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  • carboxylic
  • With dienes ethyl acrylate reacts as a good dienophile in Diels-Alder reactions e.g. with 1,3-butadiene in a [4+cycloaddition reaction to give a cyclohexene carboxylic acid ester in a high yield. (wikipedia.org)
  • US 2417748, Hugh J. Hagemeyer, "Preparation of Methyl Acrylate", published 1947-03-18, assigned to Eastman Kodak Company US 5250729, Takafumi Abe, Shinichi Hieda, "Process for preparing unsaturated carboxylic acid or ester thereof", assigned to Mitsubishi Gas Chemical Company W. Reppe, J. Liebigs Ann. (wikipedia.org)
  • methacrylates
  • None of the methods disclosed in the prior art, however, allow for the production of hydroxy alkyl methacrylates or acrylates under conditions which avoid a potential buildup of unreacted alkylene oxide while generating storage stable products of sufficient purity and freedom from deleterious amounts of catalysts. (google.com)
  • reacts
  • Methyl acrylate reacts catalysed by Lewis bases in a Michael addition with amines in high yields to β-alanine derivatives which provide amphoteric surfactants when long-chain amines are used and the ester function is hydrolysed subsequently. (wikipedia.org)
  • 1955
  • Lím worked as a member of the team of Otto Wichterle (the inventor of soft contact lenses) and in 1955, he came up with poly(hydroethyl-acrylate), the material later used for the lenses. (wikipedia.org)
  • organic
  • Ethyl acrylate is an organic compound with the formula CH2CHCO2CH2CH3. (wikipedia.org)
  • 582 (1), 116-132 (1953) US 6022990, Zhao-Tie Liu, Jia-Qi Zhang, Xian-Gui Yang, "Method for synthesizing methyl acrylate", published 2000-02-08, assigned to Chengdu Institute of Organic Chemistry H.-J. Arpe, Industrielle Organische Chemie, 6. (wikipedia.org)
  • acid
  • The standard industrial reaction for producing methyl acrylate is esterification with methanol under acid catalysis (sulfuric acid, p-toluene sulfonic acid, acidic ion exchangers. (wikipedia.org)
  • toxic
  • Environmental effects from the substance have not been investigated but the n-hexyl acrylate ICSC1288 was found toxic to aquatic organisms. (inchem.org)
  • cancer
  • The International Agency of Research on Cancer (IARC) and U.S. Environmental Protection Agency (EPA) classify ethyl acrylate as a possible human carcinogen. (safecosmetics.org)
  • The International Agency for Research on Cancer stated, "Overall evaluation, Ethyl acrylate is possibly carcinogenic to humans (Group 2B). (wikipedia.org)
  • chemical
  • The acrylate rubber differs from the butadiene based rubber by absence of double bonds, which gives the material about ten times the weathering resistance and resistance to ultraviolet radiation of ABS, higher long-term heat resistance, and better chemical resistance. (wikipedia.org)
  • 2-Ethylhexyl acrylate chemical compound which belongs to the acrylates. (wikipedia.org)
  • Data
  • Regarding its toxicological data the targeted use of ethyl acrylate as aroma in consumer goods is questionable. (wikipedia.org)
  • However, the NTP recently determined that these data were not relevant to human carcinogenicity since humans do not have a forestomach, and removed ethyl acrylate from its list of carcinogens. (wikipedia.org)
  • exposure
  • Once someone becomes sensitized to acrylates, it is incredibly difficult to effectively protect against exposure and, as a result, adverse reactions. (safecosmetics.org)
  • The United States Environmental Protection Agency (EPA) states, "Human studies on occupational exposure to ethyl acrylate. (wikipedia.org)