• Allyl alcohol is also produced primarily from allyl chloride, but production via the hydrolysis of allyl acetate route avoids the use of chlorine, and so is increasing in use. (wikipedia.org)
  • Substitution of the acetate group in allyl acetate using hydrogen chloride yields allyl chloride. (wikipedia.org)
  • CH2=CHCH2OCOCH3 + HCl → CH2=CHCH2Cl + CH3COOH CH2=CHCH2OCOCH3 + HCN → CH2=CHCH2CN + CH3COOH Allyl chloride is generally produced directly by the chlorination of propene. (wikipedia.org)
  • In the present study, an efficient hydrosilylation reaction of allyl chloride with trichlorosilane is achieved using the Rh(I) catalyst [RhCl(dppbz F )] 2 (dppbz F = 1,2-bis(diphenylphosphino)-3,4,5,6-tetrafluorobenzene) to selectively form trichloro(3-chloropropyl)silane. (nature.com)
  • Thus, 1 is now industrially synthesised on the order of several thousand tons per year via a simple hydrosilylation reaction, i.e. the reaction of allyl chloride with HSiCl 3 catalysed by conventional Pt catalysts, such as Speier's catalyst 14 or Karstedt's catalyst 15 (Fig. 1a ). (nature.com)
  • thus, the oxidative addition of two substrates, hydrosilane and allyl chloride, proceeds competitively during the hydrosilylation reaction. (nature.com)
  • Finally, the reaction was studied in borate buffer media containing the ionic liquids (ILs) 1-butyl-3-methylimidazolium tetrafluoroborate (bmimBF4), 1-allyl-3-methylimidazolium chloride (AmimCl) and 1-allyl-3-methylimidazolium acetate (AmimAc). (usp.br)
  • In contrast, the increase of the concentration of common salts, such as tetrabutylammonium chloride, tetrabutylammonium acetate and NaCl, caused a decrease in the emission quantum yields. (usp.br)
  • This colourless liquid is a precursor to especially allyl alcohol, which is a useful industrial intermediate. (wikipedia.org)
  • It is the acetate ester of allyl alcohol. (wikipedia.org)
  • Allyl acetate can be hydrolyzed to allyl alcohol: CH2=CHCH2OCOCH3 + H2O → CH2=CHCH2OH + CH3COOH Allyl alcohol is a precursor for some specialty polymers, mainly for drying oils. (wikipedia.org)
  • Allyl alcohol is also a precursor to synthetic glycerol. (wikipedia.org)
  • Allyl alcohol resistance in adhEp81 background. (yale.edu)
  • The assumption that oxides (glycidol, glycidol acetate, glycidol formate) are the intermediate molecular products of the oxidation reaction of allyl alcohol and its esters in the medium of acetic acid has been grounded. (lpnu.ua)
  • Fedevych E. The role of oxides in oxidation of allyl alcohol and its esters / Eugeniy Fedevych, Oleh Datsko, Oleh Fedevych // Chemistry & Chemical Technology. (lpnu.ua)
  • In experiments on 33 albino male rats it was established that during allyl alcohol-induced damage of the liver its excretory function is impaired that was judged by the biliary excretion of intravenously injected Bengal pink-131I. (bvsalud.org)
  • Antioxidants (tocopherol acetate, sodium selenite, unithiol) reduced the toxic effect of allyl alcohol on the liver. (bvsalud.org)
  • Amyl acetate smells decidedly like bananas, and in *very* dilute concentration tastes like bananas. (yarchive.net)
  • Pure amyl acetate is a not only a rather good solvent, but is highly flammable. (yarchive.net)
  • If you tasted *pure* amyl acetate, I can assure you that you would not taste anything else for quite some hours, although the experience would probably result in no permanent injury. (yarchive.net)
  • Breathing significant concentrations of amyl acetate can result in headache, nausea, irritation to mucous membranes, and possibly unconsciousness. (yarchive.net)
  • Amyl acetate in high concentrations has a narcotic effect. (yarchive.net)
  • It is reasonable to use allyl formate as the starting material to achieve the maximum yields of glycerin esters. (lpnu.ua)
  • Reaction with hydrogen cyanide over copper catalyst yields allyl cyanide. (wikipedia.org)
  • Dr. Reddy said: "A simple and efficient radical sulfonylation of Morita-Baylis-Hillman (MBH) allyl bromides/acetates with thiosulfonates in the presence of Cs 2 CO 3 to access a range of (hetero)aryl/alkyl allyl sulfones in good to high yields. (thieme.de)
  • Chronic exposure to ethyl acetate from use as an industrial solvent can result in secondary anemia, fatty degeneration of the liver, leucocytosis, etc., but I do not believe it is a suspected carcinogen, per se. (yarchive.net)
  • Palladium Pincer Complex Catalyzed Substitution of Vinyl Cyclopropanes, Vinyl Aziridines, and Allyl Acetates with Tetrahydroxydiboron. (organic-chemistry.org)
  • Vinyl acetate is produced similarly, using ethylene in place of propene. (wikipedia.org)
  • Various aryl, heteroaryl, alkenyl and alkyl MBH bromides/acetates and aryl/heteroaryl thiosulfonates were tolerated and reliable in scaled-up synthesis. (thieme.de)
  • Allyl acetate is an organic compound with formula C3H5OC(O)CH3. (wikipedia.org)
  • Allyl acetate is produced industrially by the gas phase reaction of propene in the presence of acetic acid using a palladium catalyst: C3H6 + CH3COOH + ½ O2 → CH2=CHCH2OCOCH3 + H2O This method is advantageous because propene is inexpensive and "green. (wikipedia.org)
  • It is worth noting that some of these allyl sulfones show activity against cancer and abnormal cell proliferation activity. (thieme.de)
  • It results in 60-fold overproduction of ADH on succinate plus acetate medium and allows growth on EtOH as sole C source. (yale.edu)
  • The final mean body weights and mean body weight gains of male rats administered 12 or 50 mg/kg allyl acetate and of male and female rats administered 10 mg/kg acrolein were significantly less than those of the vehicle controls. (nih.gov)
  • 3-Month Evaluation of the Toxicity (C93010) of Allyl Acetate (591-87-7) in F344 Rats Exposed via Gavage. (nih.gov)
  • 3-Month Evaluation of the Toxicity (C93010) of Allyl Acetate (591-87-7) in B6C3F1 Mice Exposed via Gavage. (nih.gov)
  • Genetic Toxicity Evaluation of Allyl Acetate in Salmonella/E.coli Mutagenicity Test or Ames Test. (nih.gov)
  • A 13-week subchronic toxicity study of hexyl acetate in SD rats. (nih.gov)
  • Murty P.D.: Vapor-Liquid Equilibria: Systems Acetone Ethyl Acetate Acetone-n-Propyl Acetate. (ddbst.com)
  • It is also involved in the synthesis of Allyl Amyl Glycolate by reaction with Chloroacetic Acid. (scentree.co)
  • A member of the Aldehyde Dehydrogenase family of enzymes involved in the synthesis of acetate from ethanol. (nih.gov)
  • Note: Vinyl acetate is a volatile organic ester included in the target lists of several US EPA and other methods. (restek.com)
  • For example, when allyl acetate is used as the unsaturated group-containing ester as the raw material, the corresponding hydrogenated ester refers to n-propyl acetate. (allindianpatents.com)
  • Further, when 1,3-butadienyl acetate is used as the raw material, the corresponding hydrogenated ester refers to n-butyl acetate, n-1-butenyl acetate, n-2-butenyl acetate, n-3-butenyl acetate, and mixtures of these components. (allindianpatents.com)
  • Methanol-based mixes containing halogenated compounds are slightly acidic, so it is important to minimize exposure of vinyl acetate to mixes of halogenated compounds in methanol. (restek.com)
  • Allyl acetate is produced industrially by the gas phase reaction of propene in the presence of acetic acid using a palladium catalyst: C3H6 + CH3COOH + ½ O2 → CH2=CHCH2OCOCH3 + H2O This method is advantageous because propene is inexpensive and "green. (wikipedia.org)
  • NTP Toxicology and Carcinogenesis Studies of Benzyl Acetate (CAS No. 140-11-4) in F344/N Rats and B6C3F1 Mice Feed Studies). (nih.gov)
  • The mechanism for the acetoxylation follows a similar pathway, with propene forming a π-allyl bond on the palladium. (wikipedia.org)
  • Aspirin, salicylic acid acetate, is a non-opiate analgesic, anti-inflammatory and antipyretic agent. (nih.gov)
  • Vinyl acetate is produced similarly, using ethylene in place of propene. (wikipedia.org)
  • Clinical findings related to allyl acetate administration included pallor, eye or nasal discharge, ruffled fur, lethargy, diarrhea, and thinness among rats in the 100 mg/kg groups and lethargy, abnormal breathing, thinness, and ruffled fur among mice that died early. (nih.gov)
  • An overview of Genetic Toxicology Micronucleus Mice study conclusions related to Allyl acetate (591-87-7). (nih.gov)