Reaction of 3a with CuCl, and AgOTf afforded the (aryl)-(cyclic alkyl(imino)) phosphide-stabilized tetra-nuclear Cu(I) (6), and octa-nuclear Ag(I) (7) clusters, respectively. (gdch.app)
Complexes1
The goal of this study was the synthesis of new di(imino)pyridine-vanadium(III)- complexes and the investigation of their structure/property relationships in the application as catalysts for homogeneous and heterogeneous ethylene polymerizations and oligomerizations. (uni-bayreuth.de)
Compounds1
The synthesis of such compounds is challenging, and synthetic routes to imino- and imino-C-nucleosides are reviewed, together with the nature of the N-ribosyltransferases that are targets for these analogues. (elsevierpure.com)
Phenolate1
In the title mononuclear copper(II) complex, [Cu(C 7 H 5 ClNO) 2 ], the Cu atom, situated on an inversion center, is four-coordinated, in a slightly distorted square-planar geometry, by the N- and O-donor atoms of two symmetry-related 4-chloro-2-(imino-meth-yl)phenolate Schiff base ligands. (iucr.org)
Reactivity1
Photochemical reactivity of conjugated imino ethers. (colorado.edu)
Imine2
In organic chemistry, an imino acid is any molecule that contains both imine (>C=NH) and carboxyl (-C(=O)-OH) functional groups. (wikipedia.org)
Imino acids are structurally related to amino acids, which have amino group instead of imine-a difference of single vs double-bond between nitrogen and carbon. (wikipedia.org)
Abstract1
abstract = "Continued interest in imino-sugar nucleosides derives from the observations that N-ribosyltransferases are powerfully inhibited by imino-C-nucleoside analogues that mimic the ribooxacarbenium ion nature of their transition states. (elsevierpure.com)
Acids3
D-Amino acid oxidase is an enzyme that is able to convert amino acids into imino acids. (wikipedia.org)
Secondary amino acids, amino acids containing a secondary amine group are sometimes named imino acids, though this usage is obsolescent. (wikipedia.org)
The term imino acid is also the obsolete term for imidic acids, structures containing the -C(=NH)-OH group, and should not be used for them. (wikipedia.org)
Copper1
Present study reveals that during the reaction of the Schiff base ligand N, N , -bis[3(4-dodecyloxybenzylideneamino)- propyl]-piperazine (L) with the copper and nickel perchlorate, the imino bond is destroyed. (upt.ro)
Methyl1
In this study, the complexes of Co(II), Ni(II), Cu(II) and Zn(II) with 2-{(E)-[(4-aminophenyl)imino]methyl}-4,6-dichlorophenol were prepared and characterized by physical, spectral and analytical data. (btu.edu.tr)
Amino12
Imino acids are structurally related to amino acids, which have amino group instead of imine-a difference of single vs double-bond between nitrogen and carbon. (wikipedia.org)
D-Amino acid oxidase is an enzyme that is able to convert amino acids into imino acids. (wikipedia.org)
Also the direct biosynthetic precursor to the amino acid proline is the imino acid (S)-Δ1-pyrroline-5-carboxylate (P5C). (wikipedia.org)
Secondary amino acids, amino acids containing a secondary amine group are sometimes named imino acids, though this usage is obsolescent. (wikipedia.org)
Gene expression of luminal imino and amino acid transporter SIT1 (SLC6A20) was approximately threefold lower in newborns versus adults. (nih.gov)
An imino tautomer marker carbonyl band (≈1650 cm -1 ) is enhanced at ≈65°C against an otherwise stable spectrum of bands associated with the favored amino tautomer. (utmb.edu)
Tautomeric ratios of both forms (amino/imino) were estimated in seven different solvents for 2-aminopyrrole derivatives using 1 H NMR spectroscopy. (nih.gov)
Values for K T (amino/imino ratio) varied from 0.8 in CD 3 CN to 1.8 in (CD 3 ) 2 CO. It was also suggested that tautomerization occurs on frozen CDCl 3 , too. (nih.gov)
In the 2-thiopheneamine series, amino/imino tautomerism was established using 1 H NMR and 13 C NMR (CDCl 3 ) methods. (nih.gov)
The First Proof for Amino-Imino Tautomerism of N-Monosubstituted Aminothiophenes. (nih.gov)
The mutagenic property of KP1212 was hypothesized to originate from its amino-imino tautomerism, which would explain its ability to base pair with either G or A. To test the multiple tautomer hypothesis, we used 2D IR spectroscopy, which offers subpicosecond time resolution and structural sensitivity to distinguish among rapidly interconverting tautomers. (nih.gov)
Ligand4
With an imino anchor-incorporated carbene ligand, the stereoselectivity can be switched, giving mainly Z -isomers. (nature.com)
Margulieux, GW, Turner, ZR & Chirik, PJ 2014, ' Synthesis and ligand modification chemistry of a molybdenum dinitrogen complex: Redox and chemical activity of a bis-(imino)pyridine ligand ', Angewandte Chemie - International Edition , vol. 53, no. 51, pp. 14211-14215. (princeton.edu)
Hydrolytic Cleavage of the Imino Bond in Schiff Base Ligand N, N,-bis[3(4-Dodecyloxy-Benzylideneamino)-Propyl]-Piperazine by Complexation. (upt.ro)
Present study reveals that during the reaction of the Schiff base ligand N, N , -bis[3(4-dodecyloxybenzylideneamino)- propyl]-piperazine (L) with the copper and nickel perchlorate, the imino bond is destroyed. (upt.ro)
Acid3
In organic chemistry, an imino acid is any molecule that contains both imine (>C=NH) and carboxyl (-C(=O)-OH) functional groups. (wikipedia.org)
The term imino acid is also the obsolete term for imidic acids, structures containing the -C(=NH)-OH group, and should not be used for them. (wikipedia.org)
It is further not known whether the maturation of imino acid (proline) transport is delayed as in the kidney proximal tubule. (nih.gov)
Benzenamine1
The chemical names are Benzenamine,2,6-dichloro-N-2-imidazolidinylidene monohydrochloride and 2-[(2,6-dichlorophenyl) imino]imidazolidine monohydrochloride. (nih.gov)
Chemical1
Chemical shift anisotropy of imino 15N nuclei in Watson-Crick base pairs from magic angle spinning liquid crystal NMR and nuclear spin relaxation. (nih.gov)
Present3
This band is similarly present in the UV resonance Raman spectra of the imino cytidine analogs N 3 -methylcytidine at high pH and N 4 -methoxy-2′-deoxycytidine at pH 7 and displays features attributable to the imino form of C residues and their derivatives. (utmb.edu)
60% of neutral KP1212 is present in the enol-imino form. (nih.gov)
At present, miglustat (Zavesca), an imino sugar, has been approved for the treatment of subjects with NPC1 disease in approximately 70 countries. (nih.gov)
Measurements1
Using pre-steady state NOE measurements, unambiguous assignments of all the imino proton resonances and associated adenine (H2) resonances are obtained. (nih.gov)
Form1
UV resonance Raman spectroscopy was used to detect and estimate the frequency of the unfavored imino tautomer of the transition mutagen 5-hydroxy-2′-deoxycytidine (HO 5 dCyt) in its anionic form. (utmb.edu)
Data1
From the NOE data interbase pair interproton distances involving the imino and adenine (H2) protons are determined. (nih.gov)
Base2
The fact that the imino tautomer of HO 5 dCyt occurs at a frequency consistent with its high mutagenic enhancement lends strong support to the hypothesis that unfavored base tautomers play important roles in the mispair intermediates of replication leading to substitution mutations. (utmb.edu)
Natural Medicines Comprehensive Database (La Base Exhaustiva de Datos de Medicamentos Naturales) clasifica la eficacia, basada en evidencia científica, de acuerdo a la siguiente escala: Eficaz, Probablemente Eficaz, Posiblemente Eficaz, Posiblemente Ineficaz, Probablemente Ineficaz, Ineficaz, e Insuficiente Evidencia para Hacer una Determinación. (medlineplus.gov)