Allyl compounds. Medical search

Isomeric forms and derivatives of PROPANOL (C3H7OH).

A metallic element with the atomic symbol Ir, atomic number 77, and atomic weight 192.22.

One of the Liliaceae used as a spice (SPICES) and traditional remedy. It contains alliin lyase and alliin, which is converted by alliin lyase to allicin, the pungent ingredient responsible for the aroma of fresh cut garlic.

Organic compounds with the general formula R-NCS.

Inorganic or organic compounds that contain sulfur as an integral part of the molecule.

The location of the atoms, groups or ions relative to one another in a molecule, as well as the number, type and location of covalent bonds.

Alkyl compounds containing a hydroxyl group. They are classified according to relation of the carbon atom: primary alcohols, R-CH2OH; secondary alcohols, R2-CHOH; tertiary alcohols, R3-COH. (From Grant & Hackh's Chemical Dictionary, 5th ed)

Chemical groups containing the covalent sulfur bonds -S-. The sulfur atom can be bound to inorganic or organic moieties.

The phenomenon whereby compounds whose molecules have the same number and kind of atoms and the same atomic arrangement, but differ in their spatial relationships. (From McGraw-Hill Dictionary of Scientific and Technical Terms, 5th ed)

Any of the monobasic inorganic or organic acids of sulfur with the general formula RSO(OH). (From McGraw Hill Dictionary of Scientific and Technical Terms, 4th ed)

A colorless liquid made by oxidation of aliphatic hydrocarbons that is used as a solvent and chemical intermediate.

Organic compounds containing a carbonyl group in the form -CHO.

A chemical element having an atomic weight of 106.4, atomic number of 46, and the symbol Pd. It is a white, ductile metal resembling platinum, and following it in abundance and importance of applications. It is used in dentistry in the form of gold, silver, and copper alloys.

Substances capable of inhibiting, retarding or arresting the process of fermentation, acidification or other deterioration of foods.

Organic compounds that contain the -NCO radical.

Addition of hydrogen to a compound, especially to an unsaturated fat or fatty acid. (From Stedman, 26th ed)

Chemical compound used to initiate polymerization of dental resins by the use of DENTAL CURING LIGHTS. It absorbs UV light and undergoes decomposition into free radicals that initiate polymerization process of the resins in the mix. Each photoinitiator has optimum emission spectrum and intensity for proper curing of dental materials.

Concentrated pharmaceutical preparations of plants obtained by removing active constituents with a suitable solvent, which is evaporated away, and adjusting the residue to a prescribed standard.

Reduction of pharmacologic activity or toxicity of a drug or other foreign substance by a living system, usually by enzymatic action. It includes those metabolic transformations that make the substance more soluble for faster renal excretion.

A transferase that catalyzes the addition of aliphatic, aromatic, or heterocyclic FREE RADICALS as well as EPOXIDES and arene oxides to GLUTATHIONE. Addition takes place at the SULFUR. It also catalyzes the reduction of polyol nitrate by glutathione to polyol and nitrite.

A genus of the plant family Liliaceae (sometimes classified as Alliaceae) in the order Liliales. Many produce pungent, often bacteriostatic and physiologically active compounds and are used as VEGETABLES; CONDIMENTS; and medicament, the latter in traditional medicine.

A highly poisonous compound used widely in the manufacture of plastics, adhesives and synthetic rubber.

Works containing information articles on subjects in every field of knowledge, usually arranged in alphabetical order, or a similar work limited to a special field or subject. (From The ALA Glossary of Library and Information Science, 1983)

Clusters of colonic crypts that appear different from the surrounding mucosa when visualized after staining. They are of interest as putative precursors to colorectal adenomas and potential biomarkers for colorectal carcinoma.

Organic chemistry methodology that mimics the modular nature of various biosynthetic processes. It uses highly reliable and selective reactions designed to "click" i.e., rapidly join small modular units together in high yield, without offensive byproducts. In combination with COMBINATORIAL CHEMISTRY TECHNIQUES, it is used for the synthesis of new compounds and combinatorial libraries.

An element that is a member of the chalcogen family. It has an atomic symbol S, atomic number 16, and atomic weight [32.059; 32.076]. It is found in the amino acids cysteine and methionine.

The segment of LARGE INTESTINE between the CECUM and the RECTUM. It includes the ASCENDING COLON; the TRANSVERSE COLON; the DESCENDING COLON; and the SIGMOID COLON.

A food group comprised of EDIBLE PLANTS or their parts.

Herbaceous biennial plants and their edible bulbs, belonging to the Liliaceae.

A plant genus of the family Cruciferae. It contains many species and cultivars used as food including cabbage, cauliflower, broccoli, Brussel sprouts, kale, collard greens, MUSTARD PLANT; (B. alba, B. junica, and B. nigra), turnips (BRASSICA NAPUS) and rapeseed (BRASSICA RAPA).

Agents that reduce the frequency or rate of spontaneous or induced tumors independently of the mechanism involved.

A written account of a person's life and the branch of literature concerned with the lives of people. (Harrod's Librarians' Glossary, 7th ed)

Books containing photographs, prints, drawings, portraits, plates, diagrams, facsimiles, maps, tables, or other representations or systematic arrangement of data designed to elucidate or decorate its contents. (From The ALA Glossary of Library and Information Science, 1983, p114)

Time period from 1801 through 1900 of the common era.

A loose confederation of computer communication networks around the world. The networks that make up the Internet are connected through several backbone networks. The Internet grew out of the US Government ARPAnet project and was designed to facilitate information exchange.

A form of pneumoconiosis resulting from inhalation of dust containing crystalline form of SILICON DIOXIDE, usually in the form of quartz. Amorphous silica is relatively nontoxic.

An interactive process whereby members of a community are concerned for the equality and rights of all.

The exposure to potentially harmful chemical, physical, or biological agents that occurs as a result of one's occupation.

A diffuse parenchymal lung disease caused by inhalation of dust and by tissue reaction to their presence. These inorganic, organic, particulate, or vaporized matters usually are inhaled by workers in their occupational environment, leading to the various forms (ASBESTOSIS; BYSSINOSIS; and others). Similar air pollution can also have deleterious effects on the general population.

A form of pneumoconiosis caused by inhalation of asbestos fibers which elicit potent inflammatory responses in the parenchyma of the lung. The disease is characterized by interstitial fibrosis of the lung, varying from scattered sites to extensive scarring of the alveolar interstitium.

The repetitive uterine contraction during childbirth which is associated with the progressive dilation of the uterine cervix (CERVIX UTERI). Successful labor results in the expulsion of the FETUS and PLACENTA. Obstetric labor can be spontaneous or induced (LABOR, INDUCED).

A molecule that binds to another molecule, used especially to refer to a small molecule that binds specifically to a larger molecule, e.g., an antigen binding to an antibody, a hormone or neurotransmitter binding to a receptor, or a substrate or allosteric effector binding to an enzyme. Ligands are also molecules that donate or accept a pair of electrons to form a coordinate covalent bond with the central metal atom of a coordination complex. (From Dorland, 27th ed)

Shortened forms of written words or phrases used for brevity.

Porphyrins which are combined with a metal ion. The metal is bound equally to all four nitrogen atoms of the pyrrole rings. They possess characteristic absorption spectra which can be utilized for identification or quantitative estimation of porphyrins and porphyrin-bound compounds.

Organic compounds that have the general formula R-SO-R. They are obtained by oxidation of mercaptans (analogous to the ketones). (From Hackh's Chemical Dictionary, 4th ed)

A prodromal phase of infection with the human immunodeficiency virus (HIV). Laboratory criteria separating AIDS-related complex (ARC) from AIDS include elevated or hyperactive B-cell humoral immune responses, compared to depressed or normal antibody reactivity in AIDS; follicular or mixed hyperplasia in ARC lymph nodes, leading to lymphocyte degeneration and depletion more typical of AIDS; evolving succession of histopathological lesions such as localization of Kaposi's sarcoma, signaling the transition to the full-blown AIDS.

The voluntary portion of Medicare, known as the Supplementary Medical Insurance (SMI) Program, that includes physician's services, home health care, medical services, outpatient hospital services, and laboratory, pathology, and radiology services. All persons entitled to Medicare Part A may enroll in Medicare Part B on a monthly premium basis.

Neutral or negatively charged ligands bonded to metal cations or neutral atoms. The number of ligand atoms to which the metal center is directly bonded is the metal cation's coordination number, and this number is always greater than the regular valence or oxidation number of the metal. A coordination complex can be negative, neutral, or positively charged.

Allyl-containing sulfides in garlic increase uncoupling protein content in brown adipose tissue, and noradrenaline and adrenaline secretion in rats. (1/436)

The effects of garlic supplementation on triglyceride metabolism were investigated by measurements of the degree of thermogenesis in interscapular brown adipose tissue (IBAT), and noradrenaline and adrenaline secretion in rats fed two types of dietary fat. In Experiment 1, rats were given isoenergetic high-fat diets containing either shortening or lard with or without garlic powder supplementation (8 g/kg of diet). After 28 d feeding, body weight, plasma triglyceride levels and the weights of perirenal adipose tissue and epididymal fat pad were significantly lower in rats fed diets supplemented with garlic powder than in those fed diets without garlic powder. The content of mitochondrial protein and uncoupling protein (UCP) in IBAT, and urinary noradrenaline and adrenaline excretion were significantly greater in rats fed a lard diet with garlic powder than in those fed the same diet without garlic. Other than adrenaline secretion, differences due to garlic were significant in rats fed shortening, also. In Experiment 2, the effects of various allyl-containing sulfides present in garlic on noradrenaline and adrenaline secretion were evaluated. Administration of diallyldisulfide, diallyltrisulfide and alliin, organosulfur compounds present in garlic, significantly increased plasma noradrenaline and adrenaline concentrations, whereas the administration of disulfides without allyl residues, diallylmonosulfide and S-allyl-L-cysteine did not increase adrenaline secretion. These results suggest that in rats, allyl-containing sulfides in garlic enhance thermogenesis by increasing UCP content in IBAT, and noradrenaline and adrenaline secretion. (+info)

Cytochrome P-450-dependent bioactivation of 1,1-dichloroethylene to a reactive epoxide in human lung and liver microsomes. (2/436)

We investigated the cytochrome P-450-dependent metabolism of 1, 1-dichloroethylene (DCE) by human lung and liver microsomes and compared the results from analogous experiments in mice. Metabolites were identified by HPLC analysis of their glutathione conjugates and/or hydrolyzed products and were detected by using [14C]DCE. The role of human CYP2E1 in the metabolic reactions was examined by comparing p-nitrophenol hydroxylase activities with levels of metabolites formed and by using the CYP2E1-selective inhibitor diallyl sulfone. The major products formed in microsomal incubations containing NADPH were the DCE-epoxide-derived glutathione conjugates 2-(S-glutathionyl)acetyl glutathione and 2-S-glutathionyl acetate. Lower levels of the acetal of 2,2-dichloroacetaldehyde were also detected. In lung samples from eight patients, the amounts of epoxide-derived conjugates formed ranged from 15.6 +/- 4.23 to 34.9 +/- 12.75 pmol/mg protein/min. The levels in murine lung were higher at 40.0 +/- 3.8 pmol/mg protein/min. In liver samples from five patients, conjugate levels ranged from 46.5 +/- 8.3 to 240.0 +/- 10. 5 pmol/mg protein/min, whereas levels in murine liver were 83.0 +/- 6.2 pmol/mg protein/min. Conjugate levels formed in human liver correlated with the relative levels of p-nitrophenol hydroxylase activity present, but this relationship was equivocal in human lung. Diallyl sulfone inhibited the formation of the glutathione conjugates (20-65%) in liver samples from all four patients, whereas only one of five human lung samples exhibited this inhibition (27%). These results demonstrated that the DCE-epoxide is a major metabolite formed by human microsomes and is mediated by CYP2E1 in liver and in some individuals in lung. (+info)

Inhibition of nitrifiers and methanotrophs from an agricultural humisol by allylsulfide and its implications for environmental studies. (3/436)

Allylsulfide, an inhibitor of ammonia monooxygenase, was tested to determine its ability to inhibit nitrification and methane oxidation in pure cultures, in agricultural humisol enrichment cultures, and in humisol slurries. We confirmed that allylsulfide is a differential inhibitor of cultures of nitrifiers and methanotrophs at concentrations of 1 and 200 microM, respectively, which result in 50% inhibition. However, although a nitrifying enrichment culture added to sterilized humisol was inhibited 50% by 4 microM allylsulfide, 500 microM allylsulfide was necessary for 50% inhibition of the endogenous nitrifying activity in nonsterile humisol. We concluded that native nitrifiers were protected, possibly by being in colonial aggregates or sheltered microenvironments. (+info)

Metabolism of diallyl disulfide by human liver microsomal cytochromes P-450 and flavin-containing monooxygenases. (4/436)

The metabolism of diallyl disulfide (DADS), a garlic sulfur compound, was investigated in human liver microsomes. Diallyl thiosulfinate (allicin) was the only metabolite observed and its formation followed Michaelis-Menten kinetics with a Km = 0.61 +/- 0.2 mM and a Vmax = 18.5 +/- 4.2 nmol/min/mg protein, respectively (mean +/- S.E. M., n = 4). Both flavin-containing monooxygenase and the cytochrome P-450 monooxygenases (CYP) were involved in DADS oxidation, but the contribution of CYP was predominant. The cytochrome P-450 isoforms involved in this metabolism were investigated using selective chemical inhibitors, microsomes from cells expressing recombinant CYP isoenzymes, and studying the correlation of the rate of DADS oxidation with specific monooxygenase activities of human liver microsomes. Diethyldithiocarbamate and tranylcypromine inhibited allicin formation, whereas other specific inhibitors had low or no effect. Most of the different human microsomes from cells expressing CYP were able to catalyze this reaction, but CYP2E1 showed the highest affinity with a substantial activity. Furthermore, allicin formation by human liver microsomes was correlated with p-nitrophenol hydroxylase activity, a marker of CYP2E1, and tolbutamide hydroxylase activity, a marker of CYP2C9. Among these approaches only CYP2E1 was identified in each case, which suggested that DADS is preferentially metabolized to allicin by CYP2E1 in human liver. However the minor participation of other CYP forms and flavin-containing monooxygenases is likely. (+info)

In vivo formation and localization of 1,1-dichloroethylene epoxide in murine liver: identification of its glutathione conjugate 2-S-glutathionyl acetate. (5/436)

The hepatotoxic effects induced by 1,1-dichloroethylene (DCE) are ascribed to cytochrome P-450 (CYP) 2E1-dependent formation of metabolites including 2,2-dichloroacetaldehyde and the DCE-epoxide. The DCE metabolites detected in incubations of liver microsomes are the acetal, the hydrate of 2,2-dichloroacetaldehyde, and the epoxide-derived GSH conjugates 2-S-glutathionyl acetyl glutathione ([B]) and 2-S-glutathionyl acetate ([C]). This study was undertaken to determine whether these DCE metabolites are also formed in vivo in murine liver. HPLC analysis of cytosol isolated from the livers of mice treated with [(14)C]DCE showed that [C] was the major conjugate formed, with lower levels of formation of [B]. The acetal was not detected in the cytosol. The formation of the epoxide-derived GSH conjugates was dose-dependent at 25 to 225 mg/kg DCE and occurred coincidentally with levels of covalent binding of DCE at the same doses. The acetal and conjugates [B] and [C] were also detected in bile collected from mice treated with DCE. Pretreatment of mice with buthionine sulfoximine decreased sulfhydryl levels and formation of conjugate [C], and increased DCE binding to liver proteins. In contrast, the levels of [C] and DCE binding were both reduced significantly in mice pretreated with the CYP2E1 inhibitor diallyl sulfone. Immunohistochemical studies indicated that protein adducts and conjugate [C] were localized in centrilobular hepatocytes and corresponded with the sites where CYP2E1 resided. Pretreatment with buthionine sulfoximine increased the amount of immunostaining. However, pretreatment with diallyl sulfone markedly decreased immunostaining for [C] in the hepatocytes. These results showed that 2,2-dichloroacetaldehyde and the epoxide are formed from DCE in vivo. (+info)

Effects of allitridi on intracellular Ca2+ concentration in isolated rat brain cells. (6/436)

AIM: To study actions of allitridi extracted from garlic on intracellular calcium in isolated rat brain cells. METHODS: Brain cells were isolated from newborn rat brain with Fura 2-AM measurements of intracellular Ca2+ concentration ([Ca2+]i). RESULTS: Allitridi 1-100 mumol.L-1 concentration-dependently blocked increases of [Ca2+]i caused by potassium chloride and sodium glutamate (Glu) with IC50 of 59.7 and 69.9 mumol.L-1 respectively. Allitridi 100 mumol.L-1 blocked norepinephrine (Nor)-induced [Ca2+]i elevation. CONCLUSION: Allitridi is an effective agent for blocking the [Ca2+]i increase caused by potassium chloride, Nor and Glu. (+info)

Roles of horizontal gene transfer and gene integration in evolution of 1,3-dichloropropene- and 1,2-dibromoethane-degradative pathways. (7/436)

The haloalkane-degrading bacteria Rhodococcus rhodochrous NCIMB13064, Pseudomonas pavonaceae 170, and Mycobacterium sp. strain GP1 share a highly conserved haloalkane dehalogenase gene (dhaA). Here, we describe the extent of the conserved dhaA segments in these three phylogenetically distinct bacteria and an analysis of their flanking sequences. The dhaA gene of the 1-chlorobutane-degrading strain NCIMB13064 was found to reside within a 1-chlorobutane catabolic gene cluster, which also encodes a putative invertase (invA), a regulatory protein (dhaR), an alcohol dehydrogenase (adhA), and an aldehyde dehydrogenase (aldA). The latter two enzymes may catalyze the oxidative conversion of n-butanol, the hydrolytic product of 1-chlorobutane, to n-butyric acid, a growth substrate for many bacteria. The activity of the dhaR gene product was analyzed in Pseudomonas sp. strain GJ1, in which it appeared to function as a repressor of dhaA expression. The 1,2-dibromoethane-degrading strain GP1 contained a conserved DNA segment of 2.7 kb, which included dhaR, dhaA, and part of invA. A 12-nucleotide deletion in dhaR led to constitutive expression of dhaA in strain GP1, in contrast to the inducible expression of dhaA in strain NCIMB13064. The 1, 3-dichloropropene-degrading strain 170 possessed a conserved DNA segment of 1.3 kb harboring little more than the coding region of the dhaA gene. In strains 170 and GP1, a putative integrase gene was found next to the conserved dhaA segment, which suggests that integration events were responsible for the acquisition of these DNA segments. The data indicate that horizontal gene transfer and integrase-dependent gene acquisition were the key mechanisms for the evolution of catabolic pathways for the man-made chemicals 1, 3-dichloropropene and 1,2-dibromoethane. (+info)

Ethanol and arachidonic acid increase alpha 2(I) collagen expression in rat hepatic stellate cells overexpressing cytochrome P450 2E1. Role of H2O2 and cyclooxygenase-2. (8/436)

The ability of ethanol and arachidonic acid (AA), as inducers of oxidative stress and key factors in alcoholic liver disease, to up-regulate alpha 2 collagen type I (COL1A2) gene expression was studied in a hepatic stellate cell line overexpressing the ethanol-inducible cytochrome P450 2E1 (CYP2E1) (E5 cells). A time- and dose-dependent induction in COL1A2 mRNA by ethanol or AA was observed that was prevented by diallylsulfide, a CYP2E1 inhibitor. Nuclear run-on experiments showed transcriptional activation of the COL1A2 gene by ethanol and AA. Catalase abrogated the increase in COL1A2 mRNA suggesting an H(2)O(2)-dependent mechanism. Cyclooxygenase-2 (COX-2) levels and production of prostaglandin E(2) upon addition of AA were elevated in the E5 cells. Incubation with NS-398, a COX-2 inhibitor, blocked the effect of AA, but not of ethanol, on COL1A2 expression suggesting that CYP2E1 activates COX-2 expression, and the oxidation of AA by COX-2 is responsible for the increase in COL1A2. Activity of a reporter construct driven by -378 base pairs of the proximal promoter region of the COL1A2 gene increased in E5 but not control cells and was further increased by ethanol or AA. These experiments link CYP2E1-dependent oxidative stress to induction of COX-2 and the actions of ethanol and AA on activation of collagen gene expression in hepatic stellate cells. (+info)

"Allyl Compounds". Ullmann's Encyclopedia of Industrial Chemistry. Weinheim: Wiley-VCH. doi:10.1002/14356007.a01_425. Berthelot ... Jun Li, Gongda Zhao, Shuang Gao, Ying Lv, Jian Li, and Zuwei Xi (2006). "Epoxidation of Allyl Chloride to Epichlorohydrin by a ... The compound was isolated during studies on reactions between glycerol and gaseous hydrogen chloride. Reminiscent of ... This is the same intermediate formed in the allyl chloride/hypochlorous acid process, and is likewise then treated with base to ...

https://en.wikipedia.org/wiki/Epichlorohydrin

Ludger Krähling; Jürgen Krey; Gerald Jakobson; Johann Grolig; Leopold Miksche (2002). "Allyl Compounds". Ullmann's Encyclopedia ... Or by the reaction of allyl chloride with Hexamine. Pure samples can be prepared by hydrolysis of allyl isothiocyanate. It ... Allylamine, like other allyl derivatives is a lachrymator and skin irritant. Its oral LD50 is 106 mg/kg for rats. Nomenclature ... Allylamine is an organic compound with the formula C3H5NH2. This colorless liquid is the simplest stable unsaturated amine. All ...

https://en.wikipedia.org/wiki/Allylamine

Coffey, Samuel; Ward, Charles Frederick (1921). "CXLVIII.-The preparation of some allyl compounds". J. Chem. Soc., Trans. 119: ... Dioxalin readily loses two molecules of carbon dioxide at this high temperature to form allyl alcohol and therefore offers a ... Chattaway, Frederick Daniel (1915). "XLVII.-The preparation of allyl alcohol". J. Chem. Soc., Trans. 107: 407-410. doi:10.1039/ ... method for conversion of glycerol to allyl alcohol. ...

https://en.wikipedia.org/wiki/Dioxalin

Allyl halides react with Ni(CO)4 to form pi-allyl complexes, (allyl)2Ni2Cl2. These compounds in turn are sources of allyl ... One 12 VE compound is di(mesityl)nickel prepared from (allyl)2Ni2Br2 and the corresponding Grignard reagent. (allyl)2Ni2Br2 + 4 ... Nickel compounds cause the coupling reaction between allyl and aryl halides. Other coupling reactions involving nickel in ... In (allyl)2Ni2Br2 and (allyl)Ni(C5H5), nickel is assigned to oxidation number +2, and the electron counts are 16 and 18, ...

https://en.wikipedia.org/wiki/Organonickel

Organocobalt compounds are known with alkene, allyl, diene, and Cp ligands. A famous sandwich compound is cobaltocene, a 19- ... Organocobalt compounds are involved in several organic reactions and the important biomolecule vitamin B12 has a cobalt-carbon ... Other sandwich compounds are CoCp(C6Me6) and Co(C6Me6)2, with 20 electrons and 21 electrons, respectively. Reduction of ... Cobalt compounds react with dialkynes and dienes to cyclic intermediates in cyclometalation. Other alkynes, alkenes, nitriles ...

https://en.wikipedia.org/wiki/Organocobalt_chemistry

Allyl sulfide compounds produce the characteristic odour of the onion subfamily (Allioideae). The family, which was originally ... The Allioideae produce allyl sulfide compounds which give them their characteristic smell. Type species of Amaryllidaceae ...

https://en.wikipedia.org/wiki/Amaryllidaceae

The compound is bifunctional, containing reactive trichlorsilyl and allyl groups. The SiCl3 group undergoes the usual ... Allyltrichlorosilane is an organosilicon compound with the formula Cl3SiCH2CH=CH2. It is a colorless or white low-melting solid ... Hurd, Dallas T. "Preparation of vinyl and allyl chlorosilanes" Journal of the American Chemical Society 1945, volume 67, 1813- ... It was originally prepared by the Direct process, the reaction of allyl chloride with copper-silicon alloy. ...

https://en.wikipedia.org/wiki/Allyltrichlorosilane

The compound consists of a phenyl group attached to allyl. Phenylpropene isomerizes to trans-propenylbenzene. In plant ... Phenylpropene is the organic compound with the formula C6H5CH2CH=CH2. It is a colorless liquid. ...

https://en.wikipedia.org/wiki/Phenylpropene

It decomposes in the human body into other compounds such as allyl methyl sulfide. In 1844, Theodor Wertheim separated by steam ... Allyl propyl disulfide allyl disulfide Diallyl disulfide at Sigma Aldrich Block, Eric (2010). Garlic and Other Alliums: The ... diallyl disulfide is produced from sodium disulfide and allyl bromide or allyl chloride at temperatures of 40-60 °C in an inert ... Fukao, T; Hosono, T; Misawa, S; Seki, T; Ariga, T (2004). "The effects of allyl sulfides on the induction of phase II ...

https://en.wikipedia.org/wiki/Diallyl_disulfide

Allyl isothiocyanate is an unstable compound, degrading over the course of days at 37 °C (99 °F). Because of this instability, ... The distinctive pungent taste of horseradish is from the compound allyl isothiocyanate. Upon crushing the flesh of horseradish ... The allyl isothiocyanate serves the plant as a natural defense against herbivores. Since allyl isothiocyanate is harmful to the ... When cut or grated, enzymes from within the plant cells digest sinigrin (a glucosinolate) to produce allyl isothiocyanate ( ...

https://en.wikipedia.org/wiki/Horseradish

Industrially significant organic compounds prepared from hydrobromic acid include allyl bromide, tetrabromobis(phenol), and ... Dagani, M. J.; Barda, H. J.; Benya, T. J.; Sanders, D. C. (2012). "Bromine Compounds". Ullmann's Encyclopedia of Industrial ... It is a useful reagent for generating organobromine compounds. Certain ethers are cleaved with HBr. It also catalyzes ...

https://en.wikipedia.org/wiki/Hydrobromic_acid

Silylated allylic acetates, carbonates and other substituted allyl compounds may form TMM synthons under palladium catalysis. ... Carbonyl compounds may be used as the 2π component under the appropriate conditions. For instance, in the presence of an indium ... Three classes of compounds have been used to generate synthetically useful TMM intermediates: diazenes, silyl-substituted ... Rapid racemization of chiral pi-allyl palladium complexes occurs, and only moderate diastereoselectivity is observed in ...

https://en.wikipedia.org/wiki/Trimethylenemethane_cycloaddition

... , or alpha-allyl-phenethylamine, is a chemical compound of the phenethylamine family. It was briefly investigated as ... It has now been largely superseded by the newer compounds in this class, and only rarely found in scientific literature. The " ...

https://en.wikipedia.org/wiki/Alfetamine

Allyl compounds with suitable leaving groups react with palladium(II) salts to pi-allyl complexes having hapticity 3. These ... Palladium compounds owe their reactivity to the ease of interconversion between Pd(0) and palladium(II) intermediates. There is ... Fullerene ligands also bind with palladium(II). Palladium(II) acetate and related compounds are common reagents because the ... Zerovalent Pd(0) compounds include tris(dibenzylideneacetone)dipalladium(0) and tetrakis(triphenylphosphine)palladium(0). These ...

https://en.wikipedia.org/wiki/Organopalladium

... compounds are isomeric with and less common than allyl compounds, which have the formula RCH2-CH=CH2. Propene Radical ... Many propenyl compounds are known, such as cis- and trans-1-chloropropene, propenylbenzene (β-methylstyrene). ...

https://en.wikipedia.org/wiki/Propenyl

12) Methods for the addition of allyl groups to carbonyl compounds are numerous and incorporate a variety of metals. ... These compounds are usually prepared by enantioselective reduction with a chiral reducing agent such as BINAL-H. In the ... These compounds react similarly to allylstannanes to afford homopropargyl alcohols, and any of the three reaction modes ... Reactions should be carried out in a well-ventilated fume hood, however, as volatile organotin compounds are highly toxic. Gung ...

https://en.wikipedia.org/wiki/Organostannane_addition

This is likely in cases when the allyl compound is unhindered, and a strong nucleophile is used. The products will be similar ... An allylic rearrangement or allylic shift is an organic reaction in which the double bond in an allyl chemical compound shifts ... Allyl shifts can also take place with electrophiles. In the example below the carbonyl group in benzaldehyde is activated by ... This is usual in allylic compounds which have a bulky leaving group in SN2 conditions or bulky non-leaving substituent which ...

https://en.wikipedia.org/wiki/Allylic_rearrangement

Ludger Krähling, Jürgen Krey, Gerald Jakobson, Johann Grolig, Leopold Miksche "Allyl Compounds" in Ullmann's Encyclopedia of ... It is a byproduct in the chlorination of propene to make allyl chloride. It is usually obtained as a mixture of the geometric ... 1,3-Dichloropropene, sold under diverse trade names, is an organochlorine compound. It is colorless liquid with a sweet smell. ... Compound ATSDR Toxicological Profile (9.2 MB) CDC - NIOSH Pocket Guide to Chemical Hazards. ...

https://en.wikipedia.org/wiki/1,3-Dichloropropene

... allium compounds) Allyl methyl trisulfide garlic, onions, leeks, chives, shallots. Sulfides Diallyl disulfide garlic, onions, ... Allyl isothiocyanate horseradish, mustard, wasabi. Syn-propanethial-S-oxide cut onions. Indole-3-carbinol cabbage, kale, ... Allyl isothiocyanate Phenethyl Isothiocyanate Benzyl Isothiocyanate Oxazolidine-2-thiones Nitriles Thiocyanates Polysulfides ( ... Sinigrin (the precursor to allyl isothiocyanate) broccoli family, brussels sprouts, black mustard. Glucotropaeolin (the ...

https://en.wikipedia.org/wiki/List_of_phytochemicals_in_food

The first commercial synthesis of vanillin began with the more readily available natural compound eugenol (4-allyl-2- ... Vanillin is most prominent as the principal flavor and aroma compound in vanilla. Cured vanilla pods contain about 2% by dry ... Phenolic compounds in wine Other positional isomers: Isovanillin ortho-Vanillin 2-Hydroxy-5-methoxybenzaldehyde 2-Hydroxy-4- ... Vanillin is an organic compound with the molecular formula C8H8O3. It is a phenolic aldehyde. Its functional groups include ...

https://en.wikipedia.org/wiki/Vanillin

Krähling, Ludger; Krey, Jürgen; Jakobson, Gerald; Grolig, Johann; Miksche, Leopold (2000), "Allyl Compounds", Ullmann's ... Bloomfield, G.F. (1944). "Rubber, Polyisoprenes, and Allied Compounds. Part VI. The Mechanism of Halogen-substitution Reactions ... 1948-10-01). "Brominations with N-Bromosuccinimide and Related Compounds. The Wohl-Ziegler Reaction". Chemical Reviews. 43 (2 ... Theilacker, Walter; Wessel, Heinz (1967). "Olefinreaktionen, I. Chlorierung in Allyl-Stellung". Justus Liebigs Annalen der ...

https://en.wikipedia.org/wiki/Wohl–Ziegler_bromination

It may be of interest to researchers that the allyl group in this compound and in allylprodine overlay very closely. 14- ...

https://en.wikipedia.org/wiki/14-Cinnamoyloxycodeinone

Although originally developed for benzyl compounds, the reaction also works for allyl halides, giving the respective α,β-enones ... This compound then initiates an SN2 reaction to displace the benzyl halide. Unlike in the nitroaldol reaction, where the ...

https://en.wikipedia.org/wiki/Hass–Bender_oxidation

For example, the compound Tricyclodecenyl allyl ether is often found in synthetic perfumes[60][61] and has insect repellent ... Perfume (UK: /ˈpɜːr.fjuːm/ US: /pərˈfjuːm/; French: parfum) is a mixture of fragrant essential oils or aroma compounds, ... By using a slightly hydrophilic compound such as ethanol, most of the fragrant compounds from the waxy source materials can be ... Plants are by far the largest source of fragrant compounds used in perfumery. The sources of these compounds may be derived ...

https://en.wikipedia.org/wiki/Parfume

Compounds of the type [(η3-allyl)Fe(CO)4]+X− are allyl cation synthons in allylic substitution. In contrast, compounds of the ... Organoiron chemistry is the chemistry of iron compounds containing a carbon-to-iron chemical bond. Organoiron compounds are ... compounds are known. Fe(I) compounds often feature Fe-Fe bonds, but exceptions occur, such as [Fe(anthracene)2]−. The rapid ... a very stable compound which foreshadowed the synthesis of many related sandwich compounds. Ferrocene is formed by reaction of ...

https://en.wikipedia.org/wiki/Organoiron_chemistry

This compound was reduced to the allyl alcohol 25 using the Lindlar catalyst and lithium aluminium hydride removed the ... This compound should form as a diastereomeric pair but only one compound was found although which one was not investigated. ... In this effort one of strychnine's many degradation products was synthesised first (the relay compound), a compound also ... Conversion of this compound with malonic acid to (−)-strychnine 11 was already known as a procedure. The 1993 Keuhne synthesis ...

https://en.wikipedia.org/wiki/Strychnine_total_synthesis

Doyle expanded the scope of the reaction to include diazo compounds such as ethyl diazoacetate, allyl amines and allyl halides ... An example is the reaction of ethyl diazoacetate with allyl iodide: The reaction can also be catalyzed by iron, palladium and ... in which in the original scope an allyl sulfide reacts with trimethylsilyldiazomethane to form the homoallyl sulfide compound. ... Mechanism of the rhodium- and copper-catalyzed reactions with allylic compounds Michael P. Doyle, William H. Tamblyn, Vahid ...

https://en.wikipedia.org/wiki/Doyle–Kirmse_reaction

The compound is a reagent in the Doyle-Kirmse reaction with allyl sulfides and allyl amines. Trimethylsilyldiazomethane is ... Trimethylsilyldiazomethane is the organosilicon compound with the formula (CH3)3SiCHN2. It is classified as a diazo compound. ... It has also been employed widely in tandem with GC-MS for the analysis of various carboxylic compounds which are ubiquitous in ... deprotonated by butyllithium: (CH3)3SiCHN2 + BuLi → (CH3)3SiCLiN2 + BuH The lithio compound is versatile. From it can be ...

https://en.wikipedia.org/wiki/Trimethylsilyldiazomethane

In the case of an allyl alcohol compound with a proximate carbonyl functional group, the epoxide can undergo a ring-expansion ... and conversion of nitroso compounds to nitro compounds or nitramines. For example, a mixture of hydrogen peroxide and ... The hypervalent compound is accessible in two ways, and which is chosen usually depends on what materials are available: it can ... One example is the formation of the hypervalent iodine compound (bis(trifluoroacetoxy)iodo)benzene, (CF 3COO) 2IC 6H 5 which is ...

https://en.wikipedia.org/wiki/Trifluoroperacetic_acid

Organosilanes offer the advantage of greater robustness to a wide array of reaction conditions than allyl compounds of more ... Electrophilic substitution of unsaturated silanes involves attack of an electrophile on an allyl- or vinylsilane. An allyl or ... In some cases, these compounds react more cleanly than the corresponding carbonyl compounds. (10) Iminium ions generated in ... 6) Allyl- and vinylsilanes react with a variety of electrophiles under conditions of nucleophilic catalysis or Lewis acid ...

https://en.wikipedia.org/wiki/Electrophilic_substitution_of_unsaturated_silanes

The leaf blade is usually simple, entire or dissected, rarely trifoliolate or pinnately compound. A leaf rosette at the base ... Allyl isothiocyanate (AITC). *Methyl isothiocyanate (MITC). *Benzyl isothiocyanate (BITC). *Fluorescein isothiocyanate (FITC) ... Parasitoid wasps that feed on such insect herbivores are attracted to the chemical compounds released by the plants, and thus ... which are compounds toxic to most animals, fungi and bacteria. Some insect herbivores have developed counter adaptations such ...

https://en.wikipedia.org/wiki/Brassicaceae

... compound F. Compound F continues to react with the palladium intermediate B, with regeneration of the copper halide, G. ... There are also examples of the coupling partners both being attached to allyl resins, with the Pd(0) catalyst effecting ... The active palladium catalyst is the 14 electron compound Pd0L2, complex A, which reacts with the aryl or vinyl halide in an ... In an inverse Sonogashira coupling the reactants are an aryl or vinyl compound and an alkynyl halide. While a copper co- ...

https://en.wikipedia.org/wiki/Sonogashira_coupling

The plant contains aristolochic acid, a carcinogenic compound.[36] The United States Food and Drug Administration warns that ... Allyl isothiocyanate (mustard, radish, horseradish, wasabi). *AM404. *Bradykinin. *Cannabichromene (cannabis). *Cannabidiol ( ... as the major pungent compound.[41] Zingerone is produced from gingerols during drying, having lower pungency and a spicy-sweet ...

https://en.wikipedia.org/wiki/Ginger

Elizabeth Kent noted in her Flora Domestica (1823), "The botanical name of this plant is compounded of two Latin words, ... Allyl isothiocyanate (mustard, radish, horseradish, wasabi). *AM404. *Bradykinin. *Cannabichromene (cannabis). *Cannabidiol ( ...

https://en.wikipedia.org/wiki/E392

... (also known as capsicum spray) is a lachrymatory agent (a chemical compound that irritates the eyes to cause tears ... Allyl isothiocyanate (mustard, radish, horseradish, wasabi). *AM404. *Bradykinin. *Cannabichromene (cannabis). *Cannabidiol ( ... The SHU is a measurement of the base resin compound and not what comes out in the aerosol. The rated irritant effect of the ... Italy: Any citizen over 16 years of age without a criminal record could possess, carry and purchase any OC-based compounds and ...

https://en.wikipedia.org/wiki/Pepper_spray

... is a derivative of psoralen, the parent compound of a family of naturally-occurring organic compounds known as the ... Osmium tetraoxide and sodium metraperiodate were used to oxidatively cleave the O-allyl derivative onto the aldehyde product 7 ... In particular, bergapten appears to be the primary phototoxic compound responsible for Citrus-induced phytophotodermatitis.[3] ... Bergapten is a natural compound coming from plants like the common fig, but it can also be synthesized. Most syntheses of ...

https://en.m.wikipedia.org/wiki/Bergaptene

... s constitute a natural class of organic compounds that contain sulfur and nitrogen and are derived from glucose ... Allylglucosinolate (sinigrin) is the precursor of allyl isothiocyanate. *Benzylglucosinolate (Glucotropaeolin) is the precursor ... allylglucosinolate versus allyl glucosinolate) are both in use and has equivalent meaning. Isothiocyanates must be spelled in ... it is variation in the side group that is responsible for the variation in the biological activities of these plant compounds. ...

https://en.m.wikipedia.org/wiki/Glucosinolates

In aqueous solution, like compounds of other late lanthanides, soluble ytterbium compounds form complexes with nine water ... Lou, S.; Westbrook, J. A.; Schaus, S. E. (2004). "Decarboxylative Aldol Reactions of Allyl β-Keto Esters via Heterobimetallic ... 2 oxidation state occurs only in solid compounds and reacts in some ways similarly to the alkaline earth metal compounds; for ... Marignac suspected that ytterbia was a compound of a new element that he called "ytterbium".[9][23][25][26][27] ...

https://en.m.wikipedia.org/wiki/Ytterbium

Researchers found that replacing one of the ethyl groups of milnacipran with an allyl moiety increases the norepinephrine ... Changing the SAR in milnacipran changes the stereochemistry of the compound and affects the norepinephrine and serotonin ... Clinical studies suggest that compounds that increase the concentration in the synaptic cleft of both norepinephrine and ... The nature of the aromatic substituent also has a significant influence on the activity and selectivity of the compounds as ...

https://en.wikipedia.org/wiki/Serotonin-norepinephrine_reuptake_inhibitor

Reduction of nitro compounds Nitro compounds Can be accomplished with elemental zinc, tin or iron with an acid. ... ˈæmiːn/,[1][2] UK also /ˈeɪmiːn/)[3] are compounds and functional groups that contain a basic nitrogen atom with a lone pair. ... Aryldiazonium couple with electron-rich aromatic compounds such as a phenol to form azo compounds. Such reactions are widely ... Compounds with a nitrogen atom attached to a carbonyl group, thus having the structure R-CO-NR′R″, are called amides and have ...

https://en.wikipedia.org/wiki/Amine

Inhibitors of ethylene perception include compounds that have a similar shape to ethylene, but do not elicit the ethylene ... One of the first organometallic compounds, Zeise's salt is a complex of ethylene. Useful reagents containing ethylene include ... exceeds that of any other organic compound.[7][8] Much of this production goes toward polyethylene, a widely used plastic ... Alkene (Allyl, Vinyl). *Alkyl (Methyl, Ethyl, Propyl, Butyl, Pentyl). *Alkyne. *Benzyl. *Carbene ...

https://fa.wikipedia.org/wiki/اتیلن?match=en

chemical compound comment E200 - E203 sorbic acid, sodium sorbate and sorbates common for cheese, wine, baked goods, personal ... "Preservation of Acidified Cucumbers with a Natural Preservative Combination of Fumaric Acid and Allyl Isothiocyanate that ... Nonsynthetic compounds for food preservation[edit]. Citric and ascorbic acids target enzymes that degrade fruits and vegetables ... Chemical preservation entails adding chemical compounds to the product. Physical preservation entails processes such as ...

https://en.wikipedia.org/wiki/Preservatives

Natural compounds as drugs. 2. Basel: Birkhäuser. pp. 335-59. ISBN 978-3-7643-8594-1.. Retrieved on November 8, 2009 through ...

https://en.wikipedia.org/wiki/Romidepsin

1,2,3-trichloropropane is reduced to allyl chloride by D. lykanthroporepellens, and further transformed abiotically to allyl ... It uses these compounds as electron acceptors in dihaloelimination reactions.[3] In dihaloelimination the electron donor (H2 in ... reduces it to allyl chloride which abiotically transforms in the presence of water to allyl alcohol).[1] ... these chlorinated compounds are prevalent groundwater and soil contaminants throughout the US and around the world.[11] ...

https://en.wikipedia.org/wiki/Dehalogenimonas_lykanthroporepellens

... is only a trace compound in the fly agaric Amanita muscaria; the pharmacologically more relevant compounds from this ... Treatment of the crude aldehyde with allyl bromide and zinc powder in water with NH4Cl as catalyst resulted in an anti:syn ... A paucity of research exists on the metabolism of muscarine in the human body, suggesting this compound is not metabolized by ... Peter G. Waser; Chemistry and pharmacology of muscarine, muscarone and some related compounds; Pharmacology Department, ...

https://en.wikipedia.org/wiki/Muscarine

Diacylglycerol can be mimicked by the tumor-promoting compounds phorbol esters.[6] ... Allyl isothiocyanate (mustard, radish, horseradish, wasabi). *AM404. *Bradykinin. *Cannabichromene (cannabis). *Cannabidiol ( ...

https://en.wikipedia.org/wiki/Diglyceride

Allyl compounds[edit]. Many substituents can be attached to the allyl group to give stable compounds. Commercially important ... The middle MO labeled Ψ2 is singly occupied in the allyl radical. In the allyl cation Ψ2 is unoccupied and in the allyl anion ... In 1844, Theodor Wertheim isolated an allyl derivative from garlic oil and named it "Schwefelallyl".[3][4] The term allyl ... and allylindium compounds are commonly used by organic chemists to introduce allyl groups.[9] ...

https://en.wikipedia.org/wiki/Allyl_group

Although chives are repulsive to insects in general, due to their sulfur compounds, their flowers attract bees, and they are at ... Allyl mercaptan. *syn-Propanethial-S-oxide. Related. *Garlic Is as Good as Ten Mothers (1980 documentary) ...

https://en.wikipedia.org/wiki/Chive

Some chemical compounds made from petroleum are also obtained from other fossil fuels, such as coal or natural gas, or ... allyl chloride - *epichlorohydrin - chloro-oxirane; used in epoxy resin formation *epoxy resins - a type of polymerizing glue ... Formaldehyde Moulding Compound (FMC). n-Hexene. Linear alkyl benzene (LAB). Methanol. Methyl tert-butyl ether (MTBE) Phenol. ...

https://en.wikipedia.org/wiki/Petrochemical

Nonsynthetic compounds for food preservation[edit]. Citric and ascorbic acids target enzymes that degrade fruits and vegetables ... "Preservation of Acidified Cucumbers with a Natural Preservative Combination of Fumaric Acid and Allyl Isothiocyanate that ... Chemical preservation entails adding chemical compounds to the product. Physical preservation entails processes such as ... The detailed mechanism of these chemical compounds range from inhibiting growth of the bacteria to the inhibition of specific ...

https://en.wikipedia.org/wiki/Preservative

The linear compound 1-propene has a pKa of 44, which is relatively acidic for an sp3 carbon center because the resultant allyl ... of an antiaromatic compound, it merely suggests that the compound could be antiaromatic). An antiaromatic compound may also be ... Unlike aromatic compounds, which follow Hückel's rule ([4n+2] π electrons) and are highly stable, antiaromatic compounds are ... In contrast to the diamagnetic ring current present in aromatic compounds, antiaromatic compounds have a paramagnetic ring ...

https://en.wikipedia.org/wiki/Antiaromaticity

5α,6α)-17-allyl-7,8-didehydro-4,5-epoxymorphinan-3,6-diyl dinicotinate ... Allyl compounds. *Nicotinate esters. *Morphinans. *Opioid antagonists. *Phenols. *Semisynthetic opioids. *Nervous system drug ...

https://en.wikipedia.org/wiki/Nalorphine_dinicotinate

Chemical articles with multiple compound IDs. *Chemicals using indexlabels. *Chemical articles with multiple CAS registry ... Allyl isothiocyanate (mustard, radish, horseradish, wasabi). *AM404. *Bradykinin. *Cannabichromene (cannabis). *Cannabidiol ( ...

https://en.wikipedia.org/wiki/13-oxoODE

... volatile ether compounds, which one can view as coupled compounds of alcohol and acid-water, or, according to the theory of ... Allyl hexanoate pineapple Benzyl acetate pear, strawberry, jasmine Bornyl acetate pine Butyl acetate apple, honey ... In chemistry, an ester is a chemical compound derived from an acid (organic or inorganic) in which at least one -OH (hydroxyl) ... Sources of carbon nucleophiles, e.g., Grignard reagents and organolithium compounds, add readily to the carbonyl. ...

https://en.wikipedia.org/wiki/Esters

Allyl isothiocyanate and 4-hydroxybenzyl isothiocyanate are responsible for the sharp, hot, pungent sensation in mustards and ... Mixing ground mustard seeds with water causes a chemical reaction between two compounds in the seed: the enzyme myrosinase and ... When whole mustard seeds are wetted and crushed, an enzyme is activated that releases pungent sulphurous compounds; but they ... The myrosinase enzyme turns the glucosinolates into various isothiocyanate compounds known generally as mustard oil. The ...

https://en.wikipedia.org/wiki/Mustard_

The C17α allyl derivatives allylestrenol (3-deketo-17α-allyl-19-NT) and altrenogest (17α-allyl-δ9,11-19-NT) ... Norethisterone (NET) is the parent compound of a large group of progestins that includes most of the progestins known as the 19 ... This is then reacted with metal acetylide into the corresponding C17α ethynyl compound (4). Hydrolysis of the enol ether under ... its parent compounds, testosterone, nandrolone (19-nortestosterone), and ethisterone (17α-ethynyltestosterone), have 2%, 22%, ...

https://en.wikipedia.org/wiki/Norethindrone

John's Wort, are hyperforin and adhyperforin.[9][10] These compounds are inhibitors of the reuptake of serotonin, ... Allyl isothiocyanate (mustard, radish, horseradish, wasabi). *AM404. *Bradykinin. *Cannabichromene (cannabis). *Cannabidiol ( ...

https://en.wikipedia.org/wiki/TRPC6

The compound primarily responsible for the aroma and flavor of spearmint is L-carvone. ... Allyl isothiocyanate (mustard, radish, horseradish, wasabi). *AM404. *Bradykinin. *Cannabichromene (cannabis). *Cannabidiol ( ...

https://en.wikipedia.org/wiki/Mentha

The trinuclear compound ScCp3 can also be synthesized from NaCp: ScCl3 + 3 NaCp → ScCp3 + 3 NaCl. This compound is sensitive to ... 2 two allyl ligands are η3 coordinated and one allyl ligand is η1 coordinated. ... Synthesis of Organometallic Compounds: A Practical Guide Sanshiro Komiya Ed. 1997 *^ C. Elschenbroich, A. Salzer ... Allyl complexes of scandium: synthesis and structure of neutral, cationic and anionic derivatives Sabine Standfuss, Elise ...

https://en.wikipedia.org/wiki/Organoscandium_chemistry

Phenyl compounds are derived from benzene (C6H6), at least conceptually and often in terms of their production. In terms of its ... One of the simplest phenyl-containing compounds is phenol, C6H5OH. It is often said the resonance stability of phenol makes it ... So, a given substituted phenyl compound has three isomers, ortho (1,2-disubstitution), meta (1,3-disubstitution) and para (1,4- ... Many or even most phenyl compounds are not described with the term "phenyl". For example, the chloro derivative C6H5Cl is ...

https://en.wikipedia.org/wiki/Phenyl

Organosulfur compound. Shows anticancer and anti-oxidant properties. Activates the TRPA1 ion channel in vitro. Apoptosis ... Organosulfur compound. Shows anticancer and anti-oxidant properties. Activates the TRPA1 ion channel in vitro. Apoptosis ...

https://www.abcam.com/allyl-disulfide-organosulfur-compound-ab141898.html

"Anion Exchangers Based on Allyl Compounds and Some Nitrogen- and Oxygen-Containing Monomers and Oligomers, Russian Journal of ... Anion Exchangers Based on Allyl Compounds and Some Nitrogen- and Oxygen-Containing Monomers and Oligomers. Ergozhin, E.; Chalov ... Anion Exchangers Based on Allyl Compounds and Some Nitrogen- and Oxygen-Containing Monomers and... Ergozhin, E.; Chalov, A.; ... Anion Exchangers Based on Allyl Compounds and Some Nitrogen- and Oxygen-Containing Monomers and Oligomers. ...

https://www.deepdyve.com/lp/springer_journal/anion-exchangers-based-on-allyl-compounds-and-some-nitrogen-and-oxygen-z093gFkR2t

Allyl compounds explanation free. What is Allyl compounds? Meaning of Allyl compounds medical term. What does Allyl compounds ... Looking for online definition of Allyl compounds in the Medical Dictionary? ... allyl. (redirected from Allyl compounds). Also found in: Dictionary, Thesaurus. al·lyl. (alil), The monovalent radical, CH2= ... Allyl compounds , definition of Allyl compounds by Medical dictionary https://medical-dictionary.thefreedictionary.com/Allyl+ ...

https://medical-dictionary.thefreedictionary.com/Allyl+compounds

Natural organosulfur compounds (OSCs) have been shown to have chemopreventive effects and to suppress the proliferation of ... are needed to identify the molecular targets and modes of action of these natural compounds, the allyl sulfur compounds can ... Several modes of action of these compounds have been proposed, and it seems likely that the rate of clearance of allyl sulfur ... The aim of this review is to focus attention on the effects of natural allyl sulfur compounds on the cell detoxification system ...

https://link.springer.com/article/10.1007%2Fs00726-010-0522-6

https://en.wikipedia.org/wiki/Allyl_group

Allyl Heptanoate, Allyl Phenoxyacetate, Coconut Amine and Diallylamine offered by Triveni Interchem Private Limited (Group Of ... Allyl Compounds. We are a leading Manufacturer of allyl heptanoate, allyl phenoxyacetate, coconut amine, diallylamine and ... It is chemical compounds.. Application / Uses Preparation. We are the leading wholesaler of Diallylamine compound with selling ... Allyl Heptanoate (142-19-8) is colourless liquid. also known as Heptanoic Acid Allyl Ester . Additional Information: ...

http://www.triveniinterchem.com/allyl-compounds.html

... and lipid-soluble allyl sulfur compounds arising from processed garlic inhibited ACF. The response to these allyl sulfur ... compounds appears to depend on several factors, including the speciation, quantity, and duration provided. ...

https://ecnis.openrepository.com/handle/10146/67741

Mouayed M. Mahmoud, Saad N. Ibrahim, "The Crystal Structure Analyses of Molecular Compound N ? allyl-2, 6 - di (ortho-chloro- ... The crystal structure of the N-allyl-2, 6-di (ortho-chloro-phenyl) -4-methoxyphenyl pyridinium perchlorate molecular compound ... The Crystal Structure Analyses of Molecular Compound N ? allyl-2, 6 - di (ortho-chloro-phenyl) ? 4 - methoxyphenyl pyridinium ... The Crystal Structure Analyses of Molecular Compound N ? allyl-2, 6 - di (ortho-chloro-phenyl) ? 4 - methoxyphenyl pyridinium ...

https://www.ijsr.net/get_abstract.php?paper_id=OCT1430

Allyl compounds , Aldehydes , Epoxy compounds , Peroxides , Neoplasms , Environmental exposure , Noncommunicable DiseasesNLM ... Allyl compounds, aldehydes, epoxides and peroxides / this publication represents the views and expert opinions of an IARC ... By: IARC Working Group on the Evaluation of the Carcinogenic Risk of Chemicals to Humans: Allyl compounds Aldehydes, Epoxides ... An expert evaluation of all published data useful in determining the carcinogenic risk posed by 14 allyl compounds, aldehydes, ...

https://kohahq.searo.who.int/cgi-bin/koha/opac-search.pl?q=ccl=su%3A%7BEpoxy%20compounds%7D&sort_by=relevance_dsc&limit=su-to:Neoplasms.

... offer potent anti-carcinogenic compounds unique to sulfur-containing vegetables. Heres why we need them. ... Alliums and Their Allyl Sulfur Compounds. Garlic, onions, shallots, and leeks all contain various organosulfur compounds, some ... Heat breaks down the compounds. The only problem is that those same allyl sulfur compounds that might fight cancer, boost ... If its beneficial allyl sulfur compounds you want to consume, eating your alliums raw and sliced is the ticket. ...

https://www.marksdailyapple.com/why-you-should-eat-sulfur-rich-vegetables/

Allyl alcohols in general can be prepared by allylic oxidation of allyl compounds by selenium dioxide. Allyl alcohol is ... Allyl alcohol (IUPAC name: prop-2-en-1-ol) is an organic compound with the structural formula CH2=CHCH2OH. Like many alcohols, ... Allyl alcohol is the smallest representative of the allylic alcohols. Allyl alcohol can be obtained by many methods. It was ... Today allyl alcohol is produced commercially by the Olin and Shell corporations through the hydrolysis of allyl chloride: CH2= ...

https://en.wikipedia.org/wiki/Allyl_alcohol

Allyl acetate is an organic compound with formula C3H5OC(O)CH3. This colourless liquid is a precursor to especially allyl ... Allyl acetate can be hydrolyzed to allyl alcohol: CH2=CHCH2OCOCH3 + H2O → CH2=CHCH2OH + CH3COOH Allyl alcohol is a precursor ... Allyl alcohol is also produced primarily from allyl chloride, but production via the hydrolysis of allyl acetate route avoids ... 2000). "Allyl Compounds". Ullmanns Encyclopedia of Industrial Chemistry. doi:10.1002/14356007.a01_425.. ...

https://en.wikipedia.org/wiki/Allyl_acetate

Topics: aflatoxins; aldehydes; allyl compounds; aromatic amines; aromatic hydrocarbons; benzene; biological effects; ... An evaluation of toxic and genotoxic risk from work-related exposure to chemical compounds Valutazione del rischio tossico e ... and in assessing the efficiency of radioprotective compounds is also discussed.. Central European Journal of Occupational and ...

https://www.ilo.org/dyn/cisdoc2/cismain.listDocs?p_lang=en&p_bsubject=91&p_page=5&p_pagesize=50&p_template=NORMALPAGE

allyl isothiocyanate (chemical compound). organosulfur compound: Thiocarbonyl compounds: Allyl isothiocyanate, CH2=CHCH2N=C=S, ... allyl (chemical compound). organometallic compound: Alkene and alkyne ligands: The allyl ligand, ―CH2―CH=CH2, can bind to a ... allyl chloride (chemical compound). organohalogen compound: …that bears the halogen in allyl chloride (CH2=CHCH2Cl) is singly ... allyl carbanion (chemical compound). carbanion: Delocalized ions.: The allyl carbanion (formula, C3H-5), a somewhat more ...

https://www.britannica.com/sitemap/a/83

Allyl Compounds / pharmacology* * Animals * Drug Resistance, Neoplasm / drug effects* * Humans * Immunohistochemistry * K562 ... In the present study, we evaluated the P-gp modulatory potential of diallyl sulfide (DAS), a volatile organosulfur compound ...

https://pubmed.ncbi.nlm.nih.gov/14729595/

Isothiocyanates are compounds that have been shown to exhibit anticancer effects, such […] ... a compound present in many cruciferous vegetables, on human breast cancer cell lines MCF-7 and MDA-MB-231. The results were ... a team of researchers from Taiwan examined the effect of allyl isothiocyanate (AITC), ... Allyl isothiocyanate, a compound present in human diets, found to induce cell toxicity in breast cancer cell lines. ...

https://food.news/2019-06-25-allyl-isothiocyanate-induces-cell-toxicity-breast-cancer.html

The administration of allyl propyl disulphide (APDS), a volatile substance contained in onion, to six normal volunteers after a ... Allyl Compounds / pharmacology* Actions. * Search in PubMed * Search in MeSH * Add to Search ... The administration of allyl propyl disulphide (APDS), a volatile substance contained in onion, to six normal volunteers after a ... Effect of alloxan diabetes of allyl propyl disulphide obtained from onion. Augusti KT. Augusti KT. Naturwissenschaften. 1974 ...

https://pubmed.ncbi.nlm.nih.gov/1126028/

... allyl, and propargyl organometallics of cyclopentadienyl iron, molybdenum, and tungsten complexes ... Synthesis of heterocyclic and carbocyclic compounds via alkynyl, ... of carbocyclic and heterocyclic compounds using allyl, ... Subjects list: Research, United States, Analysis, Usage, Heterocyclic compounds, Organic compounds, Organic compound synthesis ... Synthesis of heterocyclic and carbocyclic compounds via alkynyl, allyl, and propargyl organometallics of cyclopentadienyl iron ...

http://www.readabstracts.com/Chemistry/Synthesis-of-heterocyclic-and-carbocyclic-compounds-via-alkynyl-allyl-and-propargyl-organometallics-.html

Allyl compounds, aldehydes, epoxides and peroxides Conclusions of a meeting of experts (Lyon, France, June 1984). There is ... limited or inadequate evidence for the carcinogenicity of allyl chloride, allyl isothiocyanate, allyl isovalerate and eugenol ... Benzyl compounds are eluted from the sorbent with chloroform and separated on a 4mm by 2m steel column packed with (a) 5% XE-60 ... Phosphorus compounds from stabilisers were also detected. During application of polyvinyl chloride insulation another range of ...

https://www.ilo.org/dyn/cisdoc2/cismain.listDocs?p_lang=en&p_bsubject=1044&p_page=7&p_pagesize=50&p_template=NORMALPAGE

Vinyl, Allyl, Acetylenic, and Phenyl Compounds.. 2.3. Halogeno, Pseudohalogeno, and Acido Compounds. ... and coordination compounds. From fundamental theories of vibrational spectroscopy to applications in a variety of compound ... Infrared and Raman Spectra of Inorganic and Coordination Compounds, Part B: Applications in Coordination, Organometallic, and ... Infrared and Raman Spectra of Inorganic and Coordination Compounds, Part B: Applications in Coordination, Organometallic, and ...

https://www.wiley.com/en-us/Infrared+and+Raman+Spectra+of+Inorganic+and+Coordination+Compounds%2C+Part+B%3A+Applications+in+Coordination%2C+Organometallic%2C+and+Bioinorganic+Chemistry%2C+6th+Edition-p-9780470405871

Kappa agonists, Opioid receptor ligands, Drugs acting on the nervous system, Allyl compounds, Six-membered rings, Opioids, ...

http://api.chemchart.com/search?search=Kappa+agonists%2C+Opioid+receptor+ligands%2C+Drugs+acting+on+the+nervous+system%2C+Allyl+compounds%2C+Six-membered+rings%2C+Opioids%2C+Cyclohexenes%2C+Opioid+antagonists

Kappa agonists, Opioid receptor ligands, Drugs acting on the nervous system, Allyl compounds, Cyclohexenes, Cycloalkenes, Six- ... Pyrazole is an organic compound with the formula C3H3N2H. It is a heterocycle characterized by a 5-membered ring of three ... 1-Phenylpiperazine is a simple chemical compound featuring a phenyl group bound to a piperazine ring. The suffix -piprazole ...

http://api.chemchart.com/search?search=Kappa+agonists%2C+Opioid+receptor+ligands%2C+Drugs+acting+on+the+nervous+system%2C+Allyl+compounds%2C+Cyclohexenes%2C+Cycloalkenes%2C+Six-membered+rings

Among the tested compounds, s-allyl-l-cysteine-sulfoxide (SACS)/alliin showed higher affinity towards EGFR. Furthermore, wet ... The present study was aimed to analyze the interaction ability of garlic compounds in the active region of EGFR gene by in ... Lipinski CA (2004) Lead and drug-like compounds: the rule-of-five revolution. Drug Discov Today Technol 1(4):337-341. doi: ... Wang HC, Pao J, Lin SY, Sheen LY (2012) Molecular mechanisms of garlic-derived allyl sulfides in the inhibition of skin cancer ...

https://link.springer.com/article/10.1007%2Fs12539-017-0227-6

Aldehydes--Carcinogens ; Aldehydes--Toxicology ; Allyl Compounds--toxicity ; Epoxy Compounds ; Ethers, Cyclic--toxicity ; ... Allyl compounds, aldehydes, epoxides, and peroxides.. CORP Author. IARC Working Group on the Evaluation of the Carcinogenic ... Aromatic compounds--Toxicology--Congresses. ; Carcinogens--Congresses. ; Mutagenesis--Congresses. Holdings. Library. Call ... Aldehydes--Toxicology--Congresses ; Epoxy compounds--Toxicology--Congresses ; Peroxides--Toxicology--Congresses ; Carcinogens-- ...

https://cfpub.epa.gov/ols/catalog/advanced_bibliography.cfm?FIELD1=SUBJECT&INPUT1=Carcinogens%20Congresses&TYPE1=EXACT&LOGIC1=AND&COLL=&SORT_TYPE=MTIC&start_row=25

Allyl Compounds. Benzoquinones / chemistry*. Carboxylic Acids / chemistry*. Catalysis. Combinatorial Chemistry Techniques. ... 0/Alkenes; 0/Allyl Compounds; 0/Benzoquinones; 0/Carboxylic Acids; 106-51-4/benzoquinone; 7440-05-3/Palladium ...

http://www.biomedsearch.com/nih/Versatile-Catalyst-System-Decarboxylative-Olefination/19432465.html

Enzymes catalyzing the transfer of an acetyl group, usually from acetyl coenzyme A, to another compound. EC 2.3.1. ...

https://www.bioportfolio.com/resources/pmarticle/2588807/Catalyzing-the-Hydrodefluorination-of-CF3-substituted-Alkenes-by-PhSiH3-H-Transfer-from.html

Sabelli R, Iorio E, De Martino A, et al.: Rhodanese-thioredoxin system and allyl sulfur compounds. FEBS J 275 (15): 3884-99, ... Hydrogen cyanide is thought to be the main anticancer compound formed from laetrile via in situ release. ... Rhodanese can convert cyanide into the relatively harmless compound thiocyanate. Thus, it has been proposed that cancer cells ... The germ-free rats exhibited no side effects from the compound, and their blood concentrations of cyanide were ...

https://www.cancer.gov/about-cancer/treatment/cam/hp/laetrile-pdq

https://www.cancer.gov/about-cancer/treatment/cam/hp/laetrile-pdq?cid=eb_govdel_esp

D1636 Standard Specification for Allyl Molding Compounds. D1676 Standard Test Methods for Film-Insulated Magnet Wire ... D5948 Standard Specification for Molding Compounds, Thermosetting. D6040 Standard Guide to Standard Test Methods for Unsintered ... D704 Standard Specification for Melamine-Formaldehyde Molding Compounds. D788 Standard Classification System for Poly(Methyl ... D4731 Standard Specification for Hot-Application Filling Compounds for Telecommunications Wire and Cable ...

https://www.astm.org/DATABASE.CART/STD_REFERENCE/D150.htm

0 (Allyl Compounds); 0 (Esters); 0 (Iodides); 0 (samarium diiodide); 42OD65L39F (Samarium); SIV03811UC (Kainic Acid); ... Compound 3 was isolated from this plant for the first time. The protective effects against H O -induced myocardial cell injury ... Compounds 1, 5 and 7-11 provided significant protective effects on H O -induced H9c2 cells injury at the concentration of 25 g/ ... Interestingly, PEFA compounds produced by Rhodotorula taiwanensis MD1149 were more surface active due to their hypoacetylation ...

http://bases.bireme.br/cgi-bin/wxislind.exe/iah/online/?IsisScript=iah/iah.xis&nextAction=lnk&base=MEDLINE&lang=p&format=detailed.pft&indexSearch=EX&exprSearch=D02.241.400

In this study, a team of researchers from Taiwan examined the effect of allyl isothiocyanate (AITC), a compound present in many cruciferous vegetables, on human breast cancer cell lines MCF-7 and MDA-MB-231. (food.news)
Assessment of DNA damage and repair in adults consuming allyl isothiocyanate or Brassica vegetables. (nih.gov)
It can be activated by electrophilic compounds such as allyl isothiocyanate (AITC). (tcdb.org)
The compound responsible for this effect is allyl isothiocyanate. (sixwise.com)
This is possible because the oil contains allyl isothiocyanate, which works to inhibit fungal growth and stop any present infections from spreading. (davidwolfe.com)
Horseradish contains allyl isothiocyanate, a compound known for its powerful antibacterial property. (natural-homeremedies.org)
It has a strong anti-inflammatory compound known as allyl-isothiocyanate which helps to inhibit inflammation. (vitalitymagazine.com)

A direct interaction of the garlic allyl sulfur compounds with proteins involved in the detoxification system was studied in order to support the hypothesis that proteins possessing reactive thiol groups and that are involved in the detoxification system and in the cellular redox homeostasis, are likely the preferential targets of these compounds. (springer.com)
Allyl sulfur compounds from garlic modulate aberrant crypt formation. (openrepository.com)
In preclinical studies, both water- and lipid-soluble allyl sulfur compounds arising from processed garlic inhibited ACF. (openrepository.com)
Among plants, garlic ( Allium sativum L.) is emerging with anticancer properties by virtue of its organosulfur compounds. (springer.com)
The present study was aimed to analyze the interaction ability of garlic compounds in the active region of EGFR gene by in silico molecular docking studies and in vitro validation. (springer.com)
Cao HX, Zhu KX, Fan JG, Qiao L (2014) Garlic-derived allyl sulfides in cancer therapy. (springer.com)
In the present study, we evaluated the P-gp modulatory potential of diallyl sulfide (DAS), a volatile organosulfur compound present in garlic, known to possess many medicinal properties, including antimutagenic and anticarcinogenic activities. (nih.gov)
Bioactivities of allyl sulfur compounds in garlic . (biola.edu)
The sulfur compounds found in garlic cause your platelets to become slippery, preventing them from sticking together and forming blood clots. (livestrong.com)
Garlic contains compounds known as allyl sulfur. (livestrong.com)
In garlic, there are at least 100 bioactive volatile sulfur compounds and nonvolatile with medicinal valuesthat contribute toits pharmacological uses, some bioactive components of garlic include S-allylcysteine, saponins, ajoene, and flavonoid phenolic compounds [10]. (thefreelibrary.com)
For example, the glucobrassins found in crucifers and the allyl sulfur compounds in garlic. (whfoods.org)
Garlic appears particularly effective in inhibiting compounds formed by nitrates, which are preservatives used to cure meat that are thought to turn into cancer-causing compounds within the intestines. (howstuffworks.com)
Garlic contains a large number of unique sulfur-containing compounds, which are credited with many of this herb's medicinal actions. (howstuffworks.com)
That's because an enzyme in garlic promotes conversion of the chemical compound alliin to the odorous allicin. (howstuffworks.com)
A review of studies published in the Chinese Journal of Natural Medicines confirmed that aged garlic can be used as a promising daily food supplement for preventing and treating cancer because of its compound called S-allylmercaptocysteine (SAMC). (naturalnews.com)
Notably, aged garlic extract (AGE) has stronger anticancer activities than that of fresh garlic, because it is enriched with AGE-specific organosulfur compounds, including SAMC. (naturalnews.com)
In multiple studies, the sulfur-containing compounds in garlic have been directly implicated in these potential health benefits. (whfoods.com)
While garlic ranks as an excellent source of manganese and vitamin B6, a very good source of vitamin C and copper, and a good source of selenium, phosphorus, vitamin B1, and calcium in our WHFoods rating system, it is the sulfur compounds in garlic that serve as its spotlight nutrients in terms of overall health benefits. (whfoods.com)
However, it is also worth noting here that the majority of studies have not focused on the presence of compounds in fresh garlic consumed as a food, but rather on garlic supplements, whether they be oils, tablets, powders, or other types of extracts. (whfoods.com)
Potent chemo-preventive effects have been demonstrated in various in vivo and in vitro models for sulphur-containing compounds found in naturally occurring products, such as, onions and garlic ( 19 , 20 ). (spandidos-publications.com)
To evaluate a radioprotective effect of sodium n -propyl thiosulfate (NPTS) and sodium 2-propenyl thiosulfate (2PTS) derived from onions and garlic, respectively, rat hepatoma H4IIE cells and mouse lymphoma L5178Y cells were preincubated with each of these compounds for 48 hours at 37°C before receiving 10 Gy of X-ray irradiation. (hindawi.com)
Two alk(en)yl thiosulfates (Figure 1 ), sodium n -propyl thiosulfate (NPTS) and sodium 2-propenyl thiosulfate (2PTS), isolated from onions ( Allium cepa ) and garlic ( A. sativum ), respectively, were originally identified as causative agents of onion- and garlic-induced hemolytic anemia in dogs [ 7 - 10 ]. (hindawi.com)
Aged garlic extract (AGE) and sulfur‑containing compounds, including S‑allylcysteine (SAC) are well documented botanical active components of garlic. (spandidos-publications.com)

Allyl compounds, aldehydes, epoxides and peroxides / this publication represents the views and expert opinions of an IARC Working Group on the Evaluation of the Carcinogenic Risk of Chemicals to Humans which met in Lyon, 19-26 June 1984. (who.int)
An expert evaluation of all published data useful in determining the carcinogenic risk posed by 14 allyl compounds, aldehydes, epoxides and peroxides. (who.int)
Cp*Ir(2,2′-bpyO)(H 2 O)] is a highly efficient and general catalyst for transfer hydrogenation of carbonyl compounds and chemoselective transfer hydrogenation of unsaturated aldehydes with isopropanol under neutral conditions. (organic-chemistry.org)

2.2.9 Coupling of Alkenes with Organometallic Compounds. (ebooks.com)

[3] [4] The term allyl applies to many compounds related to H 2 C=CH−CH 2 , some of which are of practical or of everyday importance, for example, allyl chloride . (wikipedia.org)
Today allyl alcohol is produced commercially by the Olin and Shell corporations through the hydrolysis of allyl chloride: CH2=CHCH2Cl + NaOH → CH2=CHCH2OH + NaCl Allyl alcohol can also be made by the rearrangement of propylene oxide, a reaction that is catalyzed by potassium alum at high temperature. (wikipedia.org)
The advantage of this method relative to the allyl chloride route is that it does not generate salt. (wikipedia.org)
Also avoiding chloride-containing intermediates is the "acetoxylation" of propylene to allyl acetate: CH2=CHCH3 + 1/2 O2 + CH3COOH → CH2=CHCH2OCOCH3 + H2O Hydrolysis of this acetate gives allyl alcohol. (wikipedia.org)
Allyl alcohol is also produced primarily from allyl chloride, but production via the hydrolysis of allyl acetate route avoids the use of chlorine, and so is increasing in use. (wikipedia.org)
Substitution of the acetate group in allyl acetate using hydrogen chloride yields allyl chloride. (wikipedia.org)
CH2=CHCH2OCOCH3 + HCl → CH2=CHCH2Cl + CH3COOH CH2=CHCH2OCOCH3 + HCN → CH2=CHCH2CN + CH3COOH Allyl chloride is generally produced directly by the chlorination of propene. (wikipedia.org)
During application of polyvinyl chloride insulation another range of compounds is released, the hygienically significant of which are vinyl chloride, 1,1-dichlorethane benzene, chlorobenzene and benzaldehyde. (ilo.org)
5. The process of claim 1 wherein the transition metal compound is a titanium dichloride-aluminium chloride-arene complex. (google.com)
8. The process of claim 1 wherein before, during or after the contacting of the inorganic compound with the transition metal compound, the inorganic compound is treated with a halogen-containing compound which is hydrogen chloride, titanium tetrachloride, butyl chloride or toluoyl chloride. (google.com)
The compound is dissolved in dry MeOH and thionyl chloride (2 eq) is added drop wise at 0° under an inert atmosphere. (virginia.edu)
A very simple one-pot process involving a cross-metathesis between acryloyl chloride and a terminal olefin followed by the addition of a nucleophile allows the synthesis of various functionalized α,β-unsaturated carbonyl compounds in good yield. (organic-chemistry.org)
The compound with the chemical formula SnCl4 is generally called tin (IV) chloride. (reference.com)

Allicin, one of garlic's healthy compounds (and the one that gives it its odor), has powerful antibacterial and antiviral properties. (sixwise.com)

A highly practical and general palladium-catalyzed α,β-dehydrogenation of esters and nitriles gives synthetically useful yields of α,β-unsaturated esters, lactones, and nitriles via generation of a zinc enolate or (cyanoalkyl)zinc species followed by the addition of an allyl oxidant and a palladium catalyst. (organic-chemistry.org)

Allyl alcohol is converted mainly to glycidol, which is a chemical intermediate in the synthesis of glycerol, glycidyl ethers, esters, and amines. (wikipedia.org)
Methods for the metal-mediated synthesis of seven to nine-membered ring compounds via ring-closing metathesis, ring-expansion, cyclization, cycloaddition, and annulation reactions are described. (readabstracts.com)
Palladium Reagents and Catalysts: New Perspectives for the 21 st Century is an essential reference source and companion for students, and both industrial and academic research chemists working in organic synthesis, particularly on synthesis of natural products and medicinal compounds. (ebooks.com)
1.2 Palladium Compounds, Complexes, and Ligands Widely Used in Organic Synthesis. (ebooks.com)
Modern perfumery began in the late 19th century with the commercial synthesis of aroma compounds such as vanillin or coumarin , which allowed for the composition of perfumes with smells previously unattainable solely from natural aromatics alone. (wikipedia.org)

Allyl methyl sulfide, an organosulfur compound alleviates hyperglycemia mediated hepatic oxidative stress and inflammation in streptozotocin - induced experimental rats. (annals.org)
SAC is a water‑soluble organosulfur compound and the most abundant component of AGE. (spandidos-publications.com)
One of the major bioactive components in AGE is S-allylcysteine (SAC), a stable organosulfur compound with a thiol group ( 13 ). (spandidos-publications.com)

It was first prepared in 1856 by Auguste Cahours and August Hofmann by hydrolysis of allyl iodide. (wikipedia.org)

This invention relates to novel organosilicon compounds. (patentgenius.com)
The present invention relates to novel compounds of formula (I), process for preparation of the same and composition comprising these compounds. (patents.com)

It is the acetate ester of allyl alcohol. (wikipedia.org)
When used as a component of an olefine polymerization catalyst, the transition metal product can be mixed with an organo-aluminium compound and a Lewis Base compound such as an ester. (google.com)
5. A composition to claim 1, comprising, as the ethylenically unsaturated photopolymerisable compound, a monofunctional, bifunctional or polyfunctional acrylic acid ester or methacrylic acid ester or mixtures thereof. (google.ca)

Second, and most importantly, sulfur-rich vegetation tends to come with extremely potent organosulfur compounds that offer a lot of benefit to those who eat them. (marksdailyapple.com)
The U.S. Department of Agriculture reported that this potent compound can fight off not only E. coli but also listeria, Staphylococcus aureus and other foodborne pathogens. (sixwise.com)
These sulfur compounds are potent antimicrobials and are thought to be the source of garlic's lipid-reducing and cancer-preventing effects. (howstuffworks.com)

What Is Allyl Sulfide? (reference.com)
Allyl sulfide is a chemical compound with the formula C6H10S and a molecular weight of 114.21 g/mol. (reference.com)

Ingredient standardized to a high concentration of the bioactive compound S-allyl cysteine (SAC). (nutraceuticalsworld.com)

Allyl acetate is an organic compound with formula C3H5OC(O)CH3. (wikipedia.org)
Allyl acetate is produced industrially by the gas phase reaction of propene in the presence of acetic acid using a palladium catalyst: C3H6 + CH3COOH + ½ O2 → CH2=CHCH2OCOCH3 + H2O This method is advantageous because propene is inexpensive and "green. (wikipedia.org)
Allyl acetate can be hydrolyzed to allyl alcohol: CH2=CHCH2OCOCH3 + H2O → CH2=CHCH2OH + CH3COOH Allyl alcohol is a precursor for some specialty polymers, mainly for drying oils. (wikipedia.org)
Abiraterone acetate [17-(3-pyridyl)-5,16-androstadien-33-acetate] is a steroid compound which inhibits selectively and efficiently the enzyme 17-ohydroxylase-C17- 20-lyase, which catalyzes the conversion of dehydroepiandrosterone and androstenedione to testosterone. (google.com)

The sulfur-containing compounds in this allium vegetable have been shown to provide us with health advantages in a wide variety of body systems, including: our cardiovascular system, immune system, inflammatory system, digestive system, endocrine system, and detoxification system. (whfoods.com)
The six categories of sulfur-containing compounds presented below will give you an initial look at the remarkable complexity of this allium vegetable. (whfoods.com)
In view of the usefulness of these Allium vegetables and the multifunction of these alk(en)nyl thiosulfates for human health, the present study was undertaken to evaluate a possible radioprotective effect of NPTS and 2PTS against X-ray-induced DNA damage in cultured mammalian cells. (hindawi.com)

Disclosed herein are compounds of Formula (I), wherein each of the substituents is given the definition as set forth in the specification and claims. (patents.com)

The 6th edition of this classic comprises the most comprehensive guide to infrared and Raman spectra of inorganic, organometallic, bioinorganic, and coordination compounds. (wiley.com)
A PBI compound that includes imidazole nitrogens, at least a portion of which are substituted with an organic-inorganic hybrid moiety. (google.com)
The organic-inorganic hybrid moiety may be an organosilane moiety, for example, (R)Me 2 SiCH 2 -, where R is selected from among methyl, phenyl, vinyl, and allyl. (google.com)
A transition metal compound containing at least one π-bonded arene is contacted with an inorganic oxide, hydroxide, oxyhalide, hydroxyhalide or halide. (google.com)
The inorganic compound is preferably of high surface. (google.com)
The inorganic compound is preferably of high surface area and this may be inherent in the compound or can be achieved by a grinding procedure. (google.com)
The inorganic compound can be treated with a halogen containing compound either before, during or after the contacting with the transition metal compound. (google.com)
The process of claim 1 wherein the transition metal compound is contacted with the inorganic compound in proportions such that from 0.05 up to 50% by weight of the transition metal compound is used relative to the inorganic compound. (google.com)
6. The process of claim 1 wherein the inorganic compound is alumina, a mixture of alumina and silica, the mixed oxide of aluminium and silicon, magnesium dihalide or manganese dihalide. (google.com)
9. The process of claim 1 wherein the inorganic compound is treated with an organic-Lewis Base. (google.com)
10. The process of claim 1 wherein the contacting of the transition metal compound with the inorganic compound is effected at the temperature of below ambient temperature. (google.com)

Other reactions that tend to occur with allylic compounds are allylic oxidations , ene reactions , and the Tsuji-Trost reaction . (wikipedia.org)
[6] [7] Carbonyl allylation is a type of organic reaction in which an activated allyl group is added to carbonyl group producing an allylic tertiary alcohol . (wikipedia.org)
Allyl alcohol is the smallest representative of the allylic alcohols. (wikipedia.org)
Allyl alcohols in general can be prepared by allylic oxidation of allyl compounds by selenium dioxide. (wikipedia.org)

Allyl alcohol (IUPAC name: prop-2-en-1-ol) is an organic compound with the structural formula CH2=CHCH2OH. (wikipedia.org)
Allyl alcohol is used as a raw material for the production of glycerol, but is also used as a precursor to many specialized compounds such as flame-resistant materials, drying oils, and plasticizers. (wikipedia.org)
Allyl alcohol can be obtained by many methods. (wikipedia.org)
In principle, allyl alcohol can be obtained by dehydrogenation of propanol. (wikipedia.org)
Also, a variety of polymerizable esters are prepared from allyl alcohol, e.g. diallyl phthalate. (wikipedia.org)
Allyl alcohol is more toxic than related alcohols. (wikipedia.org)
This colourless liquid is a precursor to especially allyl alcohol, which is a useful industrial intermediate. (wikipedia.org)
Allyl alcohol is also a precursor to synthetic glycerol. (wikipedia.org)
The compound is dissolved in dry DCM and allyl alcohol (1.1 eq) is added. (virginia.edu)

2. A facile coupling reaction between arylmagnesium compounds and THF by an iodoalkane-EtMgBr system provides 2-aryltetrahydrofurans. (nii.ac.jp)

The present invention relates to a novel sulfur-containing polyenic compound, a sulfur-containing polythiol compound and photocurable compositions of these, which are useful for optical materials such as a spectacle lens, a prism, an optical fiber, an information recording substrate and a filter and useful for coating materials, adhesives and encapsulants for optical materials and relates to high-refractive-index cured products obtainable from the above photocurable compositions. (google.es)
The invention provides several molybdenum (II) complexes (see classes I and II, FIG. 1 ) as well as pharmaceutical compositions comprising these compounds, that are useful for treating cancer and describes synthetic methods and intermediates useful for preparing the compounds. (freepatentsonline.com)
This document relates to compounds and compositions useful for treating cancers, such as brain and nervous system cancers. (patents.com)
This invention is in the area of improved compounds, compositions and methods of transiently protecting healthy cells, and in particular hematopoietic stem and. (patents.com)
Described herein are compounds of Formula (S-I), pharmaceutically acceptable salts thereof, and pharmaceutical compositions thereof. (patents.com)

The biochemical transformation of the OSCs in the cell and their adducts with thiol functional groups of these proteins, could be considered relevant events to uncover the anticancer properties of the allyl sulfur compounds. (springer.com)

Allyl-nickel catalysis enables α,β-dehydrogenation of carbonyl compounds. (organic-chemistry.org)

This review addresses the construction of carbocyclic and heterocyclic compounds using allyl, propargyl, and alkynyl complexes containing transition metals iron(II), molybdenum(II), and tungsten(II). (readabstracts.com)

These organometallic compounds are mild nucleophiles and form stable carboniums. (readabstracts.com)

6. A polymerizable composition containing the sulfur-containing polyenic compound recited in claim 1 . (google.es)
These compounds can be incorporated into a polymerizable composition. (sumobrain.com)

Propiophenones of the formula I ##STR1## in which R1 is hydrogen or C1 -C4 -alkyl, --Si(CH3)3, allyl or benzyl, R2 is hydrogen, C1 -C8 -alkyl, C1 -C4 -alkyl which is substituted by C1 -C4 -alkoxy or --OH, --(CH2 --CH2 --O)n --R5 where n is 2 to 20 and R5 is H or C1 -C4 -alkyl, --Si(CH3)3, benzyl, C3. (google.ca)

Pyrazole is an organic compound with the formula C3H3N2H. (chemchart.com)

A method for producing a high-purity nitrogen-containing heterocyclic compound includes: a process (a) and a process (b): (a) a process of mixing a mixture. (patents.com)

Reaction with hydrogen cyanide over copper catalyst yields allyl cyanide. (wikipedia.org)
Selectfluor TM F-TEDA-BF 4 (1-chloromethyl-4-fluoro-1,4-diazoniabicyclo [2.2.2]octane bis(tetrafluoroborate) is not only one of the most efficient and popular reagents for electrophilic fluorination, but as a strong oxidant is also a convenient mediator or catalyst of several "fluorine-free" functionalizations of organic compounds. (mdpi.com)

Capsaicin is also an anti-inflammatory compound that helps with pain relief and many other ailments. (sixwise.com)

We'll start with a quick look at these unique sulfur-containing compounds. (whfoods.com)

1.3.9 Reactions Involving Pd(II) Compounds and Pd(0) Complexes. (ebooks.com)
2.3 Stoichiometric Reactions of π -Allyl Complexes. (ebooks.com)

The crystal structure of the N-allyl-2, 6-di (ortho-chloro-phenyl) -4-methoxyphenyl pyridinium perchlorate molecular compound was studied by X-ray diffraction. (ijsr.net)
1-Phenylpiperazine is a simple chemical compound featuring a phenyl group bound to a piperazine ring. (chemchart.com)
2. A composition according to claim 1 where in the compound of the formula I R 3 is phenyl, R 4 is C 1 -C 4 -alkyl and R 5 is hydrogen, or R 4 and R 5 together are a trimethylene or tetramethylene radical and R 6 is hydrogen. (google.ca)
2020. Crystal structure of (E)-3-(3-(5-methyl-1-phenyl-1H-1,2,3-triazol-4-yl)-1-phenyl-1H-pyrazol-4-yl)-1-phenylprop-2-en-1-one, C27H21N5O . (cardiff.ac.uk)

In addition, treatment of allyl β-iodoacetals with ethylmagnesium bromide in DME provides tetrahydrofuranylmethylmagnesium compounds. (nii.ac.jp)

The invention is concerned with the compounds of formula (I) and pharmaceutically acceptable salts thereof. (patents.com)

5. A film-forming composition as claimed in claim 1 which has been formed employing from 18 to 70 parts by weight of organosilicon compound per 100 parts by weight of polyurethane resin. (patentgenius.com)
An organosilicon compound having a hydrolyzable silyl group and a catechol group in the molecule is novel. (patents.com)

Although additional studies, using proteomic approaches and transgenic models, are needed to identify the molecular targets and modes of action of these natural compounds, the allyl sulfur compounds can represent potential ideal agents in anticancer therapy, either alone or in association with other antitumor drugs. (springer.com)
In G.B. application 2 087 909 there is provided a breathable non-porous polyurethane film of a block copolymer formed from a low molecular weight difunctional compound to provide hard segments in the film, a polyethylene glycol to provide softsegments in the film and a diisocyanate. (patentgenius.com)
Rubidium fluoride is a compound with the molecular formula RbF. (reference.com)
Iron(III) chlorate is a chemical compound represented by the molecular formula "Fe(ClO3)3. (reference.com)
Magnesium hypochlorite is a chemical compound represented by the molecular formula Mg(ClO)2. (reference.com)

Allylation is any chemical reaction that adds an allyl group to a substrate . (wikipedia.org)
Together with O -acetyl-homoserine, allyl mercaptan was added to the growth medium, followed by uptake and intracellular reaction to give Sahc. (mdpi.com)
or (C) a compound obtained by the reaction of at least two compounds from (A). (google.com)
The compound is dissolved in formic acid and stirred at room temperature until the reaction is complete by TLC (usually 12 hours). (virginia.edu)
The authors speculated that the sulfur-compounds in the onions may have been involved in a chemical reaction (electron transfer) that helped increase the availability of the lycopene. (whfoods.com)

2. Oxidative Reactions with Pd(II) Compounds. (ebooks.com)
2.7 Homocoupling and Oxidative Substitution Reactions of Aromatic Compounds. (ebooks.com)

The subject matter generally relates to compounds and methods of treatment and/or prophylaxis of CNS diseases, disorders, and/or injuries. (patents.com)
The present invention relates to compounds that are inhibitors of the orexin-1 receptor. (patents.com)

The capability of FruArg to pass through the blood‑brain barrier further supports its potential as a therapeutic compound. (spandidos-publications.com)

In sum, the results demonstrated that AITC, a compound that is ordinarily present in human diets, may be used to treat various cancers. (food.news)

Through this aging process, unique and powerful compounds like SAMC and other S-allyl compounds are produced. (naturalnews.com)
Onions are also impressive because they're such a healthy food, imparting vitamins, minerals and powerful compounds that, besides making your eyes water when you cut into them, also help heal your body. (mercola.com)

Nikitina, A. 2004-10-13 00:00:00 Anion exchangers containing different basic groups and having good physicochemical and sorption properties were prepared by polycondensation of polyallylamine and various allyl halides, diglycidyl ethers of dihydroxybenzenes, and aromatic amines with some aliphatic polyamines. (deepdyve.com)

The mechanism for the acetoxylation follows a similar pathway, with propene forming a π-allyl bond on the palladium. (wikipedia.org)

Also disclosed are methods for preparing compounds of formula III, intermediates useful. (patents.com)

Anatomy1

Organisms5

Diseases6

Chemicals and Drugs27

Analytical, Diagnostic and Therapeutic Techniques and Equipment1

Phenomena and Processes6

Anthropology, Education, Sociology and Social Phenomena1

Technology, Industry, Agriculture9

Humanities3

Information Science4

Health Care3

Publication Characteristics2

Geographicals1

Allyl-containing sulfides in garlic increase uncoupling protein content in brown adipose tissue, and noradrenaline and adrenaline secretion in rats. (1/436)

Cytochrome P-450-dependent bioactivation of 1,1-dichloroethylene to a reactive epoxide in human lung and liver microsomes. (2/436)

Inhibition of nitrifiers and methanotrophs from an agricultural humisol by allylsulfide and its implications for environmental studies. (3/436)

Metabolism of diallyl disulfide by human liver microsomal cytochromes P-450 and flavin-containing monooxygenases. (4/436)

In vivo formation and localization of 1,1-dichloroethylene epoxide in murine liver: identification of its glutathione conjugate 2-S-glutathionyl acetate. (5/436)

Effects of allitridi on intracellular Ca2+ concentration in isolated rat brain cells. (6/436)

Roles of horizontal gene transfer and gene integration in evolution of 1,3-dichloropropene- and 1,2-dibromoethane-degradative pathways. (7/436)

Ethanol and arachidonic acid increase alpha 2(I) collagen expression in rat hepatic stellate cells overexpressing cytochrome P450 2E1. Role of H2O2 and cyclooxygenase-2. (8/436)

Allyl Compounds

Propanols

Iridium

Garlic

Acrolein

Isothiocyanates

Sulfur Compounds

Molecular Structure

Alcohols

Sulfides

Stereoisomerism

Sulfinic Acids

1-Propanol

Aldehydes

Palladium

Food Preservatives

Isocyanates

Hydrogenation

Photoinitiators, Dental

Plant Extracts

Ketones

Ethers

Metabolic Detoxication, Drug

Glutathione Transferase

Allium

Acrylonitrile

Encyclopedias as Topic

Vinyl Compounds

Aberrant Crypt Foci

Click Chemistry

Sulfur

Colon

Oklahoma

Vegetables

Onions

Brassica

Anticarcinogenic Agents

Biography as Topic

Biography

Books, Illustrated

Encyclopedias

History, 19th Century

Internet

Silicosis

Social Justice

Occupational Exposure

Pneumoconiosis

Asbestosis

Pleural Diseases

Labor, Obstetric

Ligands

Abbreviations as Topic

Metalloporphyrins

Sulfoxides

AIDS-Related Complex

Medicare Part B

Coordination Complexes

Allyl-containing sulfides in garlic increase uncoupling protein content in brown adipose tissue, and noradrenaline and adrenaline secretion in rats. (1/436)

Cytochrome P-450-dependent bioactivation of 1,1-dichloroethylene to a reactive epoxide in human lung and liver microsomes. (2/436)

Inhibition of nitrifiers and methanotrophs from an agricultural humisol by allylsulfide and its implications for environmental studies. (3/436)

Metabolism of diallyl disulfide by human liver microsomal cytochromes P-450 and flavin-containing monooxygenases. (4/436)

In vivo formation and localization of 1,1-dichloroethylene epoxide in murine liver: identification of its glutathione conjugate 2-S-glutathionyl acetate. (5/436)

Effects of allitridi on intracellular Ca2+ concentration in isolated rat brain cells. (6/436)

Roles of horizontal gene transfer and gene integration in evolution of 1,3-dichloropropene- and 1,2-dibromoethane-degradative pathways. (7/436)

Ethanol and arachidonic acid increase alpha 2(I) collagen expression in rat hepatic stellate cells overexpressing cytochrome P450 2E1. Role of H2O2 and cyclooxygenase-2. (8/436)

Induction of detoxifying enzymes by garlic organosulfur compounds through transcription factor Nrf2: Effect of chemical...

Diallyl trisulfide - Wikipedia

PubPeer - Diallyl trisulfide (DATS) abrogates arsenic induced testicul...

Epigenetic Upregulation of Metallothionein 2A by Diallyl Trisulfide

diallyl disulfide 2179-57-9 Precursor & Downstream Compound Dictionary

Antioxidants | Free Full-Text | The Effects of Different Garlic-Derived Allyl Sulfides on Anaerobic Sulfur Metabolism in the...

Plus it

Chemical Summary for Arsenic trisulfide

Allyl Chloride Manufacturers | Suppliers | Exporters in India

Allyl group - Wikipedia

CURE CANCER 80- Don: 10 of The Most Functional Foods In The World Which Destroy Cancer Cells

CURE CANCER 80- Don: 10 Most Functional Foods In The World Which Destroy Cancer Cells

M. Murai, T. Inoue, M. Suzuki-Karasaki, T. Ochiai, C. Ra , S. Nishida, Y. Suzuki-Karasaki, Diallyl trisulfide sensitizes human...

allyl chloride

Diallyl sulfide | GreenMedInfo | Substance | Natural Medicine