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Stevens-Johnson Syndrome
Rare cutaneous eruption characterized by extensive KERATINOCYTE apoptosis resulting in skin detachment with mucosal involvement. It is often provoked by the use of drugs (e.g., antibiotics and anticonvulsants) or associated with PNEUMONIA, MYCOPLASMA. It is considered a continuum of Toxic Epidermal Necrolysis.
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Phenylacetates
Derivatives of phenylacetic acid. Included under this heading are a variety of acid forms, salts, esters, and amides that contain the benzeneacetic acid structure. Note that this class of compounds should not be confused with derivatives of phenyl acetate, which contain the PHENOL ester of ACETIC ACID.
Amino acid residues in the transmembrane domain of the type 1 sigma receptor critical for ligand binding. (1/262)
The type 1 sigma receptor expressed in Xenopus oocytes showed binding abilities for the sigma-1 ligands, [3H](+)pentazocine and [3H]NE-100, with similar kinetic properties as observed in native tissue membranes. Amino acid substitutions (Ser99Ala, Tyr103Phe and di-Leu105,106di-Ala) in the transmembrane domain did not alter the expression levels of the type 1 sigma receptor as determined by immunoblot analysis using an anti-type 1 sigma receptor antiserum. By contrast, ligand binding was significantly suppressed by the substitutions. These findings provide evidence that the transmembrane domain of the type 1 sigma receptor plays a critical role in ligand binding of this receptor. (+info)A-Current down-modulated by sigma receptor in frog pituitary melanotrope cells through a G protein-dependent pathway. (2/262)
Gramicidin perforated patch-clamp recordings were used to study the effects of two sigma 1 receptor ligands, (+)-N-cyclopropylmethyl-N-methyl-1, 4-diphenyl-1-ethyl-but-3-en-1-ylamine hydrochloride (JO 1784) and (+)-pentazocine, on the transient outward potassium current (IA) in cultured frog melanotrope cells. (+)-Pentazocine reversibly decreased the current amplitude in a dose-dependent manner. The effects of (+)-pentazocine were mimicked by JO 1784 and were markedly reduced by the sigma 1 receptor antagonist, N, N-dipropyl-2-[4-methoxy-3-2(2-phenylethoxy)phenyl]-ethylamine monohydrochloride (NE 100). Inactivation rate of IA was best fitted with a double exponential function, yielding time constants of 23.7 and 112.5 ms. (+)-Pentazocine (20 microM) accelerated the current decay, decreasing the time constants to 10.7 and 59 ms, respectively. Current-voltage experiments revealed that (+)-pentazocine (20 microM) did neither modify the open-state I/V curves nor the voltage dependence of IA. However, (+)-pentazocine (20 microM) shifted the steady-state inactivation curve toward more negative potentials and increased the time constant of the time-dependent removal of inactivation. In whole-cell experiments, internal dialysis of guanosine-5'-O-(3-thiophosphate) (100 microM) irreversibly prolonged the response to (+)-pentazocine. In addition, cholera toxin pretreatment (1 microgram. ml-1; 12 h) suppressed the inhibition of IA by (+)-pentazocine (20 microM). It is concluded that in frog melanotrope cells, a cholera toxin-sensitive, G protein-dependent inhibition of IA through a sigma 1 receptor activation, at least partially, underlies the excitatory effect of sigma ligands. (+info)Sigma1 recognition sites in rabbit iris-ciliary body: topical sigma1-site agonists lower intraocular pressure. (3/262)
In this study, we examined the presence of sigma1 and sigma2 sites in the rabbit iris-ciliary body by receptor binding and investigated their effects on intraocular pressure (IOP) in albino rabbits. The iris-ciliary body has binding sites for the sigma1-site agonist [3H](+)-pentazocine (Kd = 4.6 nM; Bmax = 212 fmol/mg protein) and sigma2 sites labeled with [3H]1,3-di-o-tolylguanidine (DTG) (Kd = 8. 2 nM; Bmax = 1120 fmol/mg protein). In competition binding studies, (+)-pentazocine and the sigma antagonist NE-100 displayed high affinity for sigma1 sites (Ki = 2.1 and 2.4 nM, respectively), whereas (+)-N-allylnormetazocine (NANM) was less potent (Ki = 178 nM). Unilateral topical (+)-pentazocine (0.01-0.1%) caused a significant dose-related reduction of IOP in ocular normotensive rabbits and in the alpha-chymotrypsin model of ocular hypertension. (+)-NANM was less potent than (+)-pentazocine. Neither compound altered the IOP of the contralateral eye, and their hypotensive activity was blocked by NE-100 that, by itself, had no effect on IOP. (-)-Pentazocine, (-)-NANM, and DTG had no effect on IOP. DTG prevented the hypotensive effect of (+)-pentazocine, suggesting that it acts as a sigma1-site antagonist. sigma-Site ligands did not affect pupil diameter or cause ocular inflammation. Topical [3H](+)-pentazocine reaches the intraocular tissues within 30 min, and its uptake in the iris-ciliary body and retina was significantly reduced by topical pretreatment with NE-100, as expected for a receptor-specific agent. Reverse-phase HPLC confirmed the presence of intact (+)-pentazocine in iris-ciliary body homogenates. sigma1-Site agonists may offer a novel class of agents potentially effective in the control of ocular hypertension. (+info)Mechanism-based inactivation of rat liver cytochrome P-450 2B1 by 2-methoxy-5-nitrobenzyl bromide. (4/262)
Mechanism-based inactivators serve as probes of enzyme mechanism, function, and structure. Koshland's Reagent II (2-methoxy-5-nitrobenzyl bromide, KR-II) is a potential mechanism-based inactivator of enzymes that perform O-dealkylations. The major phenobarbital-inducible form of cytochrome P-450 in male rat liver microsomes, CYP2B1, is capable of catalyzing O-dealkylations. The interactions of KR-II with purified CYP2B1 in the reconstituted system containing P-450, NADPH:P-450 oxidoreductase, and sonicated dilaurylphosphatidyl choline were studied. The benzphetamine N-demethylase activity of CYP2B1 was inactivated by KR-II in a time- and NADPH-dependent manner, and the loss of activity followed pseudo-first-order kinetics. The inactivation also required KR-II, and the rate of activity loss was dependent on the concentration of KR-II in a saturable fashion. The inactivator concentration required for the half-maximal rate of inactivation (KI) was approximately 0.1 mM. The inactivation was not prevented by the addition of the nucleophiles dithiothreitol and glutathione, nor was it reversed by gel filtration. The present results demonstrate that KR-II is a mechanism-based inactivator of rat CYP2B1. (+info)Odor response properties of rat olfactory receptor neurons. (5/262)
Molecular biology studies of olfaction have identified a multigene family of molecular receptors that are likely to be involved in odor transduction mechanisms. However, because previous functional data on peripheral coding were mainly collected from inferior vertebrates, it has been difficult to document the degree of specificity of odor interaction mechanisms. As a matter of fact, studies of the functional expression of olfactory receptors have not demonstrated the low or high specificity of olfactory receptors. In this study, the selectivity of olfactory receptor neurons was investigated in the rat at the cellular level under physiological conditions by unitary extracellular recordings. Individual olfactory receptor neurons were broadly responsive to qualitatively distinct odor compounds. We conclude that peripheral coding is based on activated arrays of olfactory receptor cells with overlapping tuning profiles. (+info)New studies on trans-anethole oxide and trans-asarone oxide. (6/262)
The widespread use of naturally occurring alkenylbenzenes as flavoring and fragrance agents has led to a long-standing interest in their toxicity and carcinogenicity. Among them several allyl- and propenylbenzenes have been found to be mutagenic and carcinogenic. It has been shown that the carcinogenicity of several allylbenzenes can be related to the formation of electrophilic sulfuric acid esters following 1'-hydroxylation. Unlike the allylbenzenes, the mechanisms of carcinogenesis of propenylbenzenes such as anethole and asarone are not clear. It has been reported that one of the main metabolic pathways of trans-anethole is the epoxidation of the side chain 1,2-double bond, which was responsible for cytotoxicity but not for genotoxicity. However, we report here that synthetic trans-anethole oxide prepared from trans-anethole and dimethyldioxirane is not only mutagenic for Salmonella tester strains but is also carcinogenic in the induction of hepatomas in B6C3F1 mice and skin papillomas in CD-1 mice. Synthetic trans-asarone oxide was also carcinogenic in the induction of hepatomas as well as mutagenic for Salmonella strains. Further studies are needed on these side chain oxides of trans-anethole and trans-asarone as possible metabolites in the toxicity, mutagenicity and carcinogenicity of these and other propenylbenzenes. (+info)Dose-response trend tests for tumorigenesis, adjusted for body weight. (7/262)
Several studies have demonstrated a relationship between rodent body weight and tumor incidence for some tissue/organ sites. It is not uncommon for a chemical tested for carcinogenicity to also affect body weight. In such cases, comparisons of tumor incidence may be biased by body-weight differences across dose groups. A simple procedure was investigated for reducing this bias. This procedure divides the animals into a few groups based on body weight. Body weight at 12 months was used, before the appearance of a tumor was likely to affect body weight. Statistics for dose-response trend tests are calculated within body weight strata and pooled to obtain an overall dose-response trend test. This procedure is analogous to that currently used, of stratifying animals, based on their age at the time of removal from a study. Age stratification is used to account for differences in animal age across dose groups, which can affect comparisons of tumor incidence. Several examples were investigated where the high-dose group had reduced body weights and associated reductions in tumor incidence. When the data were analyzed by body-weight strata, some positive dose-response trends for tumor incidence were demonstrated. In one case, the weight-adjusted analysis indicated that a negative dose-response trend in tumor incidence was a real effect, in addition to a body weight reduction. These examples indicate that it is important to consider the effects of body weight changes as low as 10%, and perhaps below, that were caused by chemicals in 2-year bioassays for carcinogenesis. The simple procedure of analyzing tumor incidence within body-weight strata can reduce the bias introduced by weight differences across dose groups. (+info)Induction of apoptosis in leukemic cells by the reversible microtubule-disrupting agent 2-methoxy-5-(2',3',4'-trimethoxyphenyl)-2,4,6-cycloheptatrien-1 -one: protection by Bcl-2 and Bcl-X(L) and cell cycle arrest. (8/262)
We have found that the bicyclic colchicine analogue 2-methoxy-5-(2',3',4'-trimethoxyphenyl)-2,4,6-cycloheptatrien-1-on e (MTC) induced a dose- and time-dependent apoptotic response in human leukemic cells. MTC and colchicine rapidly disrupted the microtubule integrity and arrested cells at the G2-M phase before the onset of apoptosis. These responses were mediated by microtubule inhibition because 2-methoxy-5-[[3-(3,4,5-trimethoxyphenyl)propionyl]amino]-2,4,6-cycloh eptatrien-1-one and lumicolchicine, inactive analogues of MTC and colchicine, respectively, were unable to promote microtubule disassembly, cell cycle arrest, and apoptosis. Although 1 microM MTC induced a complete microtubule disruption after 1 h of incubation in human leukemic HL-60 cells that led to an accumulation of cells at the G2-M phase, MTC-induced apoptosis occurred after 9 h of treatment. This indicates the existence of a rather long lag between microtubule disruption and the onset of apoptosis. Unlike colchicine, the removal of MTC during this lag resulted in rapid microtubule repolymerization, followed by restoration of normal cell cycle and cell growth. MTC, but not 2-methoxy-5-[[3-(3,4,5-trimethoxyphenyl)-propionyl]amino]-2,4,6-cyclo heptatrien-1-one, induced c-jun expression as well as c-Jun NH2-terminal kinase and caspase activation, indicating that these signaling pathways are triggered by the specific action of MTC on microtubules. Caspase inhibition prevented MTC-induced apoptosis. Overexpression of bcl-2 or bcl-xL by gene transfer in human erythroleukemic HEL cells abrogated MTC-induced apoptosis, but cells remained arrested in G2-M, suggesting that bcl-2 and bcl-xL block the signaling pathway between G2-M arrest and triggering of apoptosis. MTC-treated bcl-2 and bcl-xL-transfected HEL cells recovered their capacity to proliferate after MTC removal. These results indicate that microtubule inhibition induces G2-M arrest and apoptosis in leukemic cells, showing a lag phase between G2-M arrest and the onset of apoptosis, regulated by bcl-2 and bcl-xL, during which MTC displays a reversible action on microtubule depolymerization and G2-M cell cycle arrest. Thus, MTC is a potent apoptotic inducer on human leukemic cells and shows a remarkable reversible action on microtubule network and cell cycle before commitment for apoptosis is reached. (+info)
Alkali-metal-mediated zincation of anisole: synthesis and structures of three instructive ortho-zincated complexes<...
Peer Evaluation : Thermal, Spectroscopic and Chemical Characterization of Biofield Energy Treated Anisole
1,3-Dimethoxybenzene 99%, ACROS Organics™ 100g; Glass bottle 1,3-Dimethoxybenzene 99%, ACROS Organics™
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US Patent for Method for remediating environmental contaminants Patent (Patent # 5,711,020 issued January 20, 1998) - Justia...
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Potentiation of neuronal NMDA response induced by dehydroepiandrosterone and its suppression by progesterone: effects mediated...
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Beta-asarone, a major component of Acorus tatarinowii Schott, attenuates focal cerebral ischemia induced by middle cerebral...
Rapid conversion of glycerol to lactic acid under alkaline hydrothermal conditions, by using a continuous flow reaction system<...
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Methylation
Hiers, G. S. (1929). "Anisole". Organic Syntheses. 9: 12. doi:10.15227/orgsyn.009.0012. Icke, Roland N.; Redemann, Ernst; ... A wide variety of phenols undergo O-methylation to give anisole derivatives. This process, catalyzed by enzymes such as ...
Phenol ether
Anisole is formally known as methoxybenzene, and is formed through the condensation of methanol (CH3OH) and phenol; due to the ... Anisole (C6H5OCH3) is the simplest phenol ether, and is a versatile precursor for perfumes and pharmaceuticals. Vanillin and ... "Anisole". pubchem.ncbi.nlm.nih.gov. Retrieved 2021-03-29. Lipinski, Christopher A. (December 2004). "Lead- and drug-like ... compared to 3500-4000 mg/kg for anisole, the methyl ether. Furthermore, ethers are significantly more hydrophobic than phenols ...
Alkylation
G. S. Hiers and F. D. Hager (1941). "Anisole". Organic Syntheses.; Collective Volume, 1, p. 58 H. Perst; D. G. Seapy (2008). " ...
Ether
Anisole (methoxybenzene) An aryl ether and a major constituent of the essential oil of anise seed. ... Methyl phenyl ether is anisole, because it was originally found in aniseed. The aromatic ethers include furans. Acetals (α- ...
4-Bromoanisole
Anisole Stille, J. K.; Echavarren, Antonio M.; Williams, Robert M.; Hendrix, James A. (1993). "4-Methoxy-4'-Nitrobiphenyl". ...
Butylated hydroxyanisole
Anisole "BHA and BHT". Retrieved Nov 20, 2009. "SciFinder - Experimental properties for 121-00-6". Retrieved Nov 20, 2009. ...
Creosote
... better known as anisole, and water, which is not shown in the diagram. Anisole is listed as an acute hazard to aquatic life ... Balsama et al 1984 "Anisole". PubChem Database. National Center for Biotechnology Information. Retrieved April 7, 2019. Clarke ...
Murburn concept
"Biohalogenation as a source of halogenated anisoles in air". Chemosphere. 22 (5-6): 557-567. doi:10.1016/0045-6535(91)90067-N. ...
Tris(4-methoxyphenyl)phosphine
Triphenylphosphine 2-(Diphenylphosphino)anisole Evans, D.; Osborn, J. A.; Wilkinson, G. (1968). "Hydroformylation of alkenes by ...
Cresol
Anisole converts to cresols under these conditions. Cresols are precursors or synthetic intermediates to other compounds and ...
Fritsch-Buttenberg-Wiechell rearrangement
Wiechell, H. (1894). "Condensation des Dichloracetals mit Anisol und Phenetol". Justus Liebig's Annalen der Chemie. 279 (3): ...
Methoxy group
Other methoxy ethers include anisole and vanillin. Many alkoxides contain methoxy groups, e.g. tetramethyl orthosilicate and ...
Hexamethylbenzene
Both anisole and pentamethylbenzene have been reported as intermediates in the process. Valentin Koptyug and co-workers found ... Formation of anisole, methylated phenols, and hexamethylbenzene". J. Chem. Soc.: 821-823. doi:10.1039/JR9450000821. PMID ... though as part of a complex mixture of anisole (methoxybenzene), cresols (methylphenols), and other methylated phenols. An ...
Ether
Methyl phenyl ether is anisole, because it was originally found in aniseed. The aromatic ethers include furans. Acetals (α- ... Illustrative unsymmetrical ethers are anisole (methoxybenzene) and dimethoxyethane. In the IUPAC Nomenclature system, ethers ...
Functional group
Anisole. (Methoxybenzene) Hydroperoxide Hydroperoxy ROOH hydroperoxy- alkyl hydroperoxide tert-Butyl hydroperoxide Peroxide ...
2-Methoxybenzaldehyde
2-Anisaldehyde is prepared commercially by formylation of anisole. A. J. Sisti (1964). "o-Anisaldehyde". Org. Synth. 44: 4. doi ...
Retained name
Glycerol and acetic acid are examples of retained semisystematic names; furan and anisole are examples of retained trivial ...
Latamoxef
Deblocking with aluminium chloride and anisole gives moxalactam 14. Weitekamp MR, Aber RC (1983). "Prolonged bleeding times and ...
Tert-Butyloxycarbonyl protecting group
... scavengers such as anisole or thioanisole may be used. Selective cleavage of the N-Boc group in the presence of other ...
Di-tert-butyl dicarbonate
... scavengers such as anisole or thioanisole may be used. Selective cleavage of the N-Boc group in the presence of other ...
Weak-Link Approach
Reactivity and structure of dichlorobis(o-(diphenylphosphino)anisole)ruthenium(II)". Inorganic Chemistry. 18 (10): 2658. doi: ...
Birch reduction
The reduction of anisole is one of the simplest examples and is shown in equation 1. The reduction of benzoic acid is ... These steps are outlined below for the case of anisole. The reaction is known to be third order - first order in aromatic, ... Then in 1990 and 1993 a method was finally devised to experimentally assess whether the anisole and toluene radical anion ... doi:10.1016/0040-4020(59)85008-0. Burnham, D. R. (1969). "Orientation in the mechanism of the Birch reduction of anisole". ...
Zeisel determination
Synthetic applications: Experimental procedure with anisole and methylbenzoate Zeisel, S (1885). "Über ein Verfahren zum ...
Chromium hexacarbonyl
Such reactions proceed well with electron-rich arenes such as anisole. The products adopt a "piano-stool" structure. These ...
Physical organic chemistry
... anisole" (PDF). Journal of Physical Organic Chemistry. 25 (10): 878-882. doi:10.1002/poc.2939. Chen, Chen; Ke, Jiyuan; Zhou, X ...
Desorption atmospheric pressure photoionization
The transfer of positive ions, such as protons and charge transfers, are seen with the solvents: toluene and anisole. Toluene ... Some of the common solvents include: nitrogen, toluene, acetone, and anisole. The desorption process can occur by two ...
Fulvio Cacace
"Gas-phase reaction of free isopropyl ions with phenol and anisole". (1980) "Aromatic substitution in the gas phase. A ... "Gas-phase reaction of free isopropyl ions with phenol and anisole". Journal of the Chemical Society, Perkin Transactions 2, ...
2,4-Dinitroanisole
It has an anisole (methoxybenzene) core, with two nitro groups (-NO2) attached. It is not explosive itself unless it is mixed ...
Anethole
It is prepared commercially from 4-methoxypropiophenone, which is prepared from anisole. Anethole is distinctly sweet, ... On the constitution of anisol (anethol)]. Zeitschrift für Chemie. 2nd Series. 2: 472-474. Media related to Anethole at ...
Cyclohexenone
... is obtained by Birch reduction of anisole followed by acid hydrolysis. It can be obtained from cyclohexanone by α ...
Anisole
Anisole - Wikipedia
For example, synthetic anethole is prepared from anisole. Anisole is relatively nontoxic with an LD50 of 3700 mg/kg in rats. ... Anisole, or methoxybenzene, is an organic compound with the formula CH3OC6H5. It is a colorless liquid with a smell reminiscent ... ISBN 978-0-85404-182-4. Anisole, C6H5-O-CH3, is the only name in the class of ethers which is retained both as a preferred ... Anisole undergoes electrophilic aromatic substitution reaction at a faster speed than benzene, which in turn reacts more ...
Anisole | Definition of Anisole at Dictionary.com
Anisole definition, a colorless, water-insoluble liquid, C7H8O, having a pleasant, aromatic odor, used chiefly in perfumery and ... anisole. *. For diethyl ether see Ether, and for methyl phenyl ether (anisole) and ethyl phenyl ether (phenetole) see Carbolic ... anisole. anisogamete, anisogamous, anisogamy, anisognathous, anisokaryosis, anisole, anisomastia, anisomelia, anisomeric, ...
Anisole, p-nitroso
The National Institute of Standards and Technology (NIST) uses its best efforts to deliver a high quality copy of the Database and to verify that the data contained therein have been selected on the basis of sound scientific judgment. However, NIST makes no warranties to that effect, and NIST shall not be liable for any damage that may result from errors or omissions in the Database ...
2-(Diphenylphosphino)anisole - Wikipedia
Anisole - Registered substances - ECHA
The data comes from registration dossiers submitted to ECHA by the date indicated as last update. The Total Tonnage Band is compiled from all the dossiers with two exceptions; any tonnages claimed confidential and any quantity used as an intermediate to produce a different chemical. The Total Tonnage band published does not necessarily reflect the registered tonnage band(s).. Please note that some of the information on registered substances may belong to third parties. The use of such information may therefore require the prior permission of the third party owners. Please consult the Legal Notice for further information.. ...
The pyrolysis of anisole (C6H5OCH3) using a hyperthermal nozzle | RTI
We have investigated the pyrolysis of anisole (C6H5OCH3), a model compound for methoxy functional groups in lignin. An ... The route to the formation of naphthalene from anisole follows the simple unimolecular decomposition of anisole, which leads to ... We have investigated the pyrolysis of anisole (C6H5OCH3), a model compound for methoxy functional groups in lignin. An ... and factor analysis to demonstrate the formation of naphthalene from the pyrolysis of anisole. ...
Effects of tertiary amine catalysis on the regioselectivity of anisole chlorination with trichloroisocyanuric acid |...
... amines and their salts in dichloromethane were found to induce a strong pararegioselectivity in the chlorination of anisole as ... The regioselectivity and monochlorination selectivity for anisole chlorination with TCCA in numerous solvents are reported. The ... Effects of tertiary amine catalysis on the regioselectivity of anisole chlorination with trichloroisocyanuric acid. ... amines and their salts in dichloromethane were found to induce a strong para regioselectivity in the chlorination of anisole as ...
Managing the Halo-Anisoles (TBA, TPA, TCA) and Halo-Phenols - Unified Wine & Grape Symposium
2-Chloro-3-(trifluoromethyl)anisole, suppliers and manufacturers
NOPR: Kinetics & Mechanism of Chlorination of Anisole & Substituted Anisoles by Chloramine-T
Thermal, Spectroscopic and Chemical Characterization of Biofield Energy
Treated Anisole | OMICS International
... and chemical properties of anisole by various an.. ... Anisole, phenyl ether (Ph-O-Me, Figure 1) usually used as a ... Anisole was studied to see the influence of biofield energy treatment and isotopic abundance ratio of treated anisole was ... The method development for this assay of anisole based on its chemical properties. Anisole is polar molecule and therefore, a ... After performing various analytical studies on biofield treated anisole, it was found that anisole has shown a strong response ...
Aromatic substitution in the gas phase. Part II. Reactions of the helium tritiide ion with anisole, t-butylbenzene, and ααα...
The study of the gas-phase reactions of the HeT ion from the β-decay of molecular tritium is extended to anisole, t- ... The study of the gas-phase reactions of the HeT+ ion from the β-decay of molecular tritium is extended to anisole, t- ... Reactions of the helium tritiide ion with anisole, t-butylbenzene, and ααα-trifluorotoluene F. Cacace, R. Cipollini and G. ... Reactions of the helium tritiide ion with anisole, t-butylbenzene, and ααα-trifluorotoluene ...
[email protected]: 1087: NEW THREAD: 2% 950K MW PMMA -A (in Anisole solvent) data.
495K MW PMMA With anisole today. Come and take a spin with me... Clifford Hicks wrote: , ,I spun 2% PMMA with anisole onto ... Subject: NEW THREAD: 2% 950K MW PMMA -A (in Anisole solvent) data. From: James Conway ,[email protected], Date: Wed, 23 Feb ... Re: Spinning 5% 495K MW PMMA With anisole today. Come and take a spin with me.... Clifford Hicks wrote:. I spun 2% PMMA with ... Greetings Raith Users: During the last month I have started working with the 2% 950K MW PMMA in Anisole material, carefully ...
Deoxygenation in anisole decomposition over bimetallic catalysts supported on HZSM-5 - Strathprints
Zhang_etal_Fuel2018_Deoxygenation_in_anisole_decomposition_over_bimetallic_catalysts.pdf Accepted Author Manuscript License: ... Density Functional Theory (DFT) modelling was carried out in order to study the adsorption energy of anisole and phenol ... This work investigated the deoxygenation reaction in anisole decomposition over HZSM-5 (HZ(25)) zeolite supported bimetallic ... anisole, bimetallic supported catalyst, catalytic decomposition, deoxygenation, lignin, phenolic compounds, Chemical ...
NOPR: Excess Volume of Mixing for Binary Mixtures of Pyridine, Acrylonitrile, Anisole & Acetylacetone with Carbon Tetrachloride
Mass Spectra of Pentachloroanisole QuEChERS Extracts of Tylenol Spiked with Anisoles and TBA on Rxi-5Sil MS / Restek Searchable...
Anisole | CAS 100-66-3 | C7H8O | P212121 Store
Acid violet 43, 2-amino-4-hyd roxyethylamino anisole sulfate, 2,6-Bis[(2-hyd roxyethyl)amino]toluene, Products Catalog
2-amino-4-hyd roxyethylamino anisole sulfate, 2,6-Bis[(2-hyd roxyethyl)amino]toluene ... inquire2-amino-4-hyd roxyethylamino anisole sulfate CAS NO : 83763-48-8; MF : C9H16N2O6S ;2-smino-4-n-( beta -hydroxyethyl) ... amino anisole sulfate;5-(2-Hydroxyethylamino)-2-methoxylaniline sulfate;2-Amino-4-hydroxyethylamino anisole sulfate;2-[(3-amino ...
AROMATIC SULFONATION .91. THE SULFONATION OF ANISOLE, PHENOL, PHENYL METHANESULFONATE, POTASSIUM PHENYL SULFATE, AND A SERIES...
THE SULFONATION OF ANISOLE, PHENOL, PHENYL METHANESULFONATE, POTASSIUM PHENYL SULFATE, AND A SERIES OF METHYL-SUBSTITUTED, ... THE SULFONATION OF ANISOLE, PHENOL, PHENYL METHANESULFONATE, POTASSIUM PHENYL SULFATE, AND A SERIES OF METHYL-SUBSTITUTED, ... THE SULFONATION OF ANISOLE, PHENOL, PHENYL METHANESULFONATE, POTASSIUM PHENYL SULFATE, AND A SERIES OF METHYL-SUBSTITUTED, ... BROMO-SUBSTITUTED, AND CHLORO-SUBSTITUTED ANISOLES AND PHENOLS IN CONCENTRATED AQUEOUS SULFURIC-ACID. J CHEM SOC PERK T 2 (5) ...
Anisole Derivatives Market Forecast, Trend Analysis & Competition Tracking - Global Review 2020 to 2030
Anisole Derivatives Market research report covers detailed information on Global Anisole Derivatives Market Size, Share, ... Anisole Derivatives Market: Overview. Anisole derivatives are found in artificial and natural fragrances. Anisole derivatives ... Anisole Derivatives Market: Key Players. Global anisole derivatives market is slightly fragmented in nature with presence of ... Segmentation analysis of Anisole derivatives Market:. The global anisole derivatives market is bifurcated into four major ...
o-Anisic Acid, 2-Methoxybenzoic acid, O-Methylsalicylic acid, 2-Anisic acid, Anisol-2-carboxylic Acid, Salicylic acid methyl...
Anisol-2-carboxylic Acid, Salicylic acid methyl ether with the InChIKey ILUJQPXNXACGAN-UHFFFAOYSA-N. ... CH$NAME: Anisol-2-carboxylic Acid. CH$NAME: Salicylic acid methyl ether. CH$COMPOUND_CLASS: CLASS1 Other CLASS2 Carboxylic acid ... o-Anisic Acid, 2-Methoxybenzoic acid, O-Methylsalicylic acid, 2-Anisic acid, Anisol-2-carboxylic Acid, Salicylic acid methyl ... RECORD_TITLE: o-Anisic Acid, 2-Methoxybenzoic acid, O-Methylsalicylic acid, 2-Anisic acid, Anisol-2-carboxylic Acid, Salicylic ...
Anisoles and Related Compounds - Benzene Derivatives
Vapor−Liquid Equilibria of the Binary System 1-Pentanol + Anisole and the Quaternary System Benzene + Cyclohexane + 1-Pentanol ...
Name each of the following alkenes. a. CH2 = CH CH2 | bartleby
anisole - Manufacturers, Suppliers, Exporters, Importers in India
Anisole|Dimethoxybenzene|m-Dimethoxy benzene--Huaian Depon Chemical Co., Ltd.
Anisole and phenol and thiophenol series Products | Aromsyn Co.,Ltd.
Pharmaceutical Excipients - Butylated Hydroxy Anisole IP / BP Manufacturer from Mumbai
Hydrothermal liquefaction of kraft lignin in sub-critical water: the influence of the sodium and potassium fraction |...
The different Na/(Na + K) ratios in the feed did not influence the total yields of anisoles, alkyl phenols and phenolic dimers ... The most dominant phenolic compounds present in the bio-oil phase were found to be anisoles, guaiacols and alkyl phenols; their ... The same observation was made for these compounds in the aqueous phase (anisoles (0.6%), guaiacols (1.6 ± 0.3%) and alkyl ...
Methoxybenzene2
- Anisole, or methoxybenzene, is an organic compound with the formula CH3OC6H5. (wikipedia.org)
- Comparison of MVOCs generated by different molds growing on various building materials yielded interesting results one of which was the persistent presence and identification of methoxybenzene (anisole) associated with the growth of S. (thefreedictionary.com)
Benzene6
- Anisole undergoes electrophilic aromatic substitution reaction at a faster speed than benzene, which in turn reacts more quickly than nitrobenzene. (wikipedia.org)
- The enhanced nucleophilicity of anisole vs. benzene reflects the influence of the methoxy group, which renders the ring more electron-rich. (wikipedia.org)
- This work investigated the deoxygenation reaction in anisole decomposition over HZSM-5 (HZ(25)) zeolite supported bimetallic catalysts to produce benzene, toluene and xylene (BTX). (strath.ac.uk)
- Anisole derivatives such as (2-methoxyethyl) benzene, 1,2-Dimethoxy-4-(prop-1-enyl)-benzene, 4-methylanisole and 1,4-Dimethoxy-benzene are the most prominent anisole derivatives in the market. (factmr.com)
- Anisole itself is a benzene ring with a methoxy, OCH 3 , group. (angelo.edu)
- 1-Methoxy-4-(2-propenyl)benzene, also known as methylchavicol or estragol, belongs to the class of organic compounds known as anisoles. (hmdb.ca)
Phenyl3
- For diethyl ether see Ether, and for methyl phenyl ether ( anisole ) and ethyl phenyl ether (phenetole) see Carbolic Acid. (dictionary.com)
- Anisole, phenyl ether (Ph-O-Me, Figure 1) usually used as a starting material for various pharmaceutical/ flavonoid products and as solvent in organic synthesis and physical studies [ 1 ]. (omicsonline.org)
- Methyl phenyl ether is anisole , because it was originally found in aniseed . (wikipedia.org)
Phenol4
- Solution How Do You Convert the Following : Phenol to Anisole Concept: Preparation of Ethers from Dehydration of Alcohols and Williamson Systhesis. (shaalaa.com)
- Why do we need to add FeBr3 for bromination of anisole, but not for bromination of phenol? (stackexchange.com)
- An answer which compares bromination in phenol and anisole will be highly appreciated. (stackexchange.com)
- I'm pretty sure - at least I see no reason to doubt - that the catalyst requirements for the bromination of anisole and the bromination of phenol do not differ much, if at all. (stackexchange.com)
Aryl ether1
- The new concept of alkali-metal-mediated zincation (AMMZ), formally a zinc−hydrogen exchange reaction but one that requires the participation of an alkali metal, is applied here to the alkyl aryl ether anisole, an important molecule for studying directed ortho-metalation (DoM) chemistry. (strath.ac.uk)
Chlorination of anisole1
- Tertiary amines and their salts in dichloromethane were found to induce a strong para regioselectivity in the chlorination of anisole as the model substrate with trichloroisocyanuric acid (TCCA). (springer.com)
Decomposition of anisole2
- The route to the formation of naphthalene from anisole follows the simple unimolecular decomposition of anisole, which leads to the phenoxy radical and then cyclopentadienyl radical. (rti.org)
- The modelling results agreed well with experiments by revealing that the strong binding between phenolic compounds (Phs) and the Ni-Mo based catalysts bimetal surface would lead to a higher BTX production in the deoxygenation reaction in the decomposition of anisole. (strath.ac.uk)
Alkyl2
- Treating one molar equivalent of anisole with the lithium dialkyl-TMP zincate reagent [THF·Li(μ-TMP)(μ-tBu)Zn(tBu)] (1) in hexane solution affords the mono-ortho-zincated complex [THF·Li(μ-TMP)(μ-o-C6H4OMe)Zn(tBu)] (2), which establishes that 1 functions as an alkyl base although previously it was regarded as an amido (TMP) base in other DoM applications. (strath.ac.uk)
- Treating two molar equivalents of anisole with 1, and increasing the reaction time, affords the bis-ortho-zincated complex [THF·Li(μ-TMP)(μ-o-C6H4OMe)Zn(o-C6H4OMe)] (3), which establishes that 1 can also function as a dual alkyl base. (strath.ac.uk)
Hydroxy3
- Following a request from the European Commission, the Panel on Additives and Products or Substances used in Animal Feed (FEEDAP) was asked to deliver a scientific opinion on the safety of butylated hydroxy anisole (BHA) for all animal species. (europa.eu)
- Butylated hydroxy anisole (BHA), or 2- tert -butyl-4-methoxyphenol, is a commonly used antioxidant. (angelo.edu)
- These include butylated hydroxy anisole (BHA), butylated hydroxy toluene (BHT), and tocopherol. (encyclopedia.com)
Compounds1
- This compound belongs to the class of organic compounds known as anisoles. (hmdb.ca)
Ethers1
- Anisole, C6H5-O-CH3, is the only name in the class of ethers which is retained both as a preferred IUPAC name and for use in general nomenclature. (wikipedia.org)
Ether1
- The ether linkage is highly stable, but the methyl group can be removed with hydroiodic acid: CH3OC6H5 + HI → HOC6H5 + CH3I Anisole is prepared by methylation of sodium phenoxide with dimethyl sulfate or methyl chloride: 2 C6H5O−Na+ + (CH3O)2SO2 → 2 C6H5OCH3 + Na2SO4 Anisole is a precursor to perfumes, insect pheromones, and pharmaceuticals. (wikipedia.org)
Acid3
- Acid: anisole. (nist.gov)
- A mechanism based upon exothermic triton transfer from the gaseous Brønsted acid HeT + to the aromatic substrate is used to account for the formation of the tritiated products, and for the distribution of tritium which is found mainly in the ortho positions of anisole and in the meta positions of ααα-trifluorotoluene. (rsc.org)
- Why use glacial acetic acid in bromination of anisole? (stackexchange.com)
Substances1
- Il s'agit d'une source d'informations unique sur les substances chimiques fabriquées et importées en Europe. (europa.eu)
C6H5OCH31
- We have investigated the pyrolysis of anisole (C6H5OCH3), a model compound for methoxy functional groups in lignin. (rti.org)
Synthesis2
- These results suggested that biofield treatment has significantly altered the physical and spectroscopic properties of anisole, which could make them stable solvent for organic synthesis and as a suitable reaction intermediate in industrial applications. (omicsonline.org)
- The anisole was used selectively in various steps as a solvent in the synthesis of cefoxitin [ 6 ] and latamoxef an antibiotic administered intravenously has a broad spectrum of activity against Gram-positive and Gram-negative bacteria [ 7 ]. (omicsonline.org)
Solvent3
- Anisole is a weakly polar aprotic solvent with lower electric permittivity (εs=4.33), which allows its usability in cyclic voltammetric studies as an alternative to tetrahydrofuran and dichloromethane [ 8 ]. (omicsonline.org)
- Nowadays, a relatively green solvent, anisole, have been successfully applied to process organic/polymer solar cells [ 9 ]. (omicsonline.org)
- [email protected]: 1087: NEW THREAD: 2% 950K MW PMMA -A (in Anisole solvent) data. (stanford.edu)
Molecule1
- Anisole is a plant essential oil with relatively smaller molecule size and higher volatility, and is insecticidal. (usda.gov)
Anethole1
- For example, synthetic anethole is prepared from anisole. (wikipedia.org)
Ligands1
- Omitting THF and rerunning the reaction with one or two molar equivalents of anisole affords [Ph(Me)O·Li(μ-TMP)(μ-o-C6H4OMe)Zn(tBu)] (4), which remarkably contains a combination of neutral and ortho-deprotonated anisole ligands. (strath.ac.uk)
Methoxy1
- Illustrative of its nucleophilicity, anisole reacts with acetic anhydride to give 4-methoxyacetophenone: CH3OC6H5 + (CH3CO)2O → CH3OC6H4C(O)CH3 + CH3CO2H Unlike most acetophenones, but reflecting the influence of the methoxy group, methoxyacetophenone undergoes a second acetylation. (wikipedia.org)
Sulfate1
- 2-smino-4-n-( beta -hydroxyethyl)amino anisole sulfate;5-(2-Hydroxyethylamino)-2-methoxylaniline sulfate;2-Amino-4-hydroxyethylamino anisole sulfate;2-[(3-amino-4-methoxyphenyl)a. (chinachemnet.com)
Derivatives21
- 4-hydroxyanisole and t-butylhydroxyanisole are the most popular derivatives of anisole and used extensively as depigmenting agents and antioxidant respectively [ 4 , 5 ]. (omicsonline.org)
- Anisole derivatives are found in artificial and natural fragrances. (factmr.com)
- Anisole derivatives are extensively used as key ingredients in manufacturing of fragrances, air care, biocides and bundle of other products. (factmr.com)
- In the past half-decade, demand of anisole derivatives has substantially risen on the back of the rise of specialty foods and non-specialty food market. (factmr.com)
- Usage of anisole derivatives in food is limited in regions such as Europe and North America owing to the stringent regulations. (factmr.com)
- Gradually anisole derivatives are being integrated into European market owing to the results of safe usage of certain anisole derivatives. (factmr.com)
- Market penetration of anisole derivatives is dependent on consumer inclination towards a certain fragrance and taste of the product. (factmr.com)
- Apart from the core applications of anisole derivatives, a few mentionable niche applications such as biocides have also portrayed an image of growing demand requisite over the historical period of 2015-2019. (factmr.com)
- Furthermore, on the product life cycle graph, anisole derivatives are on the growing side, which provides enormous opportunities for the stakeholders to explore the anisole derivatives market. (factmr.com)
- Of the two major applications of anisole derivatives, flavoring and fragrance applications anisole derivatives market. (factmr.com)
- Flavoring industry captures more than half of the global anisole derivatives market, thus dominating the anisole derivatives market. (factmr.com)
- While fragrance applications are growing at a fast pace owing to the rise in research & development regarding anisole derivatives applications in fragrance. (factmr.com)
- With the complete contraction of demand and supply of fragrance products in current quarter i.e., 2rd quarter of CY2020, the effect has cascaded to the anisole derivatives market. (factmr.com)
- Other macro-economic factors post-COVID-19 such as consumer spending and recession are set to impact the anisole derivatives market in long-run. (factmr.com)
- The global anisole derivatives market is bifurcated into four major segments: Derivatives, product type, form, application, and region. (factmr.com)
- From regional perspective, East Asia holds for largest market share in global anisole derivatives market. (factmr.com)
- Extensive application of anisole derivatives have been observed in the past half-decade in this region. (factmr.com)
- Furthermore, increase in demand of food products in the period of 2015-2019 has drastically provided a thrust to the anisole derivatives market. (factmr.com)
- Expansion of demand of anisole derivatives over the assessed historical period could be observed. (factmr.com)
- Of the countries in the region such as Japan, China and South Korea, China has dominated the regional share as well as the global anisole derivatives market share. (factmr.com)
- North America and Europe are gradually adopting the anisole derivatives, post-stringent tests over health impact and long-run physiological issues. (factmr.com)
Formula1
- 2-(Diphenylphosphino)anisole is the organophosphorus compound with the formula (C6H5)2PC6H4-2-OCH3. (wikipedia.org)
Molecular2
- Finally, we have used molecular beam mass spectrometry (MBMS) and factor analysis to demonstrate the formation of naphthalene from the pyrolysis of anisole. (rti.org)
- The study of the gas-phase reactions of the HeT + ion from the β-decay of molecular tritium is extended to anisole, t-butylbenzene, and ααα-trifluorotoluene. (rsc.org)
Insect2
- Complete control of all four insect species was achieved in fumigations with anisole at different concentrations of 100 to 600 microliter/liter in 6 to 24 hours. (usda.gov)
- We evaluated anisole as a potential fumigant for controlling four insect pests including adults of three stored product pests (granary weevil, rice weevil, and confused flour beetle at 25°C), and a fresh produce product pest (western flower thrips (WFT) at 2°C) in small-scale laboratory tests. (usda.gov)
Products1
- The results of this study suggest that anisole has potential as a fumigant for postharvest pest control on fresh and stored products. (usda.gov)
Liquid1
- The objective of the present study was to evaluate the impact of biofield energy treatment on the thermal, spectroscopic , and chemical properties of anisole by various analytical methods such as gas chromatography-mass spectrometry (GC-MS), high performance liquid chromatography (HPLC), differential scanning calorimetry (DSC), Fourier transform infrared (FT-IR) spectroscopy, and ultraviolet-visible (UV-Vis) spectroscopy. (omicsonline.org)
Study1
- This study demonstrated that anisole fumigation has good efficacy against insects and, therefore, has potential as an environmentally friendly, alternative fumigant for postharvest pest control. (usda.gov)
Properties1
- Greetings Raith Users: During the last month I have started working with the 2% 950K MW PMMA in Anisole material, carefully characterizing the material's properties for SNF labmember usage. (stanford.edu)
Sample1
- The anisole sample was divided into two parts, control and treated. (omicsonline.org)
Exchange1
- Air-water exchange of brominated anisoles in the northern Baltic Sea. (arctichealth.org)
Control4
- The HPLC chromatogram showed retention time of treated anisole was slightly decreased as compared to the control. (omicsonline.org)
- Moreover, the heat change in the sharp endothermic transition of treated anisole was increased by 389.07% in DSC thermogram as compared to the control. (omicsonline.org)
- Specifically, this fourth article will give an overview of the issue (general pallet control specific to the issue of 2,4,6 TBA and 2,4,6 TCA taints) by summarizing the first three articles and giving an update on recent events that have occurred regarding wood pallets and anisole taints. (palletcentral.com)
- In a 16 h confirmatory test in a mini silo, anisole fumigation achieved 100% control of rice weevil at different depth of stored corn. (usda.gov)
Numerous1
- The regioselectivity and monochlorination selectivity for anisole chlorination with TCCA in numerous solvents are reported. (springer.com)