Grossman, RB & Varner, MA 1997, ' Selective monoalkylation of diethyl malonate, ethyl cyanoacetate, and malononitrile using a masking group for the second acidic hydrogen ', Journal of Organic Chemistry , vol. 62, no. 15, pp. 5235-5237. (uky.edu)
Utilization operon1
MadN is encoded within the malonate utilization operon of Malonomonas rubra and may be an acetate efflux pump, and PecM is encoded within a locus of Erwinia chrysanthemi controlling pectinase, cellulase and blue pigment production and might export the pigment indigoidine, produced by gene products encoded in the pecM operon. (tcdb.org)
Malonic acid3
Disodium malonate is a sodium salt of malonic acid with the chemical formula CH2(COONa)2. (wikipedia.org)
Diethyl malonate, also known as DEM, is the diethyl ester of malonic acid. (iitm.ac.in)
The extent of resonance stabilization of this compound's conjugate base is depicted by the three resonance forms below: Diethyl malonate may be prepared by reacting the sodium salt of chloroacetic acid with sodium cyanide, followed by base hydrolysis of the resultant nitrile to give the sodium salt of the malonic acid. (iitm.ac.in)
Operon1
Malonate degradation in Acinetobacter baylyi ADP1: operon organization and regulation by MdcR. (cdc.gov)
Semialdehyde1
Despite the great diversity of malonate semialdehyde decarboxylases (MSADs), one of five subgroups of the tautomerase superfamily (TSF) found throughout the biosphere , their distribution among strains within the genus Mycobacterium remains unknown. (bvsalud.org)
Decarboxylase1
Sequence of a gene cluster from Klebsiella pneumoniae encoding malonate decarboxylase and expression of the enzyme in Escherichia coli. (pseudomonas.com)
Aromatic1
Flavonoids are formed in the plants from the aromatic amino acids phenylalanine and tyrosine and malonate. (scialert.net)
Synonyms1
105-53-3 - IYXGSMUGOJNHAZ-UHFFFAOYSA-N - Diethyl malonate - Similar structures search, synonyms, formulas, resource links, and other chemical information. (iitm.ac.in)
Amino1
We applied the "one-pot" synthetic strategy which comprises of a C-acylation reaction between the N-hydroxybenzotriazole ester of the appropriate optically active amino acid 1 and diethyl malonate 3 . (hindawi.com)
Synthesis3
These results suggest that the bi-metal, 0.1% copper-zinc malonate-containing cream has the propensity to increase elastin synthesis in human skin in vivo, and that regeneration of elastic fibres may contribute to wrinkle effacement in female patients with photoaged facial skin. (researchgate.net)
6. Synthesis and Anticancer Activity of Gold Porphyrin Linked to Malonate Diamine Platinum Complexes. (nih.gov)
13. Synthesis and cytotoxicity of diam(m)ineplatinum(II) complexes with 2,2-bis(hydroxymethyl)malonate as the leaving group. (nih.gov)
Source1
We are well-recognized in the market for delivering premium quality Diethyl Malonates that we source from reliable platforms. (ryan-international.in)
Important2
Malonate utilization, an important differential trait, well recognized as being possessed by six of the seven Cronobacter species is thought to be largely absent in Cronobacter sakazakii (Csak). (nih.gov)
USE: Diethyl malonate is an important commercial chemical that is used to make other chemicals used in agriculture and drugs. (iitm.ac.in)
Group1
The methylene group (-CH2-) in the middle of the malonic part of the diethyl malonate molecule is neighboured by two carbonyl groups (-C(=O)-).[2]. (iitm.ac.in)
Sources1
Remove sources of malonate and dyes. (drclark.net)
Effects1
In this study, we have evaluated the effects of a bi-metal, 0.1% copper-zinc malonate-containing cream that has been shown to efface wrinkles in clinical trials. (researchgate.net)