• The dehydrating POP systems were exploited in the conversion of aldoximes into nitriles. (uaeu.ac.ae)
  • This process is the exact reverse of the nitrile synthesis, described above. (forostyle.com)
  • An alternative synthesis of nitrile oxides is dehydration of nitroalkanes . (chemtube3d.com)
  • Nitrile oxides are used in the formation of isoxazoles via cycloaddition. (chemtube3d.com)
  • Herein we report a method for the synthesis of 3,4,5-trisubstituted isoxazoles in water under mild basic conditions at room temperature via a [3 + 2]-cycloaddition of nitrile oxides and 1,3-diketones, β-ketoesters, or β-ketoamides. (beilstein-journals.org)
  • Engineered aldoxime dehydratase to enable the chemoenzymatic conversion of benzyl amines to aromatic nitriles. (illumina.com)
  • In the case of hydroxylamines, the resulting imine products that are formed from their interaction with a carbonyl in acidic conditions results in the formation of a special subset of imines known as oximes (from aldehyde - aldoxime/from ketone - ketoxime). (blogspot.com)
  • Treatment of 56 with hydroxylamine and then chloromethyl methyl ether provided oxime esters 88. (kaist.ac.kr)
  • Cyclization of the conjugated nitrile esters 89 followed by deprotection furnished D-(+)-showdomycin 1. (kaist.ac.kr)
  • Citronellyl Nitrile is a clear colorless liquid with lemon and citrus odor. (foreverest.net)
  • Oximes are normally colorless crystalline compounds. (blogspot.com)
  • In addition, alkylated oxime groups are more easily seperated by the technique HPLC than standard ones. (blogspot.com)
  • Mesylation of the hydroxy groups of 88 and the subsequent elimination gave nitriles 89. (kaist.ac.kr)
  • There are two key steps in the formation of the nitrile oxide: the removal of the OH proton by base and the loss of chloride. (chemtube3d.com)