• 1964, 7, 381), or from the polarization of the adsorbates by a surface electric field (surface field polarization) is minor for methane, ethane, and propane. (princeton.edu)
  • Liquefied natural gas (LNG) is natural gas (predominantly methane, CH4, with some mixture of ethane, C2H6) that has been cooled down to liquid form for ease and safety of non-pressurized storage or transport. (wikipedia.org)
  • The gas extracted from underground hydrocarbon deposits contains a varying mix of hydrocarbon components, which usually includes mostly methane (CH4), along with ethane (C2H6), propane (C3H8) and butane (C4H10). (wikipedia.org)
  • The gas stream is typically separated into the liquefied petroleum fractions (butane and propane), which can be stored in liquid form at relatively low pressure, and the lighter ethane and methane fractions. (wikipedia.org)
  • These lighter fractions of methane and ethane are then liquefied to make up the bulk of LNG that is shipped. (wikipedia.org)
  • Oxidation and oxidative carbonylation of methane and ethane by hexaoxo-μ-peroxodisulfate(2-) ion in aqueous medium. (psu.edu)
  • generated from S 2 O 8 2- ) was found to abstract a hydrogen atom from methane and ethane to form the corresponding alkyl radicals which could be trapped efficiently by carbon monoxide, the resultant acyl radicals being ultimately converted into the homologous carboxylic acids. (psu.edu)
  • Dive into the research topics of 'Oxidation and oxidative carbonylation of methane and ethane by hexaoxo-μ-peroxodisulfate(2-) ion in aqueous medium. (psu.edu)
  • NASA reports on seas of liquid methane and ethane on Saturn s moon, Titan, so the climate is very cold there. (habitat21.co.uk)
  • This is an introductory page about alkanes such as methane, ethane, propane, butane and the rest. (shout.education)
  • To improve light alkanes dehydrogenation and separation, membrane reactors are the way: very selective towards hydrogen and with high flux, coupling mechanical and chemical stability. (bizeolcat.eu)
  • Mainly light alkanes are stable at the mantle pressures and temperatures in the C-O-H and C-O-H-N systems as well as in the peridotite-fluid system under ultrareduced to moderately reduced redox conditions at the oxygen fugacity from -2 to +2.5 lg units relative to the IW (Fe-FeO) buffer. (geoscienceworld.org)
  • In organic chemistry, an alkane, or paraffin (a historical trivial name that also has other meanings), is an acyclic saturated hydrocarbon. (wikipedia.org)
  • The number of hydrogens is, therefore, 5.A hydrocarbon with no double or triple bonds is called an a. alkane b. alkene c. alkyne d. aromatic hydrocarbon Please see the attached file. (brainmass.com)
  • With their repeated -CH2 units, the alkanes constitute a homologous series of organic compounds in which the members differ in molecular mass by multiples of 14.03 u (the total mass of each such methylene-bridge unit, which comprises a single carbon atom of mass 12.01 u and two hydrogen atoms of mass ~1.01 u each). (wikipedia.org)
  • The IUPAC nomenclature (systematic way of naming compounds) for alkanes is based on identifying hydrocarbon chains. (wikipedia.org)
  • This quiz focuses on the organic compounds called Alkanes. (brainmass.com)
  • CO is oxidized to CO(2), ammonia is oxidized to hydroxylamine, and some aromatic compounds and cyclic alkanes can also be hydroxylated, but more slowly. (cathdb.info)
  • His group explores approaches to selectively activate and convert alkanes and methane, as well as elementary steps in the transformation of biomass compounds to alkanes. (pnnl.gov)
  • are petroleum and methane primal compounds? (atomicinsights.com)
  • Personal paradigm changing discoveries in progress - are petroleum and methane primal compounds? (atomicinsights.com)
  • The liquid alkanes are good solvents for many other covalent compounds. (shout.education)
  • Methane (CH4) is the simplest alkane, not an alkyne . (brainmass.com)
  • Methane, the simplest alkane, is the most abundant organic compound on earth and one of the most important gases which contribute to global warming [ 10 ]. (hindawi.com)
  • They occur in a diverse range of molecular structures and phases: they can be gases (such as methane and propane ), liquids (such as hexane and benzene ), low melting solids (such as paraffin wax and naphthalene ) or polymers (such as polyethylene and polystyrene ). (wikipedia.org)
  • N2O and NOx are reduced in this process by ammonia and/or short-chain alkanes like methane or propane yielding nitrogen as harmless product. (clariant.com)
  • The rotational spectrum of the adduct pyridine-methane shows that methane links to an aromatic molecule apparently through a C-H⋯π weak hydrogen bond. (rsc.org)
  • The alkanes range in complexity from the simplest case of methane (CH4), where n = 1 (sometimes called the parent molecule), to arbitrarily large and complex molecules, like pentacontane (C50H102) or 6-ethyl-2-methyl-5-(1-methylethyl) octane, an isomer of tetradecane (C14H30). (wikipedia.org)
  • Ball-and-stick model of the methane molecule, CH 4 . (wikipedia.org)
  • A totally symmetrical molecule like methane is completely non-polar. (shout.education)
  • These will be very small for a molecule like methane, but will increase as the molecules get bigger. (shout.education)
  • C123 , ZEOCAT-3D and BIZEOLCAT projects funded in 2019 by Horizon 2020 Research and Innovation (RIA) presented innovative and greener ways to convert alkanes into olefins and aromatics in a joint webinar. (bizeolcat.eu)
  • Very complicated structures are possible by combining linear, branch, cyclic alkanes. (wikipedia.org)
  • Methane is part of a homologous series known as the alkanes , which contain single bonds only. (wikipedia.org)
  • An example is the conversion of methane to chloroform using a chlorination reaction . (wikipedia.org)
  • The C123 project is experimenting with different types of Catalysts for Oxidative Conversion of Methane, with promising results. (bizeolcat.eu)
  • Experimental data on the dependence of the surface tension of water on the adsorption of n-alkanes (methane to butane) from the vapor phase over a range of temperatures are re-interpreted to obtain improved estimates of the two-dimensional second virial coefficients for comparison with calculations based on the Lennard-Jones (L-J) formalism in two dimensions. (princeton.edu)
  • For butane, these effects may be significant but possible changes in conformation upon adsorption may weaken the validity of the gas-phase L-J parameters in estimating the two-dimensional virial coefficients for this alkane. (princeton.edu)
  • Here, the predominant exposure of c-surface was controlled, and its influences in methane oxidation reactions (combustion and oxidative coupling over HAP and lead-substituted HAP (Pb-HAP), respectively) were studied. (osti.gov)
  • The oxide ions and vacancies in turns function as actives sites for promoting methane activation and complete oxidation into CO 2 . (osti.gov)
  • The present study explored the effects of HAP crystal orientation in methane oxidation reactions, which revealed distinct catalytic behaviors of crystal surfaces in HAP-based materials. (osti.gov)
  • article{osti_1543698, title = {Effects of Controlled Crystalline Surface of Hydroxyapatite on Methane Oxidation Reactions}, author = {Oh, Su Cheun and Xu, Jiayi and Tran, Dat T. and Liu, Bin and Liu, Dongxia}, abstractNote = {Hydroxyapatite (HAP, Ca10(PO4)6(OH)2) has a hexagonal prismatic structure that exposes two crystalline surfaces: prism-faceted a- and basal-faceted c-surfaces. (osti.gov)
  • Of manually curated genomes, 22 (18 are complete), ranging from 159 kilobase (kb) to 527 kb in length, were found to encode the pmoC gene, an enzymatically critical subunit of the particulate methane monooxygenase, the predominant methane oxidation catalyst in nature. (nature.com)
  • Thus, augmentation of bacterial methane oxidation by pmoC-phages during infection could modulate the efflux of this potent greenhouse gas into the environment. (nature.com)
  • Unreported to date is the role of phages involved in the oxidation of methane, a greenhouse gas that is 20-23 times more effective than CO 2 (ref. 8 ). (nature.com)
  • We considered the possibility that phages infecting methanotrophs could directly impact methane oxidation and thus methane release. (nature.com)
  • In the present study, we searched the unreported phage genomic fragments from this lake for genes involved in methane oxidation. (nature.com)
  • Alkanes with more than three carbon atoms can be arranged in various ways, forming structural isomers. (wikipedia.org)
  • In addition to the alkane isomers, the chain of carbon atoms may form one or more rings. (wikipedia.org)
  • By the time you get 17 carbons into an alkane, there are unbelievable numbers of isomers! (shout.education)
  • The tiny organisms cling to oil droplets and perform a great feat: As a single organism, they may produce methane from oil by a process called alkane disproportionation. (mpi-bremen.de)
  • The analysis includes the fugacity corrections for the alkane gases and takes the L-J parameters as known for the three-dimensional gases. (princeton.edu)
  • Most anthropogenic (human-generated) emissions of greenhouse gases are either carbon dioxide released by the burning of fossil fuels , or methane released from the handling of natural gas or from agriculture. (wikipedia.org)
  • Notice that the first four alkanes are gases at room temperature. (shout.education)
  • The C 6 through C 10 alkanes, alkenes and isomeric cycloalkanes are the top components of gasoline , naphtha , jet fuel and specialized industrial solvent mixtures. (wikipedia.org)
  • Alkanes, alkenes, and alkynes, all named based on the number of carbons on the backbone chain. (onlinetutorialspoint.com)
  • Ignition characteristics of dual-fuel methane- n -hexane-oxygen-diluent mixtures in a rapid compression machine and a shock tube. (springer.com)
  • Perhaps best represented by a range of alkanes, from methane CH 4 , thru hexane C 6 H 8 (gasoline) to and beyond C 16 H 34 (fuel oil). (habitat21.co.uk)
  • Methane monooxygenase (soluble). (cathdb.info)
  • Xenon and halogenated alkanes track putative substrate binding cavities in the soluble methane monooxygenase hydroxylase. (cathdb.info)
  • 1,2 Interestingly, the active site of the MMO enzyme is comprised of copper-based particulate MMO (pMMO) and iron-based soluble MMO (sMMO) that selectively capture the methane substrate. (rsc.org)
  • An alkyl group is an alkane-based molecular fragment that bears one open valence for bonding. (wikipedia.org)
  • Together with estimates of the standard entropies of adsorption, the results indicate that no significant structuring of the surface water molecules occurs upon adsorption of the alkanes. (princeton.edu)
  • You should read the whole of the page about drawing organic molecules, but there is no need to read the other two beyond where they talk about alkanes. (shout.education)
  • Understanding the mechanism(s) of biogenic methane production and predicting emissions from oil sands tailings ponds are important objectives for effective management of tailings and greenhouse gas emissions. (actapress.com)
  • Methanogenic microorganisms have been important for the earth's climate through time as their metabolic product, methane, is an important greenhouse gas that is 25 times more potent than carbon dioxide. (mpi-bremen.de)
  • Some of its relatives are multi-carbon hydrocarbon-degrading archaea, others are the long-known own methanogens that form methane as metabolic product. (mpi-bremen.de)
  • Alkanes have the general chemical formula CnH2n+2. (wikipedia.org)
  • The general formula for alkanes is CnH2n+2, where "n" represents the number of carbon atoms in the chain. (webref.org)
  • Methane is a good example of a complex alkyne hydrocarbon. (brainmass.com)
  • Microscopy suggests that the recently discovered microbe Methanoliparia produces methane from crude oil all by themselves. (mpi-bremen.de)
  • With the combined enzymatic tools of both relatives, Methanoliparia activates and degrades the oil but forms methane as final product. (mpi-bremen.de)
  • Methane is produced by methanogenic bacteria and some long-chain alkanes function as pheromones in certain animal species or as protective waxes in plants and fungi. (wikipedia.org)
  • In the present study, we reconstructed large phage genomes from freshwater lakes known to contain bacteria that oxidize methane. (nature.com)
  • It was the continual production of bubbles of methane gas that come up through heavy oil overlying the asphalts that clued the researchers to the presence of bacteria in the asphalt. (sciencedaily.com)
  • In the absence of oxygen, methane is produced by bacteria that use carbon dioxide for respiration instead of oxygen," Crowley explained.He noted that the bacteria are not uniformly distributed in the tar pits. (sciencedaily.com)
  • In other words, an alkane consists of hydrogen and carbon atoms arranged in a tree structure in which all the carbon-carbon bonds are single. (wikipedia.org)
  • In an alkane, each carbon atom is sp3-hybridized with 4 sigma bonds (either C-C or C-H), and each hydrogen atom is joined to one of the carbon atoms (in a C-H bond). (wikipedia.org)
  • Methane is the predominant component of natural gas. (wikipedia.org)
  • It has been proved that inhalation of methane also modulates leukocyte activation, affects key events of ischemia-reperfusion-induced oxidative stress, and has anti-inflammatory effects against ischemia-reperfusion damage [ 12 ]. (hindawi.com)
  • From abstract: 'Bis(di-n-hexylphosphinyl)methane, HDPM, [(C6H13)2P(O)]2CH2, has been studied as an extractant for a variety of metals. (unt.edu)
  • One group of the higher alkanes are waxes, solids at standard ambient temperature and pressure (SATP), for which the number of carbon atoms in the carbon backbone is greater than about 17. (wikipedia.org)
  • In contrast, a very long acclimation period has been observed for indigenous microbes to degrade long-chain n -alkanes (C 14 - 18 ) and branched alkanes such as 2-methylpentane. (actapress.com)
  • This is the first time we get to see a microbe that has the potential to degrade oil to methane all by itself", first-author Rafael Laso-Pérez explains. (mpi-bremen.de)
  • Most manufacturers suggest the meters be calibrated using a known methane or pentane standard. (cdc.gov)
  • Phages with very large genomes were recently reported from a man-made lake that covers a deposit of methane-generating tailings from an oil sands mine in Canada 2 . (nature.com)
  • Biogenic methane emissions have been observed from the surfaces of tailings ponds and about 40 million L of methane day -1 was estimated from a single tailings pond (Mildred Lake Settling Basin) in 1999. (actapress.com)
  • This research project was initiated to investigate the source and mechanism of methane emission from the oil sands tailings ponds. (actapress.com)
  • The alkanes have two main commercial sources: petroleum (crude oil) and natural gas. (wikipedia.org)
  • If the theories hold true, and so far I have not found any fundamental flaws in the evidence they have cited and proofs that they offer, then petroleum and methane are not fossil fuel whose overall resource on Earth is finite. (atomicinsights.com)
  • At the opposite extreme from methane lie the heavy tars that remain as the lowest fraction in a crude oil refining retort. (wikipedia.org)
  • Salmonella typhimurium (TA1535, TA97, TA98 and TA100) was treated with methane both with and without auxiliary metabolic activation (S9). (europa.eu)
  • In the present paper, a reduced n -heptane/methane model consisting of 35-step reactions was constructed using multiple reduction approaches. (springer.com)
  • Straight-chain alkanes are sometimes indicated by the prefix "n-" or "n-"(for "normal") where a non-linear isomer exists. (wikipedia.org)
  • The simplest isomer of an alkane is the one in which the carbon atoms are arranged in a single chain with no branches. (wikipedia.org)
  • His research includes low-temperature acid-base catalyzed activation, functionalization, and transformation of alkanes. (pnnl.gov)
  • A range of doses of methane was used, and the S9 was prepared from both rat and hamster livers and added at two levels. (europa.eu)