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  • silver azide
  • It turns out that silver azide in liquid ammonia slowly does redox reactions with a variety of other elements, giving a wide variety of otherwise hard-to-obtain compounds. (sciencemag.org)
  • The careful reader will have noted a defect in this scheme: you first have to make a supply of silver azide , which is enough of a show-stopper for me. (sciencemag.org)
  • As long as there is a residue of AgN3, the vessel only should be shaken very gently to prevent silver azide grains to be ground at the glass wall of the vessel. (sciencemag.org)
  • Crust formation occurring at the fluid level and consisting of silver azide at the beginning of the reaction and the respective metal azide at the end of the reaction have to be carefully scraped off the glass every day with a Teflon spatula. (sciencemag.org)
  • ions
  • Nucleophilicsubstitutions by azide ions on activated olefinichalides result in p-azidovinyl ketones, esters,nitriles, etc., and proceed predominantly with retention of configurationabout the C=C bond. (docme.ru)
  • ammonia
  • Shown is a corundum crucible before and after heating up a sample of the manganese azide product (as an ammonia complex). (sciencemag.org)
  • form
  • so some transition metals azide may form (probably because of the pseudohalegen behaviour) such complexes as hexacyanoferrate/-ite. (sciencemadness.org)
  • include
  • Energetic binders that appear to offer such promising characteristics include azide functional polymers like glycidyl azide polymer (GAP), poly(3, 3-bisazidomethyloxe-tane) (PBAMO), and poly-(3-azidomethyl-3-methyloxetane) (PAMMO), nitrato polyethers like poly-((3-nitrato methyl)-3-methyl oxetane) (PNIMMO), poly-(glycidyl nitrate) (PGLYN)), poly(vinyl nitrate)s, fluoro-polymers, etc. (thefreedictionary.com)
  • Surface modifiers currently offered include titanates, sulfonyl azide , ester-based wetting agents, and proprietary coatings. (thefreedictionary.com)
  • lead
  • I have made the material but it has been 40 years ago and I observed the same low solubility that produces a colloidal precipitate similarly as for lead azide when strong solutions of precursors are reacted. (sciencemadness.org)
  • metal
  • Personally, my metal azide requirements are minimal, and very easily satisfied. (sciencemag.org)
  • This will surely happen to everything in which you heat up samples of metal azides, and believe me, many of these items will be less sturdy than a corundum crucible. (sciencemag.org)
  • And before making the metal azide in the first place, naturally, you need to ask "Do I want to blow myself to pieces? (sciencemag.org)