu Cai, Zitong Liu*, Chenmin Yu, Hewei Luo, Yang Yang, Sifen Yang, Guanxin Zhang, and Deqing Zhang*, Tuning the Semiconducting Behaviors of New Alternating Dithienyldiketopyrrolopyrrole-Azulene Conjugated Polymers by Varying the Linking Positions of Azulene, Macromolecules, 2015, 48 (7), pp 2039-2047. DOI: ...
Azulene marine mousse (scrub). Physicochemicals elments of this product dragging deeply cleane the skin impurities that shrink daily. Due to contain azulene, prevents irritation and restores radiance and beauty to the face.. Algotonale scrub. The frequent use cleans pores in greasy skin. For its soft decaling action, it can be used in dry and brittle.. ...
Distinctive lessons of bioactive constituents are current in chamomile, which have been isolated and made use of as medicinal preparations and cosmetics (nine). The plant is made up of 0.24%-1.nine% unstable oil, made up of a range of different oils. When subjected to steam distillation, the oil ranges in color from excellent blue to deep eco-friendly when new but turns to darkish yellow following storage. Even with fading, the oil does not drop its potency. About one hundred twenty secondary metabolites are already identified in chamomile, including 28 terpenoids and 36 flavonoids (ten, 11). The principal parts of your critical oil extracted from your German chamomile bouquets would be the terpenoids α-bisabolol and its oxide azulenes including chamazulene and acetylene derivatives. Chamazulene and bisabolol are extremely unstable and therefore are very best preserved in an alcoholic tincture. The vital oil of Roman chamomile contains fewer chamazulene and is principally constituted from ...
Buy Elaine Gregg Aloe and Azulene Gel Masque 2 oz and get FREE SHIPPING, Free Samples, No-Hassle Returns, and 115% Price Protection at beautystoredepot.com. Authorized reseller and very friendly customer service staff.
34 wax strips; 3 sizes. 34 wax strips total (17 double-sided), azulene finishing oil: 0.5 fl oz (14.7 ml), instructions. Brow. Face. Bikini. Results last up to 8 weeks (individual results may vary)! Ready and easy to use. Helps to slow the appearance of regrowth. Dermatologist & salon tested. No. 1 selling wax brand in the USA. Quick and easy. Results last up to 8 weeks (individual results may vary). 1-2-3 hair free! No microwave, no mess. 3 simple steps. Pre-waxed strips, pre-cut for face and bikini area. Works on short hair. Complete Kit Includes: three different sizes; azulene finishing oil; 4 large; 12 medium; 18 small. 34 wax strips (17 double-sided), azulene finishing oil. Scan here for how to use videos. 1 800 953 5080 (USA/Canada only). sallyhansen.com. Made in USA ...
Please consult your physician or skin care professional for proper use and directions.. INGREDIENTS: Sweet Almond Oil, Mineral Oil, Guaiazulene, Peg 40 Sorbitan Peroleate. Omni Bioceutical Innovations products are not intended to be drug products that diagnose, treat, cure, or prevent any disease or condition. The products are intended to meet the FDAs definition of a cosmeceutical product. For external, topical use only.. ...
Please consult your physician or skin care professional for proper use and directions.. INGREDIENTS: Sweet Almond Oil, Mineral Oil, Guaiazulene, Peg 40 Sorbitan Peroleate. Omni Bioceutical Innovations products are not intended to be drug products that diagnose, treat, cure, or prevent any disease or condition. The products are intended to meet the FDAs definition of a cosmeceutical product. For external, topical use only.. ...
Autori: Alexandru C. Razus, Simona Nica, Liliana Cristian, Matei Raicopol, Liviu Birzan, Andreea Eugenia Dragu. Editorial: Elsivier, Dyes and Pigments, 91, p.55-61, 2011.. Rezumat:. Highly conjugated azo-aromatic systems have been prepared in high to moderate yields by linking mono- and bis-azo aromatic fragments to 4-(Rn-azulen-1-yl)-2,6-dimethyl-pyridine. The synthesized p-extended systems have been studied by NMR spectroscopy, UV-Vis and electrochemistry. Systematic increase of the conjugation along the azobenzene skeleton has affected the spectral properties of the azophenyl substituted 4-(azulen-1-yl)-pyridine. The synthesized compounds exhibit a bathochromic shift of the visible absorption maxima with the increase of the conjugating skeleton and introduction of an electron- ithdrawing group. The electrochemical behavior revealed a high stability toward oxidation owing to the higher polarization induced by the azulenyl-pyridine moiety.. Cuvinte cheie: Arylazo chromophores, Diazene ...
To compare renal function (51Cr-EDTA clearance) 48 hours post open-heart surgery (coronary bypass or valve surgery) in patients with impaired renal function after randomization to either nifedipine infusion at start of surgery and the following 24 hours or placebo (0.9% saline infusion). Study hypothesis is that nifedipine has a prophylactic effect on decline in renal function ...
Poly(ADP-ribose) polymerase-1 (PARP-1) is a member of the PARP enzyme family consisting of PARP-1 and several recently identified novel poly(ADP-ribosylating ...
We report on a series of novel poly(c-glutamic acid) (PGGA) esters, in which the chemical structure and composition, and the molecular weight are systematically changed. Modification of PGGA of microbial origin, used ...
Electron transfer reactions have been studied between 9-anthracenecarboxylic acid co-adsorbed with perylene on silica gel surfaces employing azulene as a molecular shuttle in order to facilitate hole transfer. In this paper we present for the first time a ternary system that unambiguously demonstrates an appreciable mobility of radical cations on the silica gel surface. Rates of hole transfer from the 9-anthracenecarboxylic acid radical cation to perylene via azulene have been studied using diffuse reflectance laser flash photolysis spectroscopy. Azulene has been shown to enhance the rate of electron transfer in the ternary system, proving significant mobility of the azulene and its radical cation species on silica gel surfaces. The data shows that the azulene radical cation can diffuse at an appreciable rate on the silica gel surface ...
tats This invention relates to novel organometallic compounds and their preparation. More particularly, the present invention relates to novel and useful transition metal complexes of azulene. An object of this invention is to provide a novel class of organometallic compounds. Another object is to provide a class of stable transition metal coordination compounds of azulene. A further object is to provide a novel class of stable non-ionic azulene metal complexes having unsymmetric configurations. Other objects will become apparent from the specification and claims which follow. The above objects are accomplished by providing nonionic complex compounds of the metals of groups IVB- VIII in which a metal atom or atoms are bonded to azulene, which compound is stabilized by additional covalent bonding of the metal atom or atoms to dissimilar electron-donating groups. The metal in the novel compounds of this invention is a metal of groups IVBVIII of the periodic table as shown in The Handbook of Chem ...
Abstract : Non-viral gene carriers for safe and efficient gene transfection have become of particular interest among researchers of different disciplines ranging from physical chemistry to biotechnology. Recently polymeric vectors have been extensively studied as potentially new gene transfer agents. Until now most of the research efforts were made to optimize the gene-to-polymer weight ratio of polyplexes for safe and efficient gene transfection. In this work, we report on the development of novel poly(allylamine) derivatives with different balance of the primary, secondary, tertiary, and quaternary amino groups. All derivatives were able to complex pDNA into polyplexes at low gene-to-polymer weight ratios i.e., 1:1 or 1:2. Moreover, the examined polyplexes were less cytotoxic and showed better transfection efficiency when compared to linear poly(ethyleneimine). These results indicate that the presence of quaternary ammonium groups is important in the formation of stable polyplexes. Polymers ...
Loxoprofen Sodium Nichi-Iko is a medicine available in a number of countries worldwide. A list of US medications equivalent to Loxoprofen Sodium Nichi-Iko is available on the Drugs.com website.
Fast-action face mist designed for men to cool skin temperatures almost instantly. Contains unique CNP patent, Blue Thermal Solution (Blue Guaiazulene and...
Oral tumors are often devastating for our patients. For an animal having any tumor is not easy…but when that tumor is in the mouth it also can also cause major problems such as pain, difficulty eating or swallowing food, bleeding, infection, and an overall decrease in quality of life. Oral tumors are best treated with surgical excision, as this can fix the local problem quickly. However, many times oral tumors can not be treated with surgery or surgery can not completely remove the tumor. In these cases, radiation therapy is often very useful in controlling tumors and improving quality ...
Definition Any abnormal swelling or lump in the mouth needs urgent investigation. A swelling may be a cyst or something relatively benign, however the mouth
You may also wish to search for items by Kitagawa. 11 matching references were found. Kitagawa, T.; Harada, Y.; Inokuchi, H.; Kodera, K., Absorption spectrum of vapor phase azulene in vacuum ultraviolet region, J. Mol. Spectry., 1966, 19, 1. [all data] Kitagawa, T.; Inokuchi, H.; Kodera, K., Photoionization of polycyclic aromatic compounds in vacuum ultraviolet region. Azulene, J.Mol. Spectry., 1966, 21, 267. [all data] Kitagawa, T., Absorption spectra and photoionization of polycyclic aromatics in vacuum ultraviolet region, J. Mol. Spectry., 1968, 26, 1. [all data] Mori, Y.; Ogawa, Y.; Shinoda, H.; Kitagawa, T., Two competing fragmentation processes in dimethoxybenzenes depending on their positional isomers: Elimination of CH3 and CHnO (n = 1-3) and formation of methoxycyclopentadienyl and protonated phenol ions, Org. Mass Spectrom., 1992, 27, 578. [all data] Takeuchi, K.; Fujimoto, H.; Kitagawa, T.; Fujii, H.; Okamoto, K., Structural effects on valence tautomerism. Part 5. A carbon-13 nuclear ...
TY - JOUR. T1 - Prophylactic effect of Lactobacillus oral vaccine expressing a Japanese ceder pollen allergen. AU - Ohkouchi, Kayo. AU - Kawamoto, Seiji. AU - Tatsugawa, Kenji. AU - Yoshikawa, Noboru. AU - Takaoka, Yuki. AU - Miyauchi, Sayumi. AU - Aki, Tsunehiro. AU - Yamashita, Mitsuo. AU - Murooka, Yoshikatsu. AU - Ono, Kazuhisa. PY - 2012/4/1. Y1 - 2012/4/1. M3 - Article. VL - 113. SP - 536. EP - 541. JO - Default journal. JF - Default journal. ER - ...
Policalm™ Cream is easily applied to the skin and it has soothing and palliative properties in the areas showing signs of itching-pruritus.. Its unique formulation is rich in azulene, a-bisabolol (derived from chamomile), urea, polidocanol, calendula, coconut oil, menthol, aloe vera and panthenol.. The components of Policalm™ replenish, moisturize, relieve and soothe irritated skin areas with itching trends. They also keep the skin in good condition, helping to remove dead skin cells created on the surface of the skin which aggravate itching and leave a pleasant feeling.. Apply 1-2 doses in a skin area, making a light massage until completely absorbed. It is safe for frequent use.. If you have any queries please do not hesitate to contact your pharmacist or doctor or our company.. Keep out of the reach of children. Store in a cool & dry place below 28 °C. For external use only.. ...
Significant digging around on the Internet didnt reveal to me what Yulan Oil is or where it comes from. There is a Yulan Magnolia tree but whether this oil comes from that, I couldnt tell you. Its also not listed in the ingredients (which are Glycerin, Azulene, Collogen amino acids, Hyaluronic acid, Niacinamide, Gold, Morus Alba extract, Carbomer, Proplyene glycol, Purified Water) - But the Morus Alba is a white mullberry extract, which is good for skin, along with Hyraluronic Acid which is recommended for all sorts of discolouration - its not hard to see why this would work ...
La terapia génica presenta potenciales aplicaciones terapéuticas para el tratamiento de muchas enfermedades como el cáncer, enfermedades monogénicas, enfermedad vascular, entre otras. Aunque la mayoría de protocolos de terapia génica empleen vectores virales, debido a su alta eficacia de transfección, crecientes preocupaciones debido a su activación de respuesta inmunológica motivan al desarrollo de sistemas de transportes no virales que sean seguros y eficaces. Poli(β-aminoestere)s (pBAEs) son prometedores vectores no virales debido a que su naturaleza de poliéster resulta en un atractivo perfil de biocompatibilidad debido a su alta biodegradabilidad y baja toxicidad. Este trabajo desarrolla una nueva familia de pBAEs, los cuales presentan oligopéptidos terminales, capaces de condensar tanto ADN como siRNA en partículas de tamaño nanométrico. En primer lugar, se realizan experimentos in vitro para evaluar la habilidad de estos nuevos pBAEs para transportar eficazmente tanto DNA ...
The overall aim of the study was to determine the passive prophylatic effect of bovine milk immunoglobulin administered orally either as a bolus (once a day) or as continuously (three times a day) against diarrhoea caused by Escherichia coli K 88. As the piglets have gastrointestinal structural and physiological similarities to humans they were assumed to be an appropriate model for the study. The first part of the study was done to evaluate the quantity of undigested immunoglobulin G in the gastrointestinal tract of the piglet. This was conducted in two experiments. One was a pilot study and the other was to estimate the quantity of undigested immunoglobulin G in the gut. A pilot study was conducted to evaluate the rate of movement and the quantities of digesta that can be collected in the gastrointestinal tract regions at varying time intervals. Ten piglets were randomly divided into five groups of two in each. One from each group was selected, fed with an experimental diet which contained ...
I had him to the dr after three weeks lengthened and we tried planting a course of Gefitinib for 10 days only but it didnt clear up the diarrhea, severe totally. A promising approach toward testing this central hypothesis could be to first assess the possible prophylactic effect of effective for product against the emergence abdominal or stomach pain or tenderness particularly in young
Bovine tumour are of great concern as they may cause economic losses due to negative impact on productivity, animal health and thus may reduce profit to individual farmer and dairy industry.
Hundreds of opponents turned out to give a resounding NO to chicken killer Joseph Rosario, who had wanted to build a live market on Long Island.
If you live in a beachfront cottage, you can start every day with a nourishing mask of sea kelp. For the rest of us, there s this marine face wash. Rich in ingredients sourced from land and sea, it cleanses, calms, and conditions skin of any type. Aloe, rose hip, and algae extract provide a burst of moisture, sooth irritation, and minimize wrinkles, while Azulene and chamomile tame inflammation and lavender acts as an antiseptic.
Described herein are novel block copolymers wherein one block is a poly(aryl ether ketone) oligomer and other block is a liquid crystalline polyester oligomer. Processes for the preparation of the subject copolymers are also described. The novel block copolymers display excellent mechanical properties, good high temperatures stability and excellent solvent and chemical resistance.
Broccoli sprout could be prophylactic vegetable to prevent or minimize the relapse by inflammation in the remission state of depressed patients.
Schubert, Karin; Reiml, Dieter; Accolas, Jean-Pierre und Fiedler, Franz (1993): A novel type of meso-diaminopimelic acid-based peptidoglycan and novel poly(erythritol phosphate) teichoic acids in cell walls of two coryneform isolates from the surface flora of French cooked cheeses. In: Archives of Microbiology, Vol. 160: S. 222-228 [PDF, 727kB] ...
Greenmedinfo.com - Natural Health Resource - The worlds most widely referenced, open access, natural medicine database, with 30,000+ study abstracts and growing daily
Hamari San Diego Research Center (SDRC), a subsidiary of Hamari Chemicals in Japan, specializes in near-sourcing R&D support for clients in the U.S. Our U.S. labs focus on reactions and route optimization, toll manufacturing, and up to kilo scale non-GMP manufacturing. Since 1948, Hamari Chemicals has specialized in the manufacture of APIs and pharmaceutical intermediates. […] ...
Azulenal Ointment is a natural wound-healing cream that is used for itchy skin, sore nipples, breast inflammation, and burns. It doubles up as a cracked nipple ointment, prevents mastitis, and also works as a nappy rash cream. Azulenal also works as a tattoo ointment and helps against rashes and neurodermatitis.
TY - JOUR. T1 - Prophylactic effect of diacerein against cisplatin-induced nephrotoxicity in rats. AU - Abdel-Aziz, Asmaa Mohamed. AU - Ibrahim, Mohamed Abdellah. AU - El-Shiekh, Azza Ali. AU - Osman, Nisreen Abdel Tawab. AU - Geddawy, Ayman. AU - Abdelrahman, Aly. PY - 2018. Y1 - 2018. N2 - Background and Objective: Cisplatin is an effective chemotherapeutic agent for solid tumors, however its use is limited by nephrotoxicity. The current study investigated the effect of diacerein in cisplatin-induced nephrotoxicity in rats. Materials and Methods: Rats were randomly divided into 5 groups; control (untreated), diacerein control (100 mg kgG1), cisplatin (5 mg kgG1 i.p.), cisplatin+diacerein (50 mg kgG1) and cisplatin+diacerein (100 mg kgG1). Data were analyzed by one way ANOVA using GraphPad Prism. Results: Administration of cisplatin caused significant deterioration in renal function, designated by the increase in serum levels of both urea and creatinine, reduction in creatinine clearance, ...
TY - JOUR. T1 - Biochemical and genetic characterization of the multidrug resistance phenotype in murine macrophage-like J774.2 cells. AU - Kirschner, Lawrence S.. AU - Greenberger, Lee M.. AU - Hsu, Stephen I Hong. AU - Yang, Chia-Ping H.. AU - Cohen, Dalia. AU - Piekarz, Richard L.. AU - Castillo, Gonzalo. AU - Han, Edward Kyu Ho. AU - Yu, Lijia. AU - Band Horwitz, Susan. PY - 1992/1/9. Y1 - 1992/1/9. N2 - The development of multidrug resistance (MDR) in malignant tumors is a major obstacle to the treatment of many cancers. MDR sublines have been derived from the J774.2 mouse macrophage-like cell line and utilized to characterize the phenotype at the biochemical and genetic level. Two isoforms of the drug resistance-associated P-glycoprotein are present and distinguishable both electrophoretically and pharmacologically. Genetic analysis has revealed the presence of a three-member gene family; expression of two of these genes, mdr1a and mdr1b, is associated with MDR whereas the expression of ...
Calm skin irritations with MAMONDE Blue Chamomile Soothing Repair Cream. Its formulated with Blue Chamomile, a plant-based ingredient rich in antioxidants and anti-inflammatory properties. This ingredient is rich in Azulene which functions to soothe skin irritations and reduce redness while it keeps the skin moisturiz
If youre dealing with a particularly stubborn pimple you cant resist picking at, Lee recommends using a spot treatment thatll help heal the current spot and remind you to keep your hands off. Try the one from Neogen Dermalogy, which features salicylic acid to gently exfoliate, azulene (an extract of chamomile) for redness relief, and calamine to control excess oil production. After application, youll see the light pink calamine lotion on your skin, which serves as a visual reminder not to touch it. If you want to create a physical barrier around the blemish, try pimple patches , like the popular Hero Cosmetics Mighty Patches, which claim to shrink blemishes in as little as six hours with its absorbent hydrocolloid dressing. If your acne is severe and over-the-counter products arent working, a visit to your dermatologist can help you get a better handle on controlling your acne. ...
Aloe Vera Leaf Extract Juice: Derived from the aloe vera (true aloe) plant, one of the oldest medicinal plants known. It has remarkable healing abilities because it is a natural oxygenator (drawing and holding oxygen to the skin). It is an effective cellular renewal ingredient as it has a composition similar to that of human blood plasma and sea water. It is extremely soothing and protective, and very effective in replenishing lost moisture. It is also a natural astringent.. Chamomile Flower Extract: Contains a high percentage of azulene, a powerful healer that is extremely soothing to the skin.. Arnica Montana Flower Extract: Reduces the appearance of inflammation while encouraging cellular regeneration.. GABA (gamma amino butyric acid): A natural topical muscle relaxant.. Vitamin K: helps to minimize the appearance of broken capillaries and discoloration. ...
Try out our naturally derived liquid soap colours designed for Melt & Pour Soaps. Our Melt and Pour soap colours are easily soluble in melt and pour soap bases. Red-(Beetroot Powder,Alkanet Root Powder) Yellow-(Arrowroot Powder,Turmeric) Orange-(Turmeric, Annatto Powder) Blue-(Azulene oil,Indigofera Tinctoria,Blue
TY - JOUR. T1 - Analysis of prognostic factors and patterns of failure in dogs with malignant oral tumors treated with megavoltage irradiation. AU - Theon, Alain P. AU - Rodriguez, Carlos. AU - Madewell, Bruce R.. PY - 1997/3/15. Y1 - 1997/3/15. N2 - Objective - To determine quality and duration of progression-free survival (PFS) time in dogs with malignant oral tumors after definitive megavoltage irradiation, to analyze prognostic factors for PFS time and patterns of failure, and to analyze the influence of tumor recurrence and development of metastasis on survival. Design - Prospective clinical trial. Animals - 105 dogs with squamous cell carcinoma, fibrosarcoma, or malignant melanoma of the oral cavity without evidence of metastasis. Procedure - Dogs were treated with 48 Gy over 4 weeks on an alternate-day schedule of 4 Gy/fraction. Multivariate analysis was done by use of Coxs regression model to determine significant prognostic factors and by use of a competing risk model to determine the ...
TY - JOUR. T1 - Energy and electron transfer in a poly(fluorene-alt-phenylene) bearing perylenediimides as pendant electron acceptor groups. AU - Gómez, R.. AU - Veldman, D.. AU - Blanco, R.. AU - Seoane, C.. AU - Segura, J.L.. AU - Janssen, R.A.J.. PY - 2007. Y1 - 2007. N2 - We describe the synthesis and characterization of a novel poly(fluorene-alt-phenylene) substituted with perylenediimide (PDI) moieties as pendant groups. Cyclic voltammetry experiments show the amphoteric nature of the material, which combines the good electron donor ability of the polymeric chain with the acceptor properties of the pendant PDI moieties. Absorption spectroscopy suggests the presence of PDI aggregates, whereas the emission spectra show a strong emission quenching of both the polymeric backbone and the PDI units. Further investigation on the energy and/or electron-transfer processes involved is carried out by temperature-dependent excitation spectra and photoluminescence lifetimes. These studies show the ...
Novel poly(etherimide esters) are prepared by reacting a diol, a dicarboxylic acid, a poly(oxy alkylene) diamine and a tricarboxylic acid having two vicinal carboxyl groups or the anhydride thereof.
SabzAliZanjankhah, MohammadReza and Bamshki, AliReza and AhmadiFard, Hossein and Goharian, Mohammad (2009) The Prophylactic Effect of Toothguard in Prevention of Dental Trauma during Laryngoscopy in Patients Undergoing General Anesthesia. Journal of Mashhad Dental School, 33 (2). pp. 139-144. ...
All it is is me and them, Morris told me. It simplifies the world, and were looking into each others eyes. Were sitting in a room as were sitting in a room now, looking at each other. And there is an intimacy that is much greater than doing a different kind of thing. And thats preserved, whether Im 20 feet away from them in the studio or 2,000 miles away from them on Skype. But Morris also made this statement about his predilection for electronic barriers and their socially prophylactic effect: I used to say being there is the next best thing to using the phone. Famous people whom Errol Morris has interviewed on the Interrotron include Mikhail Gorbachev, Al Sharpton, Iggy Pop, and former U.S. Secretary of Defense Robert McNamara, the subject of Morriss 2003 film, The Fog of War, who upon being introduced to the Interrotron told Morris, I dont care what you call it, I dont like it, and then sat down for what became several days of interviews anyway. He just wanted me to know, I ...
Interpret Rankings provides insight into interpreting cancer incidence statistics. When the population size for a denominator is small, the rates may be unstable. A rate is unstable when a small change in the numerator (e.g., only one or two additional cases) has a dramatic effect on the calculated rate ...
... is an azulene derivate obtained from vetiver oil. It is a bicyclic sesquiterpene and an isomer of guaiazulene. ... Gordon, Maxwell (1 February 1952). "The Azulenes". Chemical Reviews. 50 (1): 127-200. doi:10.1021/cr60155a004. v t e. ...
Hafner, = Klaus; Meinhardt, Klaus-Peter (1984). "Azulene". Organic Syntheses. 62: 134. doi:10.15227/orgsyn.062.0134. E. F. ...
Homolysis of the weakest bond in azulene occurs, followed by a hydrogen shift and ring closure so as to retain the aromaticity ... This is currently the preferred mechanism and is as follows: The isomerization of unsubstituted azulene to naphthalene was the ... The four described mechanisms would all result in the isomerization from azulene to naphthalene. Kinetic data and 13C-labeling ... At the time, they noticed the automerization of a substituted azulene shown below, but no further structural or mechanistic ...
... and the azulene molecule can be approximated as a combination of both. In order to convert the atom from sp3 to sp2, a ...
US 4286099, M. E. Nash, E. E. Huxley, "Sulfolene hydrogenation" D. M. Lemal; G. D. Goldman (1988). "Synthesis of azulene, a ...
A derivative of azulene, guaiazulene is a bicyclic sesquiterpene that is a constituent of some essential oils, mainly oil of ... Its low melting point makes guaiazulene difficult to handle, in contrast to the crystalline nature of the parent azulene. The ... Harmon AD, Weisgraber KH, Weiss U.; Weisgraber; Weiss (1979). "Preformed azulene pigments of Lactarius indigo (Schw.) Fries ( ... "The anti-inflammatory activity of azulene". Journal of the European Academy of Dermatology and Venereology. 15 (5): 486. doi: ...
Harmon AD, Weisgraber KH, Weiss U (1979). "Preformed azulene pigments of Lactarius indigo (Schw.) Fries (Russulaceae, ...
The blue color of L. indigo is due to (7-isopropenyl-4-methylazulen-1-yl)methyl stearate, an organic analogous to azulene, ... Harmon AD, Weisgraber KH, Weiss U (1979). "Preformed azulene pigments of Lactarius indigo (Schw.) Fries (Russulaceae, ...
Buenker, R. J.; Peyerimhoff, S. D. (1969). "Ab initio SCF calculations for azulene and naphthalene". Chemical Physics Letters. ... the largest molecules included were naphthalene and azulene. Abstracts of many earlier developments in ab initio theory have ...
Chamomile, azulene and other minerals are often added. There are pre-made versions of nuru gel available as well as powdered ...
Azulene - composed of fused cyclopentadiene and cycloheptatriene rings. Sesquifulvalene - composed of linked cyclopentadiene ...
Notable counterexamples are cyclooctadecanonaene, azulene and trans-bicalicene. Quinoid Aromatic compound. ...
He also studied chemical characteristics of tropones, tropolones, other troponoids, and azulenes. Tetsuo Nozoe was married to ...
Thermal rearrangement of azulene to naphthalene has been observed. Aldose-ketose isomerism, aka Lobry de Bruyn-van Ekenstein ...
utilized intramolecular carbenoid generation to produce substituted azulenes through a Buchner type ring expansion. The anti- ... Annulation Strategy for the Synthesis of Substituted Azulenes. Preparation and Suzuki Coupling Reactions of 1-Azulenyl ... "Ring Expansion-Annulation Strategy for the Synthesis of Substituted Azulenes and Oligoazulenes. 2. Synthesis of Azulenyl ...
... (2a,8b-dihydro-cyclopent[cd]azulene) is a polycyclic hydrocarbon with chemical formula C12H10, composed of one ... List of chemical compounds with unusual names Azulene Homoaromaticity Nickon, Alex; Silversmith, Ernest F. (2013). Organic ...
... is a tricyclic sesquiterpene alcohol which has a basic skeleton similar to the azulenes. It occurs in oregano among ...
"Incoherent broad-band cavity-enhanced absorption spectroscopy of azulene in a supersonic jet". Chemical Physics Letters. ...
The blue coloring of the fruit body is due to three azulene pigments. Whether Entoloma hochstetteri is poisonous or not is ...
Existence of the Doubly Excited State that Mediates the Photoionization of Azulene". J. Chem. Phys. 138 (20): 201102-1-201102-4 ...
It is a blue-violet derivative of azulene which is biosynthesized from the sesquiterpene matricin. Chamazulene has anti- ...
... is an unstable isomer of the more common benzenoid aromatic compounds naphthalene and azulene. Fulvalene consists of ...
Bicyclo[6.2.0]decapentaene is a bicyclic organic compound and an isomer of naphthalene and azulene. Whether this substance is ...
The chromophore of azulene was discovered in yarrow and wormwood and named in 1863 by Septimus Piesse. Yarrow contains ...
... azulene (8.01%), toluene (4.36%), palmitic acid (4.01%) and linoleic acid (4.01%). In 2017, a case report documented E. ...
The valence isomers of naphthalene Naphthalene Azulene IUPAC, Compendium of Chemical Terminology, 2nd ed. (the "Gold Book") ( ... no pair of valence isomers differ more strongly in appearance than colourless naphthalene and the intensely violet azulene. ...
This is in contrast to non-alternant hydrocarbons, such as azulene and fulvene that have large dipole moments. The Hückel ...
The red-coloured azulene compounds, ingested with the mushroom food, are more or less excreted with the urine. The milk cap's ...
C12H12 and Azulene]. Justus Liebigs Annalen der Chemie (in German). 560: 93-104. doi:10.1002/jlac.19485600103. }} Reppe, Walter ...
BaP's metabolites are mutagenic and highly carcinogenic, and it is listed as a Group 1 carcinogen by the IARC. Chemical agents and related occupations, Volume 10, A review of Human Carcinogens, IARC Monographs, Lyon France 2009 [13] In June 2016, BaP was added as benzo[def]chrysene to the REACH Candidate List of Substances of very high concern for Authorisation.[14] Numerous studies since the 1970s have documented links between BaP and cancers.[15] It has been more difficult to link cancers to specific BaP sources, especially in humans, and difficult to quantify risks posed by various methods of exposure (inhalation or ingestion).[citation needed] A link between vitamin A deficiency and emphysema in smokers was described in 2005 to be due to BaP, which induces vitamin A deficiency in rats.[16] A 1996 study provided molecular evidence linking components in tobacco smoke to lung cancer. BaP was shown to cause genetic damage in lung cells that was identical to the damage observed in the DNA of most ...
Compton, R.N.; Huebner, R.H., Temporary Attachment of Electrons to Azulene-h8 and Azulene-d8, J. Chem. Phys., 1969, 51, 7, 3132 ... The electron detachment from azulene- and the electron affinity of azulene, J. Chem. Phys., 1985, 83, 3983. [all data] ... Azulene and naphthalene, J. Chem. Phys., 1964, 41, 3195. [all data] Winters and Kiser, 1964. Winters, R.E.; Kiser, R.W., A mass ... Azulene, J.Mol. Spectry., 1966, 21, 267. [all data] Kitagawa, Harada, et al., 1966. Kitagawa, T.; Harada, Y.; Inokuchi, H.; ...
The National Institute of Standards and Technology (NIST) uses its best efforts to deliver a high quality copy of the Database and to verify that the data contained therein have been selected on the basis of sound scientific judgment. However, NIST makes no warranties to that effect, and NIST shall not be liable for any damage that may result from errors or omissions in the Database ...
Illustrative complexes are (azulene)Mo2(CO)6 and (azulene)Fe2(CO)5. 1-Hydroxyazulene is an unstable green oil and it does not ... In naphth[a]azulene, a naphthalene ring is condensed at the 1,2-positions of azulene. In one such system deformation from ... Azulene is an organic compound and an isomer of naphthalene. Whereas naphthalene is colourless, azulene is dark blue. Two ... azulenes by Intramolecular Tropylium Ion-Mediated Furan Ring-Opening Reaction and X-ray Investigation of a Naphth[1,2-a]azulene ...
Beyond providing Skin Deep® as an educational tool for consumers, EWG offers its EWG VERIFIED™ mark as a quick and easily identifiable way of conveying personal care products that meet EWGs strict health criteria. Before a company can use EWG VERIFIEDTM on such products, the company must show that it fully discloses the products ingredients on their labels or packaging, they do not contain EWG ingredients of concern, and are made with good manufacturing practices, among other criteria. Note that EWG receives licensing fees from all EWG VERIFIED member companies that help to support the important work we do. Learn more , Legal Disclaimer ...
Nature Pures Azulene-Seaweed Masque is a fast-acting spa treatment that improves smoothness of the skin. Blended with ... Nature Pures Azulene-Seaweed Masque is a fast-acting spa treatment that improves smoothness of the skin. Blended with ...
... azulene-10,12(5H,11H)-dione, (12aRS,12bRS)-7-chloro-2,3,12a,12b-tetrahydro-1H,4H-3a,9b,11-triazabenzonaphtho[2,1,8-cde]azulene- ... 12aRS,12bRS)-7-Chloro-2,3,12a,12b-tetrahydro-4H,4H-3a,9b,11-triazabenzo[a]naphtho[2,1,8-cde]azulene-10,12(5H,11H)-dione. To a ... 5aRS,12aSR,12bSR,12cSR)-7-chloro-2,3,5a,12a,12b,12c-hexahydro-1H,4H-3a,9b,11-triazabenzo[a]naphtho[2,1,8-cde]azulene-10,12(5H, ... 5aRS,12aSR,12bSR,12cSR)-2,3,5a,12a,12b,12c-hexahydro-1H,4H-3a,9b,11-triazabenzo[a]naphtho[2,1,8-cde]azulene-10,12(5H,11H)-dione ...
Azulene Soothing Masque (2 fl oz). Soothing, calming hydration for sensitive skin. BENEFITS: Skin which is sensitive often ... Azulene - a deep blue healing extract sourced from the essential oil of chamomile flowers, known for its superior soothing ... Azulene Soothing Masque provides a tranquil, skin drenching environment for sensitive, inflamed, rosacea prone or sunburned ...
新規合成アズレン-1-カルボキサミジン誘導体HNS-32の心血管におよぼす作用 [in Japanese] Cardiovascular Effects of Novel Azulene-1-Carboxamidine Derivative, HNS- ... A novel azulene-1-carboxamidine delivative (HNS-32) was synthesized and its cardiovascular effects were assessed using well- ... azulene-l-carboxamidine, 360.242 and dark blue, respectively. HNS-32 suppressed the sinus nodal automaticity and
... which revealed the significant impact of internally polarized azulene backbone to stabilized H2 molecules in the framework. ... Azulene based metal-organic frameworks for strong adsorption of H2†‡ Samir Barman,a Hiroyasu Furukawa,*b Olivier Blacque,a ... Azulene. based metal-organic frameworks for strong adsorption of H2 S. Barman, H. Furukawa, O. Blacque, K. Venkatesan, O. M. ...
The three azulene transitions, $^{1}L_{b}$, $^{1}L_{a}$ and $^{1}B_{b}$ shift to the blue upon solution in polar solvents. ... If so, one might expect polar solvents to shift the azulene absorption spectrum to shorter wave-lengths and the compression of ... To test these ideas the spectrum of azulene has been recorded in both polar and nonpolar solvents at temperatures down to $-80 ... Calculations by $Pariser^{1}$ have shown azulene to have excited state dipole moments opposed to that of the ground state. ...
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Start your review of Christina Moisture Cream Collagen Azulene 250ml!. How would you rate this product? ... Christina Moisture Cream Collagen Azulene 250ml. BY CHOM *. Is This Your Brand?. ...
The structure of a new naturally-occurring azulene, 1-stearoyloxymethylene-4-methyl-7-isopropenylazulene, obtained from an ... Acetone Indigo Spectral Method Acetone Extract Azulene This paper is dedicated to Prof. André Dreiding, Zürich, on the occasion ... We are aware of only 2 azulenes previously known to occur as such in nature: 1,4-dimethyl- and 1-carbomethoxy-4-methylazulene, ... For reviews on naturally-occurring azulenes, see A.J. Haagen-Smith, Fortschr. Chem. org. Nat. Stoffe5, 40 (1948); H. Taube, ...
Formulated with Azulene, a Chamomile Extract for soothing properties. Blended with Balsam Peru, a natural anti-inflammatory ... Formulated with Azulene, a Chamomile Extract for soothing properties. * Blended with Balsam Peru, a natural anti-inflammatory ...
The preparation of two new azulene-based imine ligands N-(2,6-diisopropylphenyl)-6-tBu-1-azulenylmethaneimine, 3, and N-(2,6- ... The preparation of two new azulene-based imine ligands N-(2,6-diisopropylphenyl)-6-tBu-1-azulenylmethaneimine, 3, and N-(2,6- ... Stimuli-responsive emissive behavior of 1- and 1,3-connectivities in azulene-based imine ligands: cycloplatination and Pt-Tl ... Stimuli-responsive emissive behavior of 1- and 1,3-connectivities in azulene-based imine ligands: cycloplatination and Pt-Tl ...
Mario Badescu Azulene Calming Mask: rated 4.3 out of 5 on MakeupAlley. See 3 member reviews, ingredients and photo. filter: ...
Azulene. Polarized absorption in stretched polymers and magnetic circular dichroism Erik W. Thulstrup, Patti L. Case, Josef ... Azulene : Polarized absorption in stretched polymers and magnetic circular dichroism . / Thulstrup, Erik W.; Case, Patti L.; ... Azulene : Polarized absorption in stretched polymers and magnetic circular dichroism . In: Chemical Physics. 1974 ; Vol. 6, No ... Thulstrup EW, Case PL, Michl J. Azulene: Polarized absorption in stretched polymers and magnetic circular dichroism . Chemical ...
Azulene is a main component of chamomile extract which is used as a colouring agent (azul means blue in Spanish) in cosmetics ... Examples of common substituted azulenes obtained naturally are vetivazulene (4,8-dimethyl-2-isopropylazulene) from vetiver oil ...
Substituted 1,4,10-triazadibenzo[cd,f]azulenes, substituted 1,4,5,10-tetraazadibenzo[cd,f]azulenes and.... The present ...
Увлажняющий крем с ромашкой / Chamomile Azulene Moisturizer Gigi, 75мл. Увлажняющий крем Gigi Chamomile Azulene Moisturizer ... Очищающее молочко с ромашкой / Chamomile Azulene Cleanser Gigi, 1000мл. Средство для раздраженной и гиперчувствительной кожи ... Очищающее молочко с ромашкой / Chamomile Azulene Cleanser Gigi, 250мл. Средство для раздраженной и гиперчувствительной кожи ... Маска с ромашкой для чувствительной кожи / Chamomile Azulene Mask Gigi, 250мл ...
Azulene (T3D0635). IdentificationTaxonomyBiological PropertiesPhysical PropertiesToxicity ProfileSpectraConcentrationsLinks ... Azulene is one of over 100 different polycyclic aromatic hydrocarbons (PAHs). PAHs are chemicals that are formed during the ... This compound belongs to the class of chemical entities known as azulenes. These are polycyclic aromatic compounds containing ... The Physical and Theoretical Chemistry Laboratory of Oxford University (2003). Material Safety Data Sheet (MSDS) for azulene. [ ...
Dosage AZULENE 0.05% Eye drops 10 ml bottle One drop 3 times a day in the inferior conjunctival cul-de-sac. ... Azulene side effects - Possibility of local intolerance reaction (see precautions for use). - Risk of hypersensitivity reaction ...
Tag: azulene. Nos 1-2, Janvier-Février 2007. Tome 52, Nos 1-2, Janvier-Février 2007. Download summary (PDF) ... Key words: azulene, thiophene, ethenes, carboxylic acids. 22. Maria MRACEC, Ramona RAD, Liliana OSTOPOVICI, Ana BOROTA and ... Azulene derivatives soluble in polar solvents. 1- (azulen-1-yl)-2-(thien-2- or 3-yl)-ethenes ... azulene, carbon paste electrodes, carboxylic acids, chromium complexes, cis-platinum - DNA interaction, compression, ...
Matricaria oil (azulene), arnica extract and witch hazel are blended in a naturally fragrant azulene and rose base. Tone, ... Credentials Azulene Toner is a gentle, refreshing and clarifying toner for sensitive skin. ... Home , SkinCare , Credentials Skincare , Credentials Sensitive System , Credentials Azulene Toner 6.8oz ...
... Features Quickly calms irritated and damaged skin by external stimuli or bad lifestyle ... snail secretion filtrate and azulene instead of purified water to restore damaged skin to healthier skin. Detail How To Use ... Formulated with 87% snail secretion filtrate and azulene instead of purified water to restore damaged skin to healthier skin. ...
TaC Rinseable Azulene Cleanser is specifically formulated to remove Omnis Protective Recovery Balm gently, without pain for ... Be the first to review "TaC Rinseable Azulene Cleanser" Cancel reply. Your rating *. Rate…. Perfect. Good. Average. Not that ...
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naphalene and azulene[edit]. Use a molecular gui like Macromodel make trial geometries for naphalene and azulene. Optimise the ... e.g. Azulene which has only carbon and hydrogen atoms in it but has a largeish dipole moment caused by quantum effects. This ... A good example of this is azulene, a fused pair of a five and a seven membered ring. The Huckel 4~N~+~2 rule predicts the ... Does azulene have C2v symmetry? It should have experimentally in the gas phase but some methodologies break the symmetry and ...
  • Azulene - a deep blue healing extract sourced from the essential oil of chamomile flowers, known for its superior soothing properties. (secure-booker.com)
  • The structure of a new naturally-occurring azulene, 1-stearoyloxymethylene-4-methyl-7-isopropenylazulene, obtained from an acetone extract of the blue mushroom Lactarius indigo , has been determined by chemical and spectral methods. (springer.com)
  • Azulene is a main component of chamomile extract which is used as a colouring agent (azul means blue in Spanish) in cosmetics and ointments and used as a folk medicine to treat migraine, arthritis, rheumatic diseases, and allergy. (chemicalland21.com)
  • Matricaria oil (azulene), arnica extract and witch hazel are blended in a naturally fragrant azulene and rose base. (yahoo.net)
  • Azulene, Chamomile Extract. (rosejoyce.com)
  • Formulated with 87% snail secretion filtrate and azulene instead of purified water to restore damaged skin to healthier skin. (jolse.com)
  • TIA'M Snail & Azulene Water Essence contains no filler ingredients - 87% of this magical bottle is composed of snail secretion filtrate and azulene to quickly soothe redness and irritation. (littlewonderland.nl)
  • Nature Pure's Azulene-Seaweed Masque is a fast-acting spa treatment that improves smoothness of the skin. (happi.com)
  • Azulene Soothing Masque provides a tranquil, skin drenching environment for sensitive, inflamed, rosacea prone or sunburned skin. (secure-booker.com)
  • Enter your email to be notified by email when Aloe and Azulene Gel Masque becomes available. (essencedebeaute.com)
  • Elaine Gregg Aloe and Azulene Gel Masque has been specially developed for improving skin texture and reducing irritation. (beautystoredepot.com)
  • The gel masque is formulated with a blend of Aloe Vera gel, lavender oil, azulene, sodim hyaluronate and other beneficial ingredients that aid in healing damaged or irritated skin. (beautystoredepot.com)
  • The Elaine Gregg Aloe and Azulene Gel Masque is a great treatment to soothe skin after extractions, waxing and professional glycolic and laser treatments. (beautystoredepot.com)
  • Amber Azulene Soothing Masque 4 Oz. (massagewarehouse.com)
  • By relying on a new-generation Azulene Complex, this purified skincare product almost immediately calms any discomforting sensations on the skin. (mylipfiller.com)
  • HOW IT WORKS: Bentonite Clay - deep cleanses & purifies, Arabica Coffee - invigorates, rejuvenates and helps promote hair growth and Azulene - soothes and calms. (healthyseniorlifestyle.com)
  • Azulene calms redness. (thehut.com)
  • Powerhouse ingredients betaine, allantoin, and panthenol support the moisturizing and soothing effects of snail and azulene, ensuring that redness and irritation is significantly reduced. (littlewonderland.nl)
  • Main Ingredients: Azulene Complex. (ibeautymachine.com)
  • Green Tea Botanicals Gentle Azulene Toner is an excellent toner for dry and sensitive skin types containing natural ingredients combined with Azulene (Chamomile). (skin-beauty.com)
  • These are polycyclic aromatic compounds containing the azulene skeleton, which consists of the cyclopentadiene ring fused to a cycloheptadiene ring. (t3db.ca)
  • The soothing effects of Aloe and Azulene soothe and reduce irritation. (essencedebeaute.com)
  • Green Tea Botanicals Gentle Azulene Toner helps to heal and soothe the epidermis while. (skin-beauty.com)
  • Finish with Azulene oil to soothe your skin and remove any traces of excess wax. (target.com)
  • Liquid Azulene Wax soothes the skin and reduces the redness suffered by so many clients. (spaorder.com)
  • Azulene is known for its soothing and anti-inflammatory properties and is widely used in shaving creams, bath salts and creams. (madoverchemistry.com)
  • Skin irritations and inflammations that are a direct result of excessive sebum production no longer stand a chance because Derma Science 72% Azulene Complex Ampoule 50ml targets namely this cosmetic concern. (mylipfiller.com)
  • Patients who have been struggling with any of these concerns should not think twice before adding Derma Science 72% Azulene Complex Ampoule to their daily skincare routine. (mylipfiller.com)
  • Derma Science 72% Azulene Complex Ampoule 50ml is a trusted product from Histolab's advanced Derma Science range. (mylipfiller.com)
  • Azulene is a bicyclic aromatic hydrocarbon containing a five - and seven- membered ring fused together. (madoverchemistry.com)
  • Guaiazulene (1,4-dimethyl-7-isopropylazulene) is an alkylated derivative of azulene with an almost identical intensely blue colour. (wikipedia.org)
  • The blue color of this mushroom is due to an azulene derivative. (madoverchemistry.com)
  • Two terpenoids, vetivazulene (4,8-dimethyl-2-isopropylazulene) and guaiazulene (1,4-dimethyl-7-isopropylazulene), that feature the azulene skeleton are found in nature as constituents of pigments in mushrooms, guaiac wood oil, and some marine invertebrates. (wikipedia.org)
  • Examples of common substituted azulenes obtained naturally are vetivazulene (4,8-dimethyl-2-isopropylazulene) from vetiver oil, and guaiazulene (1,4-dimethyl-7-isopropylazulene) from constituent of guaiac wood oil. (chemicalland21.com)
  • Vetivazulene is an azulene derivate obtained from vetiver oil. (wikipedia.org)
  • If so, one might expect polar solvents to shift the azulene absorption spectrum to shorter wave-lengths and the compression of such solutions to result in additional blue shifts. (osu.edu)
  • Light absorption in the azulene S-1-band, followed by fast internal conversion, leads to vibrational excitation at the azulene side of the molecules. (mpg.de)
  • Subsequent energy flow through the aliphatic chain to the aryl group at the other side of the molecules and vibrational energy transfer into a surrounding liquid solvent bath are measured either by probing the red edge of the azulene S-3-absorption band at 300 nm and/or the anthracene S-1- absorption, band at 400 nm. (mpg.de)
  • Credentials Azulene Toner is a gentle, refreshing and clarifying toner for sensitive skin. (yahoo.net)
  • Azulene is an organic compound and an isomer of naphthalene. (wikipedia.org)
  • Whereas naphthalene is colourless, azulene is dark blue. (wikipedia.org)
  • In naphth[a]azulene, a naphthalene ring is condensed at the 1,2-positions of azulene. (wikipedia.org)
  • naphthalene and azulene. (gaussian.com)
  • Studying naphthalene and azulene is useful in that doing so allows students to compare the properties of two superficially similar molecules. (gaussian.com)
  • Naphthalene is white colored whereas azulene is a dark blue colored solid . (madoverchemistry.com)
  • Azulene is one of over 100 different polycyclic aromatic hydrocarbons (PAHs). (t3db.ca)
  • Calculations by $Pariser^{1}$ have shown azulene to have excited state dipole moments opposed to that of the ground state. (osu.edu)
  • This polarity can be explained by regarding azulene as the fusion of a 6 π-electron cyclopentadienyl anion and a 6 π-electron tropylium cation: one electron from the seven-membered ring is transferred to the five-membered ring to give each ring aromatic stability by Hückel's rule. (wikipedia.org)
  • Procedure: cycloheptatriene 2+2 cycloaddition with dichloro ketene diazomethane insertion reaction dehydrohalogenation reaction with DMF Luche reduction to alcohol with sodium borohydride elimination reaction with Burgess reagent oxidation with p-chloranil dehalogenation with polymethylhydrosiloxane, palladium(II) acetate, potassium phosphate and the DPDB ligand In organometallic chemistry, azulene serves as a ligand for low-valent metal centers, which otherwise are known to form π-complexes with both cyclopentadienyl and cycloheptatrienyl ligands. (wikipedia.org)
  • The preparation of two new azulene-based imine ligands N -(2,6-diisopropylphenyl)-6- t Bu-1-azulenylmethaneimine, 3 , and N -(2,6-diisopropylphenyl)-6- t Bu-3-(2,6-diisopropylphenyliminomethyl)-1-azulenylmethaneimine, 4 , is described. (rsc.org)
  • Illustrative complexes are (azulene)Mo2(CO)6 and (azulene)Fe2(CO)5. (wikipedia.org)
  • Cycloheptatrienyl or tropylium complexes are also considered, along with cyclo-octatetraene, azulene complexes, and carborane complexes. (elsevier.com)
  • Another notable feature of azulene is that it violates Kasha's rule by exhibiting fluorescence from an upper-excited state (S2 → S0). (wikipedia.org)
  • Phosphorescence and E-type delayed fluorescence from azulene in phenazine host crystals. (mpg.de)
  • 34 wax strips total (17 double-sided), azulene finishing oil: 0.5 fl oz (14.7 ml), instructions. (jewelosco.com)
  • 34 wax strips (17 double-sided), azulene finishing oil. (jewelosco.com)
  • 30 Wax strips (15 double sided), 0.5 OZ azulene oil. (cvs.com)
  • Sensitive Skin Azulene Wax is specially designed to be extra gentle for sensitive areas of the face and body, as well as provide additional care to clients with sensitive skin conditions. (expressnailsupply.com)
  • Delicately apply Chamomile Azulene Moisturizer on thoroughly cleansed skin. (rosejoyce.com)
  • Chamomile, Azulene and Aloe leaves skin soft, smooth and decongested. (pevonia.co.uk)
  • Не забудьте правильно указать полный точный адрес доставки, чтобы получить Elastin Collagen Azulene Moisture Cream with Vitamins A, E & HA for normal skin вовремя. (sarapul-forum.ru)
  • Мы рекомендуем ознакомиться с отзывами о "Elastin Collagen Azulene Moisture Cream with Vitamins A, E & HA for normal skin" перед тем как сделать заказ. (sarapul-forum.ru)
  • Complete kit includes: Brazilian wax, Azulene finishing oil, 20 cloth strips, & 8 Natural wood spatulas. (target.com)
  • This compound belongs to the class of chemical entities known as azulenes. (t3db.ca)
  • A small-sized bomb makes this experiment practical even for a compound as expensive as azulene since a modest sample size (approximately 100 mg) can be used. (gaussian.com)
  • Start your review of Christina Moisture Cream Collagen Azulene 250ml! (influenster.com)
  • We use both pure essential blue chamomile (chama-azulene) and roman chamomile oils in our Blue Chamomile Facial Wash Cream. (carolpriest.co.nz)
  • For reviews on naturally-occurring azulenes, see A.J. Haagen-Smith, Fortschr. (springer.com)
  • Azulene is usually viewed as resulting from fusion of cyclopentadiene and cycloheptatriene rings. (wikipedia.org)
  • Preformed azulene pigments of Lactarius indigo (Schw. (wikipedia.org)
  • The guest free MOF-646 showed strong MOF-H 2 interactions (7.8-6.8 kJ mol −1 ), which revealed the significant impact of internally polarized azulene backbone to stabilized H 2 molecules in the framework. (rsc.org)
  • Contains avocado oil, vitamins & pure azulene for nourishing & soothing benefits. (ebay.co.uk)
  • Azulene has a long history, dating back to the 15th century as the azure-blue chromophore obtained by steam distillation of German chamomile. (wikipedia.org)
  • 2-picolino) azulene-l-carboxamidine, 360.242 and dark blue, respectively. (nii.ac.jp)
  • The three azulene transitions, $^{1}L_{b}$, $^{1}L_{a}$ and $^{1}B_{b}$ shift to the blue upon solution in polar solvents. (osu.edu)
  • This dipolar nature gives azulene its blue color. (madoverchemistry.com)
  • When freshly distilled this oil is blue due to the presence of azulene. (healthy.net)
  • Azulene imparts the deep blue colour to the essential oil. (healthy.net)
  • Lethal and Sublethal Effects of Azulene and Longifolene to Microtox®, Ceriodaphnia dubia, Daphnia magna, and Pimephales promelas" (PDF). (wikipedia.org)
  • A novel azulene-1-carboxamidine delivative (HNS-32) was synthesized and its cardiovascular effects were assessed using well-established isolated, blood-perfused, canine sinoatrial node, papillary muscle and atrioventricular node preparations. (nii.ac.jp)