• These enzymes have been receiving widespread attention because of their ability to degrade environmentally persistent xenobiotics as well as endocrine-disrupting chemicals like pentachlorophenol, polychlorinated biphenyls, and dioxins (Jeon et al. (springeropen.com)
  • Its reaction rate is associated with the concentrations of pollutants, ozone and ·OH, as well as the direct reaction constant of ozone and indirect reaction constant of ·OH. (studyres.com)
  • An enzymatic reaction with ß-glucosidase was also used to confirm the presence of glycosyl-conjugates. (bvsalud.org)
  • Scientists don't yet know where those pieces of the pentachlorophenol pathway came from, or what exactly they were doing in older microbes. (spectrevision.net)
  • The classic pathway is the predominant pathway, with the first and rate-limiting reaction catalyzed by a cytochrome P450 enzyme, cholesterol 7 α -hydroxylase (CYP7A1). (aspetjournals.org)
  • To determine Adsorption coefficient (KOC) on soil and on sewage sludge of the test chemical Reaction mass of Methylium, tris[4-​(diethylamino)​phenyl]​-​ & acetate using HPLC. (europa.eu)
  • The adsorption coefficient Koc in soil and in sewage sludge of test chemical Reaction mass of Methylium, tris[4-​(diethylamino)​phenyl]​-​ & acetate was determined by the Reverse Phase High Performance Liquid Chromatographic method according to OECD Guideline No. 121 for testing of Chemicals. (europa.eu)
  • Last year, for example, researchers published the genome of one such species, Sphingobium chlorophenolicum , which had been discovered in pentachlorophenol-laced soil in Minnesota in 1985. (spectrevision.net)
  • Hundreds of thousands of gallons of pentachlorophenol product (or "penta") had seeped through soil and contaminated the Thomas Street neighborhood's groundwater while Crestline and SNE were in operation. (cleanwausau.com)
  • Association of some radicals with the metal increases their stability and reduces their rate of reaction with oxygen such that they can persist for several days in the environment. (lsu.edu)
  • This enzyme catalyses the following chemical reaction (1) pentachlorophenol + 2 NADPH + H+ + O2 ⇌ {\displaystyle \rightleftharpoons } 2,3,5,6-tetrachlorohydroquinone + 2 NADP+ + chloride + H2O (2) 2,3,5,6-tetrachlorophenol + NADPH + H+ + O2 ⇌ {\displaystyle \rightleftharpoons } 2,3,5,6-tetrachlorohydroquinone + NADP+ + H2O Pentachlorophenol monooxygenase is a flavoprotein (FAD). (wikipedia.org)
  • Starting in the 1970s, however, scientists discovered some microbes that had begun to feed on pentachlorophenol. (spectrevision.net)
  • The carbon source is used as food by native microbes, which in turn, produce hydrogen through fermentation reactions. (frtr.gov)
  • Nickel on-site is at levels which could result in an allergic reaction (nickel itch) in a small part of the population that is sensitive to nickel. (illinois.gov)
  • Regulatory aspects of skin sensitizing agents cur- of allergic skin reactions, effective doses vary substan- rently comprise mostly qualitative (i.e., ``all or none'') tially, due to considerable inter-individual differences in considerations. (cdc.gov)
  • In this reaction, chlorinated compounds serve as the terminal electron acceptor, and hydrogen (sometimes acetate as well) serves as the electron donor. (frtr.gov)
  • The difficulty in modeling stems from the complex thermal remediation reaction network, where several removal mechanisms compete in parallel. (utexas.edu)
  • The current work uses pentachlorophenol and pyrene as case-studies, varying system variables and identifying removal mechanisms based on byproduct yields. (utexas.edu)
  • The results indicate that the oxidation effect of ozone on the petroleum-based pollutants is associated with water temperature, pH, dosage of ozone and reaction time. (studyres.com)
  • Result and discussion 2.1 Effects of ozone oxidation on the removal of petroleum-based pollutants from water Ozone oxidation includes direct reaction and indirect reaction. (studyres.com)
  • This paper mainly discusses the effects of ozone dosage, reaction time, reaction temperature and pH on the oxidation of petroleum-based pollutants. (studyres.com)
  • Pentachlorophenol (a wood preservative) was the organic compound present in the highest concentration (36 parts per million). (illinois.gov)
  • Related bacteria have PcpA and PcpE, and they use these enzymes to break down molecules that are similar to pentachlorophenol at this stage of the reactions. (spectrevision.net)
  • Santa Isabel in Northern Mexico and 17 similar reactions in Columbus, New Mexico President Wilson took used US resources into Mexico with plants to supply Villa full or original. (jedi-verein.de)
  • EPFRs have been found associated with soot and fly-ash produced from the combustion of hazardous wastes and Superfund soils from a former wood-treatment facility contaminated with pentachlorophenol. (lsu.edu)
  • They have summed up their current understanding of the evolution of pentachlorophenol-feeding with a diagram, which I've reprinted below. (spectrevision.net)
  • The removal efficiency of petroleum-based pollutants increases with the rise of temperature, pH, amount of ozone and reaction time, and reaches 83% under the conditions that the ratio of ozone to petroleum-based pollutants is 1:1 and the reaction time is 10 min. (studyres.com)
  • High-molecular-weight insoluble polymers that contain functional cationic groups capable of undergoing exchange reactions with anions. (lookformedical.com)
  • So a number of scientists have spent recent years dissecting the pentachlorophenol-eaters. (spectrevision.net)
  • The 3 neurobehavioral tests included in the survey were simple reaction time, symbol-digit substitution, and serial digit learning. (cdc.gov)
  • The sweet untuk of a home receives of a purpose or a ItalyCo-editor of so adventuresome reactions, and the network continue of the other metre or different. (edvgruber.eu)
  • Develop Reaction Kinetic Models of surface-mediated formation of EPFRs and PCDD/Fs. (lsu.edu)
  • The long hydrocarbon chain forms hydrophobic layers in solution that blocks any kind of reaction between the corrosive agent and the metal ions. (chemtexltd.com)