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  • pathways
  • in the degradative pathways of 2-aminobenzenesulphonic, benzenesulphonic and 4-toluenesulphonic acids in Alcaligenes sp. (wikipedia.org)
  • These pathways are characterized by the ring cleavage of HQ and BT as terminal aromatic intermediates respectively. (springeropen.com)
  • mechanisms of metalloenzymes
  • This chapter is focused on applications of quantum chemical (QC) DFT methodology to study reaction mechanisms of metalloenzymes, emphasising new insights that could be obtained thanks to the computations and showing the limitations of the QC approach. (springer.com)
  • enzymatic
  • It is also highlighted how deliberate model constructing and probing various scenarios and/or electronic states help in identifying key factors ruling enzymatic reactions. (springer.com)
  • ligand
  • All heteroatoms (N3O) of the ligand are coordinated to the iron center in complex 1 with two pyridine nitrogen atoms on the axial bonds, while one of the pyridyl arms of the ligand is left uncoordinated in complex 2. (diva-portal.org)
  • spontaneous
  • 3-9 Although the reaction with dioxygen is thermodynamically favourable, the electronic configuration of the O 2 molecule creates a strong kinetic barrier that requires activation, which is useful to prevent any spontaneous reaction of O 2 with organic molecules. (rsc.org)
  • complexes
  • The molecular structures of complexes 1 and 2 were determined by X-ray crystallography. (diva-portal.org)
  • Diiron complexes 1 and 2 contain the same bis(u-alkoxo)diiron diamond core. (diva-portal.org)
  • methyl
  • Benomyl, methyl N-[1-(butylcarbamoyl)benzimidazol-2-yl]carbamate, and its conversion product, carbendazim, methyl benzimidazol-2-yl carbamate, are systemic fungicides. (ethz.ch)
  • For instance, the reaction of methyl carbonate 1 with methyl acrylate (2) leads to the coupling product 3. (docme.ru)
  • ligands
  • Extradiol members utilize ferrous iron as the active redox state, and this center is commonly coordinated octahedrally through a 2-His-1-Glu motif with labile water ligands occupying empty positions. (wikipedia.org)
  • hydroxylase
  • Chalcone is then isomerized to naringenin by chalcone isomerase which is oxidized to eriodictyol by flavonoid 3'- hydroxylase and further oxidized to taxifolin by flavanone 3-hydroxylase. (wikipedia.org)
  • respectively
  • 2006). Two cis-dihydrodiol dehydrogenases BphB1 and BphB2, which are encoded on pRHL1 and pRHL2, respectively, catalyze the second step in biphenyl catabolism, i.e., the rearomatization of the cis-dihydrodiol to form 2,3-dihydroxybiphenyl. (alpfmedical.info)
  • Aerobic
  • Most studies on the bacterial degradation of fluorinated organics describe fluorobenzoic acids, which under aerobic conditions can be converted into the corresponding fluorocatechols ( 3 , 17 , 33 ). (asm.org)