Recent applications of ionic liquids in separation technology.
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A fast and highly efficient protocol for synthesis of pyrrolo[2,3-d]isoxazoles and a new series of novel benzyl bis-pyrrolo[2,3-d]isoxazoles using task-specific ionic liquids as catalyst and green solvent.
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We report a mild, fast, highly efficient and eco-friendly protocol for the green synthesis of pyrrolo[2,3-d]isoxazoles and a new series of novel benzyl bis-pyrrolo[2,3-d]isoxazoles from nitro styrylisoxazoles in SnCl(2)-ionic liquid by reductive cyclization. These reactions were performed at ambient temperature which resulted in good yields in short reaction time, without requiring any organic solvent and catalyst. (+info)
Carbon-carbon cross coupling reactions in ionic liquids catalysed by palladium metal nanoparticles.
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Conductive cable fibers with insulating surface prepared by coaxial electrospinning of multiwalled nanotubes and cellulose.
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Preparation and evaluation of silica-based ionic liquid-modified stationary phase for HPLC.
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A new high-performance liquid chromatography (HPLC) stationary phase was firstly synthesized based on the ionic liquid 2-ethyl-4-methylimidazole chloride. And the performances of the resulting stationary phase were determined by Fourier transform infrared (FT-IR), thermogravimetric analysis (TGA), and (13)C nuclear magnetic resonance (NMR) spectroscopy. The retention characteristics of the resulting stationary phase were evaluated by normal phase HPLC conditions to separate tanshinone I and tanshinone IIA in Danshen herb. The results demonstrated that the synthesized ionic liquid was bond-linked to the silica surface successfully and that IL-modified silica is more effective than unmodified silica when separating tanshinone I and tanshinone IIA in Danshen herb. (+info)
Electrochemical deposition of conducting polymer coatings on magnesium surfaces in ionic liquid.
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Direct electrochemistry of hemoglobin immobilized on hydrophilic ionic liquid-chitosan-ZrO2 nanoparticles composite film with carbon ionic liquid electrode as the platform.
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A stable composite film composed of 1-butyl-3-methyl-imidazolium tetrafluoroborate, chitosan, zirconia nanoparticles and the hemoglobin (Hb) was cast on the surface of an ionic liquid of an N-butylpyridinium hexafluorophosphate modified carbon paste electrode to fabricate a modified electrode. Scanning electron microscopy images of the modified electrode indicated that there was a dendritic structure on the modified electrode, and UV-Vis and FT-IR spectra showed that Hb in the composite film retained its native structure. Voltammetric experiments at the modified electrode showed that, in a pH 7.0 phosphate buffer solution, a pair of well-defined and quasi-reversible redox voltammetric peaks was obtained with the formal potential located at -0.216 V. The electrochemical parameters of Hb in the composite film were further carefully calculated: the electron-transfer rate constant was 0.52 s(-1) and the charge transfer coefficient was 0.34. The catalytic reduction peak current had a linear relationship with the concentration of trichloroacetic acid (TCA) in the range from 0.2 to 10.3 mmol/L with a detection limit of 66.7 micromol/L. Therefore, the composite film as a novel matrix opened up a possibility for further study on the design of enzymatic biosensors with potential applications. (+info)
Stability of a Ag/AgCl reference electrode equipped with an ionic liquid salt bridge composed of 1-methyl-3-octylimidazolium bis(trifluoromethanesulfonyl)-amide in potentiometry of pH standard buffers.
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The stability of a Ag/AgCl reference electrode equipped with a gelled ionic liquid, 1-methyl-3-octylimidazolium bis(trifluoromethanesulfonyl)amide (C(8)mimC(1)C(1)N), as a salt bridge, was examined in the potentiometry of pH standard solutions. The variation in the liquid junction potential (LJP) of the ionic liquid (IL)-type reference electrode, measured with respect to a double junction-type KCl reference electrode, was within 1 mV when one standard solution was replaced by another, except for the phthalate standard. The time course of the potential of the IL-type reference electrode showed a standard deviation of +/-0.3 mV in all buffer solutions. The reproducible deviation of the potential of the IL-type reference electrode in the phthalate pH standard amounted to 5 mV. The deviation is due to the partition of the hydrogen phthalate in the C(8)mimC(1)C(1)N, influencing the phase boundary potential (PBP) across the interface between C(8)mimC(1)C(1)N and the phthalate standard. If a citrate standard is used instead of the phthalate buffer, the IL salt bridge works satisfactorily as a salt bridge for a reference electrode suitable for potentiometoric pH measurements. (+info)